DP Chemistry (last assessment 2024)

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Question 23M.3.SL.TZ2.21

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Date May 2023 Marks available [Maximum mark: 2] Reference code 23M.3.SL.TZ2.21
Level SL Paper 3 Time zone TZ2
Command term State, Suggest Question number 21 Adapted from N/A
21.
[Maximum mark: 2]
23M.3.SL.TZ2.21

The production of many pharmaceutical drugs involves the use of solvents.

(a)

State one problem associated with chlorinated organic solvents as chemical waste.

[1]

Markscheme

Any one of:

«most are» toxic «to living organisms»
OR
incomplete combustion/incineration can produce toxic products/dioxins/phosgene
OR
carcinogenic ✓

«some can be» greenhouse gases ✓

ozone-depleting ✓

can contribute to formation of «photochemical» smog ✓

accumulate in groundwater
OR
have limited biodegradability ✓

cost/hazards of disposal ✓

 

Do not accept “harmful to the environment”.

Do not accept just “pollutes water”.

Do not accept “increases acid rain/acidity/acid deposition”.

(b)

Suggest how the principles of green chemistry can be used to overcome the environmental problems caused by organic solvents.

[1]

Markscheme

use solvent-free synthetic methods
OR
use water/supercritical carbon dioxide/non-toxic/low-toxic/biodegradable compounds as a solvent
OR
recover/reuse solvents
OR
use a non-chlorinated solvent ✓

 

Accept arguments based on atom economy.

Do not accept “use solvents safer for environment” alone.