DP Chemistry (last assessment 2024)

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Question 18M.3.sl.TZ2.2a

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Date May 2018 Marks available [Maximum mark: 2] Reference code 18M.3.sl.TZ2.2a
Level sl Paper 3 Time zone TZ2
Command term Describe Question number a Adapted from N/A
a.
[Maximum mark: 2]
18M.3.sl.TZ2.2a

Organic molecules can be visualized using three-dimensional models built from kits such as that pictured below.

M18/4/CHEMI/SP3/ENG/TZ2/02

(a)

Describe two differences, other than the number of atoms, between the models of ethane and ethene constructed from the kit shown.

[2]

Markscheme

Any two of:

Ethene: «carbon–carbon» double bond AND Ethane: «carbon–carbon» single bond

ethene has a shorter carbon–carbon bond «than ethane»

 

Ethene: planar/two-dimensional/2-D AND Ethane: tetrahedral «carbons»/three-dimensional/3-D

OR

Ethene: each carbon surrounded by three electron domains AND Ethane: each carbon surrounded by four electron domains

OR

different molecular geometries/shapes

 

rotation about carbon–carbon inhibited/blocked in ethene AND not in ethane

 

«H–C–C/H–C–H» bond angles different

OR

Ethene: «bond angles approximately» 120° AND Ethane: 109.5/109°

 

Do not accept “different number of atoms/hydrogens/bonds” etc.

Accept “Ethene: unsaturated AND Ethane: saturated” OR “Ethene: has a double bond AND Ethane: does not” OR “Ethene: two flexible bonds between carbon atoms AND Ethane: one”.

Accept any reasonable physical description of the two different molecular models based on a variety of kits for M1.

For ethene, accept any bond angle in the range 117–122°.

Award [2] if any two of the concepts listed are shown in a correctly labelled or annotated diagram.

Award [1 max] for two correct statements for either molecule but with no comparison given to the other.

Award [1 max] for suitable unlabeled diagrams of both compounds.

[2 marks]