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Question 21N.2.hl.TZ0.e

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Date November 2021 Marks available [Maximum mark: 1] Reference code 21N.2.hl.TZ0.e
Level hl Paper 2 Time zone TZ0
Command term Predict Question number e Adapted from N/A
e.
[Maximum mark: 1]
21N.2.hl.TZ0.e

A 4.406 g sample of a compound containing only C, H and O was burnt in excess oxygen. 8.802 g of CO2 and 3.604 g of H2O were produced.

The following spectrums show the Infrared spectra of propan-1-ol, propanal and propanoic acid.

NIST Mass Spectrometry Data Center Collection © 2021 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. Available at: https://webbook.nist.gov/cgi/cbook.cgi?ID=C71238&Units=SI&Type=IRSPEC&Index=3#IR-SPEC [Accessed 6 May 2020]. Source adapted.

NIST Mass Spectrometry Data Center Collection © 2021 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. Available at: https://webbook.nist.gov/cgi/cbook.cgi?ID=C79094&Units=SI&Mask=80#IR-Spec [Accessed 6 May 2020]. Source adapted.

NIST Mass Spectrometry Data Center Collection © 2021 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. Available at: https://webbook.nist.gov/cgi/cbook.cgi?Name=propanal&Units=SI&cIR=on&cTZ=on#IRSpec [Accessed 6 May 2020]. Source adapted.

Predict the fragment that is responsible for a m/z of 31 in the mass spectrum of propan‑1‑ol. Use section 28 of the data booklet.

[1]

Markscheme

CH3O


Accept any structure i.e. “CH2OH+”.