DP Chemistry (last assessment 2024)

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Question 20N.3.sl.TZ0.d

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Date November 2020 Marks available [Maximum mark: 1] Reference code 20N.3.sl.TZ0.d
Level sl Paper 3 Time zone TZ0
Command term Outline Question number d Adapted from N/A
d.
[Maximum mark: 1]
20N.3.sl.TZ0.d

An investigation was carried out to determine the effect of chain length of the alcohol on the equilibrium constant, Kc, for the reversible reaction:

ROH+CH3COOHH+aq CH3COOR+H2O

The reactants, products and the catalyst form a homogeneous mixture.

Fixed volumes of each alcohol, the ethanoic acid and the sulfuric acid catalyst were placed in sealed conical flasks.

At equilibrium, the flasks were placed in an ice bath, and samples of each flask titrated with NaOH(aq) to determine the ethanoic acid concentration present in the equilibrium mixture.

The following processed results were obtained.

© International Baccalaureate Organization 2020

An additional experiment was conducted in which only the sulfuric acid catalyst was titrated with NaOH(aq). Outline why this experiment was necessary.

[1]

Markscheme

to determine volume/moles of NaOH used up by the catalyst/sulfuric acid «in the titration»
OR
to eliminate/reduce «systematic» error caused by acid catalyst ✔


Do not accept “control” OR “standard” alone.

Examiners report

Some students achieved on mark. Many answers referred simple to "control" or "standard" underlining the lack of some skills as also identified in the Internal assessment. Once again very few students had the specific details necessary to explain why this separate titration was needed in their response to receive a mark.