DP Chemistry (last assessment 2024)

Test builder »

Question 19M.2.hl.TZ2.b

Select a Test
Date May 2019 Marks available [Maximum mark: 2] Reference code 19M.2.hl.TZ2.b
Level hl Paper 2 Time zone TZ2
Command term Outline Question number b Adapted from N/A
b.
[Maximum mark: 2]
19M.2.hl.TZ2.b

The thermal decomposition of dinitrogen monoxide occurs according to the equation:

2N2O (g) → 2N2 (g) + O2 (g)

The reaction can be followed by measuring the change in total pressure, at constant temperature, with time.

The x-axis and y-axis are shown with arbitrary units.

Outline, in terms of collision theory, how a decrease in pressure would affect the rate of reaction.

[2]

Markscheme

«rate of reaction decreases»
concentration/number of molecules in a given volume decreases
OR
more space between molecules    [✔]

collision rate/frequency decreases
OR
fewer collisions per unit time     [✔]

 

Note: Do not accept just “larger space/volume” for M1.

Examiners report

Few students were able to relate the effect of reduced pressure at constant volume with a decrease in concentration of gas molecules and mostly did not even refer to this, but rather concentrated on lower rate of reaction and frequency of collisions. Many candidates lost a mark by failing to explain rate as collisions per unit time, frequency, etc.