DP Chemistry (last assessment 2024)

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Question 19M.3.hl.TZ1.2b(i)

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Date May 2019 Marks available [Maximum mark: 2] Reference code 19M.3.hl.TZ1.2b(i)
Level hl Paper 3 Time zone TZ1
Command term Outline, State Question number b(i) Adapted from N/A
b(i).
[Maximum mark: 2]
19M.3.hl.TZ1.2b(i)

Powdered zinc was reacted with 25.00 cm3 of 1.000 mol dm−3 copper(II) sulfate solution in an insulated beaker. Temperature was plotted against time.

(b(i))

The maximum temperature used to calculate the enthalpy of reaction was chosen at a point on the extrapolated (dotted) line.

State the maximum temperature which should be used and outline one assumption made in choosing this temperature on the extrapolated line.

 

Maximum temperature:

Assumption:

[2]

Markscheme

Maximum temperature:
73 «°C»     [✔]

Assumption:
«temperature reached if» reaction instantaneous
OR
«temperature reached if reaction occurred» without heat loss      [✔]

 

Note: Accept “rate of heat loss is constant” OR “rate of temperature decrease is constant”.

Examiners report

Stating the maximum temperature that should be used in calculations was less well answered, with answers between 63 and 65, or 78 commonly given instead of the correct answer of 73°C. Most candidates managed to score the second mark for stating “no heat loss”.