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Question 19M.3.hl.TZ1.2b(ii)

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Date May 2019 Marks available [Maximum mark: 1] Reference code 19M.3.hl.TZ1.2b(ii)
Level hl Paper 3 Time zone TZ1
Command term Suggest Question number b(ii) Adapted from N/A
b(ii).
[Maximum mark: 1]
19M.3.hl.TZ1.2b(ii)

Powdered zinc was reacted with 25.00 cm3 of 1.000 mol dm−3 copper(II) sulfate solution in an insulated beaker. Temperature was plotted against time.

(b(ii))

To determine the enthalpy of reaction the experiment was carried out five times. The same volume and concentration of copper(II) sulfate was used but the mass of zinc was different each time. Suggest, with a reason, if zinc or copper(II) sulfate should be in excess for each trial.

[1]

Markscheme

Any one of:
copper(II) sulfate AND mass/amount of zinc is independent variable/being changed
OR
copper(II) sulfate AND with zinc in excess there is no independent variable «as amount of copper(II) sulfate is fixed»   [✔]

copper(II) sulfate AND having excess zinc will not yield different results in each trial    [✔]

zinc AND results can be used to see if amount of zinc affects temperature rise «so this can be allowed for»    [✔]

zinc AND reduces variables/keeps the amount reacting constant    [✔]

Examiners report

Many candidates struggled to explain their choice of which reagent should be in excess. This question proved quite difficult with many candidates seeming to confuse independent and dependent variables.