DP Chemistry (last assessment 2024)

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Question 19M.3.sl.TZ2.2a

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Date May 2019 Marks available [Maximum mark: 3] Reference code 19M.3.sl.TZ2.2a
Level sl Paper 3 Time zone TZ2
Command term Determine Question number a Adapted from N/A
a.
[Maximum mark: 3]
19M.3.sl.TZ2.2a

Bromine and methanoic acid react in aqueous solution.

Br2 (aq) + HCOOH (aq) → 2Br (aq) + 2H+ (aq) + CO2 (g)

The reaction was monitored by measuring the volume of carbon dioxide produced as time progressed.

(a)

Determine from the graph the rate of reaction at 20 s, in cm3 s−1, showing your working.

[3]

Markscheme

tangent drawn to curve at t = 20 s  [✔]

slope/gradient calculation  [✔]

0.35 «cm3 s–1»  [✔]

 

Note: Accept values in the range 0.32–0.42 «cm3 s–1».

Examiners report

This question was challenging for many students. Quite a few candidates did draw a tangent line at 20s for 1 mark, show a slope/gradient calculation of the line for 1 mark, and had a reasonable final value for the final mark. Some candidates only found the average rate by finding the ratio of the value at that data point and received one mark (16/20=0.80 cm3 s-1). Candidates also received one mark if they had a correct answer with no work since the question clearly asked students to show their work.