DP Chemistry (last assessment 2024)

Test builder »

Question 18M.2.sl.TZ2.7c.iii

Select a Test
Date May 2018 Marks available [Maximum mark: 2] Reference code 18M.2.sl.TZ2.7c.iii
Level sl Paper 2 Time zone TZ2
Command term Deduce Question number c.iii Adapted from N/A
c.iii.
[Maximum mark: 2]
18M.2.sl.TZ2.7c.iii

The structure of an organic molecule can help predict the type of reaction it can undergo.

Improvements in instrumentation have made identification of organic compounds routine.

The empirical formula of an unknown compound containing a phenyl group was found to be C4H4O. The molecular ion peak in its mass spectrum appears at m/z = 136.

(c.iii)

Deduce full structural formulas of two possible isomers of the unknown compound, both of which are esters.

[2]

Markscheme

Any two of:

 OR C6H5COOCH3

OR CH3COOC6H5

 OR HCOOCH2C6H5

 

Do not penalize use of Kekule structures for the phenyl group.

Accept the following structures:

M18/4/CHEMI/SP2/ENG/TZ2/07.c.iii_02/M

Award [1 max] for two correct aliphatic/linear esters with the molecular formula C8H8O2.

[2 marks]