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Question 19N.3.SL.TZ0.6b(iii)

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Date November 2019 Marks available [Maximum mark: 2] Reference code 19N.3.SL.TZ0.6b(iii)
Level SL Paper 3 Time zone TZ0
Command term Explain, State Question number b(iii) Adapted from N/A
b(iii).
[Maximum mark: 2]
19N.3.SL.TZ0.6b(iii)

An ideal gas consisting of 0.300 mol undergoes a process ABCD. AB is an adiabatic expansion from the initial volume VA to the volume 1.5 VA. BC is an isothermal compression. The pressures at C and D are the same as at A.

The following data are available.

Pressure at A = 250 kPa
Volume at C   = 3.50 × 10–3 m3
Volume at D   = 2.00 × 10–3 m3

The gas at C is further compressed to D at a constant pressure. During this compression the temperature decreases by 150 K.

For the compression CD,

(b(iii))

state and explain whether the second law of thermodynamics is violated.

[2]

Markscheme

not violated ✔

the entropy of the surroundings must have increased
OR
the overall entropy of the system and the surroundings is the same or increased ✔