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Question 22M.2.hl.TZ1.4e

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Date May 2022 Marks available [Maximum mark: 2] Reference code 22M.2.hl.TZ1.4e
Level hl Paper 2 Time zone TZ1
Command term Compare and contrast Question number e Adapted from N/A
e.
[Maximum mark: 2]
22M.2.hl.TZ1.4e

Ammonia is soluble in water and forms an alkaline solution:

NH3 (g) + H2O (l) NH4+ (aq) + HO– (aq)

(e)

Mg(OH)+ is a complex ion, but Mg is not regarded as a transition metal. Contrast Mg with manganese, Mn, in terms of one characteristic chemical property of transition metals, other than complex ion formation.

[2]

Markscheme

ALTERNATIVE 1

Property: variable oxidation state ✔

Comparison: Mn compounds can exist in different valencies/oxidation states AND Mg has a valency/oxidation state of +2 in all its compounds ✔


Accept valency.

Accept for second statement “Mg «always» has the same oxidation state”.

 

ALTERNATIVE 2

Property: coloured ions/compounds/complexes ✔

Comparison: Mn ions/compounds/complexes coloured AND Mg ions/compounds white/«as solids»/colourless «in aqueous solution» ✔


Accept Mn forms coloured ions/compounds/complexes and Mg does not.

 

ALTERNATIVE 3

Property: catalytic activity ✔

Comparison: «many» Mn compounds act as catalysts AND Mg compounds do not «generally» catalyse reactions ✔


For any property accept a correct specific example, for example manganate(VII) is purple.

Do not accept differences in atomic structure, such as partially filled d sub-levels, but award ECF for a correct discussion.