DP Chemistry (last assessment 2024)

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Question 19M.2.hl.TZ2.2f

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Date May 2019 Marks available [Maximum mark: 2] Reference code 19M.2.hl.TZ2.2f
Level hl Paper 2 Time zone TZ2
Command term Annotate, Outline Question number f Adapted from N/A
f.
[Maximum mark: 2]
19M.2.hl.TZ2.2f

The thermal decomposition of dinitrogen monoxide occurs according to the equation:

2N2O (g) → 2N2 (g) + O2 (g)

The reaction can be followed by measuring the change in total pressure, at constant temperature, with time.

The x-axis and y-axis are shown with arbitrary units.

(f)

The graph below shows the Maxwell–Boltzmann distribution of molecular energies at a particular temperature.

The rate at which dinitrogen monoxide decomposes is significantly increased by a metal oxide catalyst.

Annotate and use the graph to outline why a catalyst has this effect.

[2]

Markscheme

catalysed and uncatalysed Ea marked on graph AND with the catalysed being at lower energy     [✔]

 

«for catalysed reaction» greater proportion of/more molecules have E ≥ Ea / E > Ea
OR
«for catalysed reaction» greater area under curve to the right of the Ea     [✔]

 

Note: Accept “more molecules have the activation energy”.

Examiners report

The graph was generally well done, but in quite a few cases, candidates did not mention that increase of rate in the catalyzed reaction was due to E (particles) > Ea or did so too vaguely.