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Question 18M.3.sl.TZ1.1b.iii

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Date May 2018 Marks available [Maximum mark: 1] Reference code 18M.3.sl.TZ1.1b.iii
Level sl Paper 3 Time zone TZ1
Command term Calculate Question number b.iii Adapted from N/A
b.iii.
[Maximum mark: 1]
18M.3.sl.TZ1.1b.iii

Palmitic acid has a molar mass of 256.5 g mol−1.

The apparatus in the diagram measures the surface pressure created by palmitic acid molecules on the surface of water. This pressure is caused by palmitic acid molecules colliding with the fixed barrier. The pressure increases as the area, A, available to the palmitic acid is reduced by the movable barrier.

M18/4/CHEMI/SP3/ENG/TZ1/01.b_01

When a drop of a solution of palmitic acid in a volatile solvent is placed between the barriers, the solvent evaporates leaving a surface layer. The graph of pressure against area was obtained as the area A was reduced.

M18/4/CHEMI/SP3/ENG/TZ1/01.b_02

(b.iii)

Assuming the sudden change in gradient occurs at 240 cm2, calculate the area, in cm2, that a single molecule of palmitic acid occupies on surface of the water.

If you did not obtain an answer for (b)(ii) use a value of 8.2 × 1016, but this is not the correct answer.

[1]

Markscheme

«area =  240  c m 2 1.0 × 10 17  » 2.4 × 10–15 «cm2»

[1 mark]