SL Paper 2

Ethene belongs to the homologous series of the alkenes.

A bromoalkane, \({{\text{C}}_{\text{4}}}{{\text{H}}_{\text{9}}}{\text{Br}}\), reacts with a warm, aqueous sodium hydroxide solution, NaOH.

The time taken to produce a certain amount of product using different initial concentrations of \({{\text{C}}_{\text{4}}}{{\text{H}}_{\text{9}}}{\text{Br}}\) and NaOH is measured. The results are shown in the following table.

M13/4/CHEMI/SP2/ENG/TZ1/08.c

Outline three features of a homologous series.

[3]
a.i.

Describe a test to distinguish ethene from ethane, including what is observed in each case.

[2]
a.ii.

Bromoethane can be produced either from ethene or from ethane. State an equation for each reaction.

[2]
a.iii.

State the equation for the reaction of \({{\text{C}}_{\text{4}}}{{\text{H}}_{\text{9}}}{\text{Br}}\) with NaOH.

[1]
b.i.

Suggest what would happen to the pH of the solution as the reaction proceeds.

[1]
b.ii.

Deduce the effect of the concentration of \({{\text{C}}_{\text{4}}}{{\text{H}}_{\text{9}}}{\text{Br}}\) and NaOH on the rate of reaction.

 

C4H9Br:

 

 

NaOH:

[2]
c.i.

Suggest why warm sodium hydroxide solution is used.

[1]
c.ii.

Deduce whether C4H9Br is a primary or tertiary halogenoalkane.

[2]
c.iii.

Determine the structural formula of C4H9Br.

[1]
c.iv.

Describe, using an equation, how \({{\text{C}}_{\text{4}}}{{\text{H}}_{\text{9}}}{\text{Br}}\) can be converted into \({{\text{C}}_{\text{4}}}{{\text{H}}_{\text{8}}}{\text{B}}{{\text{r}}_{\text{2}}}\).

[1]
c.v.

Explain the mechanism for the reaction in (c) of \({{\text{C}}_{\text{4}}}{{\text{H}}_{\text{9}}}{\text{Br}}\) with NaOH, using curly arrows to represent the movement of electron pairs.

[4]
d.



Electrolysis is an important industrial process used to obtain very reactive elements from their common ores.

Molten magnesium chloride can be electrolysed using inert graphite electrodes at 800 °C.

Describe, using a labelled diagram, the essential components of this electrolytic cell.

[2]
a.i.

Molten magnesium chloride can be electrolysed using inert graphite electrodes at 800 °C.

Deduce the half-equations, including state symbols, for the reactions occurring at each electrode. (The melting points of MgCl2 and Mg are 714 °C and 649 °C respectively.)

 

Positive electrode (anode):

 

Negative electrode (cathode):

[3]
a.ii.

Outline why solid magnesium chloride does not conduct electricity.

[1]
b.

Aluminium can also be obtained by electrolysis. Suggest one reason why aluminium is often used instead of iron by engineers.

[1]
c.