DP Chemistry (last assessment 2024)

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Question 23M.3.HL.TZ2.13

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Date May 2023 Marks available [Maximum mark: 4] Reference code 23M.3.HL.TZ2.13
Level HL Paper 3 Time zone TZ2
Command term Explain Question number 13 Adapted from N/A
13.
[Maximum mark: 4]
23M.3.HL.TZ2.13

Biological pigments are coloured compounds.

The following structure is the β-carotene:

(a)

Explain in terms of its structure, why β-carotene appears orange in visible white light. Refer to section 17 of the data booklet.

[2]

Markscheme

contains many/multiple conjugated «carbon–carbon/C=C» double bonds
OR
extended system of delocalized electrons ✓

absorbs blue
OR
complementary to orange «light» ✓

 

M1 requires the concept of many or multiple conjugated double bonds in structure for mark.
Do not accept either “conjugation” OR “double bonds” alone for M1.

Anthocyanins can act as acid-base indicators. The two examples shown, are the flavylium cation and the quinoidal base.

 

(b)

Explain how these anthocyanins can act as acid-base indicators as pH increases.

[2]

Markscheme

Any two of:

equilibrium shifts right
OR
H+ ions lost ✓

red to blue ✓

loss of proton/H+ changes extent of conjugation ✓

affects frequency/wavelength of absorbed light ✓

complementary light transmitted ✓

 

Do not accept “cation red and base blue” alone.

Apply ECF from M1 to M2.