DP Chemistry (last assessment 2024)

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Question 19M.3.hl.TZ1.18

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Date May 2019 Marks available [Maximum mark: 4] Reference code 19M.3.hl.TZ1.18
Level hl Paper 3 Time zone TZ1
Command term Compare, Suggest Question number 18 Adapted from N/A
18.
[Maximum mark: 4]
19M.3.hl.TZ1.18

This question is about solar cells.

(a)

Some solar cells use photovoltaic semi-conductors. Compare, giving reasons, the electrical conductivity of metals and semi-conductors as temperature increases.

[3]

Markscheme

metal conductivity decreases AND semi-conductor conductivity increases    [✔]

metal: collisions between «already free moving» electrons/vibrating lattice ions and electrons increase    [✔]

semi-conductor:
provides sufficient energy for electrons to move to conduction band
OR
allows semiconductors to ionize forming freely moving electrons   [✔]

Examiners report

Candidates struggled to express themselves adequately in comparing the change in electrical conductivity of metals and semi-conductors as temperature increases. Many scored 1 mark for stating the effect of increasing temperature, but very few scored any marks for the explanation.

(b)

Suggest one advantage of a dye-sensitized solar cell (DSSC) over a silicon based photovoltaic cell.

[1]

Markscheme

Any one of:

cheaper    [✔]

uses light of lower energy     [✔]

plentiful resources     [✔]

renewable resources     [✔]

use of nanoparticles provides large surface area exposure to sunlight     [✔]

can absorb better under cloudy conditions     [✔]

better conductivity     [✔]

more flexible     [✔]

Examiners report

Generally answered well with most candidates able to suggest one advantage of a DSSC over a silicon based photovoltaic cell.