Directly related questions
- 20N.3.sl.TZ0.3b(i): Thermoplastic composites are increasingly replacing thermosets. Suggest one advantage of...
- 20N.3.sl.TZ0.3b(i): Thermoplastic composites are increasingly replacing thermosets. Suggest one advantage of...
- 20N.3.sl.TZ0.b(i): Thermoplastic composites are increasingly replacing thermosets. Suggest one advantage of...
- 20N.3.sl.TZ0.3c: Explain why phthalates are replaced by other plasticizers in the production of plastics.
- 20N.3.sl.TZ0.3c: Explain why phthalates are replaced by other plasticizers in the production of plastics.
- 20N.3.sl.TZ0.c: Explain why phthalates are replaced by other plasticizers in the production of plastics.
- 20N.3.sl.TZ0.4b(i): Alloying metals changes their properties. Suggest one property of magnesium that could be...
- 20N.3.sl.TZ0.4b(i): Alloying metals changes their properties. Suggest one property of magnesium that could be...
- 20N.3.sl.TZ0.b(i): Alloying metals changes their properties. Suggest one property of magnesium that could be...
- 20N.3.sl.TZ0.3b(ii): Explain how thermoplastics, such as polyvinylchloride, PVC, can be made more flexible by the...
- 20N.3.sl.TZ0.3b(ii): Explain how thermoplastics, such as polyvinylchloride, PVC, can be made more flexible by the...
- 20N.3.sl.TZ0.b(ii): Explain how thermoplastics, such as polyvinylchloride, PVC, can be made more flexible by the...
- 20N.3.sl.TZ0.4d: Experiments have been done to explore the nematic liquid crystal behaviour of CNT. Justify how...
- 20N.3.sl.TZ0.4d: Experiments have been done to explore the nematic liquid crystal behaviour of CNT. Justify how...
- 20N.3.sl.TZ0.d: Experiments have been done to explore the nematic liquid crystal behaviour of CNT. Justify how...
-
20N.3.sl.TZ0.5b:
Proteins are polymers of amino acids.
Glycine is one of the amino acids in the primary structure of hemoglobin.
State the type of bonding responsible for the α-helix in the secondary structure.
-
20N.3.sl.TZ0.5b:
Proteins are polymers of amino acids.
Glycine is one of the amino acids in the primary structure of hemoglobin.
State the type of bonding responsible for the α-helix in the secondary structure.
-
20N.3.sl.TZ0.b:
Proteins are polymers of amino acids.
Glycine is one of the amino acids in the primary structure of hemoglobin.
State the type of bonding responsible for the α-helix in the secondary structure.
-
20N.3.sl.TZ0.4b(ii):
Pure magnesium needed for making alloys can be obtained by electrolysis of molten magnesium chloride.
© International Baccalaureate Organization 2020.
Write the half-equations for the reactions occurring in this electrolysis.
-
20N.3.sl.TZ0.4b(ii):
Pure magnesium needed for making alloys can be obtained by electrolysis of molten magnesium chloride.
© International Baccalaureate Organization 2020.
Write the half-equations for the reactions occurring in this electrolysis.
-
20N.3.sl.TZ0.b(ii):
Pure magnesium needed for making alloys can be obtained by electrolysis of molten magnesium chloride.
© International Baccalaureate Organization 2020.
Write the half-equations for the reactions occurring in this electrolysis.
-
20N.3.sl.TZ0.3a:
Outline the two distinct phases of this composite.
-
20N.3.sl.TZ0.3a:
Outline the two distinct phases of this composite.
-
20N.3.sl.TZ0.a:
Outline the two distinct phases of this composite.
-
20N.3.sl.TZ0.4b(iv):
Suggest a gas which should be continuously passed over the molten magnesium in the electrolytic cell.
-
20N.3.sl.TZ0.4b(iv):
Suggest a gas which should be continuously passed over the molten magnesium in the electrolytic cell.
-
20N.3.sl.TZ0.b(iv):
Suggest a gas which should be continuously passed over the molten magnesium in the electrolytic cell.
-
20N.3.sl.TZ0.6a:
Deduce the products of the hydrolysis of a non-substituted phospholipid, where and represent long alkyl chains.
-
20N.3.sl.TZ0.6a:
Deduce the products of the hydrolysis of a non-substituted phospholipid, where and represent long alkyl chains.
-
20N.3.sl.TZ0.a:
Deduce the products of the hydrolysis of a non-substituted phospholipid, where and represent long alkyl chains.
- 20N.3.sl.TZ0.7a: The diverse functions of biological molecules depend on their structure and shape. Classify...
- 20N.3.sl.TZ0.7a: The diverse functions of biological molecules depend on their structure and shape. Classify...
- 20N.3.sl.TZ0.a: The diverse functions of biological molecules depend on their structure and shape. Classify...
-
20N.3.sl.TZ0.7b(i):
The diverse functions of biological molecules depend on their structure and shape.
Deduce the straight chain structure of deoxyribose from its ring structure drawn in section 34 of the data booklet.
-
20N.3.sl.TZ0.7b(i):
The diverse functions of biological molecules depend on their structure and shape.
Deduce the straight chain structure of deoxyribose from its ring structure drawn in section 34 of the data booklet.
-
20N.3.sl.TZ0.b(i):
The diverse functions of biological molecules depend on their structure and shape.
Deduce the straight chain structure of deoxyribose from its ring structure drawn in section 34 of the data booklet.
-
20N.3.sl.TZ0.8a:
Calculate the BMF if a shark consumes mackerel in one year. Each mackerel weighs on average. The per body weight. Assume chemical remains in the shark’s body for two years.
-
20N.3.sl.TZ0.8a:
Calculate the BMF if a shark consumes mackerel in one year. Each mackerel weighs on average. The per body weight. Assume chemical remains in the shark’s body for two years.
-
20N.3.sl.TZ0.a:
Calculate the BMF if a shark consumes mackerel in one year. Each mackerel weighs on average. The per body weight. Assume chemical remains in the shark’s body for two years.
-
20N.3.sl.TZ0.7b(ii):
The diverse functions of biological molecules depend on their structure and shape.
Sucrose is a disaccharide formed in the reaction of glucose with fructose.
Identify the reaction type and the newly formed functional group that joins the monosaccharide units in the product.
-
20N.3.sl.TZ0.7b(ii):
The diverse functions of biological molecules depend on their structure and shape.
Sucrose is a disaccharide formed in the reaction of glucose with fructose.
Identify the reaction type and the newly formed functional group that joins the monosaccharide units in the product.
-
20N.3.sl.TZ0.b(ii):
The diverse functions of biological molecules depend on their structure and shape.
Sucrose is a disaccharide formed in the reaction of glucose with fructose.
Identify the reaction type and the newly formed functional group that joins the monosaccharide units in the product.
- 20N.3.sl.TZ0.9e: Contrast the molecular structures of biodiesel and the vegetable oil from which it is formed.
- 20N.3.sl.TZ0.9e: Contrast the molecular structures of biodiesel and the vegetable oil from which it is formed.
- 20N.3.sl.TZ0.e: Contrast the molecular structures of biodiesel and the vegetable oil from which it is formed.
-
20N.3.sl.TZ0.6b(i):
A representation of a phospholipid bilayer cell membrane is shown:
© International Baccalaureate Organization 2020.
Identify the components of the phospholipid labelled A and B.
-
20N.3.sl.TZ0.6b(i):
A representation of a phospholipid bilayer cell membrane is shown:
© International Baccalaureate Organization 2020.
Identify the components of the phospholipid labelled A and B.
-
20N.3.sl.TZ0.b(i):
A representation of a phospholipid bilayer cell membrane is shown:
© International Baccalaureate Organization 2020.
Identify the components of the phospholipid labelled A and B.
-
20N.3.sl.TZ0.5a(ii):
Proteins are polymers of amino acids.
The mixture is composed of glycine, , and isoleucine, . Their structures can be found in section 33 of the data booklet.
Deduce, referring to relative affinities and , the identity of A1.
-
20N.3.sl.TZ0.5a(ii):
Proteins are polymers of amino acids.
The mixture is composed of glycine, , and isoleucine, . Their structures can be found in section 33 of the data booklet.
Deduce, referring to relative affinities and , the identity of A1.
-
20N.3.sl.TZ0.a(ii):
Proteins are polymers of amino acids.
The mixture is composed of glycine, , and isoleucine, . Their structures can be found in section 33 of the data booklet.
Deduce, referring to relative affinities and , the identity of A1.
-
20N.3.sl.TZ0.9d:
A mixture of gasoline and ethanol is often used as a fuel. Suggest an advantage of such a mixture over the use of pure gasoline. Exclude any discussion of cost.
-
20N.3.sl.TZ0.9d:
A mixture of gasoline and ethanol is often used as a fuel. Suggest an advantage of such a mixture over the use of pure gasoline. Exclude any discussion of cost.
-
20N.3.sl.TZ0.d:
A mixture of gasoline and ethanol is often used as a fuel. Suggest an advantage of such a mixture over the use of pure gasoline. Exclude any discussion of cost.
-
20N.3.sl.TZ0.11d:
Comment on the risk of overdose when taking aspirin as an analgesic, referring to the following values, for a person weighing :
Minimum therapeutic dose
Estimated minimum lethal dose
-
20N.3.sl.TZ0.11d:
Comment on the risk of overdose when taking aspirin as an analgesic, referring to the following values, for a person weighing :
Minimum therapeutic dose
Estimated minimum lethal dose
-
20N.3.sl.TZ0.d:
Comment on the risk of overdose when taking aspirin as an analgesic, referring to the following values, for a person weighing :
Minimum therapeutic dose
Estimated minimum lethal dose
-
20N.3.sl.TZ0.11a:
Deduce the structural formula of the by-product of this reaction.
-
20N.3.sl.TZ0.11a:
Deduce the structural formula of the by-product of this reaction.
-
20N.3.sl.TZ0.a:
Deduce the structural formula of the by-product of this reaction.
-
20N.3.sl.TZ0.13b:
Outline a green chemistry solution for problems generated by the use of organic solvents.
-
20N.3.sl.TZ0.13b:
Outline a green chemistry solution for problems generated by the use of organic solvents.
-
20N.3.sl.TZ0.b:
Outline a green chemistry solution for problems generated by the use of organic solvents.
- 20N.3.sl.TZ0.13a: Describe the proper disposal of low-level radioactive waste in hospitals.
- 20N.3.sl.TZ0.13a: Describe the proper disposal of low-level radioactive waste in hospitals.
- 20N.3.sl.TZ0.a: Describe the proper disposal of low-level radioactive waste in hospitals.
-
20N.3.sl.TZ0.11c:
The solubility of aspirin is increased by converting it to an ionic form. Draw the structure of the ionic form of aspirin.
-
20N.3.sl.TZ0.11c:
The solubility of aspirin is increased by converting it to an ionic form. Draw the structure of the ionic form of aspirin.
-
20N.3.sl.TZ0.c:
The solubility of aspirin is increased by converting it to an ionic form. Draw the structure of the ionic form of aspirin.
- 20N.3.sl.TZ0.14c(ii): State the natural source from which codeine, morphine and diamorphine are obtained.
- 20N.3.sl.TZ0.14c(ii): State the natural source from which codeine, morphine and diamorphine are obtained.
- 20N.3.sl.TZ0.c(ii): State the natural source from which codeine, morphine and diamorphine are obtained.
- 20N.3.sl.TZ0.14c(i): State and explain the relative solubility of codeine in water compared to morphine and diamorphine.
- 20N.3.sl.TZ0.14c(i): State and explain the relative solubility of codeine in water compared to morphine and diamorphine.
- 20N.3.sl.TZ0.c(i): State and explain the relative solubility of codeine in water compared to morphine and diamorphine.
-
20N.3.sl.TZ0.14a(ii):
Explain how zanamivir works as a preventative agent against flu viruses.
-
20N.3.sl.TZ0.14a(ii):
Explain how zanamivir works as a preventative agent against flu viruses.
-
20N.3.sl.TZ0.a(ii):
Explain how zanamivir works as a preventative agent against flu viruses.
-
20N.3.hl.TZ0.6a(ii):
Proteins are polymers of amino acids.
The mixture is composed of glycine, , and isoleucine, . Their structures can be found in section 33 of the data booklet.
Deduce, referring to relative affinities and , the identity of A1.
-
20N.3.hl.TZ0.6a(ii):
Proteins are polymers of amino acids.
The mixture is composed of glycine, , and isoleucine, . Their structures can be found in section 33 of the data booklet.
Deduce, referring to relative affinities and , the identity of A1.
-
20N.3.hl.TZ0.a(ii):
Proteins are polymers of amino acids.
The mixture is composed of glycine, , and isoleucine, . Their structures can be found in section 33 of the data booklet.
Deduce, referring to relative affinities and , the identity of A1.
-
20N.3.hl.TZ0.6b:
Proteins are polymers of amino acids.
Glycine is one of the amino acids in the primary structure of hemoglobin.
State the type of bonding responsible for the α-helix in the secondary structure.
-
20N.3.hl.TZ0.6b:
Proteins are polymers of amino acids.
Glycine is one of the amino acids in the primary structure of hemoglobin.
State the type of bonding responsible for the α-helix in the secondary structure.
-
20N.3.hl.TZ0.b:
Proteins are polymers of amino acids.
Glycine is one of the amino acids in the primary structure of hemoglobin.
State the type of bonding responsible for the α-helix in the secondary structure.
-
20N.3.hl.TZ0.10b(ii):
Outline the significance of the value of the Michaelis constant, .
-
20N.3.hl.TZ0.10b(ii):
Outline the significance of the value of the Michaelis constant, .
-
20N.3.hl.TZ0.b(ii):
Outline the significance of the value of the Michaelis constant, .
- 20N.3.hl.TZ0.14b: Doping of silicon increases the conductivity in semiconductors. Explain how doping improves the...
- 20N.3.hl.TZ0.14b: Doping of silicon increases the conductivity in semiconductors. Explain how doping improves the...
- 20N.3.hl.TZ0.b: Doping of silicon increases the conductivity in semiconductors. Explain how doping improves the...
- 20N.3.hl.TZ0.10a: Identify the type of inhibition shown in the graph.
- 20N.3.hl.TZ0.10a: Identify the type of inhibition shown in the graph.
- 20N.3.hl.TZ0.a: Identify the type of inhibition shown in the graph.
- 20N.3.hl.TZ0.12e: Thorium-234 has a higher binding energy per nucleon than uranium-238. Outline what is meant by...
- 20N.3.hl.TZ0.12e: Thorium-234 has a higher binding energy per nucleon than uranium-238. Outline what is meant by...
- 20N.3.hl.TZ0.e: Thorium-234 has a higher binding energy per nucleon than uranium-238. Outline what is meant by...
-
20N.3.hl.TZ0.6c(ii):
Proteins are polymers of amino acids.
Explain why the affinity for oxygen of foetal hemoglobin differs from that of adult hemoglobin.
-
20N.3.hl.TZ0.6c(ii):
Proteins are polymers of amino acids.
Explain why the affinity for oxygen of foetal hemoglobin differs from that of adult hemoglobin.
-
20N.3.hl.TZ0.c(ii):
Proteins are polymers of amino acids.
Explain why the affinity for oxygen of foetal hemoglobin differs from that of adult hemoglobin.
- 20N.3.hl.TZ0.4b(i): CNT can act as Type 2 superconductors. Outline why Type 2 superconductors are generally more...
- 20N.3.hl.TZ0.4b(i): CNT can act as Type 2 superconductors. Outline why Type 2 superconductors are generally more...
- 20N.3.hl.TZ0.b(i): CNT can act as Type 2 superconductors. Outline why Type 2 superconductors are generally more...
-
20N.3.hl.TZ0.11e(i):
When combusted, all three fuels can release carbon dioxide, a greenhouse gas, as well as particulates. Contrast how carbon dioxide and particulates interact with sunlight.
-
20N.3.hl.TZ0.11e(i):
When combusted, all three fuels can release carbon dioxide, a greenhouse gas, as well as particulates. Contrast how carbon dioxide and particulates interact with sunlight.
-
20N.3.hl.TZ0.e(i):
When combusted, all three fuels can release carbon dioxide, a greenhouse gas, as well as particulates. Contrast how carbon dioxide and particulates interact with sunlight.
-
20N.3.hl.TZ0.5a:
Precipitation is one method used to treat waste water.
Phosphates, , in waste water can be removed by precipitation with magnesium ions. of magnesium phosphate is .
Calculate the maximum solubility of phosphate ions in a solution containing magnesium ions.
-
20N.3.hl.TZ0.5a:
Precipitation is one method used to treat waste water.
Phosphates, , in waste water can be removed by precipitation with magnesium ions. of magnesium phosphate is .
Calculate the maximum solubility of phosphate ions in a solution containing magnesium ions.
-
20N.3.hl.TZ0.a:
Precipitation is one method used to treat waste water.
Phosphates, , in waste water can be removed by precipitation with magnesium ions. of magnesium phosphate is .
Calculate the maximum solubility of phosphate ions in a solution containing magnesium ions.
-
20N.3.hl.TZ0.4c(iii):
Suggest a gas which should be continuously passed over the molten magnesium in the electrolytic cell.
-
20N.3.hl.TZ0.4c(iii):
Suggest a gas which should be continuously passed over the molten magnesium in the electrolytic cell.
-
20N.3.hl.TZ0.c(iii):
Suggest a gas which should be continuously passed over the molten magnesium in the electrolytic cell.
- 20N.3.hl.TZ0.11b: State a class of organic compounds found in gasoline.
- 20N.3.hl.TZ0.11b: State a class of organic compounds found in gasoline.
- 20N.3.hl.TZ0.b: State a class of organic compounds found in gasoline.
-
20N.3.hl.TZ0.6a(i):
Proteins are polymers of amino acids.
A paper chromatogram of two amino acids, A1 and A2, is obtained using a non-polar solvent.
© International Baccalaureate Organization 2020.
Determine the value of A1.
-
20N.3.hl.TZ0.6a(i):
Proteins are polymers of amino acids.
A paper chromatogram of two amino acids, A1 and A2, is obtained using a non-polar solvent.
© International Baccalaureate Organization 2020.
Determine the value of A1.
-
20N.3.hl.TZ0.a(i):
Proteins are polymers of amino acids.
A paper chromatogram of two amino acids, A1 and A2, is obtained using a non-polar solvent.
© International Baccalaureate Organization 2020.
Determine the value of A1.
- 20N.3.hl.TZ0.6c(i): Proteins are polymers of amino acids. Sketch and label two oxygen dissociation curves, one for...
- 20N.3.hl.TZ0.6c(i): Proteins are polymers of amino acids. Sketch and label two oxygen dissociation curves, one for...
- 20N.3.hl.TZ0.c(i): Proteins are polymers of amino acids. Sketch and label two oxygen dissociation curves, one for...
-
20N.3.hl.TZ0.12f:
Determine the nuclear binding energy, in , of using sections 2 and 4 of the data booklet.
The mass of the nucleus is .
-
20N.3.hl.TZ0.12f:
Determine the nuclear binding energy, in , of using sections 2 and 4 of the data booklet.
The mass of the nucleus is .
-
20N.3.hl.TZ0.f:
Determine the nuclear binding energy, in , of using sections 2 and 4 of the data booklet.
The mass of the nucleus is .
- 20N.3.hl.TZ0.12c: Outline a health risk produced by exposure to radioactive decay.
- 20N.3.hl.TZ0.12c: Outline a health risk produced by exposure to radioactive decay.
- 20N.3.hl.TZ0.c: Outline a health risk produced by exposure to radioactive decay.
-
20N.3.hl.TZ0.8b(i):
The diverse functions of biological molecules depend on their structure and shape.
Deduce the straight chain structure of deoxyribose from its ring structure drawn in section 34 of the data booklet.
-
20N.3.hl.TZ0.8b(i):
The diverse functions of biological molecules depend on their structure and shape.
Deduce the straight chain structure of deoxyribose from its ring structure drawn in section 34 of the data booklet.
-
20N.3.hl.TZ0.b(i):
The diverse functions of biological molecules depend on their structure and shape.
Deduce the straight chain structure of deoxyribose from its ring structure drawn in section 34 of the data booklet.
- 20N.3.hl.TZ0.8c: The diverse functions of biological molecules depend on their structure and shape. Retinal is...
- 20N.3.hl.TZ0.8c: The diverse functions of biological molecules depend on their structure and shape. Retinal is...
- 20N.3.hl.TZ0.c: The diverse functions of biological molecules depend on their structure and shape. Retinal is...
-
20N.3.hl.TZ0.12b:
The half-life of 238U is years. Calculate the mass of 238U that remains after has decayed for years.
-
20N.3.hl.TZ0.12b:
The half-life of 238U is years. Calculate the mass of 238U that remains after has decayed for years.
-
20N.3.hl.TZ0.b:
The half-life of 238U is years. Calculate the mass of 238U that remains after has decayed for years.
-
20N.3.hl.TZ0.12d:
Deduce the nuclear equation for the decay of uranium-238 to thorium-234.
-
20N.3.hl.TZ0.12d:
Deduce the nuclear equation for the decay of uranium-238 to thorium-234.
-
20N.3.hl.TZ0.d:
Deduce the nuclear equation for the decay of uranium-238 to thorium-234.
-
20N.3.hl.TZ0.11e(iv):
Determine the relative rate of effusion of methane () to carbon dioxide (), under the same conditions of temperature and pressure. Use section 1 of the data booklet.
-
20N.3.hl.TZ0.11e(iv):
Determine the relative rate of effusion of methane () to carbon dioxide (), under the same conditions of temperature and pressure. Use section 1 of the data booklet.
-
20N.3.hl.TZ0.e(iv):
Determine the relative rate of effusion of methane () to carbon dioxide (), under the same conditions of temperature and pressure. Use section 1 of the data booklet.
-
20N.3.hl.TZ0.15c:
The solubility of aspirin is increased by converting it to an ionic form. Draw the structure of the ionic form of aspirin.
-
20N.3.hl.TZ0.15c:
The solubility of aspirin is increased by converting it to an ionic form. Draw the structure of the ionic form of aspirin.
-
20N.3.hl.TZ0.c:
The solubility of aspirin is increased by converting it to an ionic form. Draw the structure of the ionic form of aspirin.
-
20N.3.hl.TZ0.17c:
Describe the proper disposal of low-level radioactive waste in hospitals.
-
20N.3.hl.TZ0.17c:
Describe the proper disposal of low-level radioactive waste in hospitals.
-
20N.3.hl.TZ0.c:
Describe the proper disposal of low-level radioactive waste in hospitals.
-
20N.3.hl.TZ0.17a:
State the type of radiation technetium-99m emits.
-
20N.3.hl.TZ0.17a:
State the type of radiation technetium-99m emits.
-
20N.3.hl.TZ0.a:
State the type of radiation technetium-99m emits.
-
20N.3.hl.TZ0.17d:
Technetium-99m has a half-life of hours. Calculate the amount of of technetium-99m remaining after hours.
-
20N.3.hl.TZ0.17d:
Technetium-99m has a half-life of hours. Calculate the amount of of technetium-99m remaining after hours.
-
20N.3.hl.TZ0.d:
Technetium-99m has a half-life of hours. Calculate the amount of of technetium-99m remaining after hours.
-
20N.3.hl.TZ0.19a:
Explain how zanamivir works as a preventative agent against flu viruses.
-
20N.3.hl.TZ0.19a:
Explain how zanamivir works as a preventative agent against flu viruses.
-
20N.3.hl.TZ0.a:
Explain how zanamivir works as a preventative agent against flu viruses.
-
17N.3.sl.TZ0.4a:
Outline the composition of an alloy and a composite.
-
17N.3.sl.TZ0.4a:
Outline the composition of an alloy and a composite.
-
17N.3.sl.TZ0.a:
Outline the composition of an alloy and a composite.
-
17N.3.sl.TZ0.6a:
State equations for the formation of iron nanoparticles and carbon atoms from Fe(CO)5 in the HIPCO process.
-
17N.3.sl.TZ0.6a:
State equations for the formation of iron nanoparticles and carbon atoms from Fe(CO)5 in the HIPCO process.
-
17N.3.sl.TZ0.a:
State equations for the formation of iron nanoparticles and carbon atoms from Fe(CO)5 in the HIPCO process.
- 17N.3.sl.TZ0.8a.ii: The empirical formula of fructose is CH2O. Suggest why linoleic acid releases more energy per...
- 17N.3.sl.TZ0.8a.ii: The empirical formula of fructose is CH2O. Suggest why linoleic acid releases more energy per...
- 17N.3.sl.TZ0.a.ii: The empirical formula of fructose is CH2O. Suggest why linoleic acid releases more energy per...
-
17N.3.hl.TZ0.18c.i:
Calculate the loss in mass, in kg, and the energy released, in J, when 0.00100 mol of 228Ac decays, each atom losing an electron. Use section 2 of the data booklet and E = mc2.
228Ac → + 228Th
-
17N.3.hl.TZ0.18c.i:
Calculate the loss in mass, in kg, and the energy released, in J, when 0.00100 mol of 228Ac decays, each atom losing an electron. Use section 2 of the data booklet and E = mc2.
228Ac → + 228Th
-
17N.3.hl.TZ0.c.i:
Calculate the loss in mass, in kg, and the energy released, in J, when 0.00100 mol of 228Ac decays, each atom losing an electron. Use section 2 of the data booklet and E = mc2.
228Ac → + 228Th
-
17N.3.sl.TZ0.8c:
Outline the importance of linoleic acid for human health.
-
17N.3.sl.TZ0.8c:
Outline the importance of linoleic acid for human health.
-
17N.3.sl.TZ0.c:
Outline the importance of linoleic acid for human health.
- 17N.3.hl.TZ0.7b: Describe how the monomers of addition polymers and of condensation polymers differ.
- 17N.3.hl.TZ0.7b: Describe how the monomers of addition polymers and of condensation polymers differ.
- 17N.3.hl.TZ0.b: Describe how the monomers of addition polymers and of condensation polymers differ.
- 17N.3.sl.TZ0.21: Molecules of antibiotics often contain a beta-lactam ring. Explain the importance of the...
- 17N.3.sl.TZ0.21: Molecules of antibiotics often contain a beta-lactam ring. Explain the importance of the...
-
17N.3.hl.TZ0.9b:
The solubility product, Ksp , of cadmium sulfide, CdS, is 8.0 × 10–27. Determine the concentration of cadmium ions in 1.0 dm3 of a saturated solution of cadmium sulfide to which 0.10 mol of solid sodium sulfide has been added, stating any assumption you make.
-
17N.3.hl.TZ0.9b:
The solubility product, Ksp , of cadmium sulfide, CdS, is 8.0 × 10–27. Determine the concentration of cadmium ions in 1.0 dm3 of a saturated solution of cadmium sulfide to which 0.10 mol of solid sodium sulfide has been added, stating any assumption you make.
-
17N.3.hl.TZ0.b:
The solubility product, Ksp , of cadmium sulfide, CdS, is 8.0 × 10–27. Determine the concentration of cadmium ions in 1.0 dm3 of a saturated solution of cadmium sulfide to which 0.10 mol of solid sodium sulfide has been added, stating any assumption you make.
-
17N.3.hl.TZ0.11a:
Determine the value of the Michaelis constant, Km, by annotating the graph.
-
17N.3.hl.TZ0.11a:
Determine the value of the Michaelis constant, Km, by annotating the graph.
-
17N.3.hl.TZ0.a:
Determine the value of the Michaelis constant, Km, by annotating the graph.
-
17N.3.hl.TZ0.13:
The stability of DNA is due to interactions of its hydrophilic and hydrophobic components.
Outline the interactions of the phosphate groups in DNA with water and with surrounding proteins (histones).
-
17N.3.hl.TZ0.13:
The stability of DNA is due to interactions of its hydrophilic and hydrophobic components.
Outline the interactions of the phosphate groups in DNA with water and with surrounding proteins (histones).
-
17N.3.hl.TZ0.21c:
Explain the low environmental impact of most medical nuclear waste.
-
17N.3.hl.TZ0.21c:
Explain the low environmental impact of most medical nuclear waste.
-
17N.3.hl.TZ0.c:
Explain the low environmental impact of most medical nuclear waste.
-
17N.3.hl.TZ0.23b:
Explain the role of the chiral auxiliary in the synthesis of Taxol.
-
17N.3.hl.TZ0.23b:
Explain the role of the chiral auxiliary in the synthesis of Taxol.
-
17N.3.hl.TZ0.b:
Explain the role of the chiral auxiliary in the synthesis of Taxol.
-
17N.3.sl.TZ0.7b.ii:
One of the two infrared (IR) spectra is that of polyethene and the other of polytetrafluoroethene (PTFE).
Deduce, with a reason, which spectrum is that of PTFE. Infrared data is given in section 26 of the data booklet.
-
17N.3.sl.TZ0.7b.ii:
One of the two infrared (IR) spectra is that of polyethene and the other of polytetrafluoroethene (PTFE).
Deduce, with a reason, which spectrum is that of PTFE. Infrared data is given in section 26 of the data booklet.
-
17N.3.sl.TZ0.b.ii:
One of the two infrared (IR) spectra is that of polyethene and the other of polytetrafluoroethene (PTFE).
Deduce, with a reason, which spectrum is that of PTFE. Infrared data is given in section 26 of the data booklet.
-
17N.3.sl.TZ0.9c:
Explain how the inclusion of carbohydrates in plastics makes them biodegradable.
-
17N.3.sl.TZ0.9c:
Explain how the inclusion of carbohydrates in plastics makes them biodegradable.
-
17N.3.sl.TZ0.c:
Explain how the inclusion of carbohydrates in plastics makes them biodegradable.
-
17N.3.sl.TZ0.12b:
A typical wood has a specific energy of 17 × 103 kJ kg–1. Comment on the usefulness of octane and wood for powering a moving vehicle, using your answer to (a).
If you did not work out an answer for (a), use 45 × 103 kJ kg–1 but this is not the correct answer.
-
17N.3.sl.TZ0.12b:
A typical wood has a specific energy of 17 × 103 kJ kg–1. Comment on the usefulness of octane and wood for powering a moving vehicle, using your answer to (a).
If you did not work out an answer for (a), use 45 × 103 kJ kg–1 but this is not the correct answer.
-
17N.3.sl.TZ0.b:
A typical wood has a specific energy of 17 × 103 kJ kg–1. Comment on the usefulness of octane and wood for powering a moving vehicle, using your answer to (a).
If you did not work out an answer for (a), use 45 × 103 kJ kg–1 but this is not the correct answer.
-
17N.3.hl.TZ0.8a:
Calculate the total number of cobalt atoms within its unit cell.
-
17N.3.hl.TZ0.8a:
Calculate the total number of cobalt atoms within its unit cell.
-
17N.3.hl.TZ0.a:
Calculate the total number of cobalt atoms within its unit cell.
-
17N.3.hl.TZ0.18c.ii:
Determine the energy released, in J, by 0.00100 mol of 228Ac over the course of 18 hours.
-
17N.3.hl.TZ0.18c.ii:
Determine the energy released, in J, by 0.00100 mol of 228Ac over the course of 18 hours.
-
17N.3.hl.TZ0.c.ii:
Determine the energy released, in J, by 0.00100 mol of 228Ac over the course of 18 hours.
- 17N.3.hl.TZ0.18d: Outline how nuclear ionising radiation can damage DNA and enzymes in living cells.
- 17N.3.hl.TZ0.18d: Outline how nuclear ionising radiation can damage DNA and enzymes in living cells.
- 17N.3.hl.TZ0.d: Outline how nuclear ionising radiation can damage DNA and enzymes in living cells.
-
17N.3.hl.TZ0.20b:
Outline one advantage and one disadvantage of the methanol cell (DMFC) compared with a hydrogen-oxygen fuel cell.
-
17N.3.hl.TZ0.20b:
Outline one advantage and one disadvantage of the methanol cell (DMFC) compared with a hydrogen-oxygen fuel cell.
-
17N.3.hl.TZ0.b:
Outline one advantage and one disadvantage of the methanol cell (DMFC) compared with a hydrogen-oxygen fuel cell.
-
17N.3.hl.TZ0.11b.ii:
Draw a curve on the graph above showing the effect of the presence of the malonate ion inhibitor on the rate of reaction.
-
17N.3.hl.TZ0.11b.ii:
Draw a curve on the graph above showing the effect of the presence of the malonate ion inhibitor on the rate of reaction.
-
17N.3.hl.TZ0.b.ii:
Draw a curve on the graph above showing the effect of the presence of the malonate ion inhibitor on the rate of reaction.
-
17N.3.hl.TZ0.14a:
State the half-equation for the reduction of molecular oxygen to water in acidic conditions.
-
17N.3.hl.TZ0.14a:
State the half-equation for the reduction of molecular oxygen to water in acidic conditions.
-
17N.3.hl.TZ0.a:
State the half-equation for the reduction of molecular oxygen to water in acidic conditions.
- 17N.3.hl.TZ0.14b: Outline the change in oxidation state of the iron ions in heme groups that occurs when molecular...
- 17N.3.hl.TZ0.14b: Outline the change in oxidation state of the iron ions in heme groups that occurs when molecular...
- 17N.3.hl.TZ0.b: Outline the change in oxidation state of the iron ions in heme groups that occurs when molecular...
-
17N.3.hl.TZ0.19b:
The natural absorption of light by chlorophyll has been copied by those developing dye-sensitized solar cells (DSSCs). Outline how a DSSC works.
-
17N.3.hl.TZ0.19b:
The natural absorption of light by chlorophyll has been copied by those developing dye-sensitized solar cells (DSSCs). Outline how a DSSC works.
-
17N.3.hl.TZ0.b:
The natural absorption of light by chlorophyll has been copied by those developing dye-sensitized solar cells (DSSCs). Outline how a DSSC works.
-
17N.3.hl.TZ0.20a:
Deduce the half-equations and the overall equation for the reactions taking place in a direct methanol fuel cell (DMFC) under acidic conditions.
-
17N.3.hl.TZ0.20a:
Deduce the half-equations and the overall equation for the reactions taking place in a direct methanol fuel cell (DMFC) under acidic conditions.
-
17N.3.hl.TZ0.a:
Deduce the half-equations and the overall equation for the reactions taking place in a direct methanol fuel cell (DMFC) under acidic conditions.
-
17N.3.hl.TZ0.21b:
The half-life of lutetium-177 is 6.73 days. Determine the percentage of a sample of lutetium-177 remaining after 14.0 days.
-
17N.3.hl.TZ0.b:
The half-life of lutetium-177 is 6.73 days. Determine the percentage of a sample of lutetium-177 remaining after 14.0 days.
-
17N.3.hl.TZ0.21b:
The half-life of lutetium-177 is 6.73 days. Determine the percentage of a sample of lutetium-177 remaining after 14.0 days.
-
17N.3.hl.TZ0.6b:
Explain why Type 2 superconductors are generally more useful than Type 1.
-
17N.3.hl.TZ0.6b:
Explain why Type 2 superconductors are generally more useful than Type 1.
-
17N.3.hl.TZ0.b:
Explain why Type 2 superconductors are generally more useful than Type 1.
-
17N.3.hl.TZ0.7c:
Identify the type of intermolecular bonding that is responsible for Kevlar®’s strength.
-
17N.3.hl.TZ0.7c:
Identify the type of intermolecular bonding that is responsible for Kevlar®’s strength.
-
17N.3.hl.TZ0.c:
Identify the type of intermolecular bonding that is responsible for Kevlar®’s strength.
-
17N.3.hl.TZ0.8b.i:
The atomic radius, r, of cobalt is 1.18 × 10–8 cm. Determine the edge length, in cm, of the unit cell, a, using the second diagram.
-
17N.3.hl.TZ0.8b.i:
The atomic radius, r, of cobalt is 1.18 × 10–8 cm. Determine the edge length, in cm, of the unit cell, a, using the second diagram.
-
17N.3.hl.TZ0.b.i:
The atomic radius, r, of cobalt is 1.18 × 10–8 cm. Determine the edge length, in cm, of the unit cell, a, using the second diagram.
-
17N.3.hl.TZ0.8b.ii:
Determine a value for the density of cobalt, in g cm–3, using data from sections 2 and 6 of the data booklet and your answers from (a) and (b) (i).
If you did not obtain an answer to (b) (i), use 3.00 × 10–8 cm but this is not the correct answer.
-
17N.3.hl.TZ0.8b.ii:
Determine a value for the density of cobalt, in g cm–3, using data from sections 2 and 6 of the data booklet and your answers from (a) and (b) (i).
If you did not obtain an answer to (b) (i), use 3.00 × 10–8 cm but this is not the correct answer.
-
17N.3.hl.TZ0.b.ii:
Determine a value for the density of cobalt, in g cm–3, using data from sections 2 and 6 of the data booklet and your answers from (a) and (b) (i).
If you did not obtain an answer to (b) (i), use 3.00 × 10–8 cm but this is not the correct answer.
- 17N.3.hl.TZ0.9a: State the name of one method, other than precipitation, of removing heavy metal ions from...
- 17N.3.hl.TZ0.9a: State the name of one method, other than precipitation, of removing heavy metal ions from...
- 17N.3.hl.TZ0.a: State the name of one method, other than precipitation, of removing heavy metal ions from...
- 17N.3.hl.TZ0.22a.i: Both spectra show a peak at wavenumber 1700 cm–1. Identify the bond responsible for this peak.
- 17N.3.hl.TZ0.22a.i: Both spectra show a peak at wavenumber 1700 cm–1. Identify the bond responsible for this peak.
- 17N.3.hl.TZ0.a.i: Both spectra show a peak at wavenumber 1700 cm–1. Identify the bond responsible for this peak.
-
17N.3.hl.TZ0.22a.ii:
Deduce which spectrum belongs to paracetamol, giving two reasons for your choice. Use section 26 of the data booklet.
-
17N.3.hl.TZ0.22a.ii:
Deduce which spectrum belongs to paracetamol, giving two reasons for your choice. Use section 26 of the data booklet.
-
17N.3.hl.TZ0.a.ii:
Deduce which spectrum belongs to paracetamol, giving two reasons for your choice. Use section 26 of the data booklet.
- 17N.3.hl.TZ0.22b: Describe how mild analgesics function.
- 17N.3.hl.TZ0.22b: Describe how mild analgesics function.
- 17N.3.hl.TZ0.b: Describe how mild analgesics function.
- 17N.3.hl.TZ0.27: Ethanol slows down the reaction time of a driver leading to traffic accidents. Explain how the...
- 17N.3.hl.TZ0.27: Ethanol slows down the reaction time of a driver leading to traffic accidents. Explain how the...
-
17N.3.sl.TZ0.17b.ii:
Explain why opiates are addictive.
-
17N.3.sl.TZ0.17b.ii:
Explain why opiates are addictive.
-
17N.3.sl.TZ0.b.ii:
Explain why opiates are addictive.
- 17N.3.sl.TZ0.17a: Aspirin is a mild analgesic derived from salicylic acid found in willow bark. Describe how mild...
- 17N.3.sl.TZ0.17a: Aspirin is a mild analgesic derived from salicylic acid found in willow bark. Describe how mild...
- 17N.3.sl.TZ0.a: Aspirin is a mild analgesic derived from salicylic acid found in willow bark. Describe how mild...
-
17N.3.sl.TZ0.18a:
Outline the difference between the therapeutic index in animal studies and the therapeutic index in humans.
-
17N.3.sl.TZ0.18a:
Outline the difference between the therapeutic index in animal studies and the therapeutic index in humans.
-
17N.3.sl.TZ0.a:
Outline the difference between the therapeutic index in animal studies and the therapeutic index in humans.
- 17N.3.sl.TZ0.4b.i: Outline why an alloy is usually harder than its components by referring to its structure.
- 17N.3.sl.TZ0.4b.i: Outline why an alloy is usually harder than its components by referring to its structure.
- 17N.3.sl.TZ0.b.i: Outline why an alloy is usually harder than its components by referring to its structure.
- 17N.3.sl.TZ0.4b.ii: At present, composite fillings are more expensive than amalgam fillings. Suggest why a patient...
- 17N.3.sl.TZ0.4b.ii: At present, composite fillings are more expensive than amalgam fillings. Suggest why a patient...
- 17N.3.sl.TZ0.b.ii: At present, composite fillings are more expensive than amalgam fillings. Suggest why a patient...
- 17N.3.sl.TZ0.9b: Draw the structure of galactose on the skeleton provided.
- 17N.3.sl.TZ0.9b: Draw the structure of galactose on the skeleton provided.
- 17N.3.sl.TZ0.b: Draw the structure of galactose on the skeleton provided.
-
17N.3.sl.TZ0.10a:
Explain, at the molecular level, why vitamin D is soluble in fats. Use section 35 of the data booklet.
-
17N.3.sl.TZ0.10a:
Explain, at the molecular level, why vitamin D is soluble in fats. Use section 35 of the data booklet.
-
17N.3.sl.TZ0.a:
Explain, at the molecular level, why vitamin D is soluble in fats. Use section 35 of the data booklet.
-
17N.3.sl.TZ0.13a:
“Knocking” in an automobile (car) engine can be prevented by increasing the octane number of the fuel. Explain, including an equation with structural formulas, how heptane, C7H16, could be chemically converted to increase its octane number.
-
17N.3.sl.TZ0.13a:
“Knocking” in an automobile (car) engine can be prevented by increasing the octane number of the fuel. Explain, including an equation with structural formulas, how heptane, C7H16, could be chemically converted to increase its octane number.
-
17N.3.sl.TZ0.a:
“Knocking” in an automobile (car) engine can be prevented by increasing the octane number of the fuel. Explain, including an equation with structural formulas, how heptane, C7H16, could be chemically converted to increase its octane number.
-
17N.3.sl.TZ0.16:
Radioisotopes are used to diagnose and treat various diseases. Explain the low environmental impact of most medical nuclear waste.
-
17N.3.sl.TZ0.16:
Radioisotopes are used to diagnose and treat various diseases. Explain the low environmental impact of most medical nuclear waste.
-
17N.3.sl.TZ0.4c:
Explain how Inductively Coupled Plasma (ICP) Spectroscopy could be used to determine the concentration of mercury in a sample of dental filling.
-
17N.3.sl.TZ0.4c:
Explain how Inductively Coupled Plasma (ICP) Spectroscopy could be used to determine the concentration of mercury in a sample of dental filling.
-
17N.3.sl.TZ0.c:
Explain how Inductively Coupled Plasma (ICP) Spectroscopy could be used to determine the concentration of mercury in a sample of dental filling.
-
17N.3.sl.TZ0.5:
Catalysts can take many forms and are used in many industrial processes.
Suggest two reasons why it might be worth using a more expensive catalyst to increase the rate of a reaction.
-
17N.3.sl.TZ0.5:
Catalysts can take many forms and are used in many industrial processes.
Suggest two reasons why it might be worth using a more expensive catalyst to increase the rate of a reaction.
-
17N.3.sl.TZ0.9a:
Describe what is meant by a condensation reaction.
-
17N.3.sl.TZ0.9a:
Describe what is meant by a condensation reaction.
-
17N.3.sl.TZ0.a:
Describe what is meant by a condensation reaction.
- 17N.3.sl.TZ0.10b: State one function of vitamin D in the body.
- 17N.3.sl.TZ0.10b: State one function of vitamin D in the body.
- 17N.3.sl.TZ0.b: State one function of vitamin D in the body.
- 17N.3.sl.TZ0.11: Enzyme activity depends on many factors. Explain how pH change causes loss of activity of an enzyme.
- 17N.3.sl.TZ0.11: Enzyme activity depends on many factors. Explain how pH change causes loss of activity of an enzyme.
-
17N.3.sl.TZ0.7a:
Outline two properties a substance should have to be used as liquid-crystal in a liquid-crystal display.
-
17N.3.sl.TZ0.7a:
Outline two properties a substance should have to be used as liquid-crystal in a liquid-crystal display.
-
17N.3.sl.TZ0.a:
Outline two properties a substance should have to be used as liquid-crystal in a liquid-crystal display.
-
17N.3.sl.TZ0.7c:
Many plastics used to be incinerated. Deduce an equation for the complete combustion of two repeating units of PVC, (–C2H3Cl–)2.
-
17N.3.sl.TZ0.7c:
Many plastics used to be incinerated. Deduce an equation for the complete combustion of two repeating units of PVC, (–C2H3Cl–)2.
-
17N.3.sl.TZ0.c:
Many plastics used to be incinerated. Deduce an equation for the complete combustion of two repeating units of PVC, (–C2H3Cl–)2.
- 17N.3.sl.TZ0.13d: Outline how water and carbon dioxide absorb infrared radiation.
- 17N.3.sl.TZ0.13d: Outline how water and carbon dioxide absorb infrared radiation.
- 17N.3.sl.TZ0.d: Outline how water and carbon dioxide absorb infrared radiation.
-
17N.3.sl.TZ0.19a:
State the names of two functional groups that both compounds contain, using section 37 of the data booklet.
-
17N.3.sl.TZ0.19a:
State the names of two functional groups that both compounds contain, using section 37 of the data booklet.
-
17N.3.sl.TZ0.a:
State the names of two functional groups that both compounds contain, using section 37 of the data booklet.
-
17N.3.sl.TZ0.20b:
The pH is maintained in different fluids in the body by the use of buffers.
Calculate the pH of a buffer solution of 0.0200 mol dm–3 carbonic acid, H2CO3, and 0.400 mol dm–3 sodium hydrogen carbonate, NaHCO3. The pKa of carbonic acid is 6.35.
-
17N.3.sl.TZ0.20b:
The pH is maintained in different fluids in the body by the use of buffers.
Calculate the pH of a buffer solution of 0.0200 mol dm–3 carbonic acid, H2CO3, and 0.400 mol dm–3 sodium hydrogen carbonate, NaHCO3. The pKa of carbonic acid is 6.35.
-
17N.3.sl.TZ0.b:
The pH is maintained in different fluids in the body by the use of buffers.
Calculate the pH of a buffer solution of 0.0200 mol dm–3 carbonic acid, H2CO3, and 0.400 mol dm–3 sodium hydrogen carbonate, NaHCO3. The pKa of carbonic acid is 6.35.
- 17N.3.sl.TZ0.6c: Discuss one possible risk associated with the use of nanotechnology.
- 17N.3.sl.TZ0.6c: Discuss one possible risk associated with the use of nanotechnology.
- 17N.3.sl.TZ0.c: Discuss one possible risk associated with the use of nanotechnology.
-
17N.3.sl.TZ0.13b:
Many like to refer to our “carbon footprint”. Outline one difficulty in quantifying such a concept.
-
17N.3.sl.TZ0.13b:
Many like to refer to our “carbon footprint”. Outline one difficulty in quantifying such a concept.
-
17N.3.sl.TZ0.b:
Many like to refer to our “carbon footprint”. Outline one difficulty in quantifying such a concept.
-
17N.3.sl.TZ0.14b:
The amount of 228Ac in a sample decreases to one eighth of its original value in about 18 hours due to β-decay. Estimate the half-life of 228Ac.
-
17N.3.sl.TZ0.14b:
The amount of 228Ac in a sample decreases to one eighth of its original value in about 18 hours due to β-decay. Estimate the half-life of 228Ac.
-
17N.3.sl.TZ0.b:
The amount of 228Ac in a sample decreases to one eighth of its original value in about 18 hours due to β-decay. Estimate the half-life of 228Ac.
- 17N.3.sl.TZ0.15a: State the structural feature of chlorophyll that enables it to absorb visible light.
- 17N.3.sl.TZ0.15a: State the structural feature of chlorophyll that enables it to absorb visible light.
- 17N.3.sl.TZ0.a: State the structural feature of chlorophyll that enables it to absorb visible light.
- 17N.3.sl.TZ0.18b: State the method of drug administration that gives the maximum bioavailability.
- 17N.3.sl.TZ0.18b: State the method of drug administration that gives the maximum bioavailability.
- 17N.3.sl.TZ0.b: State the method of drug administration that gives the maximum bioavailability.
-
17N.3.sl.TZ0.8b.ii:
Calculate the volume of iodine solution used to reach the end-point.
-
17N.3.sl.TZ0.8b.ii:
Calculate the volume of iodine solution used to reach the end-point.
-
17N.3.sl.TZ0.b.ii:
Calculate the volume of iodine solution used to reach the end-point.
-
17N.3.sl.TZ0.12a:
Calculate the specific energy of octane, C8H18, in kJ kg–1 using sections 1, 6 and 13 of the data booklet.
-
17N.3.sl.TZ0.12a:
Calculate the specific energy of octane, C8H18, in kJ kg–1 using sections 1, 6 and 13 of the data booklet.
-
17N.3.sl.TZ0.a:
Calculate the specific energy of octane, C8H18, in kJ kg–1 using sections 1, 6 and 13 of the data booklet.
-
17N.3.sl.TZ0.13c:
Climate change or global warming is a consequence of increased levels of carbon dioxide in the atmosphere. Explain how the greenhouse effect warms the surface of the earth.
-
17N.3.sl.TZ0.13c:
Climate change or global warming is a consequence of increased levels of carbon dioxide in the atmosphere. Explain how the greenhouse effect warms the surface of the earth.
-
17N.3.sl.TZ0.c:
Climate change or global warming is a consequence of increased levels of carbon dioxide in the atmosphere. Explain how the greenhouse effect warms the surface of the earth.
-
17N.3.sl.TZ0.14a.i:
Compare and contrast fission and fusion in terms of binding energy and the types of nuclei involved.
-
17N.3.sl.TZ0.14a.i:
Compare and contrast fission and fusion in terms of binding energy and the types of nuclei involved.
-
17N.3.sl.TZ0.a.i:
Compare and contrast fission and fusion in terms of binding energy and the types of nuclei involved.
-
17N.3.sl.TZ0.14a.ii:
Suggest two advantages that fusion has over fission.
-
17N.3.sl.TZ0.14a.ii:
Suggest two advantages that fusion has over fission.
-
17N.3.sl.TZ0.a.ii:
Suggest two advantages that fusion has over fission.
- 17N.3.sl.TZ0.19b: Explain how oseltamivir and zanamivir can stop the spread of the flu virus in the body.
- 17N.3.sl.TZ0.19b: Explain how oseltamivir and zanamivir can stop the spread of the flu virus in the body.
- 17N.3.sl.TZ0.b: Explain how oseltamivir and zanamivir can stop the spread of the flu virus in the body.
- 17N.3.sl.TZ0.15b: Vegetable oils are too viscous for use as liquid fuels. Describe, using an equation, how a...
- 17N.3.sl.TZ0.15b: Vegetable oils are too viscous for use as liquid fuels. Describe, using an equation, how a...
- 17N.3.sl.TZ0.b: Vegetable oils are too viscous for use as liquid fuels. Describe, using an equation, how a...
-
17N.3.sl.TZ0.17b.i:
The strong analgesics morphine and codeine are opiates. Outline how codeine can be synthesized from morphine. The structures of morphine and codeine are in section 37 of the data booklet.
-
17N.3.sl.TZ0.17b.i:
The strong analgesics morphine and codeine are opiates. Outline how codeine can be synthesized from morphine. The structures of morphine and codeine are in section 37 of the data booklet.
-
17N.3.sl.TZ0.b.i:
The strong analgesics morphine and codeine are opiates. Outline how codeine can be synthesized from morphine. The structures of morphine and codeine are in section 37 of the data booklet.
-
17N.3.sl.TZ0.20a:
Explain how ranitidine (Zantac) reduces stomach acid production.
-
17N.3.sl.TZ0.20a:
Explain how ranitidine (Zantac) reduces stomach acid production.
-
17N.3.sl.TZ0.a:
Explain how ranitidine (Zantac) reduces stomach acid production.
-
17N.3.sl.TZ0.7b.i:
Describe how the structures of LDPE and HDPE affect one mechanical property of the plastics.
-
17N.3.sl.TZ0.7b.i:
Describe how the structures of LDPE and HDPE affect one mechanical property of the plastics.
-
17N.3.sl.TZ0.b.i:
Describe how the structures of LDPE and HDPE affect one mechanical property of the plastics.
- 17N.3.sl.TZ0.8b.i: State the type of reaction occurring during the titration.
- 17N.3.sl.TZ0.8b.i: State the type of reaction occurring during the titration.
- 17N.3.sl.TZ0.b.i: State the type of reaction occurring during the titration.
-
18M.3.hl.TZ1.4c.i:
Draw the structure of the monomer from which nylon-6 is produced by a condensation reaction.
-
18M.3.hl.TZ1.4c.i:
Draw the structure of the monomer from which nylon-6 is produced by a condensation reaction.
-
18M.3.hl.TZ1.c.i:
Draw the structure of the monomer from which nylon-6 is produced by a condensation reaction.
-
18M.3.hl.TZ1.15b:
Dye-sensitized solar cells, DSSCs, use a dye to absorb the sunlight. State two advantages that DSSCs have over traditional silicon based photovoltaic cells.
-
18M.3.hl.TZ1.15b:
Dye-sensitized solar cells, DSSCs, use a dye to absorb the sunlight. State two advantages that DSSCs have over traditional silicon based photovoltaic cells.
-
18M.3.hl.TZ1.b:
Dye-sensitized solar cells, DSSCs, use a dye to absorb the sunlight. State two advantages that DSSCs have over traditional silicon based photovoltaic cells.
-
18M.3.hl.TZ2.4a.i:
Deduce the number of atoms per unit cell in vanadium.
-
18M.3.hl.TZ2.4a.i:
Deduce the number of atoms per unit cell in vanadium.
-
18M.3.hl.TZ2.a.i:
Deduce the number of atoms per unit cell in vanadium.
-
18M.3.hl.TZ2.4b.i:
Vanadium and other transition metals can interfere with cell metabolism.
State and explain one process, other than by creating free radicals, by which transition metals interfere with cell metabolism.
-
18M.3.hl.TZ2.4b.i:
Vanadium and other transition metals can interfere with cell metabolism.
State and explain one process, other than by creating free radicals, by which transition metals interfere with cell metabolism.
-
18M.3.hl.TZ2.b.i:
Vanadium and other transition metals can interfere with cell metabolism.
State and explain one process, other than by creating free radicals, by which transition metals interfere with cell metabolism.
-
18M.3.hl.TZ2.25:
Taxol was originally obtained from the bark of the Pacific yew tree.
Outline how Green Chemistry has improved the process of obtaining Taxol.
-
18M.3.hl.TZ2.25:
Taxol was originally obtained from the bark of the Pacific yew tree.
Outline how Green Chemistry has improved the process of obtaining Taxol.
-
18M.3.hl.TZ1.5b:
The diagram illustrates the crystal structure of aluminium metal with the unit cell indicated. Outline the significance of the unit cell.
-
18M.3.hl.TZ1.5b:
The diagram illustrates the crystal structure of aluminium metal with the unit cell indicated. Outline the significance of the unit cell.
-
18M.3.hl.TZ1.b:
The diagram illustrates the crystal structure of aluminium metal with the unit cell indicated. Outline the significance of the unit cell.
-
18M.3.hl.TZ1.10a:
Outline why anthocyanins are coloured.
-
18M.3.hl.TZ1.10a:
Outline why anthocyanins are coloured.
-
18M.3.hl.TZ1.a:
Outline why anthocyanins are coloured.
-
18M.3.hl.TZ1.10b:
Explain why the blue colour of a quinoidal base changes to the red colour of a flavylium cation as pH decreases.
-
18M.3.hl.TZ1.10b:
Explain why the blue colour of a quinoidal base changes to the red colour of a flavylium cation as pH decreases.
-
18M.3.hl.TZ1.b:
Explain why the blue colour of a quinoidal base changes to the red colour of a flavylium cation as pH decreases.
-
18M.3.hl.TZ1.13a:
Outline the major technical problem affecting the direct use of vegetable oils as fuels in internal combustion engines and the chemical conversion that has overcome this.
-
18M.3.hl.TZ1.13a:
Outline the major technical problem affecting the direct use of vegetable oils as fuels in internal combustion engines and the chemical conversion that has overcome this.
-
18M.3.hl.TZ1.a:
Outline the major technical problem affecting the direct use of vegetable oils as fuels in internal combustion engines and the chemical conversion that has overcome this.
-
18M.3.hl.TZ1.13b:
State the formula of a fuel that might be produced from the vegetable oil whose formula is shown.
-
18M.3.hl.TZ1.13b:
State the formula of a fuel that might be produced from the vegetable oil whose formula is shown.
-
18M.3.hl.TZ1.b:
State the formula of a fuel that might be produced from the vegetable oil whose formula is shown.
-
18M.3.hl.TZ1.14a.i:
Complete the half-equations on the diagram and identify the species moving between the electrodes.
-
18M.3.hl.TZ1.14a.i:
Complete the half-equations on the diagram and identify the species moving between the electrodes.
-
18M.3.hl.TZ1.a.i:
Complete the half-equations on the diagram and identify the species moving between the electrodes.
-
18M.3.hl.TZ1.14a.ii:
State the factor that limits the maximum current that can be drawn from this cell and how electrodes are designed to maximize the current.
-
18M.3.hl.TZ1.14a.ii:
State the factor that limits the maximum current that can be drawn from this cell and how electrodes are designed to maximize the current.
-
18M.3.hl.TZ1.a.ii:
State the factor that limits the maximum current that can be drawn from this cell and how electrodes are designed to maximize the current.
-
18M.3.hl.TZ1.14b.ii:
Explain how the proportion of 235U in natural uranium is increased.
-
18M.3.hl.TZ1.14b.ii:
Explain how the proportion of 235U in natural uranium is increased.
-
18M.3.hl.TZ1.b.ii:
Explain how the proportion of 235U in natural uranium is increased.
-
18M.3.hl.TZ1.15a:
Early photovoltaic cells were based on silicon containing traces of other elements. State the type of semiconductor produced by doping silicon with indium, In, giving a reason that refers to its electronic structure.
-
18M.3.hl.TZ1.15a:
Early photovoltaic cells were based on silicon containing traces of other elements. State the type of semiconductor produced by doping silicon with indium, In, giving a reason that refers to its electronic structure.
-
18M.3.hl.TZ1.a:
Early photovoltaic cells were based on silicon containing traces of other elements. State the type of semiconductor produced by doping silicon with indium, In, giving a reason that refers to its electronic structure.
-
18M.3.hl.TZ1.15c:
The structure of two dyes used in DSSCs are shown.
Predict, giving a reason, which dye will absorb light of longer wavelength.
-
18M.3.hl.TZ1.15c:
The structure of two dyes used in DSSCs are shown.
Predict, giving a reason, which dye will absorb light of longer wavelength.
-
18M.3.hl.TZ1.c:
The structure of two dyes used in DSSCs are shown.
Predict, giving a reason, which dye will absorb light of longer wavelength.
-
18M.3.hl.TZ1.16e:
Many drugs are chiral. Explain how a polarimeter can be used to determine the relative proportion of two enantiomers.
-
18M.3.hl.TZ1.16e:
Many drugs are chiral. Explain how a polarimeter can be used to determine the relative proportion of two enantiomers.
-
18M.3.hl.TZ1.e:
Many drugs are chiral. Explain how a polarimeter can be used to determine the relative proportion of two enantiomers.
-
18M.3.hl.TZ1.19a:
Describe how ionizing radiation destroys cancer cells.
-
18M.3.hl.TZ1.19a:
Describe how ionizing radiation destroys cancer cells.
-
18M.3.hl.TZ1.a:
Describe how ionizing radiation destroys cancer cells.
-
18M.3.hl.TZ1.19b:
Outline how Targeted Alpha Therapy (TAT) is used for treating cancers that have spread throughout the body.
-
18M.3.hl.TZ1.19b:
Outline how Targeted Alpha Therapy (TAT) is used for treating cancers that have spread throughout the body.
-
18M.3.hl.TZ1.b:
Outline how Targeted Alpha Therapy (TAT) is used for treating cancers that have spread throughout the body.
-
18M.3.hl.TZ1.20a:
Hexane and propanone have vapour pressures of 17 kPa and 24 kPa respectively at 20 °C.
Calculate the vapour pressure, in kPa, at 20 °C of a mixture containing 60% hexane and 40% propanone by mole fraction, using Raoult’s law and assuming the mixture is ideal.
-
18M.3.hl.TZ1.20a:
Hexane and propanone have vapour pressures of 17 kPa and 24 kPa respectively at 20 °C.
Calculate the vapour pressure, in kPa, at 20 °C of a mixture containing 60% hexane and 40% propanone by mole fraction, using Raoult’s law and assuming the mixture is ideal.
-
18M.3.hl.TZ1.a:
Hexane and propanone have vapour pressures of 17 kPa and 24 kPa respectively at 20 °C.
Calculate the vapour pressure, in kPa, at 20 °C of a mixture containing 60% hexane and 40% propanone by mole fraction, using Raoult’s law and assuming the mixture is ideal.
-
18M.3.hl.TZ1.20b:
Explain how hexane and propanone may be separated by fractional distillation.
-
18M.3.hl.TZ1.20b:
Explain how hexane and propanone may be separated by fractional distillation.
-
18M.3.hl.TZ1.b:
Explain how hexane and propanone may be separated by fractional distillation.
-
18M.3.hl.TZ1.5e:
The concentration of aluminium in drinking water can be reduced by precipitating aluminium hydroxide. Calculate the maximum concentration of aluminium ions in water of pH 7 at 298 K. Solubility product of aluminium hydroxide = 3.3 × 10−34 at 298 K.
-
18M.3.hl.TZ1.5e:
The concentration of aluminium in drinking water can be reduced by precipitating aluminium hydroxide. Calculate the maximum concentration of aluminium ions in water of pH 7 at 298 K. Solubility product of aluminium hydroxide = 3.3 × 10−34 at 298 K.
-
18M.3.hl.TZ1.e:
The concentration of aluminium in drinking water can be reduced by precipitating aluminium hydroxide. Calculate the maximum concentration of aluminium ions in water of pH 7 at 298 K. Solubility product of aluminium hydroxide = 3.3 × 10−34 at 298 K.
-
18M.3.hl.TZ2.11a:
Hemoglobin’s oxygen dissociation curve is shown at a given temperature. Sketch the curve on the graph at a higher temperature.
-
18M.3.hl.TZ2.11a:
Hemoglobin’s oxygen dissociation curve is shown at a given temperature. Sketch the curve on the graph at a higher temperature.
-
18M.3.hl.TZ2.a:
Hemoglobin’s oxygen dissociation curve is shown at a given temperature. Sketch the curve on the graph at a higher temperature.
-
18M.3.hl.TZ2.13c:
Fuel cells have a higher thermodynamic efficiency than octane. The following table gives some information on a direct methanol fuel cell.
Determine the thermodynamic efficiency of a methanol fuel cell operating at 0.576 V.
Use sections 1 and 2 of the data booklet.
-
18M.3.hl.TZ2.13c:
Fuel cells have a higher thermodynamic efficiency than octane. The following table gives some information on a direct methanol fuel cell.
Determine the thermodynamic efficiency of a methanol fuel cell operating at 0.576 V.
Use sections 1 and 2 of the data booklet.
-
18M.3.hl.TZ2.c:
Fuel cells have a higher thermodynamic efficiency than octane. The following table gives some information on a direct methanol fuel cell.
Determine the thermodynamic efficiency of a methanol fuel cell operating at 0.576 V.
Use sections 1 and 2 of the data booklet.
-
18M.3.hl.TZ2.26b:
The half-life of phosphorus-32 is 14.3 days. Calculate the mass, in g, of 32P remaining after 57.2 days if the initial sample contains 2.63 × 10−8 mol. Use table 1 of the data booklet and Mr = 31.97 g mol−1.
-
18M.3.hl.TZ2.26b:
The half-life of phosphorus-32 is 14.3 days. Calculate the mass, in g, of 32P remaining after 57.2 days if the initial sample contains 2.63 × 10−8 mol. Use table 1 of the data booklet and Mr = 31.97 g mol−1.
-
18M.3.hl.TZ2.b:
The half-life of phosphorus-32 is 14.3 days. Calculate the mass, in g, of 32P remaining after 57.2 days if the initial sample contains 2.63 × 10−8 mol. Use table 1 of the data booklet and Mr = 31.97 g mol−1.
-
18M.3.hl.TZ1.5c:
When X-rays of wavelength 0.154 nm are directed at a crystal of aluminium, the first order diffraction pattern is observed at 18°. Determine the separation of layers of aluminium atoms in the crystal, in m, using section 1 of the data booklet.
-
18M.3.hl.TZ1.5c:
When X-rays of wavelength 0.154 nm are directed at a crystal of aluminium, the first order diffraction pattern is observed at 18°. Determine the separation of layers of aluminium atoms in the crystal, in m, using section 1 of the data booklet.
-
18M.3.hl.TZ1.c:
When X-rays of wavelength 0.154 nm are directed at a crystal of aluminium, the first order diffraction pattern is observed at 18°. Determine the separation of layers of aluminium atoms in the crystal, in m, using section 1 of the data booklet.
-
18M.3.hl.TZ1.6d:
Describe how DNA determines the primary structure of a protein such as insulin.
-
18M.3.hl.TZ1.6d:
Describe how DNA determines the primary structure of a protein such as insulin.
-
18M.3.hl.TZ1.d:
Describe how DNA determines the primary structure of a protein such as insulin.
-
18M.3.hl.TZ1.8b:
Outline why cellulose fibres are strong.
-
18M.3.hl.TZ1.8b:
Outline why cellulose fibres are strong.
-
18M.3.hl.TZ1.b:
Outline why cellulose fibres are strong.
-
18M.3.hl.TZ2.5c.i:
Distinguish between the manufacture of polyester and polyethene.
-
18M.3.hl.TZ2.5c.i:
Distinguish between the manufacture of polyester and polyethene.
-
18M.3.hl.TZ2.c.i:
Distinguish between the manufacture of polyester and polyethene.
-
18M.3.hl.TZ2.11b:
Outline two differences between normal hemoglobin and foetal hemoglobin.
-
18M.3.hl.TZ2.11b:
Outline two differences between normal hemoglobin and foetal hemoglobin.
-
18M.3.hl.TZ2.b:
Outline two differences between normal hemoglobin and foetal hemoglobin.
-
18M.3.hl.TZ2.18a:
Draw the Lewis (electron dot) structure for an appropriate doping element in the box in the centre identifying the type of semiconductor formed.
-
18M.3.hl.TZ2.18a:
Draw the Lewis (electron dot) structure for an appropriate doping element in the box in the centre identifying the type of semiconductor formed.
-
18M.3.hl.TZ2.a:
Draw the Lewis (electron dot) structure for an appropriate doping element in the box in the centre identifying the type of semiconductor formed.
-
18M.3.hl.TZ2.18b.ii:
Outline why complex B absorbs light of longer wavelength than complex A.
-
18M.3.hl.TZ2.18b.ii:
Outline why complex B absorbs light of longer wavelength than complex A.
-
18M.3.hl.TZ2.b.ii:
Outline why complex B absorbs light of longer wavelength than complex A.
-
18M.3.hl.TZ2.26c:
Explain the targeted alpha therapy (TAT) technique and why it is useful.
-
18M.3.hl.TZ2.26c:
Explain the targeted alpha therapy (TAT) technique and why it is useful.
-
18M.3.hl.TZ2.c:
Explain the targeted alpha therapy (TAT) technique and why it is useful.
-
18M.3.hl.TZ1.5d.i:
Deduce what the shape of the graph indicates about aluminium.
-
18M.3.hl.TZ1.5d.i:
Deduce what the shape of the graph indicates about aluminium.
-
18M.3.hl.TZ1.d.i:
Deduce what the shape of the graph indicates about aluminium.
-
18M.3.hl.TZ1.9b:
Outline the significance of the value of the Michaelis constant, Km.
-
18M.3.hl.TZ1.9b:
Outline the significance of the value of the Michaelis constant, Km.
-
18M.3.hl.TZ1.b:
Outline the significance of the value of the Michaelis constant, Km.
-
18M.3.hl.TZ2.4a.iii:
Calculate the average mass, in g, of a vanadium atom by using sections 2 and 6 of the data booklet.
-
18M.3.hl.TZ2.4a.iii:
Calculate the average mass, in g, of a vanadium atom by using sections 2 and 6 of the data booklet.
-
18M.3.hl.TZ2.a.iii:
Calculate the average mass, in g, of a vanadium atom by using sections 2 and 6 of the data booklet.
-
18M.3.hl.TZ2.6b:
MWCNT are very small in size and can greatly increase switching speeds in a liquid crystal allowing the liquid crystal to change orientation quickly.
Discuss two other properties a substance should have to be suitable for use in liquid crystal displays.
-
18M.3.hl.TZ2.6b:
MWCNT are very small in size and can greatly increase switching speeds in a liquid crystal allowing the liquid crystal to change orientation quickly.
Discuss two other properties a substance should have to be suitable for use in liquid crystal displays.
-
18M.3.hl.TZ2.b:
MWCNT are very small in size and can greatly increase switching speeds in a liquid crystal allowing the liquid crystal to change orientation quickly.
Discuss two other properties a substance should have to be suitable for use in liquid crystal displays.
-
18M.3.hl.TZ2.8d:
Calculate the pH of a buffer system with a concentration of 1.25 × 10−3 mol dm−3 carbonic acid and 2.50 × 10−2 mol dm−3 sodium hydrogen carbonate. Use section 1 of the data booklet.
pKa (carbonic acid) = 6.36
-
18M.3.hl.TZ2.8d:
Calculate the pH of a buffer system with a concentration of 1.25 × 10−3 mol dm−3 carbonic acid and 2.50 × 10−2 mol dm−3 sodium hydrogen carbonate. Use section 1 of the data booklet.
pKa (carbonic acid) = 6.36
-
18M.3.hl.TZ2.d:
Calculate the pH of a buffer system with a concentration of 1.25 × 10−3 mol dm−3 carbonic acid and 2.50 × 10−2 mol dm−3 sodium hydrogen carbonate. Use section 1 of the data booklet.
pKa (carbonic acid) = 6.36
-
18M.3.hl.TZ2.12:
DNA is a biopolymer made up of nucleotides. List two components of a nucleotide.
-
18M.3.hl.TZ2.12:
DNA is a biopolymer made up of nucleotides. List two components of a nucleotide.
-
18M.3.hl.TZ1.9a:
Explain with reference to the binding site on the enzyme how a non-competitive inhibitor lowers the value of Vmax.
-
18M.3.hl.TZ1.9a:
Explain with reference to the binding site on the enzyme how a non-competitive inhibitor lowers the value of Vmax.
-
18M.3.hl.TZ1.a:
Explain with reference to the binding site on the enzyme how a non-competitive inhibitor lowers the value of Vmax.
-
18M.3.hl.TZ2.4a.ii:
Calculate the expected first order diffraction pattern angle, in degrees, if x-rays of wavelength 150 pm are directed at a crystal of vanadium. Assume the edge length of the crystal to be the same as separation of layers of vanadium atoms found by x-ray diffraction. Use section 1 of the data booklet.
-
18M.3.hl.TZ2.4a.ii:
Calculate the expected first order diffraction pattern angle, in degrees, if x-rays of wavelength 150 pm are directed at a crystal of vanadium. Assume the edge length of the crystal to be the same as separation of layers of vanadium atoms found by x-ray diffraction. Use section 1 of the data booklet.
-
18M.3.hl.TZ2.a.ii:
Calculate the expected first order diffraction pattern angle, in degrees, if x-rays of wavelength 150 pm are directed at a crystal of vanadium. Assume the edge length of the crystal to be the same as separation of layers of vanadium atoms found by x-ray diffraction. Use section 1 of the data booklet.
-
18M.3.hl.TZ2.4a.iv:
Determine the volume, in cm3, of a vanadium unit cell.
-
18M.3.hl.TZ2.4a.iv:
Determine the volume, in cm3, of a vanadium unit cell.
-
18M.3.hl.TZ2.a.iv:
Determine the volume, in cm3, of a vanadium unit cell.
-
18M.3.hl.TZ2.10b:
Explain how the structure of vitamin A is important to vision using section 35 of the data booklet.
-
18M.3.hl.TZ2.10b:
Explain how the structure of vitamin A is important to vision using section 35 of the data booklet.
-
18M.3.hl.TZ2.b:
Explain how the structure of vitamin A is important to vision using section 35 of the data booklet.
-
18M.3.hl.TZ2.16c.i:
Calculate the relative rate of effusion of 235UF6(g) to 238UF6(g) using sections 1 and 6 of the data booklet.
-
18M.3.hl.TZ2.16c.i:
Calculate the relative rate of effusion of 235UF6(g) to 238UF6(g) using sections 1 and 6 of the data booklet.
-
18M.3.hl.TZ2.c.i:
Calculate the relative rate of effusion of 235UF6(g) to 238UF6(g) using sections 1 and 6 of the data booklet.
-
18M.3.hl.TZ2.18b.i:
State the feature of the molecules responsible for the absorption of light.
-
18M.3.hl.TZ2.18b.i:
State the feature of the molecules responsible for the absorption of light.
-
18M.3.hl.TZ2.b.i:
State the feature of the molecules responsible for the absorption of light.
-
18M.3.hl.TZ2.26a:
Phosphorous-32 undergoes beta decay. Formulate a balanced nuclear equation for this process.
-
18M.3.hl.TZ2.26a:
Phosphorous-32 undergoes beta decay. Formulate a balanced nuclear equation for this process.
-
18M.3.hl.TZ2.a:
Phosphorous-32 undergoes beta decay. Formulate a balanced nuclear equation for this process.
-
18M.3.hl.TZ2.27a:
Fuel cells use an electrochemical process to determine the concentration of ethanol.
Formulate the overall equation for this process.
-
18M.3.hl.TZ2.27a:
Fuel cells use an electrochemical process to determine the concentration of ethanol.
Formulate the overall equation for this process.
-
18M.3.hl.TZ2.a:
Fuel cells use an electrochemical process to determine the concentration of ethanol.
Formulate the overall equation for this process.
-
18M.3.hl.TZ1.5d.ii:
Outline why the resistance of aluminium increases above 1.2 K.
-
18M.3.hl.TZ1.5d.ii:
Outline why the resistance of aluminium increases above 1.2 K.
-
18M.3.hl.TZ1.d.ii:
Outline why the resistance of aluminium increases above 1.2 K.
-
18M.3.hl.TZ2.4a.v:
Determine the density, in g cm−3, of vanadium by using your answers to (a)(i), (a)(iii) and (a)(iv).
-
18M.3.hl.TZ2.4a.v:
Determine the density, in g cm−3, of vanadium by using your answers to (a)(i), (a)(iii) and (a)(iv).
-
18M.3.hl.TZ2.a.v:
Determine the density, in g cm−3, of vanadium by using your answers to (a)(i), (a)(iii) and (a)(iv).
-
18M.3.hl.TZ2.16c.ii:
Explain, based on molecular structure and bonding, why diffusion or centrifuging can be used for enrichment of UF6 but not UO2.
-
18M.3.hl.TZ2.16c.ii:
Explain, based on molecular structure and bonding, why diffusion or centrifuging can be used for enrichment of UF6 but not UO2.
-
18M.3.hl.TZ2.c.ii:
Explain, based on molecular structure and bonding, why diffusion or centrifuging can be used for enrichment of UF6 but not UO2.
-
18M.3.hl.TZ2.4b.ii:
Vanadium(IV) ions can create free radicals by a Fenton reaction.
Deduce the equation for the reaction of V4+ with hydrogen peroxide.
-
18M.3.hl.TZ2.4b.ii:
Vanadium(IV) ions can create free radicals by a Fenton reaction.
Deduce the equation for the reaction of V4+ with hydrogen peroxide.
-
18M.3.hl.TZ2.b.ii:
Vanadium(IV) ions can create free radicals by a Fenton reaction.
Deduce the equation for the reaction of V4+ with hydrogen peroxide.
-
18M.3.hl.TZ2.8c:
Draw the structures of the main form of glycine in buffer solutions of pH 1.0 and 6.0.
The pKa of glycine is 2.34.
-
18M.3.hl.TZ2.8c:
Draw the structures of the main form of glycine in buffer solutions of pH 1.0 and 6.0.
The pKa of glycine is 2.34.
-
18M.3.hl.TZ2.c:
Draw the structures of the main form of glycine in buffer solutions of pH 1.0 and 6.0.
The pKa of glycine is 2.34.
-
18M.3.hl.TZ2.27b:
Predict the chemical shifts and integration for each signal in the 1H NMR spectrum for ethanol using section 27 of the data booklet.
-
18M.3.hl.TZ2.27b:
Predict the chemical shifts and integration for each signal in the 1H NMR spectrum for ethanol using section 27 of the data booklet.
-
18M.3.hl.TZ2.b:
Predict the chemical shifts and integration for each signal in the 1H NMR spectrum for ethanol using section 27 of the data booklet.
-
18M.3.sl.TZ1.3a:
Discuss, in terms of its structure, why an aluminium saucepan is impermeable to water.
-
18M.3.sl.TZ1.3a:
Discuss, in terms of its structure, why an aluminium saucepan is impermeable to water.
-
18M.3.sl.TZ1.a:
Discuss, in terms of its structure, why an aluminium saucepan is impermeable to water.
-
18M.3.sl.TZ1.3b.i:
State the name given to a material composed of two distinct solid phases.
-
18M.3.sl.TZ1.3b.i:
State the name given to a material composed of two distinct solid phases.
-
18M.3.sl.TZ1.b.i:
State the name given to a material composed of two distinct solid phases.
-
18M.3.sl.TZ1.3b.ii:
State one physical property of HDPE that will be affected by the incorporation of carbon nanotubes.
-
18M.3.sl.TZ1.3b.ii:
State one physical property of HDPE that will be affected by the incorporation of carbon nanotubes.
-
18M.3.sl.TZ1.b.ii:
State one physical property of HDPE that will be affected by the incorporation of carbon nanotubes.
-
18M.3.sl.TZ1.3b.iii:
Describe how carbon nanotubes are produced by chemical vapour deposition (CVD).
-
18M.3.sl.TZ1.3b.iii:
Describe how carbon nanotubes are produced by chemical vapour deposition (CVD).
-
18M.3.sl.TZ1.b.iii:
Describe how carbon nanotubes are produced by chemical vapour deposition (CVD).
-
18M.3.sl.TZ1.3b.iv:
State the property of carbon nanotubes that enables them to form a nematic liquid crystal phase.
-
18M.3.sl.TZ1.3b.iv:
State the property of carbon nanotubes that enables them to form a nematic liquid crystal phase.
-
18M.3.sl.TZ1.b.iv:
State the property of carbon nanotubes that enables them to form a nematic liquid crystal phase.
-
18M.3.sl.TZ1.4a:
Both of these are thermoplastic polymers. Outline what this term means.
-
18M.3.sl.TZ1.4a:
Both of these are thermoplastic polymers. Outline what this term means.
-
18M.3.sl.TZ1.a:
Both of these are thermoplastic polymers. Outline what this term means.
-
18M.3.sl.TZ1.4b.i:
Compare and contrast the structures of HDPE and LDPE.
-
18M.3.sl.TZ1.4b.i:
Compare and contrast the structures of HDPE and LDPE.
-
18M.3.sl.TZ1.b.i:
Compare and contrast the structures of HDPE and LDPE.
-
18M.3.sl.TZ1.4b.ii:
State one way in which a physical property of HDPE, other than density, differs from that of LDPE as a result of this structural difference.
-
18M.3.sl.TZ1.4b.ii:
State one way in which a physical property of HDPE, other than density, differs from that of LDPE as a result of this structural difference.
-
18M.3.sl.TZ1.b.ii:
State one way in which a physical property of HDPE, other than density, differs from that of LDPE as a result of this structural difference.
-
18M.3.sl.TZ1.4c.i:
The production of HDPE involves the use of homogeneous catalysts. Outline how homogeneous catalysts reduce the activation energy of reactions.
-
18M.3.sl.TZ1.4c.i:
The production of HDPE involves the use of homogeneous catalysts. Outline how homogeneous catalysts reduce the activation energy of reactions.
-
18M.3.sl.TZ1.c.i:
The production of HDPE involves the use of homogeneous catalysts. Outline how homogeneous catalysts reduce the activation energy of reactions.
-
18M.3.sl.TZ1.4c.ii:
Trace amounts of metal from the catalysts used in the production of HDPE sometimes remain in the product. State a technique that could be used to measure the concentration of the metal.
-
18M.3.sl.TZ1.4c.ii:
Trace amounts of metal from the catalysts used in the production of HDPE sometimes remain in the product. State a technique that could be used to measure the concentration of the metal.
-
18M.3.sl.TZ1.c.ii:
Trace amounts of metal from the catalysts used in the production of HDPE sometimes remain in the product. State a technique that could be used to measure the concentration of the metal.
-
18M.3.sl.TZ1.4d:
Suggest two of the major obstacles, other than collection and economic factors, which have to be overcome in plastic recycling.
-
18M.3.sl.TZ1.4d:
Suggest two of the major obstacles, other than collection and economic factors, which have to be overcome in plastic recycling.
-
18M.3.sl.TZ1.d:
Suggest two of the major obstacles, other than collection and economic factors, which have to be overcome in plastic recycling.
-
18M.3.sl.TZ1.7a.ii:
State one factor that increases the rate at which saturated lipids become rancid.
-
18M.3.sl.TZ1.7a.ii:
State one factor that increases the rate at which saturated lipids become rancid.
-
18M.3.sl.TZ1.a.ii:
State one factor that increases the rate at which saturated lipids become rancid.
-
18M.3.sl.TZ1.7c.iv:
Plastics are another source of marine pollution. Outline one way in which plastics can be made more biodegradable.
-
18M.3.sl.TZ1.7c.iv:
Plastics are another source of marine pollution. Outline one way in which plastics can be made more biodegradable.
-
18M.3.sl.TZ1.c.iv:
Plastics are another source of marine pollution. Outline one way in which plastics can be made more biodegradable.
-
18M.3.sl.TZ1.8b:
A person with diabetes suffering very low blood sugar (hypoglycaemia) may be advised to consume glucose immediately and then eat a small amount of starchy food such as a sandwich. Explain this advice in terms of the properties of glucose and starch.
-
18M.3.sl.TZ1.8b:
A person with diabetes suffering very low blood sugar (hypoglycaemia) may be advised to consume glucose immediately and then eat a small amount of starchy food such as a sandwich. Explain this advice in terms of the properties of glucose and starch.
-
18M.3.sl.TZ1.b:
A person with diabetes suffering very low blood sugar (hypoglycaemia) may be advised to consume glucose immediately and then eat a small amount of starchy food such as a sandwich. Explain this advice in terms of the properties of glucose and starch.
-
18M.3.sl.TZ1.13d.i:
Morphine and codeine are strong analgesics. Outline how strong analgesics function.
-
18M.3.sl.TZ1.13d.i:
Morphine and codeine are strong analgesics. Outline how strong analgesics function.
-
18M.3.sl.TZ1.d.i:
Morphine and codeine are strong analgesics. Outline how strong analgesics function.
-
18M.3.sl.TZ1.14b:
Explain how omeprazole (Prilosec) reduces stomach acidity.
-
18M.3.sl.TZ1.14b:
Explain how omeprazole (Prilosec) reduces stomach acidity.
-
18M.3.sl.TZ1.b:
Explain how omeprazole (Prilosec) reduces stomach acidity.
-
18M.3.sl.TZ1.15b:
Shikimic acid, the precursor for oseltamivir (Tamiflu), was originally extracted from star anise, and is now produced using genetically modified E. coli bacteria.
Suggest one difficulty associated with synthesizing oseltamivir (Tamiflu) from star anise.
-
18M.3.sl.TZ1.15b:
Shikimic acid, the precursor for oseltamivir (Tamiflu), was originally extracted from star anise, and is now produced using genetically modified E. coli bacteria.
Suggest one difficulty associated with synthesizing oseltamivir (Tamiflu) from star anise.
-
18M.3.sl.TZ1.b:
Shikimic acid, the precursor for oseltamivir (Tamiflu), was originally extracted from star anise, and is now produced using genetically modified E. coli bacteria.
Suggest one difficulty associated with synthesizing oseltamivir (Tamiflu) from star anise.
-
18M.3.sl.TZ1.9a:
Identify one naturally occurring greenhouse gas, other than carbon dioxide or water vapour, and its natural source.
-
18M.3.sl.TZ1.9a:
Identify one naturally occurring greenhouse gas, other than carbon dioxide or water vapour, and its natural source.
-
18M.3.sl.TZ1.a:
Identify one naturally occurring greenhouse gas, other than carbon dioxide or water vapour, and its natural source.
-
18M.3.sl.TZ1.11a.ii:
State the formula of a fuel that might be produced from the vegetable oil whose formula is shown.
-
18M.3.sl.TZ1.11a.ii:
State the formula of a fuel that might be produced from the vegetable oil whose formula is shown.
-
18M.3.sl.TZ1.a.ii:
State the formula of a fuel that might be produced from the vegetable oil whose formula is shown.
-
18M.3.sl.TZ1.11b:
Outline why biofuels are considered more environmentally friendly, even though they produce more carbon dioxide per kJ of energy than petroleum based fuels.
-
18M.3.sl.TZ1.11b:
Outline why biofuels are considered more environmentally friendly, even though they produce more carbon dioxide per kJ of energy than petroleum based fuels.
-
18M.3.sl.TZ1.b:
Outline why biofuels are considered more environmentally friendly, even though they produce more carbon dioxide per kJ of energy than petroleum based fuels.
-
18M.3.sl.TZ1.13c.i:
Compare and contrast the IR spectrum of aspirin with that of salicylic acid, using section 26 of the data booklet.
-
18M.3.sl.TZ1.13c.i:
Compare and contrast the IR spectrum of aspirin with that of salicylic acid, using section 26 of the data booklet.
-
18M.3.sl.TZ1.c.i:
Compare and contrast the IR spectrum of aspirin with that of salicylic acid, using section 26 of the data booklet.
-
18M.3.sl.TZ1.14a.i:
An antacid tablet contains 680 mg of calcium carbonate, CaCO3, and 80 mg of magnesium carbonate, MgCO3.
State the equation for the reaction of magnesium carbonate with hydrochloric acid.
-
18M.3.sl.TZ1.14a.i:
An antacid tablet contains 680 mg of calcium carbonate, CaCO3, and 80 mg of magnesium carbonate, MgCO3.
State the equation for the reaction of magnesium carbonate with hydrochloric acid.
-
18M.3.sl.TZ1.a.i:
An antacid tablet contains 680 mg of calcium carbonate, CaCO3, and 80 mg of magnesium carbonate, MgCO3.
State the equation for the reaction of magnesium carbonate with hydrochloric acid.
-
18M.3.sl.TZ1.7b:
Butter contains varying proportions of oleic, myristic, palmitic and stearic acids. Explain in terms of their structures why stearic acid has a higher melting point than oleic acid, using section 34 of the data booklet.
-
18M.3.sl.TZ1.7b:
Butter contains varying proportions of oleic, myristic, palmitic and stearic acids. Explain in terms of their structures why stearic acid has a higher melting point than oleic acid, using section 34 of the data booklet.
-
18M.3.sl.TZ1.b:
Butter contains varying proportions of oleic, myristic, palmitic and stearic acids. Explain in terms of their structures why stearic acid has a higher melting point than oleic acid, using section 34 of the data booklet.
-
18M.3.sl.TZ1.7c.iii:
Explain why sharks and swordfish sometimes contain high concentrations of mercury and polychlorinated biphenyls (PCBs).
-
18M.3.sl.TZ1.7c.iii:
Explain why sharks and swordfish sometimes contain high concentrations of mercury and polychlorinated biphenyls (PCBs).
-
18M.3.sl.TZ1.c.iii:
Explain why sharks and swordfish sometimes contain high concentrations of mercury and polychlorinated biphenyls (PCBs).
-
18M.3.sl.TZ1.8a:
State the specific type of linkage formed between α-glucose fragments in both maltose and amylose.
-
18M.3.sl.TZ1.8a:
State the specific type of linkage formed between α-glucose fragments in both maltose and amylose.
-
18M.3.sl.TZ1.a:
State the specific type of linkage formed between α-glucose fragments in both maltose and amylose.
-
18M.3.sl.TZ1.10c.i:
Determine the specific energy and energy density of petrol (gasoline), using data from sections 1 and 13 of the data booklet. Assume petrol is pure octane, C8H18. Octane: molar mass = 114.26 g mol−1, density = 0.703 g cm−3.
-
18M.3.sl.TZ1.10c.i:
Determine the specific energy and energy density of petrol (gasoline), using data from sections 1 and 13 of the data booklet. Assume petrol is pure octane, C8H18. Octane: molar mass = 114.26 g mol−1, density = 0.703 g cm−3.
-
18M.3.sl.TZ1.c.i:
Determine the specific energy and energy density of petrol (gasoline), using data from sections 1 and 13 of the data booklet. Assume petrol is pure octane, C8H18. Octane: molar mass = 114.26 g mol−1, density = 0.703 g cm−3.
-
18M.3.sl.TZ1.6b:
Deduce the strongest intermolecular forces that would occur between the following amino acid residues in a protein chain.
-
18M.3.sl.TZ1.6b:
Deduce the strongest intermolecular forces that would occur between the following amino acid residues in a protein chain.
-
18M.3.sl.TZ1.b:
Deduce the strongest intermolecular forces that would occur between the following amino acid residues in a protein chain.
-
18M.3.sl.TZ1.6c.ii:
Outline how the amino acids may be identified from a paper chromatogram.
-
18M.3.sl.TZ1.6c.ii:
Outline how the amino acids may be identified from a paper chromatogram.
-
18M.3.sl.TZ1.c.ii:
Outline how the amino acids may be identified from a paper chromatogram.
-
18M.3.sl.TZ1.7a.i:
Identify the type of rancidity occurring in saturated lipids and the structural feature that causes it.
-
18M.3.sl.TZ1.7a.i:
Identify the type of rancidity occurring in saturated lipids and the structural feature that causes it.
-
18M.3.sl.TZ1.a.i:
Identify the type of rancidity occurring in saturated lipids and the structural feature that causes it.
-
18M.3.sl.TZ1.9c:
The concentrations of oxygen and nitrogen in the atmosphere are much greater than those of greenhouse gases. Outline why these gases do not absorb infrared radiation.
-
18M.3.sl.TZ1.9c:
The concentrations of oxygen and nitrogen in the atmosphere are much greater than those of greenhouse gases. Outline why these gases do not absorb infrared radiation.
-
18M.3.sl.TZ1.c:
The concentrations of oxygen and nitrogen in the atmosphere are much greater than those of greenhouse gases. Outline why these gases do not absorb infrared radiation.
-
18M.3.sl.TZ1.10a:
Identify an element, other than carbon and hydrogen, found at significant concentrations in fossil fuels.
-
18M.3.sl.TZ1.10a:
Identify an element, other than carbon and hydrogen, found at significant concentrations in fossil fuels.
-
18M.3.sl.TZ1.a:
Identify an element, other than carbon and hydrogen, found at significant concentrations in fossil fuels.
-
18M.3.sl.TZ1.10b:
Petroleum contains many hydrocarbons. Explain how these are separated by fractional distillation.
-
18M.3.sl.TZ1.10b:
Petroleum contains many hydrocarbons. Explain how these are separated by fractional distillation.
-
18M.3.sl.TZ1.b:
Petroleum contains many hydrocarbons. Explain how these are separated by fractional distillation.
-
18M.3.sl.TZ1.10c.ii:
Outline why the energy available from an engine will be less than these theoretical values.
-
18M.3.sl.TZ1.10c.ii:
Outline why the energy available from an engine will be less than these theoretical values.
-
18M.3.sl.TZ1.c.ii:
Outline why the energy available from an engine will be less than these theoretical values.
-
18M.3.sl.TZ1.11a.i:
Outline the major technical problem affecting the direct use of vegetable oils as fuels in internal combustion engines and the chemical conversion that has overcome this.
-
18M.3.sl.TZ1.11a.i:
Outline the major technical problem affecting the direct use of vegetable oils as fuels in internal combustion engines and the chemical conversion that has overcome this.
-
18M.3.sl.TZ1.a.i:
Outline the major technical problem affecting the direct use of vegetable oils as fuels in internal combustion engines and the chemical conversion that has overcome this.
-
18M.3.sl.TZ1.12b:
Suggest one reason why there is opposition to the increased use of nuclear fission reactors.
-
18M.3.sl.TZ1.12b:
Suggest one reason why there is opposition to the increased use of nuclear fission reactors.
-
18M.3.sl.TZ1.b:
Suggest one reason why there is opposition to the increased use of nuclear fission reactors.
-
18M.3.sl.TZ1.13a:
Aspirin is often taken to reduce pain, swelling or fever. State one other use of aspirin.
-
18M.3.sl.TZ1.13a:
Aspirin is often taken to reduce pain, swelling or fever. State one other use of aspirin.
-
18M.3.sl.TZ1.a:
Aspirin is often taken to reduce pain, swelling or fever. State one other use of aspirin.
-
18M.3.sl.TZ1.13b.i:
State what is meant by the bioavailability of a drug.
-
18M.3.sl.TZ1.13b.i:
State what is meant by the bioavailability of a drug.
-
18M.3.sl.TZ1.b.i:
State what is meant by the bioavailability of a drug.
-
18M.3.sl.TZ1.9b:
Formulate an equation that shows how aqueous carbon dioxide produces hydrogen ions, H+(aq).
-
18M.3.sl.TZ1.9b:
Formulate an equation that shows how aqueous carbon dioxide produces hydrogen ions, H+(aq).
-
18M.3.sl.TZ1.b:
Formulate an equation that shows how aqueous carbon dioxide produces hydrogen ions, H+(aq).
-
18M.3.sl.TZ1.13b.ii:
Outline how the bioavailability of aspirin may be increased.
-
18M.3.sl.TZ1.13b.ii:
Outline how the bioavailability of aspirin may be increased.
-
18M.3.sl.TZ1.b.ii:
Outline how the bioavailability of aspirin may be increased.
-
18M.3.sl.TZ1.13c.ii:
Describe how penicillin combats bacterial infections.
-
18M.3.sl.TZ1.13c.ii:
Describe how penicillin combats bacterial infections.
-
18M.3.sl.TZ1.c.ii:
Describe how penicillin combats bacterial infections.
-
18M.3.sl.TZ1.13c.iii:
Outline two consequences of prescribing antibiotics such as penicillin unnecessarily.
-
18M.3.sl.TZ1.13c.iii:
Outline two consequences of prescribing antibiotics such as penicillin unnecessarily.
-
18M.3.sl.TZ1.c.iii:
Outline two consequences of prescribing antibiotics such as penicillin unnecessarily.
-
18M.3.sl.TZ1.13c.iv:
State how penicillins may be modified to increase their effectiveness.
-
18M.3.sl.TZ1.13c.iv:
State how penicillins may be modified to increase their effectiveness.
-
18M.3.sl.TZ1.c.iv:
State how penicillins may be modified to increase their effectiveness.
-
18M.3.sl.TZ1.13d.ii:
Suggest one reason why codeine is more widely used than morphine as an analgesic.
-
18M.3.sl.TZ1.13d.ii:
Suggest one reason why codeine is more widely used than morphine as an analgesic.
-
18M.3.sl.TZ1.d.ii:
Suggest one reason why codeine is more widely used than morphine as an analgesic.
-
18M.3.sl.TZ1.14a.ii:
Determine the amount, in mol, of hydrochloric acid neutralized by one antacid tablet.
-
18M.3.sl.TZ1.14a.ii:
Determine the amount, in mol, of hydrochloric acid neutralized by one antacid tablet.
-
18M.3.sl.TZ1.a.ii:
Determine the amount, in mol, of hydrochloric acid neutralized by one antacid tablet.
-
18M.3.sl.TZ1.15a:
Oseltamivir (Tamiflu) and zanamivir (Relenza) are used against flu viruses. Explain how these drugs function.
-
18M.3.sl.TZ1.15a:
Oseltamivir (Tamiflu) and zanamivir (Relenza) are used against flu viruses. Explain how these drugs function.
-
18M.3.sl.TZ1.a:
Oseltamivir (Tamiflu) and zanamivir (Relenza) are used against flu viruses. Explain how these drugs function.
-
18M.3.sl.TZ2.3a:
ICP-OES/MS can be used to analyse alloys and composites. Distinguish between alloys and composites.
-
18M.3.sl.TZ2.3a:
ICP-OES/MS can be used to analyse alloys and composites. Distinguish between alloys and composites.
-
18M.3.sl.TZ2.a:
ICP-OES/MS can be used to analyse alloys and composites. Distinguish between alloys and composites.
-
18M.3.sl.TZ2.3b:
ICP-MS is a reference mode for analysis. The following correlation graphs between ICP-OES and ICP-MS were produced for yttrium and nickel.
Each y-axis shows concentrations calculated by ICP-OES; each x-axis shows concentrations for the same sample as found by ICP-MS.
The line in each graph is y = x.
Discuss the effectiveness of ICP-OES for yttrium and nickel.
-
18M.3.sl.TZ2.3b:
ICP-MS is a reference mode for analysis. The following correlation graphs between ICP-OES and ICP-MS were produced for yttrium and nickel.
Each y-axis shows concentrations calculated by ICP-OES; each x-axis shows concentrations for the same sample as found by ICP-MS.
The line in each graph is y = x.
Discuss the effectiveness of ICP-OES for yttrium and nickel.
-
18M.3.sl.TZ2.b:
ICP-MS is a reference mode for analysis. The following correlation graphs between ICP-OES and ICP-MS were produced for yttrium and nickel.
Each y-axis shows concentrations calculated by ICP-OES; each x-axis shows concentrations for the same sample as found by ICP-MS.
The line in each graph is y = x.
Discuss the effectiveness of ICP-OES for yttrium and nickel.
-
18M.3.sl.TZ2.3c.i:
Identify the purpose of each graph.
-
18M.3.sl.TZ2.3c.i:
Identify the purpose of each graph.
-
18M.3.sl.TZ2.c.i:
Identify the purpose of each graph.
-
18M.3.sl.TZ2.3c.ii:
Calculate, to four significant figures, the concentration, in μg kg−1, of vanadium in oil giving a signal intensity of 14 950.
-
18M.3.sl.TZ2.3c.ii:
Calculate, to four significant figures, the concentration, in μg kg−1, of vanadium in oil giving a signal intensity of 14 950.
-
18M.3.sl.TZ2.c.ii:
Calculate, to four significant figures, the concentration, in μg kg−1, of vanadium in oil giving a signal intensity of 14 950.
-
18M.3.sl.TZ2.3c.iii:
Vanadium(V) oxide is used as the catalyst in the conversion of sulfur dioxide to sulfur trioxide.
SO2(g) + V2O5(s) → SO3(g) + 2VO2(s)
O2(g) + 2VO2(s) → V2O5(s)
Outline how vanadium(V) oxide acts as a catalyst.
-
18M.3.sl.TZ2.3c.iii:
Vanadium(V) oxide is used as the catalyst in the conversion of sulfur dioxide to sulfur trioxide.
SO2(g) + V2O5(s) → SO3(g) + 2VO2(s)
O2(g) + 2VO2(s) → V2O5(s)
Outline how vanadium(V) oxide acts as a catalyst.
-
18M.3.sl.TZ2.c.iii:
Vanadium(V) oxide is used as the catalyst in the conversion of sulfur dioxide to sulfur trioxide.
SO2(g) + V2O5(s) → SO3(g) + 2VO2(s)
O2(g) + 2VO2(s) → V2O5(s)
Outline how vanadium(V) oxide acts as a catalyst.
-
18M.3.sl.TZ2.4a:
Sketch four repeating units of the polymer to show atactic and isotactic polypropene.
-
18M.3.sl.TZ2.4a:
Sketch four repeating units of the polymer to show atactic and isotactic polypropene.
-
18M.3.sl.TZ2.a:
Sketch four repeating units of the polymer to show atactic and isotactic polypropene.
-
18M.3.sl.TZ2.4b.i:
State the chemical reason why plastics do not degrade easily.
-
18M.3.sl.TZ2.4b.i:
State the chemical reason why plastics do not degrade easily.
-
18M.3.sl.TZ2.b.i:
State the chemical reason why plastics do not degrade easily.
-
18M.3.sl.TZ2.5a:
State the source of carbon for MWCNT produced by arc discharge and by CVD.
-
18M.3.sl.TZ2.5a:
State the source of carbon for MWCNT produced by arc discharge and by CVD.
-
18M.3.sl.TZ2.a:
State the source of carbon for MWCNT produced by arc discharge and by CVD.
-
18M.3.sl.TZ2.5b:
Discuss three properties a substance should have to be suitable for use in liquid crystal displays.
-
18M.3.sl.TZ2.5b:
Discuss three properties a substance should have to be suitable for use in liquid crystal displays.
-
18M.3.sl.TZ2.b:
Discuss three properties a substance should have to be suitable for use in liquid crystal displays.
-
18M.3.sl.TZ2.6a:
Identify the type of chemical reaction that occurs between fatty acids and glycerol to form lipids and the by-product of the reaction.
-
18M.3.sl.TZ2.6a:
Identify the type of chemical reaction that occurs between fatty acids and glycerol to form lipids and the by-product of the reaction.
-
18M.3.sl.TZ2.a:
Identify the type of chemical reaction that occurs between fatty acids and glycerol to form lipids and the by-product of the reaction.
-
18M.3.sl.TZ2.6c:
Deduce the structure of the lipid formed by the reaction between lauric acid and glycerol (propane-1,2,3-triol) using section 34 of the data booklet.
-
18M.3.sl.TZ2.6c:
Deduce the structure of the lipid formed by the reaction between lauric acid and glycerol (propane-1,2,3-triol) using section 34 of the data booklet.
-
18M.3.sl.TZ2.c:
Deduce the structure of the lipid formed by the reaction between lauric acid and glycerol (propane-1,2,3-triol) using section 34 of the data booklet.
-
18M.3.sl.TZ2.6d:
Outline one impact food labelling has had on the consumption of foods containing different types of lipids.
-
18M.3.sl.TZ2.6d:
Outline one impact food labelling has had on the consumption of foods containing different types of lipids.
-
18M.3.sl.TZ2.d:
Outline one impact food labelling has had on the consumption of foods containing different types of lipids.
-
18M.3.sl.TZ2.8:
Green Chemistry reduces the production of hazardous materials and chemical waste.
Outline two specific examples or technological processes of how Green Chemistry has accomplished this environmental impact.
-
18M.3.sl.TZ2.8:
Green Chemistry reduces the production of hazardous materials and chemical waste.
Outline two specific examples or technological processes of how Green Chemistry has accomplished this environmental impact.
-
18M.3.sl.TZ2.9:
Explain the solubility of vitamins A and C using section 35 of the data booklet.
-
18M.3.sl.TZ2.9:
Explain the solubility of vitamins A and C using section 35 of the data booklet.
-
18M.3.sl.TZ2.11a:
Explain the molecular mechanism by which carbon dioxide acts as a greenhouse gas.
-
18M.3.sl.TZ2.11a:
Explain the molecular mechanism by which carbon dioxide acts as a greenhouse gas.
-
18M.3.sl.TZ2.a:
Explain the molecular mechanism by which carbon dioxide acts as a greenhouse gas.
-
18M.3.sl.TZ2.12b:
Power plants generating electricity by burning coal to boil water operate at approximately 35% efficiency.
State what this means and suggest why it is lower than the thermal efficiency.
-
18M.3.sl.TZ2.12b:
Power plants generating electricity by burning coal to boil water operate at approximately 35% efficiency.
State what this means and suggest why it is lower than the thermal efficiency.
-
18M.3.sl.TZ2.b:
Power plants generating electricity by burning coal to boil water operate at approximately 35% efficiency.
State what this means and suggest why it is lower than the thermal efficiency.
-
18M.3.sl.TZ2.14a:
Deduce the equation for the transesterification reaction of pentyl octanoate, C7H15COOC5H11, with methanol.
-
18M.3.sl.TZ2.14a:
Deduce the equation for the transesterification reaction of pentyl octanoate, C7H15COOC5H11, with methanol.
-
18M.3.sl.TZ2.a:
Deduce the equation for the transesterification reaction of pentyl octanoate, C7H15COOC5H11, with methanol.
-
18M.3.sl.TZ2.15:
Drug testing is necessary to determine safe and effective doses.
Distinguish between the lethal dose (LD50) and the toxic dose (TD50).
-
18M.3.sl.TZ2.15:
Drug testing is necessary to determine safe and effective doses.
Distinguish between the lethal dose (LD50) and the toxic dose (TD50).
-
18M.3.sl.TZ2.16b:
State the type of reaction used to synthesize aspirin from salicylic acid.
-
18M.3.sl.TZ2.b:
State the type of reaction used to synthesize aspirin from salicylic acid.
-
18M.3.sl.TZ2.16b:
State the type of reaction used to synthesize aspirin from salicylic acid.
-
18M.3.sl.TZ2.16c:
Explain why aspirin is not stored in a hot, humid location.
-
18M.3.sl.TZ2.c:
Explain why aspirin is not stored in a hot, humid location.
-
18M.3.sl.TZ2.16c:
Explain why aspirin is not stored in a hot, humid location.
-
18M.3.sl.TZ2.17:
Morphine and diamorphine (heroin) are both opioids.
Explain why diamorphine is more potent than morphine using section 37 of the data booklet.
-
18M.3.sl.TZ2.17:
Morphine and diamorphine (heroin) are both opioids.
Explain why diamorphine is more potent than morphine using section 37 of the data booklet.
-
18M.3.sl.TZ2.20:
Drug synthesis often involves solvents.
Identify a common hazardous solvent and a Green solvent that could replace it.
-
18M.3.sl.TZ2.20:
Drug synthesis often involves solvents.
Identify a common hazardous solvent and a Green solvent that could replace it.
-
18M.3.sl.TZ2.6b:
Arachidonic acid is a polyunsaturated omega-6 fatty acid found in peanut oil.
Determine the number of carbon–carbon double bonds present if the iodine number for the compound is 334. (Arachidonic acid Mr = 304.5)
-
18M.3.sl.TZ2.6b:
Arachidonic acid is a polyunsaturated omega-6 fatty acid found in peanut oil.
Determine the number of carbon–carbon double bonds present if the iodine number for the compound is 334. (Arachidonic acid Mr = 304.5)
-
18M.3.sl.TZ2.b:
Arachidonic acid is a polyunsaturated omega-6 fatty acid found in peanut oil.
Determine the number of carbon–carbon double bonds present if the iodine number for the compound is 334. (Arachidonic acid Mr = 304.5)
-
18M.3.sl.TZ2.6f:
Explain why lipids provide more energy than carbohydrates and proteins.
-
18M.3.sl.TZ2.6f:
Explain why lipids provide more energy than carbohydrates and proteins.
-
18M.3.sl.TZ2.f:
Explain why lipids provide more energy than carbohydrates and proteins.
-
18M.3.sl.TZ2.10c.i:
Outline how higher octane fuels help eliminate “knocking” in engines.
-
18M.3.sl.TZ2.10c.i:
Outline how higher octane fuels help eliminate “knocking” in engines.
-
18M.3.sl.TZ2.c.i:
Outline how higher octane fuels help eliminate “knocking” in engines.
-
18M.3.sl.TZ2.7a:
Draw the dipeptide represented by the formula Ala-Gly using section 33 of the data booklet.
-
18M.3.sl.TZ2.7a:
Draw the dipeptide represented by the formula Ala-Gly using section 33 of the data booklet.
-
18M.3.sl.TZ2.a:
Draw the dipeptide represented by the formula Ala-Gly using section 33 of the data booklet.
-
18M.3.sl.TZ2.7c:
Outline why amino acids have high melting points.
-
18M.3.sl.TZ2.7c:
Outline why amino acids have high melting points.
-
18M.3.sl.TZ2.c:
Outline why amino acids have high melting points.
-
18M.3.sl.TZ2.10a:
Outline two reasons why oil is one of the world’s significant energy sources.
-
18M.3.sl.TZ2.10a:
Outline two reasons why oil is one of the world’s significant energy sources.
-
18M.3.sl.TZ2.a:
Outline two reasons why oil is one of the world’s significant energy sources.
-
18M.3.sl.TZ2.10b.i:
Formulate an equation for the cracking of C16H34 into two products with eight carbon atoms each.
-
18M.3.sl.TZ2.10b.i:
Formulate an equation for the cracking of C16H34 into two products with eight carbon atoms each.
-
18M.3.sl.TZ2.b.i:
Formulate an equation for the cracking of C16H34 into two products with eight carbon atoms each.
-
18M.3.sl.TZ2.10b.ii:
Identify, giving a reason, which product in (b)(i) could be used in petrol (gasoline).
-
18M.3.sl.TZ2.10b.ii:
Identify, giving a reason, which product in (b)(i) could be used in petrol (gasoline).
-
18M.3.sl.TZ2.b.ii:
Identify, giving a reason, which product in (b)(i) could be used in petrol (gasoline).
-
18M.3.sl.TZ2.10c.ii:
The performance of hydrocarbons as fuels can be improved by catalytic reforming.
Outline how catalytic reforming increases a fuel’s octane rating.
-
18M.3.sl.TZ2.10c.ii:
The performance of hydrocarbons as fuels can be improved by catalytic reforming.
Outline how catalytic reforming increases a fuel’s octane rating.
-
18M.3.sl.TZ2.c.ii:
The performance of hydrocarbons as fuels can be improved by catalytic reforming.
Outline how catalytic reforming increases a fuel’s octane rating.
-
18M.3.sl.TZ2.11b:
Discuss the significance of two greenhouse gases, other than carbon dioxide, in causing global warming or climate change.
-
18M.3.sl.TZ2.11b:
Discuss the significance of two greenhouse gases, other than carbon dioxide, in causing global warming or climate change.
-
18M.3.sl.TZ2.b:
Discuss the significance of two greenhouse gases, other than carbon dioxide, in causing global warming or climate change.
-
18M.3.sl.TZ2.12a:
Calculate the thermal efficiency of a steam turbine supplied with steam at 540°C and using a river as the choice of sink at 23 °C.
-
18M.3.sl.TZ2.12a:
Calculate the thermal efficiency of a steam turbine supplied with steam at 540°C and using a river as the choice of sink at 23 °C.
-
18M.3.sl.TZ2.a:
Calculate the thermal efficiency of a steam turbine supplied with steam at 540°C and using a river as the choice of sink at 23 °C.
-
18M.3.sl.TZ2.13a:
Compare and contrast the process of nuclear fusion with nuclear fission.
-
18M.3.sl.TZ2.13a:
Compare and contrast the process of nuclear fusion with nuclear fission.
-
18M.3.sl.TZ2.a:
Compare and contrast the process of nuclear fusion with nuclear fission.
-
18M.3.sl.TZ2.13b:
Dubnium-261 has a half-life of 27 seconds and rutherfordium-261 has a half-life of 81 seconds.
Estimate what fraction of the dubnium-261 isotope remains in the same amount of time that of rutherfordium-261 decays.
-
18M.3.sl.TZ2.13b:
Dubnium-261 has a half-life of 27 seconds and rutherfordium-261 has a half-life of 81 seconds.
Estimate what fraction of the dubnium-261 isotope remains in the same amount of time that of rutherfordium-261 decays.
-
18M.3.sl.TZ2.b:
Dubnium-261 has a half-life of 27 seconds and rutherfordium-261 has a half-life of 81 seconds.
Estimate what fraction of the dubnium-261 isotope remains in the same amount of time that of rutherfordium-261 decays.
-
18M.3.sl.TZ2.14b:
Outline why the ester product of this reaction is a better diesel fuel than pentyl octanoate.
-
18M.3.sl.TZ2.14b:
Outline why the ester product of this reaction is a better diesel fuel than pentyl octanoate.
-
18M.3.sl.TZ2.b:
Outline why the ester product of this reaction is a better diesel fuel than pentyl octanoate.
-
18M.3.sl.TZ2.16a.i:
Describe how penicillin combats bacterial infections.
-
18M.3.sl.TZ2.16a.i:
Describe how penicillin combats bacterial infections.
-
18M.3.sl.TZ2.a.i:
Describe how penicillin combats bacterial infections.
-
18M.3.sl.TZ2.16a.ii:
State how penicillins may be modified to increase their effectiveness.
-
18M.3.sl.TZ2.a.ii:
State how penicillins may be modified to increase their effectiveness.
-
18M.3.sl.TZ2.16a.ii:
State how penicillins may be modified to increase their effectiveness.
-
18M.3.sl.TZ2.18a:
Formulate a chemical equation for the neutralization of stomach acid with calcium carbonate.
-
18M.3.sl.TZ2.18a:
Formulate a chemical equation for the neutralization of stomach acid with calcium carbonate.
-
18M.3.sl.TZ2.a:
Formulate a chemical equation for the neutralization of stomach acid with calcium carbonate.
-
18M.3.sl.TZ2.18b:
Calculate the amount, in mol, of stomach acid neutralized by an antacid tablet containing 0.750 g calcium carbonate.
-
18M.3.sl.TZ2.18b:
Calculate the amount, in mol, of stomach acid neutralized by an antacid tablet containing 0.750 g calcium carbonate.
-
18M.3.sl.TZ2.b:
Calculate the amount, in mol, of stomach acid neutralized by an antacid tablet containing 0.750 g calcium carbonate.
-
18M.3.sl.TZ2.19a:
Identify the names of two functional groups present in zanamivir using section 37 of the data booklet.
-
18M.3.sl.TZ2.19a:
Identify the names of two functional groups present in zanamivir using section 37 of the data booklet.
-
18M.3.sl.TZ2.a:
Identify the names of two functional groups present in zanamivir using section 37 of the data booklet.
-
18M.3.sl.TZ2.19b:
Distinguish between bacteria and viruses.
-
18M.3.sl.TZ2.19b:
Distinguish between bacteria and viruses.
-
18M.3.sl.TZ2.b:
Distinguish between bacteria and viruses.
- 18N.3.sl.TZ0.6a: Describe the interaction responsible for the secondary structure of a protein.
- 18N.3.sl.TZ0.6a: Describe the interaction responsible for the secondary structure of a protein.
- 18N.3.sl.TZ0.a: Describe the interaction responsible for the secondary structure of a protein.
-
18N.3.sl.TZ0.15a:
State one way in which viruses differ from bacteria.
-
18N.3.sl.TZ0.15a:
State one way in which viruses differ from bacteria.
-
18N.3.sl.TZ0.a:
State one way in which viruses differ from bacteria.
-
18N.3.sl.TZ0.10a:
Formulate equation(s) for the conversion of coal and steam to methane.
-
18N.3.sl.TZ0.10a:
Formulate equation(s) for the conversion of coal and steam to methane.
-
18N.3.sl.TZ0.a:
Formulate equation(s) for the conversion of coal and steam to methane.
- 18N.3.sl.TZ0.13c: Outline the meaning of the bioavailability of a drug.
- 18N.3.sl.TZ0.13c: Outline the meaning of the bioavailability of a drug.
- 18N.3.sl.TZ0.c: Outline the meaning of the bioavailability of a drug.
-
18N.3.hl.TZ0.2b:
Structures of poly(methyl acrylate), PMA, and Bakelite® are shown.
Suggest, giving reasons, which is the thermoplastic polymer and which is the thermosetting polymer.
-
18N.3.hl.TZ0.2b:
Structures of poly(methyl acrylate), PMA, and Bakelite® are shown.
Suggest, giving reasons, which is the thermoplastic polymer and which is the thermosetting polymer.
-
18N.3.hl.TZ0.b:
Structures of poly(methyl acrylate), PMA, and Bakelite® are shown.
Suggest, giving reasons, which is the thermoplastic polymer and which is the thermosetting polymer.
- 18N.3.hl.TZ0.10c.i: Outline the difference between their structures.
- 18N.3.hl.TZ0.10c.i: Outline the difference between their structures.
- 18N.3.hl.TZ0.c.i: Outline the difference between their structures.
- 18N.3.sl.TZ0.5a: The formation of proteins from amino acids is an example of an anabolic reaction in the human...
- 18N.3.sl.TZ0.5a: The formation of proteins from amino acids is an example of an anabolic reaction in the human...
- 18N.3.sl.TZ0.a: The formation of proteins from amino acids is an example of an anabolic reaction in the human...
-
18N.3.sl.TZ0.14a:
Determine the pH of a buffer solution that is 0.0100 mol dm−3 sodium hydrogen carbonate and 0.0200 mol dm−3 sodium carbonate, using section 1 of the data booklet.
Ka (hydrogen carbonate ion) = 4.8 × 10−11
-
18N.3.sl.TZ0.14a:
Determine the pH of a buffer solution that is 0.0100 mol dm−3 sodium hydrogen carbonate and 0.0200 mol dm−3 sodium carbonate, using section 1 of the data booklet.
Ka (hydrogen carbonate ion) = 4.8 × 10−11
-
18N.3.sl.TZ0.a:
Determine the pH of a buffer solution that is 0.0100 mol dm−3 sodium hydrogen carbonate and 0.0200 mol dm−3 sodium carbonate, using section 1 of the data booklet.
Ka (hydrogen carbonate ion) = 4.8 × 10−11
-
18N.3.sl.TZ0.16:
Suggest two reasons why chlorinated solvents should neither be released into the atmosphere nor incinerated (burnt).
-
18N.3.sl.TZ0.16:
Suggest two reasons why chlorinated solvents should neither be released into the atmosphere nor incinerated (burnt).
-
18N.3.sl.TZ0.2b.ii:
In an incomplete combustion of the polyvinyl chloride, PVC, it was found that hydrogen chloride, carbon monoxide, carbon dioxide, and water vapour were released.
Formulate an equation for this reaction using the formula of the PVC repeating unit.
-
18N.3.sl.TZ0.2b.ii:
In an incomplete combustion of the polyvinyl chloride, PVC, it was found that hydrogen chloride, carbon monoxide, carbon dioxide, and water vapour were released.
Formulate an equation for this reaction using the formula of the PVC repeating unit.
-
18N.3.sl.TZ0.b.ii:
In an incomplete combustion of the polyvinyl chloride, PVC, it was found that hydrogen chloride, carbon monoxide, carbon dioxide, and water vapour were released.
Formulate an equation for this reaction using the formula of the PVC repeating unit.
-
18N.3.hl.TZ0.13a:
Formulate equation(s) for the conversion of coal and steam to methane.
-
18N.3.hl.TZ0.13a:
Formulate equation(s) for the conversion of coal and steam to methane.
-
18N.3.hl.TZ0.a:
Formulate equation(s) for the conversion of coal and steam to methane.
-
18N.3.hl.TZ0.15d.iv:
Deduce the reduction half-equation at the cathode.
-
18N.3.hl.TZ0.15d.iv:
Deduce the reduction half-equation at the cathode.
-
18N.3.hl.TZ0.d.iv:
Deduce the reduction half-equation at the cathode.
-
18N.3.sl.TZ0.3c:
Electrolysis is used to obtain lead from Pb2+ (aq) solution.
Determine the time, in hours, required to produce 0.0500 mol lead using a current (I) of 1.34 A. Use section 2 of the data booklet and the equation, charge (Q) = current (I) × time (t, in seconds).
-
18N.3.sl.TZ0.3c:
Electrolysis is used to obtain lead from Pb2+ (aq) solution.
Determine the time, in hours, required to produce 0.0500 mol lead using a current (I) of 1.34 A. Use section 2 of the data booklet and the equation, charge (Q) = current (I) × time (t, in seconds).
-
18N.3.sl.TZ0.c:
Electrolysis is used to obtain lead from Pb2+ (aq) solution.
Determine the time, in hours, required to produce 0.0500 mol lead using a current (I) of 1.34 A. Use section 2 of the data booklet and the equation, charge (Q) = current (I) × time (t, in seconds).
- 18N.3.sl.TZ0.7c: Outline one effect of increased levels of low-density lipoproteins in the blood.
- 18N.3.sl.TZ0.7c: Outline one effect of increased levels of low-density lipoproteins in the blood.
- 18N.3.sl.TZ0.c: Outline one effect of increased levels of low-density lipoproteins in the blood.
-
18N.3.sl.TZ0.9c:
Nuclear disasters release radioactive caesium into the atmosphere, which presents serious health risks.
Cs-137 has a half-life of 30 years.
Calculate the percentage of Cs-137 remaining in the atmosphere after 240 years.
-
18N.3.sl.TZ0.9c:
Nuclear disasters release radioactive caesium into the atmosphere, which presents serious health risks.
Cs-137 has a half-life of 30 years.
Calculate the percentage of Cs-137 remaining in the atmosphere after 240 years.
-
18N.3.sl.TZ0.c:
Nuclear disasters release radioactive caesium into the atmosphere, which presents serious health risks.
Cs-137 has a half-life of 30 years.
Calculate the percentage of Cs-137 remaining in the atmosphere after 240 years.
- 18N.3.hl.TZ0.10b: Outline how the two monomer structures, galactose and glucose, differ.
- 18N.3.hl.TZ0.10b: Outline how the two monomer structures, galactose and glucose, differ.
- 18N.3.hl.TZ0.b: Outline how the two monomer structures, galactose and glucose, differ.
-
18N.3.hl.TZ0.13c:
Calculate the mass, in kg, of carbon dioxide produced by the complete combustion of 72.0 dm3 octane, C8H18.
Density of C8H18 = 703 g dm−3
C8H18 (l) + 12.5O2 (g) → 8CO2 (g) + 9H2O (g)
-
18N.3.hl.TZ0.13c:
Calculate the mass, in kg, of carbon dioxide produced by the complete combustion of 72.0 dm3 octane, C8H18.
Density of C8H18 = 703 g dm−3
C8H18 (l) + 12.5O2 (g) → 8CO2 (g) + 9H2O (g)
-
18N.3.hl.TZ0.c:
Calculate the mass, in kg, of carbon dioxide produced by the complete combustion of 72.0 dm3 octane, C8H18.
Density of C8H18 = 703 g dm−3
C8H18 (l) + 12.5O2 (g) → 8CO2 (g) + 9H2O (g)
- 18N.3.sl.TZ0.12c: Outline one effect of over-prescription of penicillin.
- 18N.3.sl.TZ0.12c: Outline one effect of over-prescription of penicillin.
- 18N.3.sl.TZ0.c: Outline one effect of over-prescription of penicillin.
- 18N.3.sl.TZ0.11a: Suggest another advantage and one disadvantage of solar energy.
- 18N.3.sl.TZ0.11a: Suggest another advantage and one disadvantage of solar energy.
- 18N.3.sl.TZ0.a: Suggest another advantage and one disadvantage of solar energy.
- 18N.3.hl.TZ0.15d.ii: Outline the effect of sunlight on the dye in the solar cell.
- 18N.3.hl.TZ0.15d.ii: Outline the effect of sunlight on the dye in the solar cell.
- 18N.3.hl.TZ0.d.ii: Outline the effect of sunlight on the dye in the solar cell.
- 18N.3.hl.TZ0.17b: Outline the meaning of the bioavailability of a drug.
- 18N.3.hl.TZ0.17b: Outline the meaning of the bioavailability of a drug.
- 18N.3.hl.TZ0.b: Outline the meaning of the bioavailability of a drug.
-
18N.3.sl.TZ0.3b:
An unknown antacid sample has a lead ion concentration of 0.50 μg dm‒3.
Calculate the concentration of lead ions in the sample in mol dm‒3.
-
18N.3.sl.TZ0.3b:
An unknown antacid sample has a lead ion concentration of 0.50 μg dm‒3.
Calculate the concentration of lead ions in the sample in mol dm‒3.
-
18N.3.sl.TZ0.b:
An unknown antacid sample has a lead ion concentration of 0.50 μg dm‒3.
Calculate the concentration of lead ions in the sample in mol dm‒3.
- 18N.3.sl.TZ0.9b.i: Outline why the term breeder is used for the reactors.
- 18N.3.sl.TZ0.9b.i: Outline why the term breeder is used for the reactors.
- 18N.3.sl.TZ0.b.i: Outline why the term breeder is used for the reactors.
- 18N.3.hl.TZ0.7a: State the feature of DNA that determines the primary structure of proteins synthesised by a cell.
- 18N.3.hl.TZ0.7a: State the feature of DNA that determines the primary structure of proteins synthesised by a cell.
- 18N.3.hl.TZ0.a: State the feature of DNA that determines the primary structure of proteins synthesised by a cell.
- 18N.3.hl.TZ0.16b: Explain how the open β-lactam ring kills bacteria.
- 18N.3.hl.TZ0.16b: Explain how the open β-lactam ring kills bacteria.
- 18N.3.hl.TZ0.b: Explain how the open β-lactam ring kills bacteria.
- 18N.3.sl.TZ0.2c.i: A zeolite is an alternative catalyst for this reaction. Explain how zeolites act as selective...
- 18N.3.sl.TZ0.2c.i: A zeolite is an alternative catalyst for this reaction. Explain how zeolites act as selective...
- 18N.3.sl.TZ0.c.i: A zeolite is an alternative catalyst for this reaction. Explain how zeolites act as selective...
-
18N.3.hl.TZ0.11b:
Explain why carbon monoxide is very toxic and how it may be possible to treat carbon monoxide poisoning.
-
18N.3.hl.TZ0.11b:
Explain why carbon monoxide is very toxic and how it may be possible to treat carbon monoxide poisoning.
-
18N.3.hl.TZ0.b:
Explain why carbon monoxide is very toxic and how it may be possible to treat carbon monoxide poisoning.
-
18N.3.sl.TZ0.11e:
Explain, using an equation, the effect of increased carbon dioxide in the atmosphere on the pH of lake water.
-
18N.3.sl.TZ0.11e:
Explain, using an equation, the effect of increased carbon dioxide in the atmosphere on the pH of lake water.
-
18N.3.sl.TZ0.e:
Explain, using an equation, the effect of increased carbon dioxide in the atmosphere on the pH of lake water.
-
18N.3.sl.TZ0.14b:
State the equation for the reaction of calcium carbonate, the active ingredient in some antacids, with stomach acid.
-
18N.3.sl.TZ0.14b:
State the equation for the reaction of calcium carbonate, the active ingredient in some antacids, with stomach acid.
-
18N.3.sl.TZ0.b:
State the equation for the reaction of calcium carbonate, the active ingredient in some antacids, with stomach acid.
-
18N.3.hl.TZ0.3d.ii:
An aqueous lead(II) ion reacts with three ethane-1,2-diamine molecules to form an octahedral chelate ion.
Outline why the chelate ion is more stable than the reactants.
-
18N.3.hl.TZ0.3d.ii:
An aqueous lead(II) ion reacts with three ethane-1,2-diamine molecules to form an octahedral chelate ion.
Outline why the chelate ion is more stable than the reactants.
-
18N.3.hl.TZ0.d.ii:
An aqueous lead(II) ion reacts with three ethane-1,2-diamine molecules to form an octahedral chelate ion.
Outline why the chelate ion is more stable than the reactants.
-
18N.3.hl.TZ0.22b.ii:
Suggest why the percentage of technetium-99m remaining in the human body two days after injection will be lower than that calculated in (b)(i).
-
18N.3.hl.TZ0.22b.ii:
Suggest why the percentage of technetium-99m remaining in the human body two days after injection will be lower than that calculated in (b)(i).
-
18N.3.hl.TZ0.b.ii:
Suggest why the percentage of technetium-99m remaining in the human body two days after injection will be lower than that calculated in (b)(i).
-
18N.3.sl.TZ0.10b.ii:
Comment on the specific energies of hydrogen and methane.
-
18N.3.sl.TZ0.10b.ii:
Comment on the specific energies of hydrogen and methane.
-
18N.3.sl.TZ0.b.ii:
Comment on the specific energies of hydrogen and methane.
-
18N.3.sl.TZ0.10b.i:
Calculate the specific energy, in kJ g−1, of methane.
-
18N.3.sl.TZ0.10b.i:
Calculate the specific energy, in kJ g−1, of methane.
-
18N.3.sl.TZ0.b.i:
Calculate the specific energy, in kJ g−1, of methane.
- 18N.3.sl.TZ0.12a: State the internal bond angles in the β-lactam ring and the expected bond angles for the same...
- 18N.3.sl.TZ0.12a: State the internal bond angles in the β-lactam ring and the expected bond angles for the same...
- 18N.3.sl.TZ0.a: State the internal bond angles in the β-lactam ring and the expected bond angles for the same...
- 18N.3.sl.TZ0.12e: Suggest why human cells are not affected by penicillin.
- 18N.3.sl.TZ0.12e: Suggest why human cells are not affected by penicillin.
- 18N.3.sl.TZ0.e: Suggest why human cells are not affected by penicillin.
- 18N.3.hl.TZ0.8b: Explain the action of an enzyme and state one of its limitations.
- 18N.3.hl.TZ0.8b: Explain the action of an enzyme and state one of its limitations.
- 18N.3.hl.TZ0.b: Explain the action of an enzyme and state one of its limitations.
-
18N.3.hl.TZ0.14d:
Explain, using an equation, the effect of increased carbon dioxide in the atmosphere on the pH of lake water.
-
18N.3.hl.TZ0.14d:
Explain, using an equation, the effect of increased carbon dioxide in the atmosphere on the pH of lake water.
-
18N.3.hl.TZ0.d:
Explain, using an equation, the effect of increased carbon dioxide in the atmosphere on the pH of lake water.
- 18N.3.sl.TZ0.11c.i: State a physical property of vegetable oils that makes them very difficult to use as fuel in...
- 18N.3.sl.TZ0.11c.i: State a physical property of vegetable oils that makes them very difficult to use as fuel in...
- 18N.3.sl.TZ0.c.i: State a physical property of vegetable oils that makes them very difficult to use as fuel in...
- 18N.3.sl.TZ0.12b: Explain how the open β-lactam ring kills bacteria.
- 18N.3.sl.TZ0.12b: Explain how the open β-lactam ring kills bacteria.
- 18N.3.sl.TZ0.b: Explain how the open β-lactam ring kills bacteria.
- 18N.3.sl.TZ0.12d: State how the structure of penicillin can be changed to combat this effect.
- 18N.3.sl.TZ0.12d: State how the structure of penicillin can be changed to combat this effect.
- 18N.3.sl.TZ0.d: State how the structure of penicillin can be changed to combat this effect.
- 18N.3.sl.TZ0.14c: Suggest a technique for measuring the percentage mass of calcium carbonate in this type of...
- 18N.3.sl.TZ0.14c: Suggest a technique for measuring the percentage mass of calcium carbonate in this type of...
- 18N.3.sl.TZ0.c: Suggest a technique for measuring the percentage mass of calcium carbonate in this type of...
-
18N.3.hl.TZ0.21a:
The diagram shows part of a Taxol molecule in skeletal form.
Draw a circle around each chiral carbon.
-
18N.3.hl.TZ0.21a:
The diagram shows part of a Taxol molecule in skeletal form.
Draw a circle around each chiral carbon.
-
18N.3.hl.TZ0.a:
The diagram shows part of a Taxol molecule in skeletal form.
Draw a circle around each chiral carbon.
- 18N.3.sl.TZ0.6b.ii: Enzymes are widely used in washing detergents. Outline how they improve the efficiency of the...
- 18N.3.sl.TZ0.6b.ii: Enzymes are widely used in washing detergents. Outline how they improve the efficiency of the...
- 18N.3.sl.TZ0.b.ii: Enzymes are widely used in washing detergents. Outline how they improve the efficiency of the...
-
18N.3.sl.TZ0.7b.i:
The iodine number is the maximum mass of iodine that reacts with 100 g of an unsaturated compound.
Determine the iodine number of stearidonic acid, C17H27COOH.
-
18N.3.sl.TZ0.7b.i:
The iodine number is the maximum mass of iodine that reacts with 100 g of an unsaturated compound.
Determine the iodine number of stearidonic acid, C17H27COOH.
-
18N.3.sl.TZ0.b.i:
The iodine number is the maximum mass of iodine that reacts with 100 g of an unsaturated compound.
Determine the iodine number of stearidonic acid, C17H27COOH.
- 18N.3.hl.TZ0.11a: A graph showing saturation of oxygen against partial pressure of oxygen is shown. Explain the...
- 18N.3.hl.TZ0.11a: A graph showing saturation of oxygen against partial pressure of oxygen is shown. Explain the...
- 18N.3.hl.TZ0.a: A graph showing saturation of oxygen against partial pressure of oxygen is shown. Explain the...
-
18N.3.sl.TZ0.2a:
Outline why this type of classification is not entirely satisfactory by using magnesium diboride, MgB2, as an example. Refer to sections 8 and 29 of the data booklet.
-
18N.3.sl.TZ0.2a:
Outline why this type of classification is not entirely satisfactory by using magnesium diboride, MgB2, as an example. Refer to sections 8 and 29 of the data booklet.
-
18N.3.sl.TZ0.a:
Outline why this type of classification is not entirely satisfactory by using magnesium diboride, MgB2, as an example. Refer to sections 8 and 29 of the data booklet.
-
18N.3.sl.TZ0.4c:
Arc discharge, consisting of two inert metal electrodes in a liquid solvent, is one method of producing carbon nanotubes (CNTs).
Predict, giving a reason, the electrode at which the solvent cyclohexane, C6H12, will decompose to form CNTs.
-
18N.3.sl.TZ0.4c:
Arc discharge, consisting of two inert metal electrodes in a liquid solvent, is one method of producing carbon nanotubes (CNTs).
Predict, giving a reason, the electrode at which the solvent cyclohexane, C6H12, will decompose to form CNTs.
-
18N.3.sl.TZ0.c:
Arc discharge, consisting of two inert metal electrodes in a liquid solvent, is one method of producing carbon nanotubes (CNTs).
Predict, giving a reason, the electrode at which the solvent cyclohexane, C6H12, will decompose to form CNTs.
- 18N.3.sl.TZ0.8a: Name the type of link between the two monosaccharide residues.
- 18N.3.sl.TZ0.8a: Name the type of link between the two monosaccharide residues.
- 18N.3.sl.TZ0.a: Name the type of link between the two monosaccharide residues.
- 18N.3.sl.TZ0.11d: Contrast the importance of carbon dioxide and methane as greenhouse gases.
- 18N.3.sl.TZ0.11d: Contrast the importance of carbon dioxide and methane as greenhouse gases.
- 18N.3.sl.TZ0.d: Contrast the importance of carbon dioxide and methane as greenhouse gases.
-
18N.3.sl.TZ0.13a:
Explain why diamorphine (heroin) crosses the blood–brain barrier more easily than morphine.
-
18N.3.sl.TZ0.13a:
Explain why diamorphine (heroin) crosses the blood–brain barrier more easily than morphine.
-
18N.3.sl.TZ0.a:
Explain why diamorphine (heroin) crosses the blood–brain barrier more easily than morphine.
-
18N.3.hl.TZ0.2a:
Outline why this type of classification is not entirely satisfactory by using magnesium diboride, MgB2, as an example. Refer to sections 8 and 29 of the data booklet.
-
18N.3.hl.TZ0.2a:
Outline why this type of classification is not entirely satisfactory by using magnesium diboride, MgB2, as an example. Refer to sections 8 and 29 of the data booklet.
-
18N.3.hl.TZ0.a:
Outline why this type of classification is not entirely satisfactory by using magnesium diboride, MgB2, as an example. Refer to sections 8 and 29 of the data booklet.
- 18N.3.hl.TZ0.2d.i: State the names of the two terminal functional groups in X.
- 18N.3.hl.TZ0.2d.i: State the names of the two terminal functional groups in X.
- 18N.3.hl.TZ0.d.i: State the names of the two terminal functional groups in X.
- 18N.3.hl.TZ0.12d.ii: Explain why free radicals are harmful to living cells.
- 18N.3.hl.TZ0.12d.ii: Explain why free radicals are harmful to living cells.
- 18N.3.hl.TZ0.d.ii: Explain why free radicals are harmful to living cells.
-
18N.3.hl.TZ0.13b:
Comment on the specific energies of hydrogen and methane.
-
18N.3.hl.TZ0.13b:
Comment on the specific energies of hydrogen and methane.
-
18N.3.hl.TZ0.b:
Comment on the specific energies of hydrogen and methane.
-
18N.3.hl.TZ0.15c:
A voltaic cell consists of a nickel electrode in 1.0 mol dm−3 Ni2+ (aq) solution and a cadmium electrode in a Cd2+ (aq) solution of unknown concentration.
Cd (s) + Ni2+ (aq) → Cd2+ (aq) + Ni (s) EΘcell = 0.14 V
Determine the concentration of the Cd2+ (aq) solution if the cell voltage, E, is 0.19 V at 298 K. Use section 1 of the data booklet.
-
18N.3.hl.TZ0.15c:
A voltaic cell consists of a nickel electrode in 1.0 mol dm−3 Ni2+ (aq) solution and a cadmium electrode in a Cd2+ (aq) solution of unknown concentration.
Cd (s) + Ni2+ (aq) → Cd2+ (aq) + Ni (s) EΘcell = 0.14 V
Determine the concentration of the Cd2+ (aq) solution if the cell voltage, E, is 0.19 V at 298 K. Use section 1 of the data booklet.
-
18N.3.hl.TZ0.c:
A voltaic cell consists of a nickel electrode in 1.0 mol dm−3 Ni2+ (aq) solution and a cadmium electrode in a Cd2+ (aq) solution of unknown concentration.
Cd (s) + Ni2+ (aq) → Cd2+ (aq) + Ni (s) EΘcell = 0.14 V
Determine the concentration of the Cd2+ (aq) solution if the cell voltage, E, is 0.19 V at 298 K. Use section 1 of the data booklet.
- 18N.3.hl.TZ0.15d.i: Identify the structural feature of the dye that allows the conversion of solar energy into...
- 18N.3.hl.TZ0.15d.i: Identify the structural feature of the dye that allows the conversion of solar energy into...
- 18N.3.hl.TZ0.d.i: Identify the structural feature of the dye that allows the conversion of solar energy into...
- 18N.3.sl.TZ0.4a: Outline two observations that he could have made.
- 18N.3.sl.TZ0.4a: Outline two observations that he could have made.
- 18N.3.sl.TZ0.a: Outline two observations that he could have made.
- 18N.3.sl.TZ0.7b.ii: State two functions of lipids in the body.
- 18N.3.sl.TZ0.7b.ii: State two functions of lipids in the body.
- 18N.3.sl.TZ0.b.ii: State two functions of lipids in the body.
-
18N.3.hl.TZ0.3c:
Electrolysis is used to obtain lead from Pb2+ (aq) solution.
Determine the time, in hours, required to produce 0.0500 mol lead using a current (I) of 1.34 A. Use section 2 of the data booklet and the equation, charge (Q) = current (I) × time (t, in seconds).
-
18N.3.hl.TZ0.3c:
Electrolysis is used to obtain lead from Pb2+ (aq) solution.
Determine the time, in hours, required to produce 0.0500 mol lead using a current (I) of 1.34 A. Use section 2 of the data booklet and the equation, charge (Q) = current (I) × time (t, in seconds).
-
18N.3.hl.TZ0.c:
Electrolysis is used to obtain lead from Pb2+ (aq) solution.
Determine the time, in hours, required to produce 0.0500 mol lead using a current (I) of 1.34 A. Use section 2 of the data booklet and the equation, charge (Q) = current (I) × time (t, in seconds).
-
18N.3.hl.TZ0.12d.i:
Deduce a Lewis (electron dot) structure of the superoxide, O2–, free radical.
-
18N.3.hl.TZ0.12d.i:
Deduce a Lewis (electron dot) structure of the superoxide, O2–, free radical.
-
18N.3.hl.TZ0.d.i:
Deduce a Lewis (electron dot) structure of the superoxide, O2–, free radical.
- 18N.3.sl.TZ0.7a: A phospholipid generally consists of two hydrophobic fatty acids and a hydrophilic...
- 18N.3.sl.TZ0.7a: A phospholipid generally consists of two hydrophobic fatty acids and a hydrophilic...
- 18N.3.sl.TZ0.a: A phospholipid generally consists of two hydrophobic fatty acids and a hydrophilic...
- 18N.3.sl.TZ0.11b: Light can be absorbed by chlorophyll and other pigments. Consider molecules A and B represented...
- 18N.3.sl.TZ0.11b: Light can be absorbed by chlorophyll and other pigments. Consider molecules A and B represented...
- 18N.3.sl.TZ0.b: Light can be absorbed by chlorophyll and other pigments. Consider molecules A and B represented...
- 18N.3.sl.TZ0.15b: Outline two different ways in which antiviral medications work.
- 18N.3.sl.TZ0.15b: Outline two different ways in which antiviral medications work.
- 18N.3.sl.TZ0.b: Outline two different ways in which antiviral medications work.
- 18N.3.hl.TZ0.14c: Contrast the importance of carbon dioxide and methane as greenhouse gases.
- 18N.3.hl.TZ0.14c: Contrast the importance of carbon dioxide and methane as greenhouse gases.
- 18N.3.hl.TZ0.c: Contrast the importance of carbon dioxide and methane as greenhouse gases.
-
18N.3.sl.TZ0.2d:
Repeating units of several polymers are listed.
The infrared (IR) spectrum of one of these polymers is shown.
Deduce, giving a reason, the name of this polymer and its Resin Identification Code (RIC), using sections 26 and 30 in the data booklet.
-
18N.3.sl.TZ0.2d:
Repeating units of several polymers are listed.
The infrared (IR) spectrum of one of these polymers is shown.
Deduce, giving a reason, the name of this polymer and its Resin Identification Code (RIC), using sections 26 and 30 in the data booklet.
-
18N.3.sl.TZ0.d:
Repeating units of several polymers are listed.
The infrared (IR) spectrum of one of these polymers is shown.
Deduce, giving a reason, the name of this polymer and its Resin Identification Code (RIC), using sections 26 and 30 in the data booklet.
- 18N.3.sl.TZ0.8b: Outline how the two monomer structures, galactose and glucose, differ.
- 18N.3.sl.TZ0.8b: Outline how the two monomer structures, galactose and glucose, differ.
- 18N.3.sl.TZ0.b: Outline how the two monomer structures, galactose and glucose, differ.
- 18N.3.sl.TZ0.11c.ii: Describe how vegetable oils can be converted to a more suitable fuel.
- 18N.3.sl.TZ0.11c.ii: Describe how vegetable oils can be converted to a more suitable fuel.
- 18N.3.sl.TZ0.c.ii: Describe how vegetable oils can be converted to a more suitable fuel.
- 18N.3.hl.TZ0.9c: Outline one effect of increased levels of low-density lipoproteins in the blood.
- 18N.3.hl.TZ0.9c: Outline one effect of increased levels of low-density lipoproteins in the blood.
- 18N.3.hl.TZ0.c: Outline one effect of increased levels of low-density lipoproteins in the blood.
- 18N.3.hl.TZ0.10a: Name the type of link between the two monosaccharide residues.
- 18N.3.hl.TZ0.10a: Name the type of link between the two monosaccharide residues.
- 18N.3.hl.TZ0.a: Name the type of link between the two monosaccharide residues.
- 18N.3.sl.TZ0.5c: Explain how a xenobiotic is biomagnified.
- 18N.3.sl.TZ0.5c: Explain how a xenobiotic is biomagnified.
- 18N.3.sl.TZ0.c: Explain how a xenobiotic is biomagnified.
- 18N.3.sl.TZ0.9a: Explain fusion reactions with reference to binding energy.
- 18N.3.sl.TZ0.9a: Explain fusion reactions with reference to binding energy.
- 18N.3.sl.TZ0.a: Explain fusion reactions with reference to binding energy.
- 18N.3.sl.TZ0.13b: Describe the analgesic action of an opiate.
- 18N.3.sl.TZ0.13b: Describe the analgesic action of an opiate.
- 18N.3.sl.TZ0.b: Describe the analgesic action of an opiate.
- 18N.3.hl.TZ0.2c: A zeolite is an alternative catalyst for this reaction. Explain how zeolites act as selective...
- 18N.3.hl.TZ0.2c: A zeolite is an alternative catalyst for this reaction. Explain how zeolites act as selective...
- 18N.3.hl.TZ0.c: A zeolite is an alternative catalyst for this reaction. Explain how zeolites act as selective...
- 18N.3.sl.TZ0.3a: State the type of particle present in the plasma formed.
- 18N.3.sl.TZ0.3a: State the type of particle present in the plasma formed.
- 18N.3.sl.TZ0.a: State the type of particle present in the plasma formed.
- 18N.3.hl.TZ0.7b: Suggest one concern about the use of genetically modified, GM, food.
- 18N.3.hl.TZ0.7b: Suggest one concern about the use of genetically modified, GM, food.
- 18N.3.hl.TZ0.b: Suggest one concern about the use of genetically modified, GM, food.
- 18N.3.hl.TZ0.10c.ii: Outline why cellulose is an essential part of human diet.
- 18N.3.hl.TZ0.10c.ii: Outline why cellulose is an essential part of human diet.
- 18N.3.hl.TZ0.c.ii: Outline why cellulose is an essential part of human diet.
-
18N.3.sl.TZ0.10c:
Calculate the mass, in kg, of carbon dioxide produced by the complete combustion of 72.0 dm3 octane, C8H18.
Density of C8H18 = 703 g dm−3
C8H18 (l) + 12.5O2 (g) → 8CO2 (g) + 9H2O (g)
-
18N.3.sl.TZ0.10c:
Calculate the mass, in kg, of carbon dioxide produced by the complete combustion of 72.0 dm3 octane, C8H18.
Density of C8H18 = 703 g dm−3
C8H18 (l) + 12.5O2 (g) → 8CO2 (g) + 9H2O (g)
-
18N.3.sl.TZ0.c:
Calculate the mass, in kg, of carbon dioxide produced by the complete combustion of 72.0 dm3 octane, C8H18.
Density of C8H18 = 703 g dm−3
C8H18 (l) + 12.5O2 (g) → 8CO2 (g) + 9H2O (g)
- 18N.3.hl.TZ0.12a: Explain fusion reactions with reference to binding energy.
- 18N.3.hl.TZ0.12a: Explain fusion reactions with reference to binding energy.
- 18N.3.hl.TZ0.a: Explain fusion reactions with reference to binding energy.
-
18N.3.hl.TZ0.12c:
Nuclear disasters release radioactive caesium into the atmosphere, which presents serious health risks.
Cs-137 has a half-life of 30 years.
Calculate the percentage of Cs-137 remaining in the atmosphere after 240 years.
-
18N.3.hl.TZ0.12c:
Nuclear disasters release radioactive caesium into the atmosphere, which presents serious health risks.
Cs-137 has a half-life of 30 years.
Calculate the percentage of Cs-137 remaining in the atmosphere after 240 years.
-
18N.3.hl.TZ0.c:
Nuclear disasters release radioactive caesium into the atmosphere, which presents serious health risks.
Cs-137 has a half-life of 30 years.
Calculate the percentage of Cs-137 remaining in the atmosphere after 240 years.
- 18N.3.hl.TZ0.16c: State how the structure of penicillin can be modified to combat the effect of resistance caused...
- 18N.3.hl.TZ0.16c: State how the structure of penicillin can be modified to combat the effect of resistance caused...
- 18N.3.hl.TZ0.c: State how the structure of penicillin can be modified to combat the effect of resistance caused...
-
18N.3.hl.TZ0.23a:
State an analytical technique used to separate anabolic steroids from other compounds in an athlete’s urine or blood.
-
18N.3.hl.TZ0.23a:
State an analytical technique used to separate anabolic steroids from other compounds in an athlete’s urine or blood.
-
18N.3.hl.TZ0.a:
State an analytical technique used to separate anabolic steroids from other compounds in an athlete’s urine or blood.
-
18N.3.hl.TZ0.23b:
Ethanol in breath can be detected by a redox reaction. Outline this method of detection. An equation is not required.
-
18N.3.hl.TZ0.23b:
Ethanol in breath can be detected by a redox reaction. Outline this method of detection. An equation is not required.
-
18N.3.hl.TZ0.b:
Ethanol in breath can be detected by a redox reaction. Outline this method of detection. An equation is not required.
- 18N.3.hl.TZ0.2d.ii: Deduce the repeating unit of the polymer of X.
- 18N.3.hl.TZ0.2d.ii: Deduce the repeating unit of the polymer of X.
- 18N.3.hl.TZ0.d.ii: Deduce the repeating unit of the polymer of X.
-
18N.3.hl.TZ0.3b.i:
Calculate the concentration of lead ions in the sample in mol dm‒3.
-
18N.3.hl.TZ0.3b.i:
Calculate the concentration of lead ions in the sample in mol dm‒3.
-
18N.3.hl.TZ0.b.i:
Calculate the concentration of lead ions in the sample in mol dm‒3.
-
18N.3.hl.TZ0.3b.ii:
Lead ions are toxic and can be precipitated using hydroxide ions.
Pb2+ (aq) + 2OH‒ (aq) Pb(OH)2 (s)
Sufficient sodium hydroxide solid is added to the antacid sample to produce a 1.0 × 10‒2 mol dm‒3 hydroxide ion solution at 298 K.
Deduce if a precipitate will be formed, using section 32 of the data booklet.
If you did not calculate the concentration of lead ions in (b)(i), use the value of 2.4 × 10−4 mol dm‒3, but this is not the correct value.
-
18N.3.hl.TZ0.3b.ii:
Lead ions are toxic and can be precipitated using hydroxide ions.
Pb2+ (aq) + 2OH‒ (aq) Pb(OH)2 (s)
Sufficient sodium hydroxide solid is added to the antacid sample to produce a 1.0 × 10‒2 mol dm‒3 hydroxide ion solution at 298 K.
Deduce if a precipitate will be formed, using section 32 of the data booklet.
If you did not calculate the concentration of lead ions in (b)(i), use the value of 2.4 × 10−4 mol dm‒3, but this is not the correct value.
-
18N.3.hl.TZ0.b.ii:
Lead ions are toxic and can be precipitated using hydroxide ions.
Pb2+ (aq) + 2OH‒ (aq) Pb(OH)2 (s)
Sufficient sodium hydroxide solid is added to the antacid sample to produce a 1.0 × 10‒2 mol dm‒3 hydroxide ion solution at 298 K.
Deduce if a precipitate will be formed, using section 32 of the data booklet.
If you did not calculate the concentration of lead ions in (b)(i), use the value of 2.4 × 10−4 mol dm‒3, but this is not the correct value.
- 18N.3.hl.TZ0.14b.i: State a physical property of vegetable oils that makes them very difficult to use as fuel in...
- 18N.3.hl.TZ0.14b.i: State a physical property of vegetable oils that makes them very difficult to use as fuel in...
- 18N.3.hl.TZ0.b.i: State a physical property of vegetable oils that makes them very difficult to use as fuel in...
-
18N.3.hl.TZ0.17a:
Explain why diamorphine (heroin) crosses the blood–brain barrier more easily than morphine.
-
18N.3.hl.TZ0.17a:
Explain why diamorphine (heroin) crosses the blood–brain barrier more easily than morphine.
-
18N.3.hl.TZ0.a:
Explain why diamorphine (heroin) crosses the blood–brain barrier more easily than morphine.
-
18N.3.hl.TZ0.22a:
Alpha particles are more damaging to human cells than any other nuclear radiation and yet they are used in targeted alpha therapy (TAT).
Explain how TAT is relatively safe to use in the treatment of dispersed cancers.
-
18N.3.hl.TZ0.22a:
Alpha particles are more damaging to human cells than any other nuclear radiation and yet they are used in targeted alpha therapy (TAT).
Explain how TAT is relatively safe to use in the treatment of dispersed cancers.
-
18N.3.hl.TZ0.a:
Alpha particles are more damaging to human cells than any other nuclear radiation and yet they are used in targeted alpha therapy (TAT).
Explain how TAT is relatively safe to use in the treatment of dispersed cancers.
- 18N.3.hl.TZ0.3a: State the type of particle present in the plasma formed.
- 18N.3.hl.TZ0.3a: State the type of particle present in the plasma formed.
- 18N.3.hl.TZ0.a: State the type of particle present in the plasma formed.
- 18N.3.hl.TZ0.15d.iii: State the purpose of TiO2.
- 18N.3.hl.TZ0.15d.iii: State the purpose of TiO2.
- 18N.3.hl.TZ0.d.iii: State the purpose of TiO2.
-
18N.3.hl.TZ0.5a.ii:
Calculate the number of atoms per unit cell of gold, showing your working.
-
18N.3.hl.TZ0.5a.ii:
Calculate the number of atoms per unit cell of gold, showing your working.
-
18N.3.hl.TZ0.a.ii:
Calculate the number of atoms per unit cell of gold, showing your working.
- 18N.3.hl.TZ0.12b.i: Outline why the term breeder is used for the reactors.
- 18N.3.hl.TZ0.12b.i: Outline why the term breeder is used for the reactors.
- 18N.3.hl.TZ0.b.i: Outline why the term breeder is used for the reactors.
- 18N.3.hl.TZ0.16a: State the internal bond angles in the b-lactam ring and the expected bond angles in sp2 and sp3...
- 18N.3.hl.TZ0.16a: State the internal bond angles in the b-lactam ring and the expected bond angles in sp2 and sp3...
- 18N.3.hl.TZ0.a: State the internal bond angles in the b-lactam ring and the expected bond angles in sp2 and sp3...
-
18N.3.hl.TZ0.15b:
Formulate half-equations for the reactions at the anode (negative electrode) and cathode (positive electrode) during discharge of a lithium-ion battery.
-
18N.3.hl.TZ0.15b:
Formulate half-equations for the reactions at the anode (negative electrode) and cathode (positive electrode) during discharge of a lithium-ion battery.
-
18N.3.hl.TZ0.b:
Formulate half-equations for the reactions at the anode (negative electrode) and cathode (positive electrode) during discharge of a lithium-ion battery.
- 18N.3.hl.TZ0.16d: Suggest why human cells are not affected by penicillin.
- 18N.3.hl.TZ0.16d: Suggest why human cells are not affected by penicillin.
- 18N.3.hl.TZ0.d: Suggest why human cells are not affected by penicillin.
- 18N.3.hl.TZ0.19: Outline two different ways in which antiviral medications work.
- 18N.3.hl.TZ0.19: Outline two different ways in which antiviral medications work.
- 18N.3.hl.TZ0.12b.ii: Deduce the fission reaction when 239Pu is bombarded with a neutron to produce 133Xe and 103Zr.
- 18N.3.hl.TZ0.12b.ii: Deduce the fission reaction when 239Pu is bombarded with a neutron to produce 133Xe and 103Zr.
- 18N.3.hl.TZ0.b.ii: Deduce the fission reaction when 239Pu is bombarded with a neutron to produce 133Xe and 103Zr.
- 18N.3.hl.TZ0.5a.i: State the name of the crystal structure of gold.
- 18N.3.hl.TZ0.5a.i: State the name of the crystal structure of gold.
- 18N.3.hl.TZ0.a.i: State the name of the crystal structure of gold.
-
18N.3.hl.TZ0.5b:
The edge length of the gold unit cell is 4.08 × 10‒8 cm.
Determine the density of gold in g cm‒3, using sections 2 and 6 of the data booklet.
-
18N.3.hl.TZ0.5b:
The edge length of the gold unit cell is 4.08 × 10‒8 cm.
Determine the density of gold in g cm‒3, using sections 2 and 6 of the data booklet.
-
18N.3.hl.TZ0.b:
The edge length of the gold unit cell is 4.08 × 10‒8 cm.
Determine the density of gold in g cm‒3, using sections 2 and 6 of the data booklet.
-
18N.3.hl.TZ0.8c:
Contrast the actions of non-competitive and competitive inhibitors of an enzyme and state their effects on the maximum rate of reaction, Vmax, and the Michaelis–Menten constant, Km.
-
18N.3.hl.TZ0.8c:
Contrast the actions of non-competitive and competitive inhibitors of an enzyme and state their effects on the maximum rate of reaction, Vmax, and the Michaelis–Menten constant, Km.
-
18N.3.hl.TZ0.c:
Contrast the actions of non-competitive and competitive inhibitors of an enzyme and state their effects on the maximum rate of reaction, Vmax, and the Michaelis–Menten constant, Km.
-
18N.3.hl.TZ0.9a:
The iodine number is the maximum mass of iodine that reacts with 100 g of an unsaturated compound.
Determine the iodine number of stearidonic acid, C17H27COOH.
-
18N.3.hl.TZ0.9a:
The iodine number is the maximum mass of iodine that reacts with 100 g of an unsaturated compound.
Determine the iodine number of stearidonic acid, C17H27COOH.
-
18N.3.hl.TZ0.a:
The iodine number is the maximum mass of iodine that reacts with 100 g of an unsaturated compound.
Determine the iodine number of stearidonic acid, C17H27COOH.
- 18N.3.hl.TZ0.9b: State two functions of lipids in the body.
- 18N.3.hl.TZ0.9b: State two functions of lipids in the body.
- 18N.3.hl.TZ0.b: State two functions of lipids in the body.
- 18N.3.hl.TZ0.14b.ii: Describe how vegetable oils can be converted to a more suitable fuel.
- 18N.3.hl.TZ0.14b.ii: Describe how vegetable oils can be converted to a more suitable fuel.
- 18N.3.hl.TZ0.b.ii: Describe how vegetable oils can be converted to a more suitable fuel.
- 18N.3.hl.TZ0.15a: Outline how a rechargeable battery differs from a primary cell.
- 18N.3.hl.TZ0.15a: Outline how a rechargeable battery differs from a primary cell.
- 18N.3.hl.TZ0.a: Outline how a rechargeable battery differs from a primary cell.
- 18N.3.hl.TZ0.21b: Outline how chiral auxiliaries are used to synthesize the desired enantiomer.
- 18N.3.hl.TZ0.21b: Outline how chiral auxiliaries are used to synthesize the desired enantiomer.
- 18N.3.hl.TZ0.b: Outline how chiral auxiliaries are used to synthesize the desired enantiomer.
- 18N.3.hl.TZ0.21c: Explain the process of solvent extraction by which Taxol is isolated.
- 18N.3.hl.TZ0.21c: Explain the process of solvent extraction by which Taxol is isolated.
- 18N.3.hl.TZ0.c: Explain the process of solvent extraction by which Taxol is isolated.
-
18N.3.hl.TZ0.22b.i:
Technetium-99m () has a half-life of 6.0 hours. Calculate the percentage of remaining in a sample of the radioisotope after two days.
-
18N.3.hl.TZ0.22b.i:
Technetium-99m () has a half-life of 6.0 hours. Calculate the percentage of remaining in a sample of the radioisotope after two days.
-
18N.3.hl.TZ0.b.i:
Technetium-99m () has a half-life of 6.0 hours. Calculate the percentage of remaining in a sample of the radioisotope after two days.
-
19M.3.hl.TZ1.4e:
State one factor considered when making green chemistry polymers.
-
19M.3.hl.TZ1.4e:
State one factor considered when making green chemistry polymers.
-
19M.3.hl.TZ1.e:
State one factor considered when making green chemistry polymers.
-
19M.3.hl.TZ1.3e:
Lithium forms a crystalline lattice with the unit cell structure shown below.
X-ray diffraction shows that the length of the edge of the unit cell is 3.51 × 10−8 cm.
Determine the density of lithium, in g cm−3, using sections 2 and 6 of the data booklet.
-
19M.3.hl.TZ1.3e:
Lithium forms a crystalline lattice with the unit cell structure shown below.
X-ray diffraction shows that the length of the edge of the unit cell is 3.51 × 10−8 cm.
Determine the density of lithium, in g cm−3, using sections 2 and 6 of the data booklet.
-
19M.3.hl.TZ1.e:
Lithium forms a crystalline lattice with the unit cell structure shown below.
X-ray diffraction shows that the length of the edge of the unit cell is 3.51 × 10−8 cm.
Determine the density of lithium, in g cm−3, using sections 2 and 6 of the data booklet.
-
19M.3.hl.TZ1.5b:
Explain the effects of very low and high temperatures on the liquid-crystal behaviour of this molecule.
Low temperature:
High temperature:
-
19M.3.hl.TZ1.5b:
Explain the effects of very low and high temperatures on the liquid-crystal behaviour of this molecule.
Low temperature:
High temperature:
-
19M.3.hl.TZ1.b:
Explain the effects of very low and high temperatures on the liquid-crystal behaviour of this molecule.
Low temperature:
High temperature:
-
19M.3.hl.TZ1.4c:
Tyre fires emit trace quantities of polychlorinated dibenzofurans and polychlorinated dibenzo-p-dioxin.
Outline, using section 31 of the data booklet, why polychlorinated dibenzofuran is not classed chemically as a dioxin but considered “dioxin-like”.
-
19M.3.hl.TZ1.4c:
Tyre fires emit trace quantities of polychlorinated dibenzofurans and polychlorinated dibenzo-p-dioxin.
Outline, using section 31 of the data booklet, why polychlorinated dibenzofuran is not classed chemically as a dioxin but considered “dioxin-like”.
-
19M.3.hl.TZ1.c:
Tyre fires emit trace quantities of polychlorinated dibenzofurans and polychlorinated dibenzo-p-dioxin.
Outline, using section 31 of the data booklet, why polychlorinated dibenzofuran is not classed chemically as a dioxin but considered “dioxin-like”.
-
19M.3.hl.TZ1.3b(i):
Identify the colour of the emission spectrum of lithium using section 17 of the data booklet.
-
19M.3.hl.TZ1.3b(i):
Identify the colour of the emission spectrum of lithium using section 17 of the data booklet.
-
19M.3.hl.TZ1.b(i):
Identify the colour of the emission spectrum of lithium using section 17 of the data booklet.
-
19M.3.hl.TZ1.6b:
Suggest one application for carbon nanotubes.
-
19M.3.hl.TZ1.6b:
Suggest one application for carbon nanotubes.
-
19M.3.hl.TZ1.b:
Suggest one application for carbon nanotubes.
-
19M.3.hl.TZ1.4d:
Classify polybutadiene as either an addition or condensation polymer, giving a reason.
-
19M.3.hl.TZ1.4d:
Classify polybutadiene as either an addition or condensation polymer, giving a reason.
-
19M.3.hl.TZ1.d:
Classify polybutadiene as either an addition or condensation polymer, giving a reason.
-
19M.3.hl.TZ1.3b(iii):
Suggest a better method.
-
19M.3.hl.TZ1.3b(iii):
Suggest a better method.
-
19M.3.hl.TZ1.b(iii):
Suggest a better method.
-
19M.3.hl.TZ1.9a:
Draw a circle around the functional group formed between the amino acids and state its name.
Name:
-
19M.3.hl.TZ1.9a:
Draw a circle around the functional group formed between the amino acids and state its name.
Name:
-
19M.3.hl.TZ1.a:
Draw a circle around the functional group formed between the amino acids and state its name.
Name:
-
19M.3.hl.TZ1.9b:
A mixture of phenylalanine and aspartic acid is separated by gel electrophoresis with a buffer of pH = 5.5.
Deduce their relative positions after electrophoresis, annotating them on the diagram. Use section 33 of the data booklet.
-
19M.3.hl.TZ1.9b:
A mixture of phenylalanine and aspartic acid is separated by gel electrophoresis with a buffer of pH = 5.5.
Deduce their relative positions after electrophoresis, annotating them on the diagram. Use section 33 of the data booklet.
-
19M.3.hl.TZ1.b:
A mixture of phenylalanine and aspartic acid is separated by gel electrophoresis with a buffer of pH = 5.5.
Deduce their relative positions after electrophoresis, annotating them on the diagram. Use section 33 of the data booklet.
-
19M.3.hl.TZ1.12a(i):
A Michaelis–Menten plot for an enzyme-catalysed reaction is shown.
Sketch a curve to show the effect of a competitive inhibitor.
-
19M.3.hl.TZ1.12a(i):
A Michaelis–Menten plot for an enzyme-catalysed reaction is shown.
Sketch a curve to show the effect of a competitive inhibitor.
-
19M.3.hl.TZ1.a(i):
A Michaelis–Menten plot for an enzyme-catalysed reaction is shown.
Sketch a curve to show the effect of a competitive inhibitor.
-
19M.3.hl.TZ1.16a(ii):
Outline why the reaction releases energy.
-
19M.3.hl.TZ1.16a(ii):
Outline why the reaction releases energy.
-
19M.3.hl.TZ1.a(ii):
Outline why the reaction releases energy.
-
19M.3.hl.TZ1.3c:
Lithium is obtained by electrolysis of molten lithium chloride. Calculate the time, in seconds, taken to deposit 0.694 g Li using a current of 2.00 A.
Q (charge) = I (current) × t (time)
-
19M.3.hl.TZ1.3c:
Lithium is obtained by electrolysis of molten lithium chloride. Calculate the time, in seconds, taken to deposit 0.694 g Li using a current of 2.00 A.
Q (charge) = I (current) × t (time)
-
19M.3.hl.TZ1.c:
Lithium is obtained by electrolysis of molten lithium chloride. Calculate the time, in seconds, taken to deposit 0.694 g Li using a current of 2.00 A.
Q (charge) = I (current) × t (time)
-
19M.3.hl.TZ1.8d:
Explain how the inclusion of starch in plastics makes them biodegradable.
-
19M.3.hl.TZ1.8d:
Explain how the inclusion of starch in plastics makes them biodegradable.
-
19M.3.hl.TZ1.d:
Explain how the inclusion of starch in plastics makes them biodegradable.
-
19M.3.hl.TZ1.9c:
Aspartic acid is obtained synthetically as a racemic mixture. Draw the three‑dimensional shape of each isomer showing their spatial relationship to each other. Use section 33 of the data booklet.
-
19M.3.hl.TZ1.9c:
Aspartic acid is obtained synthetically as a racemic mixture. Draw the three‑dimensional shape of each isomer showing their spatial relationship to each other. Use section 33 of the data booklet.
-
19M.3.hl.TZ1.c:
Aspartic acid is obtained synthetically as a racemic mixture. Draw the three‑dimensional shape of each isomer showing their spatial relationship to each other. Use section 33 of the data booklet.
-
19M.3.hl.TZ1.3a:
Identify the type of bonding in lithium hydride, using sections 8 and 29 of the data booklet.
-
19M.3.hl.TZ1.3a:
Identify the type of bonding in lithium hydride, using sections 8 and 29 of the data booklet.
-
19M.3.hl.TZ1.a:
Identify the type of bonding in lithium hydride, using sections 8 and 29 of the data booklet.
-
19M.3.hl.TZ1.4b:
Suggest, giving a reason, how elastomers used for the tyre tread can increase the traction between the tyre and the road.
-
19M.3.hl.TZ1.4b:
Suggest, giving a reason, how elastomers used for the tyre tread can increase the traction between the tyre and the road.
-
19M.3.hl.TZ1.b:
Suggest, giving a reason, how elastomers used for the tyre tread can increase the traction between the tyre and the road.
-
19M.3.hl.TZ1.15c(i):
Methane can also be obtained by fractional distillation of crude oil.
[Source: Image used with kind permission of science-resources.co.uk]
Draw a circle on the diagram to show where the methane fraction is withdrawn.
-
19M.3.hl.TZ1.15c(i):
Methane can also be obtained by fractional distillation of crude oil.
[Source: Image used with kind permission of science-resources.co.uk]
Draw a circle on the diagram to show where the methane fraction is withdrawn.
-
19M.3.hl.TZ1.c(i):
Methane can also be obtained by fractional distillation of crude oil.
[Source: Image used with kind permission of science-resources.co.uk]
Draw a circle on the diagram to show where the methane fraction is withdrawn.
-
19M.3.hl.TZ1.16a(iii):
The masses of the particles involved in this fission reaction are shown below.
Mass of neutron = 1.00867 amu
Mass of U-235 nucleus = 234.99346 amu
Mass of Ba-144 nucleus = 143.89223 amu
Mass of Kr-89 nucleus = 88.89788 amuDetermine the energy released, in J, when one uranium-235 nucleus undergoes fission. Use this data and information from sections 1 and 2 of the data booklet.
-
19M.3.hl.TZ1.16a(iii):
The masses of the particles involved in this fission reaction are shown below.
Mass of neutron = 1.00867 amu
Mass of U-235 nucleus = 234.99346 amu
Mass of Ba-144 nucleus = 143.89223 amu
Mass of Kr-89 nucleus = 88.89788 amuDetermine the energy released, in J, when one uranium-235 nucleus undergoes fission. Use this data and information from sections 1 and 2 of the data booklet.
-
19M.3.hl.TZ1.a(iii):
The masses of the particles involved in this fission reaction are shown below.
Mass of neutron = 1.00867 amu
Mass of U-235 nucleus = 234.99346 amu
Mass of Ba-144 nucleus = 143.89223 amu
Mass of Kr-89 nucleus = 88.89788 amuDetermine the energy released, in J, when one uranium-235 nucleus undergoes fission. Use this data and information from sections 1 and 2 of the data booklet.
-
19M.3.hl.TZ1.21a:
Formulate an equation for the neutralization of stomach acid with calcium carbonate, CaCO3 (s).
-
19M.3.hl.TZ1.21a:
Formulate an equation for the neutralization of stomach acid with calcium carbonate, CaCO3 (s).
-
19M.3.hl.TZ1.a:
Formulate an equation for the neutralization of stomach acid with calcium carbonate, CaCO3 (s).
-
19M.3.hl.TZ1.23b:
Discuss how the difference in structure of two opiates, codeine and morphine, affect their ability to cross the blood–brain barrier. Use section 37 of the data booklet.
-
19M.3.hl.TZ1.23b:
Discuss how the difference in structure of two opiates, codeine and morphine, affect their ability to cross the blood–brain barrier. Use section 37 of the data booklet.
-
19M.3.hl.TZ1.b:
Discuss how the difference in structure of two opiates, codeine and morphine, affect their ability to cross the blood–brain barrier. Use section 37 of the data booklet.
-
19M.3.hl.TZ1.24a(ii):
Technetium-99 decays further, emitting beta radiation. Formulate the equation for the decay of technetium-99.
-
19M.3.hl.TZ1.24a(ii):
Technetium-99 decays further, emitting beta radiation. Formulate the equation for the decay of technetium-99.
-
19M.3.hl.TZ1.a(ii):
Technetium-99 decays further, emitting beta radiation. Formulate the equation for the decay of technetium-99.
-
19M.3.hl.TZ1.24b(i):
Outline what is meant by low-level waste.
-
19M.3.hl.TZ1.24b(i):
Outline what is meant by low-level waste.
-
19M.3.hl.TZ1.b(i):
Outline what is meant by low-level waste.
-
19M.3.hl.TZ1.3d(i):
Lithium has shown some superconductive properties when doped into graphene or when under high pressure. Under high pressure, however, the Meissner effect is absent.
Describe the Meissner effect.
-
19M.3.hl.TZ1.3d(i):
Lithium has shown some superconductive properties when doped into graphene or when under high pressure. Under high pressure, however, the Meissner effect is absent.
Describe the Meissner effect.
-
19M.3.hl.TZ1.d(i):
Lithium has shown some superconductive properties when doped into graphene or when under high pressure. Under high pressure, however, the Meissner effect is absent.
Describe the Meissner effect.
-
19M.3.hl.TZ1.4a:
Outline two differences between heterogeneous and homogeneous catalysts.
-
19M.3.hl.TZ1.4a:
Outline two differences between heterogeneous and homogeneous catalysts.
-
19M.3.hl.TZ1.a:
Outline two differences between heterogeneous and homogeneous catalysts.
-
19M.3.hl.TZ1.10b:
Fats contain triglycerides that are esters of glycerol and fatty acids. Deduce an equation for the acid hydrolysis of the following triglyceride.
-
19M.3.hl.TZ1.10b:
Fats contain triglycerides that are esters of glycerol and fatty acids. Deduce an equation for the acid hydrolysis of the following triglyceride.
-
19M.3.hl.TZ1.b:
Fats contain triglycerides that are esters of glycerol and fatty acids. Deduce an equation for the acid hydrolysis of the following triglyceride.
-
19M.3.hl.TZ1.6a:
Describe the structure and bonding of a carbon nanotube.
Structure:
Bonding:
-
19M.3.hl.TZ1.6a:
Describe the structure and bonding of a carbon nanotube.
Structure:
Bonding:
-
19M.3.hl.TZ1.a:
Describe the structure and bonding of a carbon nanotube.
Structure:
Bonding:
-
19M.3.hl.TZ1.7b:
State the number of coordinate covalent bonds EDTA forms with Ni2+.
-
19M.3.hl.TZ1.7b:
State the number of coordinate covalent bonds EDTA forms with Ni2+.
-
19M.3.hl.TZ1.b:
State the number of coordinate covalent bonds EDTA forms with Ni2+.
-
19M.3.hl.TZ1.14b:
Outline one benefit of the use of these products.
-
19M.3.hl.TZ1.14b:
Outline one benefit of the use of these products.
-
19M.3.hl.TZ1.b:
Outline one benefit of the use of these products.
-
19M.3.hl.TZ1.15d(ii):
Compare methane’s atmospheric abundance and greenhouse effect to that of carbon dioxide.
-
19M.3.hl.TZ1.15d(ii):
Compare methane’s atmospheric abundance and greenhouse effect to that of carbon dioxide.
-
19M.3.hl.TZ1.d(ii):
Compare methane’s atmospheric abundance and greenhouse effect to that of carbon dioxide.
-
19M.3.hl.TZ1.3b(ii):
Suggest why ICP-OES does not give good quantitative results for distinguishing 6Li from naturally occurring lithium.
-
19M.3.hl.TZ1.3b(ii):
Suggest why ICP-OES does not give good quantitative results for distinguishing 6Li from naturally occurring lithium.
-
19M.3.hl.TZ1.b(ii):
Suggest why ICP-OES does not give good quantitative results for distinguishing 6Li from naturally occurring lithium.
-
19M.3.hl.TZ1.3d(ii):
At very low temperatures, lithium atoms enhance the phonon binding of electrons in graphene suggesting the formation of Cooper pairs.
Explain how Cooper pairs are formed.
-
19M.3.hl.TZ1.3d(ii):
At very low temperatures, lithium atoms enhance the phonon binding of electrons in graphene suggesting the formation of Cooper pairs.
Explain how Cooper pairs are formed.
-
19M.3.hl.TZ1.d(ii):
At very low temperatures, lithium atoms enhance the phonon binding of electrons in graphene suggesting the formation of Cooper pairs.
Explain how Cooper pairs are formed.
-
19M.3.hl.TZ1.8c:
Calculate the energy released, in kJ g−1, when 3.49 g of starch are completely combusted in a calorimeter, increasing the temperature of 975 g of water from 21.0 °C to 36.0 °C. Use section 1 of the data booklet.
-
19M.3.hl.TZ1.8c:
Calculate the energy released, in kJ g−1, when 3.49 g of starch are completely combusted in a calorimeter, increasing the temperature of 975 g of water from 21.0 °C to 36.0 °C. Use section 1 of the data booklet.
-
19M.3.hl.TZ1.c:
Calculate the energy released, in kJ g−1, when 3.49 g of starch are completely combusted in a calorimeter, increasing the temperature of 975 g of water from 21.0 °C to 36.0 °C. Use section 1 of the data booklet.
-
19M.3.hl.TZ1.11a:
The absorption spectrum of β-carotene is shown below.
Explain its colour in terms of its absorption bands. Use section 17 of the data booklet.
-
19M.3.hl.TZ1.11a:
The absorption spectrum of β-carotene is shown below.
Explain its colour in terms of its absorption bands. Use section 17 of the data booklet.
-
19M.3.hl.TZ1.a:
The absorption spectrum of β-carotene is shown below.
Explain its colour in terms of its absorption bands. Use section 17 of the data booklet.
-
19M.3.hl.TZ1.5a:
Label with an asterisk, *, the chiral carbon atom.
-
19M.3.hl.TZ1.5a:
Label with an asterisk, *, the chiral carbon atom.
-
19M.3.hl.TZ1.a:
Label with an asterisk, *, the chiral carbon atom.
-
19M.3.hl.TZ1.23a:
Explain how opiates act to provide pain relief.
-
19M.3.hl.TZ1.23a:
Explain how opiates act to provide pain relief.
-
19M.3.hl.TZ1.a:
Explain how opiates act to provide pain relief.
-
19M.3.hl.TZ1.7a:
Explain how entropy affects this equilibrium.
-
19M.3.hl.TZ1.7a:
Explain how entropy affects this equilibrium.
-
19M.3.hl.TZ1.a:
Explain how entropy affects this equilibrium.
-
19M.3.hl.TZ2.4c:
Explain the action of metals as heterogeneous catalysts.
-
19M.3.hl.TZ2.4c:
Explain the action of metals as heterogeneous catalysts.
-
19M.3.hl.TZ2.c:
Explain the action of metals as heterogeneous catalysts.
-
19M.3.hl.TZ1.22c:
Anti-HIV drugs, such as zidovudine, often become less effective over time.
Explain the development of resistant virus strains in the presence of antiviral drugs.
-
19M.3.hl.TZ1.22c:
Anti-HIV drugs, such as zidovudine, often become less effective over time.
Explain the development of resistant virus strains in the presence of antiviral drugs.
-
19M.3.hl.TZ1.c:
Anti-HIV drugs, such as zidovudine, often become less effective over time.
Explain the development of resistant virus strains in the presence of antiviral drugs.
-
19M.3.hl.TZ1.11b:
The absorption spectrum of chlorophyll a is shown below.
Suggest how the combination of chlorophyll a and carotenoids is beneficial for photosynthesis.
-
19M.3.hl.TZ1.11b:
The absorption spectrum of chlorophyll a is shown below.
Suggest how the combination of chlorophyll a and carotenoids is beneficial for photosynthesis.
-
19M.3.hl.TZ1.b:
The absorption spectrum of chlorophyll a is shown below.
Suggest how the combination of chlorophyll a and carotenoids is beneficial for photosynthesis.
-
19M.3.hl.TZ1.22a(i):
Draw a circle around the functional group that can be converted to the carboxylate by hydrolysis.
-
19M.3.hl.TZ1.22a(i):
Draw a circle around the functional group that can be converted to the carboxylate by hydrolysis.
-
19M.3.hl.TZ1.a(i):
Draw a circle around the functional group that can be converted to the carboxylate by hydrolysis.
-
19M.3.hl.TZ1.19b(ii):
Identify the splitting pattern of signals X and Y.
X:
Y:
-
19M.3.hl.TZ1.19b(ii):
Identify the splitting pattern of signals X and Y.
X:
Y:
-
19M.3.hl.TZ1.b(ii):
Identify the splitting pattern of signals X and Y.
X:
Y:
-
19M.3.hl.TZ1.25a:
Identify the chiral carbon atom using an asterisk, *.
-
19M.3.hl.TZ1.25a:
Identify the chiral carbon atom using an asterisk, *.
-
19M.3.hl.TZ1.a:
Identify the chiral carbon atom using an asterisk, *.
-
19M.3.hl.TZ1.10a:
The melting points of cocoa butter and coconut oil are 34 °C and 25 °C respectively.
Explain this in terms of their saturated fatty acid composition.
-
19M.3.hl.TZ1.10a:
The melting points of cocoa butter and coconut oil are 34 °C and 25 °C respectively.
Explain this in terms of their saturated fatty acid composition.
-
19M.3.hl.TZ1.a:
The melting points of cocoa butter and coconut oil are 34 °C and 25 °C respectively.
Explain this in terms of their saturated fatty acid composition.
-
19M.3.hl.TZ1.14a:
Outline what is meant by genetically modified organisms.
-
19M.3.hl.TZ1.14a:
Outline what is meant by genetically modified organisms.
-
19M.3.hl.TZ1.a:
Outline what is meant by genetically modified organisms.
-
19M.3.hl.TZ1.15b(i):
Calculate the maximum electric energy output, in MJ, which can be obtained from burning 1.00 kg of methane by using your answer from (a).
-
19M.3.hl.TZ1.15b(i):
Calculate the maximum electric energy output, in MJ, which can be obtained from burning 1.00 kg of methane by using your answer from (a).
-
19M.3.hl.TZ1.b(i):
Calculate the maximum electric energy output, in MJ, which can be obtained from burning 1.00 kg of methane by using your answer from (a).
-
19M.3.hl.TZ1.15b(ii):
Hydroelectric power plants produced 16% of the world’s energy in 2015, down from 21% in 1971.
Suggest why hydroelectric power production has a higher efficiency than the other sources given in (b) and why its relative use has decreased despite the high efficiency.
Reason for higher efficiency:
Reason for decreased use:
-
19M.3.hl.TZ1.15b(ii):
Hydroelectric power plants produced 16% of the world’s energy in 2015, down from 21% in 1971.
Suggest why hydroelectric power production has a higher efficiency than the other sources given in (b) and why its relative use has decreased despite the high efficiency.
Reason for higher efficiency:
Reason for decreased use:
-
19M.3.hl.TZ1.b(ii):
Hydroelectric power plants produced 16% of the world’s energy in 2015, down from 21% in 1971.
Suggest why hydroelectric power production has a higher efficiency than the other sources given in (b) and why its relative use has decreased despite the high efficiency.
Reason for higher efficiency:
Reason for decreased use:
-
19M.3.hl.TZ1.17b(i):
Ethanol can be used in a direct-ethanol fuel cell (DEFC) as illustrated by the flow chart.
Deduce the half-equations occurring at electrodes A and B.
Electrode A:
Electrode B:
-
19M.3.hl.TZ1.17b(i):
Ethanol can be used in a direct-ethanol fuel cell (DEFC) as illustrated by the flow chart.
Deduce the half-equations occurring at electrodes A and B.
Electrode A:
Electrode B:
-
19M.3.hl.TZ1.b(i):
Ethanol can be used in a direct-ethanol fuel cell (DEFC) as illustrated by the flow chart.
Deduce the half-equations occurring at electrodes A and B.
Electrode A:
Electrode B:
-
19M.3.hl.TZ1.22b:
Suggest a reason for using a phosphate salt of oseltamivir in oral tablets.
-
19M.3.hl.TZ1.22b:
Suggest a reason for using a phosphate salt of oseltamivir in oral tablets.
-
19M.3.hl.TZ1.b:
Suggest a reason for using a phosphate salt of oseltamivir in oral tablets.
-
19M.3.hl.TZ1.25b:
Enantiomers can be identified using a polarimeter. Outline how this instrument differentiates the enantiomers.
-
19M.3.hl.TZ1.25b:
Enantiomers can be identified using a polarimeter. Outline how this instrument differentiates the enantiomers.
-
19M.3.hl.TZ1.b:
Enantiomers can be identified using a polarimeter. Outline how this instrument differentiates the enantiomers.
-
19M.3.hl.TZ1.8b:
Formulate the equation for the complete hydrolysis of a starch molecule, (C6H10O5)n.
-
19M.3.hl.TZ1.8b:
Formulate the equation for the complete hydrolysis of a starch molecule, (C6H10O5)n.
-
19M.3.hl.TZ1.b:
Formulate the equation for the complete hydrolysis of a starch molecule, (C6H10O5)n.
-
19M.3.hl.TZ1.10c:
The addition of partially hydrogenated cocoa butter to chocolate increases its melting point and the content of trans-fatty acids (trans-fats).
Outline one effect of trans-fatty acids on health.
-
19M.3.hl.TZ1.10c:
The addition of partially hydrogenated cocoa butter to chocolate increases its melting point and the content of trans-fatty acids (trans-fats).
Outline one effect of trans-fatty acids on health.
-
19M.3.hl.TZ1.c:
The addition of partially hydrogenated cocoa butter to chocolate increases its melting point and the content of trans-fatty acids (trans-fats).
Outline one effect of trans-fatty acids on health.
-
19M.3.hl.TZ1.15d(i):
Explain how methane absorbs infrared (IR) radiation by referring to its molecular geometry and dipole moment.
-
19M.3.hl.TZ1.15d(i):
Explain how methane absorbs infrared (IR) radiation by referring to its molecular geometry and dipole moment.
-
19M.3.hl.TZ1.d(i):
Explain how methane absorbs infrared (IR) radiation by referring to its molecular geometry and dipole moment.
-
19M.3.hl.TZ1.17c:
Biodiesel containing ethanol can be made from renewable resources.
Suggest one environmental disadvantage of producing biodiesel from renewable resources.
-
19M.3.hl.TZ1.c:
Biodiesel containing ethanol can be made from renewable resources.
Suggest one environmental disadvantage of producing biodiesel from renewable resources.
-
19M.3.hl.TZ1.17c:
Biodiesel containing ethanol can be made from renewable resources.
Suggest one environmental disadvantage of producing biodiesel from renewable resources.
-
19M.3.hl.TZ1.18a:
Some solar cells use photovoltaic semi-conductors. Compare, giving reasons, the electrical conductivity of metals and semi-conductors as temperature increases.
-
19M.3.hl.TZ1.18a:
Some solar cells use photovoltaic semi-conductors. Compare, giving reasons, the electrical conductivity of metals and semi-conductors as temperature increases.
-
19M.3.hl.TZ1.a:
Some solar cells use photovoltaic semi-conductors. Compare, giving reasons, the electrical conductivity of metals and semi-conductors as temperature increases.
-
19M.3.hl.TZ1.19b(i):
Deduce the protons responsible for signals X and Y by marking them on the structure of aspirin in (a). Use section 27 of the data booklet.
-
19M.3.hl.TZ1.19b(i):
Deduce the protons responsible for signals X and Y by marking them on the structure of aspirin in (a). Use section 27 of the data booklet.
-
19M.3.hl.TZ1.b(i):
Deduce the protons responsible for signals X and Y by marking them on the structure of aspirin in (a). Use section 27 of the data booklet.
-
19M.3.hl.TZ1.24b(ii):
Outline the disposal of LLW.
-
19M.3.hl.TZ1.24b(ii):
Outline the disposal of LLW.
-
19M.3.hl.TZ1.b(ii):
Outline the disposal of LLW.
-
19M.3.hl.TZ1.24c:
Magnetic resonance imaging (MRI) is an application of NMR technology using radiowaves.
Suggest why MRI is much less dangerous than imaging techniques such as X-rays and radiotracers. Use section 3 of the data booklet.
-
19M.3.hl.TZ1.24c:
Magnetic resonance imaging (MRI) is an application of NMR technology using radiowaves.
Suggest why MRI is much less dangerous than imaging techniques such as X-rays and radiotracers. Use section 3 of the data booklet.
-
19M.3.hl.TZ1.c:
Magnetic resonance imaging (MRI) is an application of NMR technology using radiowaves.
Suggest why MRI is much less dangerous than imaging techniques such as X-rays and radiotracers. Use section 3 of the data booklet.
-
19M.3.hl.TZ2.3:
Describe the characteristics of the nematic liquid crystal phase.
Shape of molecules:
Distribution:
-
19M.3.hl.TZ2.3:
Describe the characteristics of the nematic liquid crystal phase.
Shape of molecules:
Distribution:
-
19M.3.hl.TZ1.16b:
The critical mass for weapons-grade uranium can be as small as 15 kg. Outline what is meant by critical mass by referring to the equation in (a)(i).
-
19M.3.hl.TZ1.16b:
The critical mass for weapons-grade uranium can be as small as 15 kg. Outline what is meant by critical mass by referring to the equation in (a)(i).
-
19M.3.hl.TZ1.b:
The critical mass for weapons-grade uranium can be as small as 15 kg. Outline what is meant by critical mass by referring to the equation in (a)(i).
-
19M.3.hl.TZ1.17b(ii):
State the name and function of X in the diagram in (b)(i).
Name:
Function:
-
19M.3.hl.TZ1.b(ii):
State the name and function of X in the diagram in (b)(i).
Name:
Function:
-
19M.3.hl.TZ1.17b(ii):
State the name and function of X in the diagram in (b)(i).
Name:
Function:
-
19M.3.hl.TZ1.19a:
Unreacted salicylic acid may be present as an impurity in aspirin and can be detected in the infrared (IR) spectrum.
Name the functional group and identify the absorption band that diff erentiates salicylic acid from aspirin. Use section 26 of the data booklet.
Name:
Absorption band:
-
19M.3.hl.TZ1.19a:
Unreacted salicylic acid may be present as an impurity in aspirin and can be detected in the infrared (IR) spectrum.
Name the functional group and identify the absorption band that diff erentiates salicylic acid from aspirin. Use section 26 of the data booklet.
Name:
Absorption band:
-
19M.3.hl.TZ1.a:
Unreacted salicylic acid may be present as an impurity in aspirin and can be detected in the infrared (IR) spectrum.
Name the functional group and identify the absorption band that diff erentiates salicylic acid from aspirin. Use section 26 of the data booklet.
Name:
Absorption band:
-
19M.3.hl.TZ1.24a(i):
Determine the percentage of technetium-99m remaining after 24.0 hours.
-
19M.3.hl.TZ1.24a(i):
Determine the percentage of technetium-99m remaining after 24.0 hours.
-
19M.3.hl.TZ1.a(i):
Determine the percentage of technetium-99m remaining after 24.0 hours.
-
19M.3.hl.TZ1.15a:
Calculate the specific energy of methane, in MJ kg−1, using sections 1, 6 and 13 of the data booklet.
-
19M.3.hl.TZ1.15a:
Calculate the specific energy of methane, in MJ kg−1, using sections 1, 6 and 13 of the data booklet.
-
19M.3.hl.TZ1.a:
Calculate the specific energy of methane, in MJ kg−1, using sections 1, 6 and 13 of the data booklet.
-
19M.3.hl.TZ1.15c(ii):
List the following products, which are also obtained by fractional distillation, according to decreasing volatility: asphalt, diesel, gasoline, lubricating motor oil.
-
19M.3.hl.TZ1.15c(ii):
List the following products, which are also obtained by fractional distillation, according to decreasing volatility: asphalt, diesel, gasoline, lubricating motor oil.
-
19M.3.hl.TZ1.c(ii):
List the following products, which are also obtained by fractional distillation, according to decreasing volatility: asphalt, diesel, gasoline, lubricating motor oil.
-
19M.3.hl.TZ1.16c:
The daughter product, 89Kr, has a half-life of 3.15 min.
Calculate the time required, in minutes, for its radioactivity to fall to 10% of its initial value, using section 1 of the data booklet.
-
19M.3.hl.TZ1.16c:
The daughter product, 89Kr, has a half-life of 3.15 min.
Calculate the time required, in minutes, for its radioactivity to fall to 10% of its initial value, using section 1 of the data booklet.
-
19M.3.hl.TZ1.c:
The daughter product, 89Kr, has a half-life of 3.15 min.
Calculate the time required, in minutes, for its radioactivity to fall to 10% of its initial value, using section 1 of the data booklet.
-
19M.3.hl.TZ1.22a(ii):
The resulting active metabolite of oseltamivir can be detected by mass spectrometry (MS) analysis.
Deduce the mass of the expected carboxylate ion.
Mr oseltamivir = 312
-
19M.3.hl.TZ1.22a(ii):
The resulting active metabolite of oseltamivir can be detected by mass spectrometry (MS) analysis.
Deduce the mass of the expected carboxylate ion.
Mr oseltamivir = 312
-
19M.3.hl.TZ1.a(ii):
The resulting active metabolite of oseltamivir can be detected by mass spectrometry (MS) analysis.
Deduce the mass of the expected carboxylate ion.
Mr oseltamivir = 312
-
19M.3.hl.TZ2.10a(i):
Outline which pKa value should be used when calculating the pH of the solution, giving your reason.
-
19M.3.hl.TZ2.10a(i):
Outline which pKa value should be used when calculating the pH of the solution, giving your reason.
-
19M.3.hl.TZ2.a(i):
Outline which pKa value should be used when calculating the pH of the solution, giving your reason.
-
19M.3.hl.TZ2.13a:
Outline why the complex formed between Fe2+ and oxygen is red. Refer to the diagram above and section 17 of the data booklet.
-
19M.3.hl.TZ2.13a:
Outline why the complex formed between Fe2+ and oxygen is red. Refer to the diagram above and section 17 of the data booklet.
-
19M.3.hl.TZ2.a:
Outline why the complex formed between Fe2+ and oxygen is red. Refer to the diagram above and section 17 of the data booklet.
-
19M.3.hl.TZ2.16a(iii):
Outline one advantage of allowing all countries access to the technology to generate electricity by nuclear fission.
-
19M.3.hl.TZ2.16a(iii):
Outline one advantage of allowing all countries access to the technology to generate electricity by nuclear fission.
-
19M.3.hl.TZ2.a(iii):
Outline one advantage of allowing all countries access to the technology to generate electricity by nuclear fission.
-
19M.3.hl.TZ2.22b(ii):
Determine the percentage purity of the synthesized aspirin.
-
19M.3.hl.TZ2.22b(ii):
Determine the percentage purity of the synthesized aspirin.
-
19M.3.hl.TZ2.b(ii):
Determine the percentage purity of the synthesized aspirin.
-
19M.3.hl.TZ1.18b:
Suggest one advantage of a dye-sensitized solar cell (DSSC) over a silicon based photovoltaic cell.
-
19M.3.hl.TZ1.18b:
Suggest one advantage of a dye-sensitized solar cell (DSSC) over a silicon based photovoltaic cell.
-
19M.3.hl.TZ1.b:
Suggest one advantage of a dye-sensitized solar cell (DSSC) over a silicon based photovoltaic cell.
-
19M.3.hl.TZ1.20a:
Identify the feature in penicillin responsible for its antibiotic activity.
-
19M.3.hl.TZ1.20a:
Identify the feature in penicillin responsible for its antibiotic activity.
-
19M.3.hl.TZ1.a:
Identify the feature in penicillin responsible for its antibiotic activity.
-
19M.3.hl.TZ1.20b(i):
The widespread use of penicillin and its derivatives has led to the appearance of resistant S. aureus strains.
Outline how these bacteria inactivate the antibiotics.
-
19M.3.hl.TZ1.20b(i):
The widespread use of penicillin and its derivatives has led to the appearance of resistant S. aureus strains.
Outline how these bacteria inactivate the antibiotics.
-
19M.3.hl.TZ1.b(i):
The widespread use of penicillin and its derivatives has led to the appearance of resistant S. aureus strains.
Outline how these bacteria inactivate the antibiotics.
-
19M.3.hl.TZ1.20b(ii):
Outline how the structure of penicillin has been modified to overcome this resistance.
-
19M.3.hl.TZ1.20b(ii):
Outline how the structure of penicillin has been modified to overcome this resistance.
-
19M.3.hl.TZ1.b(ii):
Outline how the structure of penicillin has been modified to overcome this resistance.
-
19M.3.hl.TZ2.9d(i):
Suggest two reasons why oil decomposes faster at the surface of the ocean than at greater depth.
-
19M.3.hl.TZ2.9d(i):
Suggest two reasons why oil decomposes faster at the surface of the ocean than at greater depth.
-
19M.3.hl.TZ2.d(i):
Suggest two reasons why oil decomposes faster at the surface of the ocean than at greater depth.
-
19M.3.hl.TZ1.16a(i):
Write the nuclear equation for this fission reaction.
-
19M.3.hl.TZ1.16a(i):
Write the nuclear equation for this fission reaction.
-
19M.3.hl.TZ1.a(i):
Write the nuclear equation for this fission reaction.
-
19M.3.hl.TZ1.21b:
Acid secretion can be regulated by other types of drugs such as omeprazole and ranitidine. Outline how each of these drugs acts to reduce excess stomach acid.
Omeprazole:
Ranitidine:
-
19M.3.hl.TZ1.21b:
Acid secretion can be regulated by other types of drugs such as omeprazole and ranitidine. Outline how each of these drugs acts to reduce excess stomach acid.
Omeprazole:
Ranitidine:
-
19M.3.hl.TZ1.b:
Acid secretion can be regulated by other types of drugs such as omeprazole and ranitidine. Outline how each of these drugs acts to reduce excess stomach acid.
Omeprazole:
Ranitidine:
-
19M.3.hl.TZ2.17:
This question is about biofuel.
Evaluate the use of biodiesel in place of diesel from crude oil.
-
19M.3.hl.TZ2.17:
This question is about biofuel.
Evaluate the use of biodiesel in place of diesel from crude oil.
-
19M.3.hl.TZ2.19a:
Outline how a microbial fuel cell produces an electric current from glucose.
C6H12O6 (aq) + 6O2 (g) → 6CO2 (g) + 6H2O (l)
-
19M.3.hl.TZ2.19a:
Outline how a microbial fuel cell produces an electric current from glucose.
C6H12O6 (aq) + 6O2 (g) → 6CO2 (g) + 6H2O (l)
-
19M.3.hl.TZ2.a:
Outline how a microbial fuel cell produces an electric current from glucose.
C6H12O6 (aq) + 6O2 (g) → 6CO2 (g) + 6H2O (l)
- 19M.3.hl.TZ2.19c: Outline one difference between a primary and a secondary cell.
- 19M.3.hl.TZ2.19c: Outline one difference between a primary and a secondary cell.
- 19M.3.hl.TZ2.c: Outline one difference between a primary and a secondary cell.
-
19M.3.hl.TZ2.20a:
Sketch graphs to show the general effect of increasing temperature on the electrical conductivity of semiconductors and metals on the axes below.
-
19M.3.hl.TZ2.20a:
Sketch graphs to show the general effect of increasing temperature on the electrical conductivity of semiconductors and metals on the axes below.
-
19M.3.hl.TZ2.a:
Sketch graphs to show the general effect of increasing temperature on the electrical conductivity of semiconductors and metals on the axes below.
-
19M.3.hl.TZ2.11c:
Lecithin aids the body’s absorption of vitamin E.
Suggest why vitamin E is fat-soluble.
-
19M.3.hl.TZ2.11c:
Lecithin aids the body’s absorption of vitamin E.
Suggest why vitamin E is fat-soluble.
-
19M.3.hl.TZ2.c:
Lecithin aids the body’s absorption of vitamin E.
Suggest why vitamin E is fat-soluble.
-
19M.3.hl.TZ2.15a:
Crude oil can be converted into fuels by fractional distillation and cracking.
Contrast these two processes.
-
19M.3.hl.TZ2.15a:
Crude oil can be converted into fuels by fractional distillation and cracking.
Contrast these two processes.
-
19M.3.hl.TZ2.a:
Crude oil can be converted into fuels by fractional distillation and cracking.
Contrast these two processes.
-
19M.3.hl.TZ2.22c:
Outline how aspirin can be chemically modified to increase its solubility in water.
-
19M.3.hl.TZ2.22c:
Outline how aspirin can be chemically modified to increase its solubility in water.
-
19M.3.hl.TZ2.c:
Outline how aspirin can be chemically modified to increase its solubility in water.
-
19M.3.hl.TZ2.5f:
Draw the full structural formula of the organic functional group formed during the polymerization of the two reactants below.
-
19M.3.hl.TZ2.5f:
Draw the full structural formula of the organic functional group formed during the polymerization of the two reactants below.
-
19M.3.hl.TZ2.f:
Draw the full structural formula of the organic functional group formed during the polymerization of the two reactants below.
-
19M.3.hl.TZ2.21b:
Explain why diamorphine (heroin) is more potent than morphine using section 37 of the data booklet.
-
19M.3.hl.TZ2.21b:
Explain why diamorphine (heroin) is more potent than morphine using section 37 of the data booklet.
-
19M.3.hl.TZ2.b:
Explain why diamorphine (heroin) is more potent than morphine using section 37 of the data booklet.
-
19M.3.hl.TZ2.25a:
Examine the synthesis of taxol in terms of green chemistry criteria.
-
19M.3.hl.TZ2.25a:
Examine the synthesis of taxol in terms of green chemistry criteria.
-
19M.3.hl.TZ2.a:
Examine the synthesis of taxol in terms of green chemistry criteria.
-
19M.3.hl.TZ2.27a:
Describe how a fuel cell breathalyser works.
-
19M.3.hl.TZ2.27a:
Describe how a fuel cell breathalyser works.
-
19M.3.hl.TZ2.a:
Describe how a fuel cell breathalyser works.
-
19M.3.hl.TZ2.4d:
Outline how alloys conduct electricity and why they are often harder than pure metals.
Conduct electricity:
Harder than pure metals:
-
19M.3.hl.TZ2.4d:
Outline how alloys conduct electricity and why they are often harder than pure metals.
Conduct electricity:
Harder than pure metals:
-
19M.3.hl.TZ2.d:
Outline how alloys conduct electricity and why they are often harder than pure metals.
Conduct electricity:
Harder than pure metals:
-
19M.3.hl.TZ2.5d:
Suggest why the addition of plasticizers is controversial.
-
19M.3.hl.TZ2.5d:
Suggest why the addition of plasticizers is controversial.
-
19M.3.hl.TZ2.d:
Suggest why the addition of plasticizers is controversial.
-
19M.3.hl.TZ2.26a:
Evaluate the suitability of technetium-99m for this use.
-
19M.3.hl.TZ2.26a:
Evaluate the suitability of technetium-99m for this use.
-
19M.3.hl.TZ2.a:
Evaluate the suitability of technetium-99m for this use.
-
19M.3.hl.TZ2.26b:
Calculate the percentage of technetium-99m remaining after 10.0 hours. Use section 1 of the data booklet.
-
19M.3.hl.TZ2.26b:
Calculate the percentage of technetium-99m remaining after 10.0 hours. Use section 1 of the data booklet.
-
19M.3.hl.TZ2.b:
Calculate the percentage of technetium-99m remaining after 10.0 hours. Use section 1 of the data booklet.
-
19M.3.hl.TZ2.4a:
Determine the mass of aluminium, in g, that could be extracted from an appropriate solution by a charge of 48 250 C. Use sections 2 and 6 of the data booklet.
-
19M.3.hl.TZ2.4a:
Determine the mass of aluminium, in g, that could be extracted from an appropriate solution by a charge of 48 250 C. Use sections 2 and 6 of the data booklet.
-
19M.3.hl.TZ2.a:
Determine the mass of aluminium, in g, that could be extracted from an appropriate solution by a charge of 48 250 C. Use sections 2 and 6 of the data booklet.
-
19M.3.hl.TZ2.9a(ii):
Compare and contrast the bonding responsible for the two secondary structures.
One similarity:
One difference:
-
19M.3.hl.TZ2.9a(ii):
Compare and contrast the bonding responsible for the two secondary structures.
One similarity:
One difference:
-
19M.3.hl.TZ2.a(ii):
Compare and contrast the bonding responsible for the two secondary structures.
One similarity:
One difference:
-
19M.3.hl.TZ2.12a:
State the name of the functional group forming part of the ring structure of each monosaccharide unit.
-
19M.3.hl.TZ2.12a:
State the name of the functional group forming part of the ring structure of each monosaccharide unit.
-
19M.3.hl.TZ2.a:
State the name of the functional group forming part of the ring structure of each monosaccharide unit.
-
19M.3.hl.TZ2.12c:
Sketch the cyclic structures of the two monosaccharides which combine to form sucrose.
-
19M.3.hl.TZ2.12c:
Sketch the cyclic structures of the two monosaccharides which combine to form sucrose.
-
19M.3.hl.TZ2.c:
Sketch the cyclic structures of the two monosaccharides which combine to form sucrose.
-
19M.3.hl.TZ2.15c:
Hydrocarbons need treatment to increase their octane number to prevent pre-ignition (knocking) before they can be used in internal combustion engines.
Describe how this is carried out and the molecular changes that take place.
-
19M.3.hl.TZ2.15c:
Hydrocarbons need treatment to increase their octane number to prevent pre-ignition (knocking) before they can be used in internal combustion engines.
Describe how this is carried out and the molecular changes that take place.
-
19M.3.hl.TZ2.c:
Hydrocarbons need treatment to increase their octane number to prevent pre-ignition (knocking) before they can be used in internal combustion engines.
Describe how this is carried out and the molecular changes that take place.
-
19M.3.hl.TZ2.16d:
Calculate the half-life of an isotope whose mass falls from 5.0 × 10−5 g to 4.0 × 10−5 g in 31.4 s, using section 1 of the data booklet.
-
19M.3.hl.TZ2.16d:
Calculate the half-life of an isotope whose mass falls from 5.0 × 10−5 g to 4.0 × 10−5 g in 31.4 s, using section 1 of the data booklet.
-
19M.3.hl.TZ2.d:
Calculate the half-life of an isotope whose mass falls from 5.0 × 10−5 g to 4.0 × 10−5 g in 31.4 s, using section 1 of the data booklet.
-
19M.3.hl.TZ2.19b:
The cell potential for the spontaneous reaction when standard magnesium and silver half-cells are connected is +3.17 V.
Determine the cell potential at 298 K when:
[Mg2+] = 0.0500 mol dm−3
[Ag+] = 0.100 mol dm−3Use sections 1 and 2 of the data booklet.
-
19M.3.hl.TZ2.19b:
The cell potential for the spontaneous reaction when standard magnesium and silver half-cells are connected is +3.17 V.
Determine the cell potential at 298 K when:
[Mg2+] = 0.0500 mol dm−3
[Ag+] = 0.100 mol dm−3Use sections 1 and 2 of the data booklet.
-
19M.3.hl.TZ2.b:
The cell potential for the spontaneous reaction when standard magnesium and silver half-cells are connected is +3.17 V.
Determine the cell potential at 298 K when:
[Mg2+] = 0.0500 mol dm−3
[Ag+] = 0.100 mol dm−3Use sections 1 and 2 of the data booklet.
-
19M.3.hl.TZ2.23b:
Some antacids contain carbonates.
Determine the pH of a buffer solution which contains 0.160 mol dm−3 CO32− and 0.200 mol dm−3 HCO3−, using section 1 of the data booklet.
pKa (HCO3−) = 10.32
-
19M.3.hl.TZ2.23b:
Some antacids contain carbonates.
Determine the pH of a buffer solution which contains 0.160 mol dm−3 CO32− and 0.200 mol dm−3 HCO3−, using section 1 of the data booklet.
pKa (HCO3−) = 10.32
-
19M.3.hl.TZ2.b:
Some antacids contain carbonates.
Determine the pH of a buffer solution which contains 0.160 mol dm−3 CO32− and 0.200 mol dm−3 HCO3−, using section 1 of the data booklet.
pKa (HCO3−) = 10.32
-
19M.3.hl.TZ2.24b:
Discuss two difficulties associated with solving the AIDS problem.
-
19M.3.hl.TZ2.24b:
Discuss two difficulties associated with solving the AIDS problem.
-
19M.3.hl.TZ2.b:
Discuss two difficulties associated with solving the AIDS problem.
-
19M.3.hl.TZ2.9c:
State and explain how a competitive inhibitor affects the maximum rate, Vmax, of an enzyme-catalyzed reaction.
-
19M.3.hl.TZ2.9c:
State and explain how a competitive inhibitor affects the maximum rate, Vmax, of an enzyme-catalyzed reaction.
-
19M.3.hl.TZ2.c:
State and explain how a competitive inhibitor affects the maximum rate, Vmax, of an enzyme-catalyzed reaction.
-
19M.3.hl.TZ2.10b:
Describe what is meant by the genetic code and how it relates to protein synthesis.
-
19M.3.hl.TZ2.10b:
Describe what is meant by the genetic code and how it relates to protein synthesis.
-
19M.3.hl.TZ2.b:
Describe what is meant by the genetic code and how it relates to protein synthesis.
-
19M.3.hl.TZ2.22a:
Predict one absorption band present in an infrared (IR) spectrum of aspirin, using section 26 of the data booklet.
-
19M.3.hl.TZ2.22a:
Predict one absorption band present in an infrared (IR) spectrum of aspirin, using section 26 of the data booklet.
-
19M.3.hl.TZ2.a:
Predict one absorption band present in an infrared (IR) spectrum of aspirin, using section 26 of the data booklet.
-
19M.3.hl.TZ2.22b(i):
Determine the mass of aspirin which reacted with 16.25 cm3 of 0.100 mol dm−3 NaOH solution.
-
19M.3.hl.TZ2.22b(i):
Determine the mass of aspirin which reacted with 16.25 cm3 of 0.100 mol dm−3 NaOH solution.
-
19M.3.hl.TZ2.b(i):
Determine the mass of aspirin which reacted with 16.25 cm3 of 0.100 mol dm−3 NaOH solution.
-
19M.3.hl.TZ2.15b:
Determine the specific energy, in kJ g−1, and energy density, in kJ cm−3, of hexane, C6H14. Give both answers to three significant figures.
Hexane: Mr = 86.2; ΔHc = −4163 kJ mol−1; density = 0.660 g cm−3
Specific energy:
Energy density:
-
19M.3.hl.TZ2.15b:
Determine the specific energy, in kJ g−1, and energy density, in kJ cm−3, of hexane, C6H14. Give both answers to three significant figures.
Hexane: Mr = 86.2; ΔHc = −4163 kJ mol−1; density = 0.660 g cm−3
Specific energy:
Energy density:
-
19M.3.hl.TZ2.b:
Determine the specific energy, in kJ g−1, and energy density, in kJ cm−3, of hexane, C6H14. Give both answers to three significant figures.
Hexane: Mr = 86.2; ΔHc = −4163 kJ mol−1; density = 0.660 g cm−3
Specific energy:
Energy density:
-
19M.3.hl.TZ2.18b:
Outline one approach to controlling industrial emissions of carbon dioxide.
-
19M.3.hl.TZ2.18b:
Outline one approach to controlling industrial emissions of carbon dioxide.
-
19M.3.hl.TZ2.b:
Outline one approach to controlling industrial emissions of carbon dioxide.
- 19M.3.hl.TZ2.13b(ii): Sketch another line to show the effect of an increase in body temperature on the oxygen...
- 19M.3.hl.TZ2.13b(ii): Sketch another line to show the effect of an increase in body temperature on the oxygen...
- 19M.3.hl.TZ2.b(ii): Sketch another line to show the effect of an increase in body temperature on the oxygen...
-
19M.3.hl.TZ2.23a(i):
Outline how ranitidine (Zantac) inhibits stomach acid production.
-
19M.3.hl.TZ2.23a(i):
Outline how ranitidine (Zantac) inhibits stomach acid production.
-
19M.3.hl.TZ2.a(i):
Outline how ranitidine (Zantac) inhibits stomach acid production.
-
19M.3.hl.TZ2.23a(ii):
Outline two advantages of taking ranitidine instead of an antacid which neutralizes excess acid.
-
19M.3.hl.TZ2.23a(ii):
Outline two advantages of taking ranitidine instead of an antacid which neutralizes excess acid.
-
19M.3.hl.TZ2.a(ii):
Outline two advantages of taking ranitidine instead of an antacid which neutralizes excess acid.
-
19M.3.hl.TZ2.8a:
Outline why heavy metals are toxic.
-
19M.3.hl.TZ2.8a:
Outline why heavy metals are toxic.
-
19M.3.hl.TZ2.a:
Outline why heavy metals are toxic.
-
19M.3.hl.TZ2.8b:
Determine the maximum concentration of lead(II) ions at 298 K in a solution in which the concentration of carbonate ions is maintained at 1.10 × 10−4 mol dm−3. Use section 32 of the data booklet.
-
19M.3.hl.TZ2.8b:
Determine the maximum concentration of lead(II) ions at 298 K in a solution in which the concentration of carbonate ions is maintained at 1.10 × 10−4 mol dm−3. Use section 32 of the data booklet.
-
19M.3.hl.TZ2.b:
Determine the maximum concentration of lead(II) ions at 298 K in a solution in which the concentration of carbonate ions is maintained at 1.10 × 10−4 mol dm−3. Use section 32 of the data booklet.
-
19M.3.hl.TZ2.13b(i):
Explain the shape of the curve.
-
19M.3.hl.TZ2.13b(i):
Explain the shape of the curve.
-
19M.3.hl.TZ2.b(i):
Explain the shape of the curve.
-
19M.3.hl.TZ2.25b:
Outline the operation of a polarimeter used to distinguish between enantiomers.
-
19M.3.hl.TZ2.25b:
Outline the operation of a polarimeter used to distinguish between enantiomers.
-
19M.3.hl.TZ2.b:
Outline the operation of a polarimeter used to distinguish between enantiomers.
-
19M.3.hl.TZ2.16a(i):
Determine the other product of the fission reaction of plutonium-239.
-
19M.3.hl.TZ2.16a(i):
Determine the other product of the fission reaction of plutonium-239.
-
19M.3.hl.TZ2.a(i):
Determine the other product of the fission reaction of plutonium-239.
-
19M.3.hl.TZ2.21a:
Distinguish between therapeutic window and therapeutic index in humans.
Therapeutic window:
Therapeutic index:
-
19M.3.hl.TZ2.21a:
Distinguish between therapeutic window and therapeutic index in humans.
Therapeutic window:
Therapeutic index:
-
19M.3.hl.TZ2.a:
Distinguish between therapeutic window and therapeutic index in humans.
Therapeutic window:
Therapeutic index:
-
19M.3.hl.TZ2.9d(ii):
Oil spills can be treated with an enzyme mixture to speed up decomposition.
Outline one factor to be considered when assessing the greenness of an enzyme mixture.
-
19M.3.hl.TZ2.9d(ii):
Oil spills can be treated with an enzyme mixture to speed up decomposition.
Outline one factor to be considered when assessing the greenness of an enzyme mixture.
-
19M.3.hl.TZ2.d(ii):
Oil spills can be treated with an enzyme mixture to speed up decomposition.
Outline one factor to be considered when assessing the greenness of an enzyme mixture.
-
19M.3.hl.TZ2.14:
The regular rise and fall of sea levels, known as tides, can be used to generate energy.
State one advantage, other than limiting greenhouse gas emissions, and one disadvantage of tidal power.
Advantage:
Disadvantage:
-
19M.3.hl.TZ2.14:
The regular rise and fall of sea levels, known as tides, can be used to generate energy.
State one advantage, other than limiting greenhouse gas emissions, and one disadvantage of tidal power.
Advantage:
Disadvantage:
-
19M.3.hl.TZ2.16a(ii):
Outline the concept of critical mass with respect to fission reactions.
-
19M.3.hl.TZ2.16a(ii):
Outline the concept of critical mass with respect to fission reactions.
-
19M.3.hl.TZ2.a(ii):
Outline the concept of critical mass with respect to fission reactions.
-
19M.3.hl.TZ2.20b:
Explain the function of dyes in a dye-sensitized solar cell (DSSC).
-
19M.3.hl.TZ2.20b:
Explain the function of dyes in a dye-sensitized solar cell (DSSC).
-
19M.3.hl.TZ2.b:
Explain the function of dyes in a dye-sensitized solar cell (DSSC).
-
19M.3.hl.TZ2.16b:
State one advantage of using fusion reactions rather than fission to generate electrical power.
-
19M.3.hl.TZ2.16b:
State one advantage of using fusion reactions rather than fission to generate electrical power.
-
19M.3.hl.TZ2.b:
State one advantage of using fusion reactions rather than fission to generate electrical power.
-
19M.3.hl.TZ2.16c:
Outline how the energy of a fission reaction can be calculated.
-
19M.3.hl.TZ2.16c:
Outline how the energy of a fission reaction can be calculated.
-
19M.3.hl.TZ2.c:
Outline how the energy of a fission reaction can be calculated.
-
19M.3.hl.TZ2.18a:
Describe the effect of infrared (IR) radiation on carbon dioxide molecules.
-
19M.3.hl.TZ2.18a:
Describe the effect of infrared (IR) radiation on carbon dioxide molecules.
-
19M.3.hl.TZ2.a:
Describe the effect of infrared (IR) radiation on carbon dioxide molecules.
-
19M.3.hl.TZ2.27b:
Alcohol levels in the breath can also be determined using IR spectroscopy.
Suggest, giving a reason, which bond’s absorbance is most useful for detecting ethanol in breath.
Bond:
Reason:
-
19M.3.hl.TZ2.27b:
Alcohol levels in the breath can also be determined using IR spectroscopy.
Suggest, giving a reason, which bond’s absorbance is most useful for detecting ethanol in breath.
Bond:
Reason:
-
19M.3.hl.TZ2.b:
Alcohol levels in the breath can also be determined using IR spectroscopy.
Suggest, giving a reason, which bond’s absorbance is most useful for detecting ethanol in breath.
Bond:
Reason:
-
19M.3.sl.TZ1.11b(ii):
Hydroelectric power plants produced 16 % of the world’s energy in 2015, down from 21 % in 1971.
Suggest why hydroelectric power production has a higher efficiency than the other sources given in (b) and why its relative use has decreased despite the high efficiency.
Reason for higher efficiency:
Reason for decreased use:
-
19M.3.sl.TZ1.11b(ii):
Hydroelectric power plants produced 16 % of the world’s energy in 2015, down from 21 % in 1971.
Suggest why hydroelectric power production has a higher efficiency than the other sources given in (b) and why its relative use has decreased despite the high efficiency.
Reason for higher efficiency:
Reason for decreased use:
-
19M.3.sl.TZ1.b(ii):
Hydroelectric power plants produced 16 % of the world’s energy in 2015, down from 21 % in 1971.
Suggest why hydroelectric power production has a higher efficiency than the other sources given in (b) and why its relative use has decreased despite the high efficiency.
Reason for higher efficiency:
Reason for decreased use:
-
19M.3.sl.TZ1.8a:
Draw a circle around the functional group formed between the amino acids and state its name.
Name:
-
19M.3.sl.TZ1.8a:
Draw a circle around the functional group formed between the amino acids and state its name.
Name:
-
19M.3.sl.TZ1.a:
Draw a circle around the functional group formed between the amino acids and state its name.
Name:
-
19M.3.sl.TZ1.11c(i):
Methane can also be obtained by fractional distillation of crude oil.
Draw a circle on the diagram to show where the methane fraction is withdrawn.
-
19M.3.sl.TZ1.11c(i):
Methane can also be obtained by fractional distillation of crude oil.
Draw a circle on the diagram to show where the methane fraction is withdrawn.
-
19M.3.sl.TZ1.c(i):
Methane can also be obtained by fractional distillation of crude oil.
Draw a circle on the diagram to show where the methane fraction is withdrawn.
-
19M.3.sl.TZ1.6b:
Suggest one application for carbon nanotubes.
-
19M.3.sl.TZ1.6b:
Suggest one application for carbon nanotubes.
-
19M.3.sl.TZ1.b:
Suggest one application for carbon nanotubes.
-
19M.3.sl.TZ1.14:
Aspirin can be obtained from salicylic acid.
Unreacted salicylic acid may be present as an impurity in aspirin and can be detected in the infrared (IR) spectrum.
Name the functional group and identify the absorption band that differentiates salicylic acid from aspirin. Use section 26 of the data booklet.
Name:
Absorption band:
-
19M.3.sl.TZ1.14:
Aspirin can be obtained from salicylic acid.
Unreacted salicylic acid may be present as an impurity in aspirin and can be detected in the infrared (IR) spectrum.
Name the functional group and identify the absorption band that differentiates salicylic acid from aspirin. Use section 26 of the data booklet.
Name:
Absorption band:
-
19M.3.sl.TZ1.19b:
Outline the disposal of LLW.
-
19M.3.sl.TZ1.19b:
Outline the disposal of LLW.
-
19M.3.sl.TZ1.b:
Outline the disposal of LLW.
-
19M.3.sl.TZ1.3b(i):
Suggest why ICP-OES does not give good quantitative results for distinguishing 6Li from naturally occurring lithium.
-
19M.3.sl.TZ1.3b(i):
Suggest why ICP-OES does not give good quantitative results for distinguishing 6Li from naturally occurring lithium.
-
19M.3.sl.TZ1.b(i):
Suggest why ICP-OES does not give good quantitative results for distinguishing 6Li from naturally occurring lithium.
-
19M.3.sl.TZ1.4c(i):
Tyre fires emit trace quantities of polychlorinated dibenzofurans and polychlorinated dibenzo-p-dioxin.
Outline, using section 31 of the data booklet, why polychlorinated dibenzofuran is not classed chemically as a dioxin but considered “dioxin-like”.
-
19M.3.sl.TZ1.4c(i):
Tyre fires emit trace quantities of polychlorinated dibenzofurans and polychlorinated dibenzo-p-dioxin.
Outline, using section 31 of the data booklet, why polychlorinated dibenzofuran is not classed chemically as a dioxin but considered “dioxin-like”.
-
19M.3.sl.TZ1.c(i):
Tyre fires emit trace quantities of polychlorinated dibenzofurans and polychlorinated dibenzo-p-dioxin.
Outline, using section 31 of the data booklet, why polychlorinated dibenzofuran is not classed chemically as a dioxin but considered “dioxin-like”.
-
19M.3.sl.TZ1.7b:
Formulate the equation for the complete hydrolysis of a starch molecule, (C6H10O5)n.
-
19M.3.sl.TZ1.7b:
Formulate the equation for the complete hydrolysis of a starch molecule, (C6H10O5)n.
-
19M.3.sl.TZ1.b:
Formulate the equation for the complete hydrolysis of a starch molecule, (C6H10O5)n.
-
19M.3.sl.TZ1.10:
Ascorbic acid and retinol are two important vitamins.
Explain why ascorbic acid is soluble in water and retinol is not. Use section 35 of the data booklet.
-
19M.3.sl.TZ1.10:
Ascorbic acid and retinol are two important vitamins.
Explain why ascorbic acid is soluble in water and retinol is not. Use section 35 of the data booklet.
-
19M.3.sl.TZ1.13c:
Biodiesel containing ethanol can be made from renewable resources.
Suggest one environmental disadvantage of producing biodiesel from renewable resources.
-
19M.3.sl.TZ1.13c:
Biodiesel containing ethanol can be made from renewable resources.
Suggest one environmental disadvantage of producing biodiesel from renewable resources.
-
19M.3.sl.TZ1.c:
Biodiesel containing ethanol can be made from renewable resources.
Suggest one environmental disadvantage of producing biodiesel from renewable resources.
-
19M.3.sl.TZ1.11a:
Calculate the specific energy of methane, in MJ kg−1, using sections 1, 6 and 13 of the data booklet.
-
19M.3.sl.TZ1.11a:
Calculate the specific energy of methane, in MJ kg−1, using sections 1, 6 and 13 of the data booklet.
-
19M.3.sl.TZ1.a:
Calculate the specific energy of methane, in MJ kg−1, using sections 1, 6 and 13 of the data booklet.
-
19M.3.sl.TZ1.11d(ii):
Compare methane’s atmospheric abundance and greenhouse effect to that of carbon dioxide.
-
19M.3.sl.TZ1.11d(ii):
Compare methane’s atmospheric abundance and greenhouse effect to that of carbon dioxide.
-
19M.3.sl.TZ1.d(ii):
Compare methane’s atmospheric abundance and greenhouse effect to that of carbon dioxide.
-
19M.3.sl.TZ1.19a:
Outline what is meant by low-level waste.
-
19M.3.sl.TZ1.19a:
Outline what is meant by low-level waste.
-
19M.3.sl.TZ1.a:
Outline what is meant by low-level waste.
-
19M.3.sl.TZ1.13a:
Ethanol has a Research Octane Number (RON) of 108.6.
Outline how higher octane fuels affect engine performance.
-
19M.3.sl.TZ1.13a:
Ethanol has a Research Octane Number (RON) of 108.6.
Outline how higher octane fuels affect engine performance.
-
19M.3.sl.TZ1.a:
Ethanol has a Research Octane Number (RON) of 108.6.
Outline how higher octane fuels affect engine performance.
-
19M.3.sl.TZ1.16a(ii):
Determine the volume of CO2 (g), in dm3, produced at STP, when 1.00 g of CaCO3 (s) reacts completely with stomach acid.
Mr CaCO3 = 100.09
-
19M.3.sl.TZ1.16a(ii):
Determine the volume of CO2 (g), in dm3, produced at STP, when 1.00 g of CaCO3 (s) reacts completely with stomach acid.
Mr CaCO3 = 100.09
-
19M.3.sl.TZ1.a(ii):
Determine the volume of CO2 (g), in dm3, produced at STP, when 1.00 g of CaCO3 (s) reacts completely with stomach acid.
Mr CaCO3 = 100.09
-
19M.3.sl.TZ1.18a:
Explain how opiates act to provide pain relief.
-
19M.3.sl.TZ1.18a:
Explain how opiates act to provide pain relief.
-
19M.3.sl.TZ1.a:
Explain how opiates act to provide pain relief.
-
19M.3.sl.TZ1.18b:
Discuss how the difference in structure of two opiates, codeine and morphine, affect their ability to cross the blood–brain barrier. Use section 37 of the data booklet.
-
19M.3.sl.TZ1.18b:
Discuss how the difference in structure of two opiates, codeine and morphine, affect their ability to cross the blood–brain barrier. Use section 37 of the data booklet.
-
19M.3.sl.TZ1.b:
Discuss how the difference in structure of two opiates, codeine and morphine, affect their ability to cross the blood–brain barrier. Use section 37 of the data booklet.
-
19M.3.sl.TZ1.12c:
The daughter product, 89Kr, has a half-life of 3.15 min.
Calculate the time required, in minutes, for the mass of 89Kr to fall to 6.25 % of its initial value.
-
19M.3.sl.TZ1.12c:
The daughter product, 89Kr, has a half-life of 3.15 min.
Calculate the time required, in minutes, for the mass of 89Kr to fall to 6.25 % of its initial value.
-
19M.3.sl.TZ1.c:
The daughter product, 89Kr, has a half-life of 3.15 min.
Calculate the time required, in minutes, for the mass of 89Kr to fall to 6.25 % of its initial value.
-
19M.3.sl.TZ1.6a:
Describe the structure and bonding of a carbon nanotube.
Structure:
Bonding:
-
19M.3.sl.TZ1.6a:
Describe the structure and bonding of a carbon nanotube.
Structure:
Bonding:
-
19M.3.sl.TZ1.a:
Describe the structure and bonding of a carbon nanotube.
Structure:
Bonding:
-
19M.3.sl.TZ1.7c:
Calculate the energy released, in kJ g−1, when 3.49 g of starch are completely combusted in a calorimeter, increasing the temperature of 975 g of water from 21.0 °C to 36.0 °C. Use section 1 of the data booklet.
-
19M.3.sl.TZ1.7c:
Calculate the energy released, in kJ g−1, when 3.49 g of starch are completely combusted in a calorimeter, increasing the temperature of 975 g of water from 21.0 °C to 36.0 °C. Use section 1 of the data booklet.
-
19M.3.sl.TZ1.c:
Calculate the energy released, in kJ g−1, when 3.49 g of starch are completely combusted in a calorimeter, increasing the temperature of 975 g of water from 21.0 °C to 36.0 °C. Use section 1 of the data booklet.
-
19M.3.sl.TZ1.11b(i):
Calculate the maximum electric energy output, in MJ, which can be obtained from burning 1.00 kg of methane by using your answer from (a).
-
19M.3.sl.TZ1.11b(i):
Calculate the maximum electric energy output, in MJ, which can be obtained from burning 1.00 kg of methane by using your answer from (a).
-
19M.3.sl.TZ1.b(i):
Calculate the maximum electric energy output, in MJ, which can be obtained from burning 1.00 kg of methane by using your answer from (a).
-
19M.3.sl.TZ1.16b:
Acid secretion can be regulated by other types of drugs such as omeprazole and ranitidine. Outline how each of these drugs acts to reduce excess stomach acid.
Omeprazole:
Ranitidine:
-
19M.3.sl.TZ1.16b:
Acid secretion can be regulated by other types of drugs such as omeprazole and ranitidine. Outline how each of these drugs acts to reduce excess stomach acid.
Omeprazole:
Ranitidine:
-
19M.3.sl.TZ1.b:
Acid secretion can be regulated by other types of drugs such as omeprazole and ranitidine. Outline how each of these drugs acts to reduce excess stomach acid.
Omeprazole:
Ranitidine:
-
19M.3.sl.TZ1.17a(ii):
Suggest a reason for using a phosphate salt of oseltamivir in oral tablets.
-
19M.3.sl.TZ1.17a(ii):
Suggest a reason for using a phosphate salt of oseltamivir in oral tablets.
-
19M.3.sl.TZ1.a(ii):
Suggest a reason for using a phosphate salt of oseltamivir in oral tablets.
-
19M.3.sl.TZ1.5b:
Explain the effects of very low and high temperatures on the liquid-crystal behaviour of this molecule.
Low temperature:
High temperature:
-
19M.3.sl.TZ1.5b:
Explain the effects of very low and high temperatures on the liquid-crystal behaviour of this molecule.
Low temperature:
High temperature:
-
19M.3.sl.TZ1.b:
Explain the effects of very low and high temperatures on the liquid-crystal behaviour of this molecule.
Low temperature:
High temperature:
-
19M.3.sl.TZ1.7d:
Explain how the inclusion of starch in plastics makes them biodegradable.
-
19M.3.sl.TZ1.7d:
Explain how the inclusion of starch in plastics makes them biodegradable.
-
19M.3.sl.TZ1.d:
Explain how the inclusion of starch in plastics makes them biodegradable.
-
19M.3.sl.TZ1.7a:
Draw the structure of the repeating unit of starch and state the type of linkage formed between these units.
Type of linkage:
-
19M.3.sl.TZ1.7a:
Draw the structure of the repeating unit of starch and state the type of linkage formed between these units.
Type of linkage:
-
19M.3.sl.TZ1.a:
Draw the structure of the repeating unit of starch and state the type of linkage formed between these units.
Type of linkage:
-
19M.3.sl.TZ1.12a(i):
Write the nuclear equation for this fission reaction.
-
19M.3.sl.TZ1.12a(i):
Write the nuclear equation for this fission reaction.
-
19M.3.sl.TZ1.a(i):
Write the nuclear equation for this fission reaction.
-
19M.3.sl.TZ1.15b(ii):
Outline how the structure of penicillin has been modified to overcome this resistance.
-
19M.3.sl.TZ1.15b(ii):
Outline how the structure of penicillin has been modified to overcome this resistance.
-
19M.3.sl.TZ1.b(ii):
Outline how the structure of penicillin has been modified to overcome this resistance.
-
19M.3.sl.TZ1.17b:
Anti-HIV drugs, such as zidovudine, often become less effective over time.
Explain the development of resistant virus strains in the presence of antiviral drugs.
-
19M.3.sl.TZ1.17b:
Anti-HIV drugs, such as zidovudine, often become less effective over time.
Explain the development of resistant virus strains in the presence of antiviral drugs.
-
19M.3.sl.TZ1.b:
Anti-HIV drugs, such as zidovudine, often become less effective over time.
Explain the development of resistant virus strains in the presence of antiviral drugs.
-
19M.3.sl.TZ1.3c:
Lithium is obtained by electrolysis of molten lithium chloride. Calculate the time, in seconds, taken to deposit 0.694 g Li using a current of 2.00 A.
Q (charge) = I (current) × t (time)
-
19M.3.sl.TZ1.3c:
Lithium is obtained by electrolysis of molten lithium chloride. Calculate the time, in seconds, taken to deposit 0.694 g Li using a current of 2.00 A.
Q (charge) = I (current) × t (time)
-
19M.3.sl.TZ1.c:
Lithium is obtained by electrolysis of molten lithium chloride. Calculate the time, in seconds, taken to deposit 0.694 g Li using a current of 2.00 A.
Q (charge) = I (current) × t (time)
-
19M.3.sl.TZ1.5a:
State the name of the functional group which allows the molecule to be responsive to applied electric fields.
-
19M.3.sl.TZ1.5a:
State the name of the functional group which allows the molecule to be responsive to applied electric fields.
-
19M.3.sl.TZ1.a:
State the name of the functional group which allows the molecule to be responsive to applied electric fields.
-
19M.3.sl.TZ1.11d(i):
Explain how methane absorbs infrared (IR) radiation by referring to its molecular geometry and dipole moment.
-
19M.3.sl.TZ1.11d(i):
Explain how methane absorbs infrared (IR) radiation by referring to its molecular geometry and dipole moment.
-
19M.3.sl.TZ1.d(i):
Explain how methane absorbs infrared (IR) radiation by referring to its molecular geometry and dipole moment.
-
19M.3.sl.TZ1.16a(i):
Formulate an equation for the neutralization of stomach acid with calcium carbonate, CaCO3 (s).
-
19M.3.sl.TZ1.16a(i):
Formulate an equation for the neutralization of stomach acid with calcium carbonate, CaCO3 (s).
-
19M.3.sl.TZ1.a(i):
Formulate an equation for the neutralization of stomach acid with calcium carbonate, CaCO3 (s).
-
19M.3.sl.TZ1.3a(i):
Identify the type of bonding in lithium hydride, using sections 8 and 29 of the data booklet.
-
19M.3.sl.TZ1.3a(i):
Identify the type of bonding in lithium hydride, using sections 8 and 29 of the data booklet.
-
19M.3.sl.TZ1.a(i):
Identify the type of bonding in lithium hydride, using sections 8 and 29 of the data booklet.
-
19M.3.sl.TZ1.8b:
A mixture of phenylalanine and aspartic acid is separated by gel electrophoresis with a buffer of pH = 5.5.
Deduce their relative positions after electrophoresis, annotating them on the diagram. Use section 33 of the data booklet.
-
19M.3.sl.TZ1.8b:
A mixture of phenylalanine and aspartic acid is separated by gel electrophoresis with a buffer of pH = 5.5.
Deduce their relative positions after electrophoresis, annotating them on the diagram. Use section 33 of the data booklet.
-
19M.3.sl.TZ1.b:
A mixture of phenylalanine and aspartic acid is separated by gel electrophoresis with a buffer of pH = 5.5.
Deduce their relative positions after electrophoresis, annotating them on the diagram. Use section 33 of the data booklet.
-
19M.3.sl.TZ1.9c:
The addition of partially hydrogenated cocoa butter to chocolate increases its melting point and the content of trans-fatty acids (trans-fats).
Outline two effects of trans-fatty acids on health.
-
19M.3.sl.TZ1.9c:
The addition of partially hydrogenated cocoa butter to chocolate increases its melting point and the content of trans-fatty acids (trans-fats).
Outline two effects of trans-fatty acids on health.
-
19M.3.sl.TZ1.c:
The addition of partially hydrogenated cocoa butter to chocolate increases its melting point and the content of trans-fatty acids (trans-fats).
Outline two effects of trans-fatty acids on health.
-
19M.3.sl.TZ1.12a(ii):
Outline why the reaction releases energy.
-
19M.3.sl.TZ1.12a(ii):
Outline why the reaction releases energy.
-
19M.3.sl.TZ1.a(ii):
Outline why the reaction releases energy.
-
19M.3.sl.TZ1.13b:
Show that, for combustion of equal masses of fuel, ethanol (Mr = 46 g mol−1) has a lower carbon footprint than octane (Mr = 114 g mol−1).
-
19M.3.sl.TZ1.13b:
Show that, for combustion of equal masses of fuel, ethanol (Mr = 46 g mol−1) has a lower carbon footprint than octane (Mr = 114 g mol−1).
-
19M.3.sl.TZ1.b:
Show that, for combustion of equal masses of fuel, ethanol (Mr = 46 g mol−1) has a lower carbon footprint than octane (Mr = 114 g mol−1).
-
19M.3.sl.TZ1.15a:
Identify the feature in penicillin responsible for its antibiotic activity.
-
19M.3.sl.TZ1.15a:
Identify the feature in penicillin responsible for its antibiotic activity.
-
19M.3.sl.TZ1.a:
Identify the feature in penicillin responsible for its antibiotic activity.
-
19M.3.sl.TZ1.17a(i):
Draw a circle around the functional group that can be converted to the carboxylate by hydrolysis.
-
19M.3.sl.TZ1.17a(i):
Draw a circle around the functional group that can be converted to the carboxylate by hydrolysis.
-
19M.3.sl.TZ1.a(i):
Draw a circle around the functional group that can be converted to the carboxylate by hydrolysis.
-
19M.3.sl.TZ1.15b(i):
The widespread use of penicillin and its derivatives has led to the appearance of resistant S. aureus strains.
Outline how these bacteria inactivate the antibiotics.
-
19M.3.sl.TZ1.15b(i):
The widespread use of penicillin and its derivatives has led to the appearance of resistant S. aureus strains.
Outline how these bacteria inactivate the antibiotics.
-
19M.3.sl.TZ1.b(i):
The widespread use of penicillin and its derivatives has led to the appearance of resistant S. aureus strains.
Outline how these bacteria inactivate the antibiotics.
-
19M.3.sl.TZ2.4a:
Determine the mass of aluminium, in g, that could be extracted from an appropriate solution by a charge of 48250 C. Use sections 2 and 6 of the data booklet.
-
19M.3.sl.TZ2.4a:
Determine the mass of aluminium, in g, that could be extracted from an appropriate solution by a charge of 48250 C. Use sections 2 and 6 of the data booklet.
-
19M.3.sl.TZ2.a:
Determine the mass of aluminium, in g, that could be extracted from an appropriate solution by a charge of 48250 C. Use sections 2 and 6 of the data booklet.
-
19M.3.sl.TZ2.4c:
Explain the action of metals as heterogeneous catalysts.
-
19M.3.sl.TZ2.4c:
Explain the action of metals as heterogeneous catalysts.
-
19M.3.sl.TZ2.c:
Explain the action of metals as heterogeneous catalysts.
-
19M.3.sl.TZ2.7a(i):
Deduce the structural formula of phosphatidylcholine.
-
19M.3.sl.TZ2.a(i):
Deduce the structural formula of phosphatidylcholine.
-
19M.3.sl.TZ2.7a(i):
Deduce the structural formula of phosphatidylcholine.
-
19M.3.sl.TZ2.10c:
Hydrocarbons need treatment to increase their octane number to prevent pre-ignition (knocking) before they can be used in internal combustion engines.
Describe how this is carried out and the molecular changes that take place.
-
19M.3.sl.TZ2.10c:
Hydrocarbons need treatment to increase their octane number to prevent pre-ignition (knocking) before they can be used in internal combustion engines.
Describe how this is carried out and the molecular changes that take place.
-
19M.3.sl.TZ2.c:
Hydrocarbons need treatment to increase their octane number to prevent pre-ignition (knocking) before they can be used in internal combustion engines.
Describe how this is carried out and the molecular changes that take place.
-
19M.3.sl.TZ2.15d:
State why aspirin should not be taken with alcohol.
-
19M.3.sl.TZ2.15d:
State why aspirin should not be taken with alcohol.
-
19M.3.sl.TZ2.d:
State why aspirin should not be taken with alcohol.
-
19M.3.sl.TZ2.5a:
Draw a section of isotactic polychloroethene (polyvinylchloride, PVC) showing all the atoms and all the bonds of four monomer units.
-
19M.3.sl.TZ2.5a:
Draw a section of isotactic polychloroethene (polyvinylchloride, PVC) showing all the atoms and all the bonds of four monomer units.
-
19M.3.sl.TZ2.a:
Draw a section of isotactic polychloroethene (polyvinylchloride, PVC) showing all the atoms and all the bonds of four monomer units.
-
19M.3.sl.TZ2.6a(i) :
Some proteins form an α-helix. State the name of another secondary protein structure.
-
19M.3.sl.TZ2.6a(i):
Some proteins form an α-helix. State the name of another secondary protein structure.
-
19M.3.sl.TZ2.a(i):
Some proteins form an α-helix. State the name of another secondary protein structure.
-
19M.3.sl.TZ2.6a(ii):
Compare and contrast the bonding responsible for the two secondary structures.
One similarity:
One difference:
-
19M.3.sl.TZ2.6a(ii):
Compare and contrast the bonding responsible for the two secondary structures.
One similarity:
One difference:
-
19M.3.sl.TZ2.a(ii):
Compare and contrast the bonding responsible for the two secondary structures.
One similarity:
One difference:
-
19M.3.sl.TZ2.7b:
Lecithin is a major component of cell membranes. Describe the structure of a cell membrane.
-
19M.3.sl.TZ2.b:
Lecithin is a major component of cell membranes. Describe the structure of a cell membrane.
-
19M.3.sl.TZ2.7b:
Lecithin is a major component of cell membranes. Describe the structure of a cell membrane.
-
19M.3.sl.TZ2.4b:
Once extracted, the purity of the metal can be assessed using ICP-MS. Suggest two advantages of using plasma technology rather than regular mass spectrometry.
-
19M.3.sl.TZ2.4b:
Once extracted, the purity of the metal can be assessed using ICP-MS. Suggest two advantages of using plasma technology rather than regular mass spectrometry.
-
19M.3.sl.TZ2.b:
Once extracted, the purity of the metal can be assessed using ICP-MS. Suggest two advantages of using plasma technology rather than regular mass spectrometry.
-
19M.3.sl.TZ2.4d:
Outline how alloys conduct electricity and why they are often harder than pure metals.
Conduct electricity:
Harder than pure metals:
-
19M.3.sl.TZ2.4d:
Outline how alloys conduct electricity and why they are often harder than pure metals.
Conduct electricity:
Harder than pure metals:
-
19M.3.sl.TZ2.d:
Outline how alloys conduct electricity and why they are often harder than pure metals.
Conduct electricity:
Harder than pure metals:
-
19M.3.sl.TZ2.6c(i):
Suggest two reasons why oil decomposes faster at the surface of the ocean than at greater depth.
-
19M.3.sl.TZ2.6c(i):
Suggest two reasons why oil decomposes faster at the surface of the ocean than at greater depth.
-
19M.3.sl.TZ2.c(i):
Suggest two reasons why oil decomposes faster at the surface of the ocean than at greater depth.
-
19M.3.sl.TZ2.10b:
Determine the specific energy, in kJ g−1, and energy density, in kJ cm−3, of hexane, C6H14. Give both answers to three significant figures.
Hexane: Mr = 86.2; ΔHc = −4163 kJ mol−1; density = 0.660 g cm−3
Specific energy:
Energy density:
-
19M.3.sl.TZ2.10b:
Determine the specific energy, in kJ g−1, and energy density, in kJ cm−3, of hexane, C6H14. Give both answers to three significant figures.
Hexane: Mr = 86.2; ΔHc = −4163 kJ mol−1; density = 0.660 g cm−3
Specific energy:
Energy density:
-
19M.3.sl.TZ2.b:
Determine the specific energy, in kJ g−1, and energy density, in kJ cm−3, of hexane, C6H14. Give both answers to three significant figures.
Hexane: Mr = 86.2; ΔHc = −4163 kJ mol−1; density = 0.660 g cm−3
Specific energy:
Energy density:
-
19M.3.sl.TZ2.12b:
Evaluate the use of biodiesel in place of diesel from crude oil.
Strength:
Limitation:
-
19M.3.sl.TZ2.12b:
Evaluate the use of biodiesel in place of diesel from crude oil.
Strength:
Limitation:
-
19M.3.sl.TZ2.b:
Evaluate the use of biodiesel in place of diesel from crude oil.
Strength:
Limitation:
-
19M.3.sl.TZ2.13c:
Outline one approach to controlling industrial emissions of carbon dioxide.
-
19M.3.sl.TZ2.13c:
Outline one approach to controlling industrial emissions of carbon dioxide.
-
19M.3.sl.TZ2.c:
Outline one approach to controlling industrial emissions of carbon dioxide.
-
19M.3.sl.TZ2.7a(ii):
Identify the type of reaction in (a).
-
19M.3.sl.TZ2.a(ii):
Identify the type of reaction in (a).
-
19M.3.sl.TZ2.7a(ii):
Identify the type of reaction in (a).
-
19M.3.sl.TZ2.7d:
Lecithin aids the body’s absorption of vitamin E.
Suggest why vitamin E is fat-soluble.
-
19M.3.sl.TZ2.7d:
Lecithin aids the body’s absorption of vitamin E.
Suggest why vitamin E is fat-soluble.
-
19M.3.sl.TZ2.d:
Lecithin aids the body’s absorption of vitamin E.
Suggest why vitamin E is fat-soluble.
-
19M.3.sl.TZ2.14b(i):
State one advantage of using morphine as an analgesic.
-
19M.3.sl.TZ2.14b(i):
State one advantage of using morphine as an analgesic.
-
19M.3.sl.TZ2.b(i):
State one advantage of using morphine as an analgesic.
-
19M.3.sl.TZ2.15a:
Predict one absorption band present in an infrared (IR) spectrum of aspirin, using section 26 of the data booklet.
-
19M.3.sl.TZ2.15a:
Predict one absorption band present in an infrared (IR) spectrum of aspirin, using section 26 of the data booklet.
-
19M.3.sl.TZ2.a:
Predict one absorption band present in an infrared (IR) spectrum of aspirin, using section 26 of the data booklet.
-
19M.3.sl.TZ2.5c:
Identify a hazardous product of the incineration of polychloroethene.
-
19M.3.sl.TZ2.5c:
Identify a hazardous product of the incineration of polychloroethene.
-
19M.3.sl.TZ2.c:
Identify a hazardous product of the incineration of polychloroethene.
-
19M.3.sl.TZ2.13a:
State one greenhouse gas, other than carbon dioxide.
-
19M.3.sl.TZ2.13a:
State one greenhouse gas, other than carbon dioxide.
-
19M.3.sl.TZ2.a:
State one greenhouse gas, other than carbon dioxide.
-
19M.3.sl.TZ2.14a:
Distinguish between therapeutic window and therapeutic index in humans.
Therapeutic window:
Therapeutic index:
-
19M.3.sl.TZ2.14a:
Distinguish between therapeutic window and therapeutic index in humans.
Therapeutic window:
Therapeutic index:
-
19M.3.sl.TZ2.a:
Distinguish between therapeutic window and therapeutic index in humans.
Therapeutic window:
Therapeutic index:
-
19M.3.sl.TZ2.15c:
Outline how aspirin can be chemically modified to increase its solubility in water.
-
19M.3.sl.TZ2.15c:
Outline how aspirin can be chemically modified to increase its solubility in water.
-
19M.3.sl.TZ2.c:
Outline how aspirin can be chemically modified to increase its solubility in water.
-
19M.3.sl.TZ2.16b:
Some antacids contain carbonates.
Determine the pH of a buffer solution which contains 0.160 mol dm−3 CO32− and 0.200 mol dm−3 HCO3−, using section 1 of the data booklet.
pKa (HCO3−) = 10.32
-
19M.3.sl.TZ2.16b:
Some antacids contain carbonates.
Determine the pH of a buffer solution which contains 0.160 mol dm−3 CO32− and 0.200 mol dm−3 HCO3−, using section 1 of the data booklet.
pKa (HCO3−) = 10.32
-
19M.3.sl.TZ2.b:
Some antacids contain carbonates.
Determine the pH of a buffer solution which contains 0.160 mol dm−3 CO32− and 0.200 mol dm−3 HCO3−, using section 1 of the data booklet.
pKa (HCO3−) = 10.32
-
19M.3.sl.TZ2.5d:
Explain how plasticizers affect the properties of plastics.
-
19M.3.sl.TZ2.5d:
Explain how plasticizers affect the properties of plastics.
-
19M.3.sl.TZ2.d:
Explain how plasticizers affect the properties of plastics.
-
19M.3.sl.TZ2.5e:
Suggest why the addition of plasticizers is controversial.
-
19M.3.sl.TZ2.5e:
Suggest why the addition of plasticizers is controversial.
-
19M.3.sl.TZ2.e:
Suggest why the addition of plasticizers is controversial.
-
19M.3.sl.TZ2.3:
Describe the characteristics of the nematic liquid crystal phase and the effect that an electric field has on it.
Shape of molecules:Distribution:
Effect of electric field:
-
19M.3.sl.TZ2.3:
Describe the characteristics of the nematic liquid crystal phase and the effect that an electric field has on it.
Shape of molecules:Distribution:
Effect of electric field:
-
19M.3.sl.TZ2.8b:
Sketch the cyclic structures of the two monosaccharides which combine to form sucrose.
-
19M.3.sl.TZ2.8b:
Sketch the cyclic structures of the two monosaccharides which combine to form sucrose.
-
19M.3.sl.TZ2.b:
Sketch the cyclic structures of the two monosaccharides which combine to form sucrose.
-
19M.3.sl.TZ2.9:
The regular rise and fall of sea levels, known as tides, can be used to generate energy.
State one advantage, other than limiting greenhouse gas emissions, and one disadvantage of tidal power.
Advantage:
Disadvantage:
-
19M.3.sl.TZ2.9:
The regular rise and fall of sea levels, known as tides, can be used to generate energy.
State one advantage, other than limiting greenhouse gas emissions, and one disadvantage of tidal power.
Advantage:
Disadvantage:
-
19M.3.sl.TZ2.14b(ii):
Explain why diamorphine (heroin) is more potent than morphine using section 37 of the data booklet.
-
19M.3.sl.TZ2.14b(ii):
Explain why diamorphine (heroin) is more potent than morphine using section 37 of the data booklet.
-
19M.3.sl.TZ2.b(ii):
Explain why diamorphine (heroin) is more potent than morphine using section 37 of the data booklet.
-
19M.3.sl.TZ2.6c(ii):
Oil spills can be treated with an enzyme mixture to speed up decomposition.
Outline one factor to be considered when assessing the greenness of an enzyme mixture.
-
19M.3.sl.TZ2.6c(ii):
Oil spills can be treated with an enzyme mixture to speed up decomposition.
Outline one factor to be considered when assessing the greenness of an enzyme mixture.
-
19M.3.sl.TZ2.c(ii):
Oil spills can be treated with an enzyme mixture to speed up decomposition.
Outline one factor to be considered when assessing the greenness of an enzyme mixture.
-
19M.3.sl.TZ2.10a:
Crude oil can be converted into fuels by fractional distillation and cracking.
Contrast these two processes.
-
19M.3.sl.TZ2.10a:
Crude oil can be converted into fuels by fractional distillation and cracking.
Contrast these two processes.
-
19M.3.sl.TZ2.a:
Crude oil can be converted into fuels by fractional distillation and cracking.
Contrast these two processes.
-
19M.3.sl.TZ2.12a:
The structure of chlorophyll is given in section 35 of the data booklet.
State the feature of the chlorophyll molecule that enables it to absorb light in the visible spectrum.
-
19M.3.sl.TZ2.12a:
The structure of chlorophyll is given in section 35 of the data booklet.
State the feature of the chlorophyll molecule that enables it to absorb light in the visible spectrum.
-
19M.3.sl.TZ2.a:
The structure of chlorophyll is given in section 35 of the data booklet.
State the feature of the chlorophyll molecule that enables it to absorb light in the visible spectrum.
-
19M.3.sl.TZ2.6b:
Explain why an increase in temperature reduces the rate of an enzyme-catalyzed reaction.
-
19M.3.sl.TZ2.6b:
Explain why an increase in temperature reduces the rate of an enzyme-catalyzed reaction.
-
19M.3.sl.TZ2.b:
Explain why an increase in temperature reduces the rate of an enzyme-catalyzed reaction.
-
19M.3.sl.TZ2.15b(i):
Determine the mass of aspirin which reacted with 16.25 cm3 of 0.100 mol dm−3 NaOH solution.
-
19M.3.sl.TZ2.15b(i):
Determine the mass of aspirin which reacted with 16.25 cm3 of 0.100 mol dm−3 NaOH solution.
-
19M.3.sl.TZ2.b(i):
Determine the mass of aspirin which reacted with 16.25 cm3 of 0.100 mol dm−3 NaOH solution.
-
19M.3.sl.TZ2.7e:
Phospholipids are also found in lipoprotein structures.
Describe two effects of increased levels of low-density lipoprotein (LDL) on health.
-
19M.3.sl.TZ2.7e:
Phospholipids are also found in lipoprotein structures.
Describe two effects of increased levels of low-density lipoprotein (LDL) on health.
-
19M.3.sl.TZ2.e:
Phospholipids are also found in lipoprotein structures.
Describe two effects of increased levels of low-density lipoprotein (LDL) on health.
-
19M.3.sl.TZ2.7c:
Predict, giving a reason, the relative energy density of a carbohydrate and a lipid of similar molar mass.
-
19M.3.sl.TZ2.7c:
Predict, giving a reason, the relative energy density of a carbohydrate and a lipid of similar molar mass.
-
19M.3.sl.TZ2.c:
Predict, giving a reason, the relative energy density of a carbohydrate and a lipid of similar molar mass.
-
19M.3.sl.TZ2.11a(i):
Determine the other product of the fission reaction of plutonium-239.
-
19M.3.sl.TZ2.11a(i):
Determine the other product of the fission reaction of plutonium-239.
-
19M.3.sl.TZ2.a(i):
Determine the other product of the fission reaction of plutonium-239.
-
19M.3.sl.TZ2.16a(i):
Outline how ranitidine (Zantac) inhibits stomach acid production.
-
19M.3.sl.TZ2.16a(i):
Outline how ranitidine (Zantac) inhibits stomach acid production.
-
19M.3.sl.TZ2.a(i):
Outline how ranitidine (Zantac) inhibits stomach acid production.
-
19M.3.sl.TZ2.17a:
Outline one way in which antiviral drugs work.
-
19M.3.sl.TZ2.17a:
Outline one way in which antiviral drugs work.
-
19M.3.sl.TZ2.a:
Outline one way in which antiviral drugs work.
-
19M.3.sl.TZ2.17b:
Discuss two difficulties associated with solving the AIDS problem.
-
19M.3.sl.TZ2.17b:
Discuss two difficulties associated with solving the AIDS problem.
-
19M.3.sl.TZ2.b:
Discuss two difficulties associated with solving the AIDS problem.
-
19M.3.sl.TZ2.11c:
90Sr, a common product of fission, has a half-life of 28.8 years.
Determine the number of years for the activity of a sample of 90Sr to fall to one eighth () of its initial value.
-
19M.3.sl.TZ2.11c:
90Sr, a common product of fission, has a half-life of 28.8 years.
Determine the number of years for the activity of a sample of 90Sr to fall to one eighth () of its initial value.
-
19M.3.sl.TZ2.c:
90Sr, a common product of fission, has a half-life of 28.8 years.
Determine the number of years for the activity of a sample of 90Sr to fall to one eighth () of its initial value.
-
19M.3.sl.TZ2.13b:
Describe the effect of infrared (IR) radiation on carbon dioxide molecules.
-
19M.3.sl.TZ2.13b:
Describe the effect of infrared (IR) radiation on carbon dioxide molecules.
-
19M.3.sl.TZ2.b:
Describe the effect of infrared (IR) radiation on carbon dioxide molecules.
-
19M.3.sl.TZ2.15e:
Outline two factors which must be considered to assess the greenness of any chemical process.
-
19M.3.sl.TZ2.15e:
Outline two factors which must be considered to assess the greenness of any chemical process.
-
19M.3.sl.TZ2.e:
Outline two factors which must be considered to assess the greenness of any chemical process.
-
19M.3.sl.TZ2.11a(ii):
Outline the concept of critical mass with respect to fission reactions.
-
19M.3.sl.TZ2.11a(ii):
Outline the concept of critical mass with respect to fission reactions.
-
19M.3.sl.TZ2.a(ii):
Outline the concept of critical mass with respect to fission reactions.
-
19M.3.sl.TZ2.11a(iii):
Outline one advantage of allowing all countries access to the technology to generate electricity by nuclear fission.
-
19M.3.sl.TZ2.11a(iii):
Outline one advantage of allowing all countries access to the technology to generate electricity by nuclear fission.
-
19M.3.sl.TZ2.a(iii):
Outline one advantage of allowing all countries access to the technology to generate electricity by nuclear fission.
-
19M.3.sl.TZ2.11b:
State one advantage of using fusion reactions rather than fission to generate electrical power.
-
19M.3.sl.TZ2.11b:
State one advantage of using fusion reactions rather than fission to generate electrical power.
-
19M.3.sl.TZ2.b:
State one advantage of using fusion reactions rather than fission to generate electrical power.
-
19M.3.sl.TZ2.15b(ii):
Determine the percentage purity of the synthesized aspirin.
-
19M.3.sl.TZ2.15b(ii):
Determine the percentage purity of the synthesized aspirin.
-
19M.3.sl.TZ2.b(ii):
Determine the percentage purity of the synthesized aspirin.
-
19M.3.sl.TZ2.16a(ii):
Outline two advantages of taking ranitidine instead of an antacid which neutralizes excess acid.
-
19M.3.sl.TZ2.16a(ii):
Outline two advantages of taking ranitidine instead of an antacid which neutralizes excess acid.
-
19M.3.sl.TZ2.a(ii):
Outline two advantages of taking ranitidine instead of an antacid which neutralizes excess acid.
- 19N.3.hl.TZ0.5c: Discuss why the recycling of plastics is an energy intensive process.
- 19N.3.hl.TZ0.5c: Discuss why the recycling of plastics is an energy intensive process.
- 19N.3.hl.TZ0.c: Discuss why the recycling of plastics is an energy intensive process.
- 19N.3.sl.TZ0.9c: Explain why stearic acid has a higher melting point than oleic acid.
- 19N.3.sl.TZ0.9c: Explain why stearic acid has a higher melting point than oleic acid.
- 19N.3.sl.TZ0.c: Explain why stearic acid has a higher melting point than oleic acid.
- 19N.3.sl.TZ0.4c: Polypropene is a thermoplastic. Outline what is meant by thermoplastic.
- 19N.3.sl.TZ0.4c: Polypropene is a thermoplastic. Outline what is meant by thermoplastic.
- 19N.3.sl.TZ0.c: Polypropene is a thermoplastic. Outline what is meant by thermoplastic.
-
19N.3.sl.TZ0.5a:
Discuss why different methods of reduction are needed to extract metals.
-
19N.3.sl.TZ0.5a:
Discuss why different methods of reduction are needed to extract metals.
-
19N.3.sl.TZ0.a:
Discuss why different methods of reduction are needed to extract metals.
- 19N.3.sl.TZ0.6b: State how liquid crystals are affected by an electric field.
- 19N.3.sl.TZ0.6b: State how liquid crystals are affected by an electric field.
- 19N.3.sl.TZ0.b: State how liquid crystals are affected by an electric field.
- 19N.3.sl.TZ0.4d: Discuss why the recycling of plastics is an energy intensive process.
- 19N.3.sl.TZ0.4d: Discuss why the recycling of plastics is an energy intensive process.
- 19N.3.sl.TZ0.d: Discuss why the recycling of plastics is an energy intensive process.
- 19N.3.sl.TZ0.6a: Describe the arrangement of soap molecules in the nematic liquid crystal phase.
- 19N.3.sl.TZ0.6a: Describe the arrangement of soap molecules in the nematic liquid crystal phase.
- 19N.3.sl.TZ0.a: Describe the arrangement of soap molecules in the nematic liquid crystal phase.
- 19N.3.hl.TZ0.16b: Outline what is meant by the degradation of energy.
- 19N.3.hl.TZ0.16b: Outline what is meant by the degradation of energy.
- 19N.3.hl.TZ0.b: Outline what is meant by the degradation of energy.
- 19N.3.sl.TZ0.17a: Suggest one reactant used to prepare aspirin from salicylic acid.
- 19N.3.sl.TZ0.17a: Suggest one reactant used to prepare aspirin from salicylic acid.
- 19N.3.sl.TZ0.a: Suggest one reactant used to prepare aspirin from salicylic acid.
- 19N.3.sl.TZ0.8a: The graph shows the relationship between the temperature and the rate of an enzyme-catalysed...
- 19N.3.sl.TZ0.8a: The graph shows the relationship between the temperature and the rate of an enzyme-catalysed...
- 19N.3.sl.TZ0.a: The graph shows the relationship between the temperature and the rate of an enzyme-catalysed...
-
19N.3.sl.TZ0.4a:
Draw a section of an isotactic polypropene polymer chain containing four repeating units.
-
19N.3.sl.TZ0.4a:
Draw a section of an isotactic polypropene polymer chain containing four repeating units.
-
19N.3.sl.TZ0.a:
Draw a section of an isotactic polypropene polymer chain containing four repeating units.
-
19N.3.sl.TZ0.13b:
Beryllium-8 is a radioactive isotope with a half-life of 6.70 × 10−17 s.
Calculate the mass of beryllium-8 remaining after 2.01 × 10−16 s from a sample initially containing 4.00 g of beryllium-8.
-
19N.3.sl.TZ0.13b:
Beryllium-8 is a radioactive isotope with a half-life of 6.70 × 10−17 s.
Calculate the mass of beryllium-8 remaining after 2.01 × 10−16 s from a sample initially containing 4.00 g of beryllium-8.
-
19N.3.sl.TZ0.b:
Beryllium-8 is a radioactive isotope with a half-life of 6.70 × 10−17 s.
Calculate the mass of beryllium-8 remaining after 2.01 × 10−16 s from a sample initially containing 4.00 g of beryllium-8.
-
19N.3.hl.TZ0.18a(iii):
Calculate the heat energy released, in J, by the fusion reaction producing one atom of carbon-12. Use section 2 of the data booklet and E = mc2.
-
19N.3.hl.TZ0.18a(iii):
Calculate the heat energy released, in J, by the fusion reaction producing one atom of carbon-12. Use section 2 of the data booklet and E = mc2.
-
19N.3.hl.TZ0.a(iii):
Calculate the heat energy released, in J, by the fusion reaction producing one atom of carbon-12. Use section 2 of the data booklet and E = mc2.
- 19N.3.hl.TZ0.20d(i): Outline the functions of the dye, TiO2 and the electrolyte in the operation of the...
- 19N.3.hl.TZ0.20d(i): Outline the functions of the dye, TiO2 and the electrolyte in the operation of the...
- 19N.3.hl.TZ0.d(i): Outline the functions of the dye, TiO2 and the electrolyte in the operation of the...
- 19N.3.sl.TZ0.4b: Predict, with a reason, whether isotactic or atactic polypropene has the higher melting point.
- 19N.3.sl.TZ0.4b: Predict, with a reason, whether isotactic or atactic polypropene has the higher melting point.
- 19N.3.sl.TZ0.b: Predict, with a reason, whether isotactic or atactic polypropene has the higher melting point.
-
19N.3.hl.TZ0.10b(iii):
Calculate the ratio of [A−] : [HA] in a buffer of pH 6.0 given that pKa for the acid is 4.83, using section 1 of the data booklet.
-
19N.3.hl.TZ0.10b(iii):
Calculate the ratio of [A−] : [HA] in a buffer of pH 6.0 given that pKa for the acid is 4.83, using section 1 of the data booklet.
-
19N.3.hl.TZ0.b(iii):
Calculate the ratio of [A−] : [HA] in a buffer of pH 6.0 given that pKa for the acid is 4.83, using section 1 of the data booklet.
- 19N.3.hl.TZ0.14a: The graph shows the change in oxygen partial pressure in blood, measured at different pH...
- 19N.3.hl.TZ0.14a: The graph shows the change in oxygen partial pressure in blood, measured at different pH...
- 19N.3.hl.TZ0.a: The graph shows the change in oxygen partial pressure in blood, measured at different pH...
- 19N.3.sl.TZ0.12b(ii): The 1H NMR spectrum of one of the products has four signals. The integration trace shows a ratio...
- 19N.3.sl.TZ0.12b(ii): The 1H NMR spectrum of one of the products has four signals. The integration trace shows a ratio...
- 19N.3.sl.TZ0.b(ii): The 1H NMR spectrum of one of the products has four signals. The integration trace shows a ratio...
- 19N.3.sl.TZ0.19b: Suggest a concern about the disposal of solvents from drug manufacturing.
- 19N.3.sl.TZ0.19b: Suggest a concern about the disposal of solvents from drug manufacturing.
- 19N.3.sl.TZ0.b: Suggest a concern about the disposal of solvents from drug manufacturing.
-
19N.3.sl.TZ0.7b:
The isoelectric point of amino acids is the intermediate pH at which an amino acid is electrically neutral.
Suggest why Asp and Phe have different isoelectric points.
-
19N.3.sl.TZ0.7b:
The isoelectric point of amino acids is the intermediate pH at which an amino acid is electrically neutral.
Suggest why Asp and Phe have different isoelectric points.
-
19N.3.sl.TZ0.b:
The isoelectric point of amino acids is the intermediate pH at which an amino acid is electrically neutral.
Suggest why Asp and Phe have different isoelectric points.
- 19N.3.hl.TZ0.13b: Explain how the double-helical structure of DNA is stabilized once formed.
- 19N.3.hl.TZ0.13b: Explain how the double-helical structure of DNA is stabilized once formed.
- 19N.3.hl.TZ0.b: Explain how the double-helical structure of DNA is stabilized once formed.
- 19N.3.hl.TZ0.4a(i): Outline how resistance to electric currents occurs in metals.
- 19N.3.hl.TZ0.4a(i): Outline how resistance to electric currents occurs in metals.
- 19N.3.hl.TZ0.a(i): Outline how resistance to electric currents occurs in metals.
-
19N.3.sl.TZ0.7a:
Draw the structure of the dipeptide Asp–Phe using section 33 of the data booklet.
-
19N.3.sl.TZ0.7a:
Draw the structure of the dipeptide Asp–Phe using section 33 of the data booklet.
-
19N.3.sl.TZ0.a:
Draw the structure of the dipeptide Asp–Phe using section 33 of the data booklet.
-
19N.3.hl.TZ0.20b(ii):
Suggest how PEM fuel cells can be used to produce a larger voltage than that calculated in (b)(i).
-
19N.3.hl.TZ0.20b(ii):
Suggest how PEM fuel cells can be used to produce a larger voltage than that calculated in (b)(i).
-
19N.3.hl.TZ0.b(ii):
Suggest how PEM fuel cells can be used to produce a larger voltage than that calculated in (b)(i).
-
19N.3.sl.TZ0.9a:
The iodine number is the number of grams of iodine which reacts with 100 g of fat. Calculate the iodine number of oleic acid.
-
19N.3.sl.TZ0.9a:
The iodine number is the number of grams of iodine which reacts with 100 g of fat. Calculate the iodine number of oleic acid.
-
19N.3.sl.TZ0.a:
The iodine number is the number of grams of iodine which reacts with 100 g of fat. Calculate the iodine number of oleic acid.
- 19N.3.sl.TZ0.9d(i): State one similarity and one difference in composition between phospholipids and...
- 19N.3.sl.TZ0.9d(i): State one similarity and one difference in composition between phospholipids and...
- 19N.3.sl.TZ0.d(i): State one similarity and one difference in composition between phospholipids and...
-
19N.3.sl.TZ0.16d:
Calculate the pH of a buffer solution which contains 0.20 mol dm−3 ethanoic acid and 0.50 mol dm−3 sodium ethanoate. Use section 1 of the data booklet.
pKa (ethanoic acid) = 4.76
-
19N.3.sl.TZ0.16d:
Calculate the pH of a buffer solution which contains 0.20 mol dm−3 ethanoic acid and 0.50 mol dm−3 sodium ethanoate. Use section 1 of the data booklet.
pKa (ethanoic acid) = 4.76
-
19N.3.sl.TZ0.d:
Calculate the pH of a buffer solution which contains 0.20 mol dm−3 ethanoic acid and 0.50 mol dm−3 sodium ethanoate. Use section 1 of the data booklet.
pKa (ethanoic acid) = 4.76
- 19N.3.hl.TZ0.27a: State two common side effects of radiotherapy.
- 19N.3.hl.TZ0.27a: State two common side effects of radiotherapy.
- 19N.3.hl.TZ0.a: State two common side effects of radiotherapy.
-
19N.3.sl.TZ0.8b:
Explain why a change in pH affects the tertiary structure of an enzyme in solution.
-
19N.3.sl.TZ0.8b:
Explain why a change in pH affects the tertiary structure of an enzyme in solution.
-
19N.3.sl.TZ0.b:
Explain why a change in pH affects the tertiary structure of an enzyme in solution.
-
19N.3.hl.TZ0.7:
X-ray crystallography of a metal crystal produces a diffraction pattern of bright spots.
Using X-rays of wavelength 1.54 × 10−10 m, the first bright spots were produced at an angle θ of 22.3° from the centre.
Calculate the separation between planes of atoms in the lattice, in meters, using section 1 of the data booklet.
-
19N.3.hl.TZ0.7:
X-ray crystallography of a metal crystal produces a diffraction pattern of bright spots.
Using X-rays of wavelength 1.54 × 10−10 m, the first bright spots were produced at an angle θ of 22.3° from the centre.
Calculate the separation between planes of atoms in the lattice, in meters, using section 1 of the data booklet.
-
19N.3.hl.TZ0.8:
1.40 × 10−3 g of NaOH (s) are dissolved in 250.0 cm3 of 1.00 × 10−11 mol dm−3 Pb(OH)2 (aq) solution.
Determine the change in lead ion concentration in the solution, using section 32 of the data booklet.
-
19N.3.hl.TZ0.8:
1.40 × 10−3 g of NaOH (s) are dissolved in 250.0 cm3 of 1.00 × 10−11 mol dm−3 Pb(OH)2 (aq) solution.
Determine the change in lead ion concentration in the solution, using section 32 of the data booklet.
-
19N.3.sl.TZ0.9d(ii):
Identify a reagent that hydrolyses triglycerides.
-
19N.3.sl.TZ0.9d(ii):
Identify a reagent that hydrolyses triglycerides.
-
19N.3.sl.TZ0.d(ii):
Identify a reagent that hydrolyses triglycerides.
-
19N.3.sl.TZ0.11a:
Discuss the data.
-
19N.3.sl.TZ0.11a:
Discuss the data.
-
19N.3.sl.TZ0.a:
Discuss the data.
- 19N.3.sl.TZ0.12b(i): Reforming reactions are used to increase the octane number of a hydrocarbon fuel. Suggest the...
- 19N.3.sl.TZ0.12b(i): Reforming reactions are used to increase the octane number of a hydrocarbon fuel. Suggest the...
- 19N.3.sl.TZ0.b(i): Reforming reactions are used to increase the octane number of a hydrocarbon fuel. Suggest the...
- 19N.3.sl.TZ0.15b: Explain why diamorphine has greater potency than morphine.
- 19N.3.sl.TZ0.15b: Explain why diamorphine has greater potency than morphine.
- 19N.3.sl.TZ0.b: Explain why diamorphine has greater potency than morphine.
- 19N.3.sl.TZ0.8c: State one use of enzymes in reducing environmental problems.
- 19N.3.sl.TZ0.8c: State one use of enzymes in reducing environmental problems.
- 19N.3.sl.TZ0.c: State one use of enzymes in reducing environmental problems.
-
19N.3.sl.TZ0.5b(ii):
Write half-equations for the electrolysis of molten alumina using graphite electrodes, deducing the state symbols of the products.
Anode (positive electrode):
Cathode (negative electrode):
-
19N.3.sl.TZ0.5b(ii):
Write half-equations for the electrolysis of molten alumina using graphite electrodes, deducing the state symbols of the products.
Anode (positive electrode):
Cathode (negative electrode):
-
19N.3.sl.TZ0.b(ii):
Write half-equations for the electrolysis of molten alumina using graphite electrodes, deducing the state symbols of the products.
Anode (positive electrode):
Cathode (negative electrode):
- 19N.3.sl.TZ0.10c: Explain why maltose, C12H22O11, is soluble in water.
- 19N.3.sl.TZ0.10c: Explain why maltose, C12H22O11, is soluble in water.
- 19N.3.sl.TZ0.c: Explain why maltose, C12H22O11, is soluble in water.
- 19N.3.sl.TZ0.13a(ii): Explain why fusion is an exothermic process.
- 19N.3.sl.TZ0.13a(ii): Explain why fusion is an exothermic process.
- 19N.3.sl.TZ0.a(ii): Explain why fusion is an exothermic process.
-
19N.3.sl.TZ0.16b:
An antacid contains calcium carbonate and magnesium carbonate.
Write the equation for the reaction of magnesium carbonate with excess stomach acid.
-
19N.3.sl.TZ0.16b:
An antacid contains calcium carbonate and magnesium carbonate.
Write the equation for the reaction of magnesium carbonate with excess stomach acid.
-
19N.3.sl.TZ0.b:
An antacid contains calcium carbonate and magnesium carbonate.
Write the equation for the reaction of magnesium carbonate with excess stomach acid.
-
19N.3.sl.TZ0.17b:
Aspirin, C6H4(OCOCH3)COOH, is only slightly soluble in water.
Outline, including an equation, how aspirin can be made more water-soluble. Use section 37 in the data booklet.
-
19N.3.sl.TZ0.17b:
Aspirin, C6H4(OCOCH3)COOH, is only slightly soluble in water.
Outline, including an equation, how aspirin can be made more water-soluble. Use section 37 in the data booklet.
-
19N.3.sl.TZ0.b:
Aspirin, C6H4(OCOCH3)COOH, is only slightly soluble in water.
Outline, including an equation, how aspirin can be made more water-soluble. Use section 37 in the data booklet.
- 19N.3.hl.TZ0.25b: Outline the impact of antibiotic waste on the environment.
- 19N.3.hl.TZ0.25b: Outline the impact of antibiotic waste on the environment.
- 19N.3.hl.TZ0.b: Outline the impact of antibiotic waste on the environment.
-
19N.3.hl.TZ0.26b:
Describe how the challenge in (a) was resolved by pharmaceutical companies.
-
19N.3.hl.TZ0.b:
Describe how the challenge in (a) was resolved by pharmaceutical companies.
-
19N.3.hl.TZ0.26b:
Describe how the challenge in (a) was resolved by pharmaceutical companies.
- 19N.3.sl.TZ0.18b: Discuss two difficulties, apart from socio-economic factors, associated with finding a cure for...
- 19N.3.sl.TZ0.18b: Discuss two difficulties, apart from socio-economic factors, associated with finding a cure for...
- 19N.3.sl.TZ0.b: Discuss two difficulties, apart from socio-economic factors, associated with finding a cure for...
- 19N.3.sl.TZ0.18c: The discovery of penicillins contributed to the development of antibiotics. Explain how the...
- 19N.3.sl.TZ0.18c: The discovery of penicillins contributed to the development of antibiotics. Explain how the...
- 19N.3.sl.TZ0.c: The discovery of penicillins contributed to the development of antibiotics. Explain how the...
- 19N.3.hl.TZ0.11a: Outline the significance of the Michaelis constant Km.
- 19N.3.hl.TZ0.11a: Outline the significance of the Michaelis constant Km.
- 19N.3.hl.TZ0.a: Outline the significance of the Michaelis constant Km.
-
19N.3.hl.TZ0.12b:
The chemical change in stored fats causes rancidity characterized by an unpleasant smell or taste.
Compare hydrolytic and oxidative rancidity.
-
19N.3.hl.TZ0.12b:
The chemical change in stored fats causes rancidity characterized by an unpleasant smell or taste.
Compare hydrolytic and oxidative rancidity.
-
19N.3.hl.TZ0.b:
The chemical change in stored fats causes rancidity characterized by an unpleasant smell or taste.
Compare hydrolytic and oxidative rancidity.
- 19N.3.hl.TZ0.15b: Compare and contrast the structures of starch and cellulose. One similarity: One difference:
- 19N.3.hl.TZ0.15b: Compare and contrast the structures of starch and cellulose. One similarity: One difference:
- 19N.3.hl.TZ0.b: Compare and contrast the structures of starch and cellulose. One similarity: One difference:
- 19N.3.sl.TZ0.15a: State the names of two functional groups present in all three molecules, using section 37 of the...
- 19N.3.sl.TZ0.15a: State the names of two functional groups present in all three molecules, using section 37 of the...
- 19N.3.sl.TZ0.a: State the names of two functional groups present in all three molecules, using section 37 of the...
- 19N.3.hl.TZ0.25c: Suggest a concern about the disposal of solvents from drug manufacturing.
- 19N.3.hl.TZ0.25c: Suggest a concern about the disposal of solvents from drug manufacturing.
- 19N.3.hl.TZ0.c: Suggest a concern about the disposal of solvents from drug manufacturing.
- 19N.3.hl.TZ0.25d: Discuss two difficulties, apart from socio-economic factors, associated with finding a cure for...
- 19N.3.hl.TZ0.25d: Discuss two difficulties, apart from socio-economic factors, associated with finding a cure for...
- 19N.3.hl.TZ0.d: Discuss two difficulties, apart from socio-economic factors, associated with finding a cure for...
- 19N.3.hl.TZ0.5b: State and explain why plasticizers are added to polymers.
- 19N.3.hl.TZ0.5b: State and explain why plasticizers are added to polymers.
- 19N.3.hl.TZ0.b: State and explain why plasticizers are added to polymers.
-
19N.3.sl.TZ0.14a:
Write the equation for the complete combustion of ethanol.
-
19N.3.sl.TZ0.14a:
Write the equation for the complete combustion of ethanol.
-
19N.3.sl.TZ0.a:
Write the equation for the complete combustion of ethanol.
-
19N.3.hl.TZ0.24c:
Explain how redox chemistry is used to measure the ethanol concentration in a breathalyser.
-
19N.3.hl.TZ0.24c:
Explain how redox chemistry is used to measure the ethanol concentration in a breathalyser.
-
19N.3.hl.TZ0.c:
Explain how redox chemistry is used to measure the ethanol concentration in a breathalyser.
- 19N.3.hl.TZ0.26a: State the feature of Taxol that is a major challenge in its synthesis. Use section 37 of the data...
- 19N.3.hl.TZ0.26a: State the feature of Taxol that is a major challenge in its synthesis. Use section 37 of the data...
- 19N.3.hl.TZ0.a: State the feature of Taxol that is a major challenge in its synthesis. Use section 37 of the data...
- 19N.3.sl.TZ0.10a: State the name of one functional group common to all three vitamins shown in section 35 of the...
- 19N.3.sl.TZ0.10a: State the name of one functional group common to all three vitamins shown in section 35 of the...
- 19N.3.sl.TZ0.a: State the name of one functional group common to all three vitamins shown in section 35 of the...
- 19N.3.hl.TZ0.15a: Describe the function of chlorophyll in photosynthesis.
- 19N.3.hl.TZ0.15a: Describe the function of chlorophyll in photosynthesis.
- 19N.3.hl.TZ0.a: Describe the function of chlorophyll in photosynthesis.
-
19N.3.sl.TZ0.14b:
Outline the evidence that relates global warming to increasing concentrations of greenhouse gases in the atmosphere.
-
19N.3.sl.TZ0.14b:
Outline the evidence that relates global warming to increasing concentrations of greenhouse gases in the atmosphere.
-
19N.3.sl.TZ0.b:
Outline the evidence that relates global warming to increasing concentrations of greenhouse gases in the atmosphere.
-
19N.3.hl.TZ0.24b:
Describe a technique for the detection of steroids in blood and urine.
-
19N.3.hl.TZ0.24b:
Describe a technique for the detection of steroids in blood and urine.
-
19N.3.hl.TZ0.b:
Describe a technique for the detection of steroids in blood and urine.
- 19N.3.sl.TZ0.19a: Outline the impact of antibiotic waste on the environment.
- 19N.3.sl.TZ0.19a: Outline the impact of antibiotic waste on the environment.
- 19N.3.sl.TZ0.a: Outline the impact of antibiotic waste on the environment.
- 19N.3.hl.TZ0.20d(ii): Suggest an advantage of the DSSC over silicon-based photovoltaic cells.
- 19N.3.hl.TZ0.20d(ii): Suggest an advantage of the DSSC over silicon-based photovoltaic cells.
- 19N.3.hl.TZ0.d(ii): Suggest an advantage of the DSSC over silicon-based photovoltaic cells.
- 19N.3.sl.TZ0.12a: Suggest why a high-octane number fuel is preferable.
- 19N.3.sl.TZ0.12a: Suggest why a high-octane number fuel is preferable.
- 19N.3.sl.TZ0.a: Suggest why a high-octane number fuel is preferable.
- 19N.3.hl.TZ0.20c: Suggest an advantage of the PEM fuel cell over the lead-acid battery for use in cars.
- 19N.3.hl.TZ0.20c: Suggest an advantage of the PEM fuel cell over the lead-acid battery for use in cars.
- 19N.3.hl.TZ0.c: Suggest an advantage of the PEM fuel cell over the lead-acid battery for use in cars.
- 19N.3.hl.TZ0.21b: Experimental research on both animals and humans contributes to the development...
- 19N.3.hl.TZ0.21b: Experimental research on both animals and humans contributes to the development...
- 19N.3.hl.TZ0.b: Experimental research on both animals and humans contributes to the development...
-
19N.3.sl.TZ0.18a:
State one difference between bacteria and viruses.
-
19N.3.sl.TZ0.18a:
State one difference between bacteria and viruses.
-
19N.3.sl.TZ0.a:
State one difference between bacteria and viruses.
- 19N.3.sl.TZ0.14d: State the type of reaction that occurs when ethanol reacts with vegetable oil to form biodiesel.
- 19N.3.sl.TZ0.14d: State the type of reaction that occurs when ethanol reacts with vegetable oil to form biodiesel.
- 19N.3.sl.TZ0.d: State the type of reaction that occurs when ethanol reacts with vegetable oil to form biodiesel.
-
19N.3.hl.TZ0.20b(i):
Calculate the cell potential, Eθ, in V, using section 24 of the data booklet.
-
19N.3.hl.TZ0.20b(i):
Calculate the cell potential, Eθ, in V, using section 24 of the data booklet.
-
19N.3.hl.TZ0.b(i):
Calculate the cell potential, Eθ, in V, using section 24 of the data booklet.
-
19N.3.hl.TZ0.27c:
25.0 μg of iodine-131, with a half-life of 8.00 days, was left to decay.
Calculate the mass of iodine-131, in μg, remaining after 32.0 days. Use section 1 of the data booklet.
-
19N.3.hl.TZ0.27c:
25.0 μg of iodine-131, with a half-life of 8.00 days, was left to decay.
Calculate the mass of iodine-131, in μg, remaining after 32.0 days. Use section 1 of the data booklet.
-
19N.3.hl.TZ0.c:
25.0 μg of iodine-131, with a half-life of 8.00 days, was left to decay.
Calculate the mass of iodine-131, in μg, remaining after 32.0 days. Use section 1 of the data booklet.
-
19N.3.sl.TZ0.13a(i):
State the nuclear equation for the fusion reaction.
-
19N.3.sl.TZ0.13a(i):
State the nuclear equation for the fusion reaction.
-
19N.3.sl.TZ0.a(i):
State the nuclear equation for the fusion reaction.
- 19N.3.sl.TZ0.16c: Outline how ranitidine reduces stomach acidity.
- 19N.3.sl.TZ0.16c: Outline how ranitidine reduces stomach acidity.
- 19N.3.sl.TZ0.c: Outline how ranitidine reduces stomach acidity.
-
19N.3.hl.TZ0.12a:
The iodine number is the number of grams of iodine which reacts with 100 g of fat. Calculate the iodine number of oleic acid.
-
19N.3.hl.TZ0.12a:
The iodine number is the number of grams of iodine which reacts with 100 g of fat. Calculate the iodine number of oleic acid.
-
19N.3.hl.TZ0.a:
The iodine number is the number of grams of iodine which reacts with 100 g of fat. Calculate the iodine number of oleic acid.
- 19N.3.hl.TZ0.12c: State one similarity and one difference in composition between phospholipids and...
- 19N.3.hl.TZ0.12c: State one similarity and one difference in composition between phospholipids and...
- 19N.3.hl.TZ0.c: State one similarity and one difference in composition between phospholipids and...
- 19N.3.hl.TZ0.25a: Explain how the beta-lactam ring is responsible for the antibiotic properties of penicillin....
- 19N.3.hl.TZ0.25a: Explain how the beta-lactam ring is responsible for the antibiotic properties of penicillin....
- 19N.3.hl.TZ0.a: Explain how the beta-lactam ring is responsible for the antibiotic properties of penicillin....
-
19N.3.hl.TZ0.18b:
Beryllium-8 is a radioactive isotope with a half-life of 6.70 × 10−17 s.
Calculate the mass of beryllium-8 remaining after 2.01 × 10−16 s from a sample initially containing 4.00 g of beryllium-8.
-
19N.3.hl.TZ0.18b:
Beryllium-8 is a radioactive isotope with a half-life of 6.70 × 10−17 s.
Calculate the mass of beryllium-8 remaining after 2.01 × 10−16 s from a sample initially containing 4.00 g of beryllium-8.
-
19N.3.hl.TZ0.b:
Beryllium-8 is a radioactive isotope with a half-life of 6.70 × 10−17 s.
Calculate the mass of beryllium-8 remaining after 2.01 × 10−16 s from a sample initially containing 4.00 g of beryllium-8.
- 17N.3.sl.TZ0.6b: Outline why the iron nanoparticle catalysts produced by the HIPCO process are more efficient than...
- 17N.3.sl.TZ0.6b: Outline why the iron nanoparticle catalysts produced by the HIPCO process are more efficient than...
- 17N.3.sl.TZ0.b: Outline why the iron nanoparticle catalysts produced by the HIPCO process are more efficient than...
-
17N.3.sl.TZ0.12c:
State the name of one renewable source of energy other than wood.
-
17N.3.sl.TZ0.12c:
State the name of one renewable source of energy other than wood.
-
17N.3.sl.TZ0.c:
State the name of one renewable source of energy other than wood.
-
17N.3.hl.TZ0.11b.i:
The malonate ion acts as an inhibitor for the enzyme.
Suggest, on the molecular level, how the malonate ion is able to inhibit the enzyme.
-
17N.3.hl.TZ0.11b.i:
The malonate ion acts as an inhibitor for the enzyme.
Suggest, on the molecular level, how the malonate ion is able to inhibit the enzyme.
-
17N.3.hl.TZ0.b.i:
The malonate ion acts as an inhibitor for the enzyme.
Suggest, on the molecular level, how the malonate ion is able to inhibit the enzyme.
-
17N.3.hl.TZ0.15b:
Retinal is the key molecule involved in vision. Explain the roles of cis and trans-retinal in vision and how the isomers are formed in the visual cycle.
-
17N.3.hl.TZ0.15b:
Retinal is the key molecule involved in vision. Explain the roles of cis and trans-retinal in vision and how the isomers are formed in the visual cycle.
-
17N.3.hl.TZ0.b:
Retinal is the key molecule involved in vision. Explain the roles of cis and trans-retinal in vision and how the isomers are formed in the visual cycle.
-
17N.3.hl.TZ0.21a:
State a nuclear equation to show the decay of lutetium-177.
-
17N.3.hl.TZ0.a:
State a nuclear equation to show the decay of lutetium-177.
-
17N.3.hl.TZ0.21a:
State a nuclear equation to show the decay of lutetium-177.
-
18M.3.hl.TZ1.4c.ii:
Deduce, giving a reason, whether the atom economy of a condensation polymerization, such as this, would be greater or less than an addition polymerization, such as the formation of HDPE.
-
18M.3.hl.TZ1.4c.ii:
Deduce, giving a reason, whether the atom economy of a condensation polymerization, such as this, would be greater or less than an addition polymerization, such as the formation of HDPE.
-
18M.3.hl.TZ1.c.ii:
Deduce, giving a reason, whether the atom economy of a condensation polymerization, such as this, would be greater or less than an addition polymerization, such as the formation of HDPE.
-
18M.3.hl.TZ2.8e:
Sketch the wedge and dash (3-D) representations of alanine enantiomers.
-
18M.3.hl.TZ2.8e:
Sketch the wedge and dash (3-D) representations of alanine enantiomers.
-
18M.3.hl.TZ2.e:
Sketch the wedge and dash (3-D) representations of alanine enantiomers.
-
18M.3.hl.TZ2.8f:
UV-Vis spectroscopy can be used to determine the unknown concentration of a substance in a solution.
Calculate the concentration of an unknown sample of pepsin with an absorbance of 0.725 using section 1 of the data booklet.
Cell length = 1.00 cm
Molar absorptivity (extinction coefficient) of the sample = 49650 dm3 cm−1 mol−1
-
18M.3.hl.TZ2.f:
UV-Vis spectroscopy can be used to determine the unknown concentration of a substance in a solution.
Calculate the concentration of an unknown sample of pepsin with an absorbance of 0.725 using section 1 of the data booklet.
Cell length = 1.00 cm
Molar absorptivity (extinction coefficient) of the sample = 49650 dm3 cm−1 mol−1
-
18M.3.hl.TZ2.8f:
UV-Vis spectroscopy can be used to determine the unknown concentration of a substance in a solution.
Calculate the concentration of an unknown sample of pepsin with an absorbance of 0.725 using section 1 of the data booklet.
Cell length = 1.00 cm
Molar absorptivity (extinction coefficient) of the sample = 49650 dm3 cm−1 mol−1
-
18M.3.hl.TZ2.8g:
A different series of pepsin samples is used to develop a calibration curve.
Estimate the concentration of an unknown sample of pepsin with an absorbance of 0.30 from the graph.
-
18M.3.hl.TZ2.g:
A different series of pepsin samples is used to develop a calibration curve.
Estimate the concentration of an unknown sample of pepsin with an absorbance of 0.30 from the graph.
-
18M.3.hl.TZ2.8g:
A different series of pepsin samples is used to develop a calibration curve.
Estimate the concentration of an unknown sample of pepsin with an absorbance of 0.30 from the graph.
-
18M.3.sl.TZ1.4e:
Suggest why there are so many different ways in which plastics can be classified. HDPE can, for example, be categorized thermoplastic, an addition polymer, having Resin Identification Code (RIC) 2, etc.
-
18M.3.sl.TZ1.4e:
Suggest why there are so many different ways in which plastics can be classified. HDPE can, for example, be categorized thermoplastic, an addition polymer, having Resin Identification Code (RIC) 2, etc.
-
18M.3.sl.TZ1.e:
Suggest why there are so many different ways in which plastics can be classified. HDPE can, for example, be categorized thermoplastic, an addition polymer, having Resin Identification Code (RIC) 2, etc.
-
18M.3.sl.TZ1.5:
Aluminium is produced by the electrolysis of a molten electrolyte containing bauxite.
Determine the mass, in g, of aluminium produced by the passage of a charge of 1.296 × 1013 C. Use sections 2 and 6 of the data booklet.
-
18M.3.sl.TZ1.5:
Aluminium is produced by the electrolysis of a molten electrolyte containing bauxite.
Determine the mass, in g, of aluminium produced by the passage of a charge of 1.296 × 1013 C. Use sections 2 and 6 of the data booklet.
-
18M.3.sl.TZ1.6a:
Draw the structural formula of a dipeptide containing the residues of valine, Val, and asparagine, Asn, using section 33 of the data booklet.
-
18M.3.sl.TZ1.6a:
Draw the structural formula of a dipeptide containing the residues of valine, Val, and asparagine, Asn, using section 33 of the data booklet.
-
18M.3.sl.TZ1.a:
Draw the structural formula of a dipeptide containing the residues of valine, Val, and asparagine, Asn, using section 33 of the data booklet.
-
18M.3.sl.TZ1.6c.i:
State the name of the process used to break down the insulin protein into its constituent amino acids.
-
18M.3.sl.TZ1.6c.i:
State the name of the process used to break down the insulin protein into its constituent amino acids.
-
18M.3.sl.TZ1.c.i:
State the name of the process used to break down the insulin protein into its constituent amino acids.
-
18M.3.sl.TZ1.7c.i:
Fish oil is an excellent dietary source of omega-3 fatty acids. Outline one impact on health of consuming omega-3 fatty acids.
-
18M.3.sl.TZ1.7c.i:
Fish oil is an excellent dietary source of omega-3 fatty acids. Outline one impact on health of consuming omega-3 fatty acids.
-
18M.3.sl.TZ1.c.i:
Fish oil is an excellent dietary source of omega-3 fatty acids. Outline one impact on health of consuming omega-3 fatty acids.
-
18M.3.sl.TZ1.7c.ii:
Predict the solubility of retinol (vitamin A) in body fat, giving a reason. Use section 35 of the data booklet.
-
18M.3.sl.TZ1.7c.ii:
Predict the solubility of retinol (vitamin A) in body fat, giving a reason. Use section 35 of the data booklet.
-
18M.3.sl.TZ1.c.ii:
Predict the solubility of retinol (vitamin A) in body fat, giving a reason. Use section 35 of the data booklet.
-
18M.3.sl.TZ1.12a.ii:
Explain how 235U fission results in a chain reaction, including the concept of critical mass.
-
18M.3.sl.TZ1.12a.ii:
Explain how 235U fission results in a chain reaction, including the concept of critical mass.
-
18M.3.sl.TZ1.a.ii:
Explain how 235U fission results in a chain reaction, including the concept of critical mass.
-
18M.3.sl.TZ2.4b.ii:
Compare two ways in which recycling differs from reusing plastics.
-
18M.3.sl.TZ2.4b.ii:
Compare two ways in which recycling differs from reusing plastics.
-
18M.3.sl.TZ2.b.ii:
Compare two ways in which recycling differs from reusing plastics.
-
18M.3.sl.TZ2.4c:
Civilizations are often characterized by the materials they use.
Suggest an advantage polymers have over materials from the iron age.
-
18M.3.sl.TZ2.4c:
Civilizations are often characterized by the materials they use.
Suggest an advantage polymers have over materials from the iron age.
-
18M.3.sl.TZ2.c:
Civilizations are often characterized by the materials they use.
Suggest an advantage polymers have over materials from the iron age.
-
18M.3.sl.TZ2.6e:
Determine, to the correct number of significant figures, the energy produced by the respiration of 29.9 g of C5H10O5.
ΔHc (C5H10O5) = 205.9 kJ mol−1
-
18M.3.sl.TZ2.6e:
Determine, to the correct number of significant figures, the energy produced by the respiration of 29.9 g of C5H10O5.
ΔHc (C5H10O5) = 205.9 kJ mol−1
-
18M.3.sl.TZ2.e:
Determine, to the correct number of significant figures, the energy produced by the respiration of 29.9 g of C5H10O5.
ΔHc (C5H10O5) = 205.9 kJ mol−1
-
18M.3.sl.TZ2.18c:
Explain how omeprazole (Prilosec) regulates pH in the stomach.
-
18M.3.sl.TZ2.18c:
Explain how omeprazole (Prilosec) regulates pH in the stomach.
-
18M.3.sl.TZ2.c:
Explain how omeprazole (Prilosec) regulates pH in the stomach.
-
18N.3.sl.TZ0.2b.i:
Structures of poly(methyl acrylate), PMA, and Bakelite® are shown.
Suggest, giving reasons, which is the thermoplastic polymer and which is the thermosetting polymer.
-
18N.3.sl.TZ0.2b.i:
Structures of poly(methyl acrylate), PMA, and Bakelite® are shown.
Suggest, giving reasons, which is the thermoplastic polymer and which is the thermosetting polymer.
-
18N.3.sl.TZ0.b.i:
Structures of poly(methyl acrylate), PMA, and Bakelite® are shown.
Suggest, giving reasons, which is the thermoplastic polymer and which is the thermosetting polymer.
- 18N.3.sl.TZ0.2c.ii: Identify another advantage of using a zeolite instead of concentrated sulfuric acid.
- 18N.3.sl.TZ0.2c.ii: Identify another advantage of using a zeolite instead of concentrated sulfuric acid.
- 18N.3.sl.TZ0.c.ii: Identify another advantage of using a zeolite instead of concentrated sulfuric acid.
- 18N.3.sl.TZ0.4b: The structure of biphenyl nitrile is shown. Describe, giving a reason, a feature of the...
- 18N.3.sl.TZ0.4b: The structure of biphenyl nitrile is shown. Describe, giving a reason, a feature of the...
- 18N.3.sl.TZ0.b: The structure of biphenyl nitrile is shown. Describe, giving a reason, a feature of the...
-
18N.3.sl.TZ0.5b:
Suggest why it is advisable for those living in northerly or southerly latitudes (that is away from the equator) to take vitamin D supplements during the winter.
-
18N.3.sl.TZ0.5b:
Suggest why it is advisable for those living in northerly or southerly latitudes (that is away from the equator) to take vitamin D supplements during the winter.
-
18N.3.sl.TZ0.b:
Suggest why it is advisable for those living in northerly or southerly latitudes (that is away from the equator) to take vitamin D supplements during the winter.
- 18N.3.sl.TZ0.6b.i: Explain the action of an enzyme and state one of its limitations.
- 18N.3.sl.TZ0.6b.i: Explain the action of an enzyme and state one of its limitations.
- 18N.3.sl.TZ0.b.i: Explain the action of an enzyme and state one of its limitations.
- 18N.3.sl.TZ0.9b.ii: Deduce the fission reaction when 239Pu is bombarded with a neutron to produce 133Xe and 103Zr.
- 18N.3.sl.TZ0.9b.ii: Deduce the fission reaction when 239Pu is bombarded with a neutron to produce 133Xe and 103Zr.
- 18N.3.sl.TZ0.b.ii: Deduce the fission reaction when 239Pu is bombarded with a neutron to produce 133Xe and 103Zr.
-
18N.3.hl.TZ0.2d.iii:
Repeating units of several polymers are listed.
The infrared (IR) spectrum of one of these polymers is shown.
Deduce, giving a reason, the name of this polymer and its Resin Identification Code (RIC), using sections 26 and 30 in the data booklet.
-
18N.3.hl.TZ0.2d.iii:
Repeating units of several polymers are listed.
The infrared (IR) spectrum of one of these polymers is shown.
Deduce, giving a reason, the name of this polymer and its Resin Identification Code (RIC), using sections 26 and 30 in the data booklet.
-
18N.3.hl.TZ0.d.iii:
Repeating units of several polymers are listed.
The infrared (IR) spectrum of one of these polymers is shown.
Deduce, giving a reason, the name of this polymer and its Resin Identification Code (RIC), using sections 26 and 30 in the data booklet.
- 18N.3.hl.TZ0.3d.i: State one feature of a chelating agent.
- 18N.3.hl.TZ0.3d.i: State one feature of a chelating agent.
- 18N.3.hl.TZ0.d.i: State one feature of a chelating agent.
- 18N.3.hl.TZ0.8a: Describe the interaction responsible for the secondary structure of a protein.
- 18N.3.hl.TZ0.8a: Describe the interaction responsible for the secondary structure of a protein.
- 18N.3.hl.TZ0.a: Describe the interaction responsible for the secondary structure of a protein.
- 18N.3.hl.TZ0.14a: Suggest another advantage and one disadvantage of solar energy.
- 18N.3.hl.TZ0.14a: Suggest another advantage and one disadvantage of solar energy.
- 18N.3.hl.TZ0.a: Suggest another advantage and one disadvantage of solar energy.
-
19M.3.hl.TZ1.8a:
Draw the structure of the repeating unit of starch and state the type of linkage formed between these units.
Type of linkage:
-
19M.3.hl.TZ1.8a:
Draw the structure of the repeating unit of starch and state the type of linkage formed between these units.
Type of linkage:
-
19M.3.hl.TZ1.a:
Draw the structure of the repeating unit of starch and state the type of linkage formed between these units.
Type of linkage:
-
19M.3.hl.TZ1.12a(ii):
Suggest, based on the Michaelis–Menten plot, how a competitive inhibitor such as ethanol reduces the toxicity of methanol.
-
19M.3.hl.TZ1.12a(ii):
Suggest, based on the Michaelis–Menten plot, how a competitive inhibitor such as ethanol reduces the toxicity of methanol.
-
19M.3.hl.TZ1.a(ii):
Suggest, based on the Michaelis–Menten plot, how a competitive inhibitor such as ethanol reduces the toxicity of methanol.
-
19M.3.hl.TZ1.12b:
Enzymatic activity is studied in buffered aqueous solutions.
Calculate the ratio in which 0.1 mol dm−3 NaH2PO4 (aq) and 0.1 mol dm−3 Na2HPO4 (aq) should be mixed to obtain a buffer with pH = 6.10. Use section 1 of the data booklet.
pKa (NaH2PO4) = 7.20
-
19M.3.hl.TZ1.12b:
Enzymatic activity is studied in buffered aqueous solutions.
Calculate the ratio in which 0.1 mol dm−3 NaH2PO4 (aq) and 0.1 mol dm−3 Na2HPO4 (aq) should be mixed to obtain a buffer with pH = 6.10. Use section 1 of the data booklet.
pKa (NaH2PO4) = 7.20
-
19M.3.hl.TZ1.b:
Enzymatic activity is studied in buffered aqueous solutions.
Calculate the ratio in which 0.1 mol dm−3 NaH2PO4 (aq) and 0.1 mol dm−3 Na2HPO4 (aq) should be mixed to obtain a buffer with pH = 6.10. Use section 1 of the data booklet.
pKa (NaH2PO4) = 7.20
-
19M.3.hl.TZ1.13:
Ascorbic acid and retinol are two important vitamins.
Explain why ascorbic acid is soluble in water and retinol is not. Use section 35 of the data booklet.
-
19M.3.hl.TZ1.13:
Ascorbic acid and retinol are two important vitamins.
Explain why ascorbic acid is soluble in water and retinol is not. Use section 35 of the data booklet.
-
19M.3.hl.TZ1.17a:
Ethanol has a Research Octane Number (RON) of 108.6.
Outline how higher octane fuels affect engine performance.
-
19M.3.hl.TZ1.17a:
Ethanol has a Research Octane Number (RON) of 108.6.
Outline how higher octane fuels affect engine performance.
-
19M.3.hl.TZ1.a:
Ethanol has a Research Octane Number (RON) of 108.6.
Outline how higher octane fuels affect engine performance.
-
19M.3.hl.TZ1.17b(iii):
Outline why aqueous ethanol, rather than pure ethanol, is used in a DEFC.
-
19M.3.hl.TZ1.b(iii):
Outline why aqueous ethanol, rather than pure ethanol, is used in a DEFC.
-
19M.3.hl.TZ1.17b(iii):
Outline why aqueous ethanol, rather than pure ethanol, is used in a DEFC.
-
19M.3.hl.TZ2.4b:
Once extracted, the purity of the metal can be assessed using ICP-MS. Suggest two advantages of using plasma technology rather than regular mass spectrometry.
-
19M.3.hl.TZ2.4b:
Once extracted, the purity of the metal can be assessed using ICP-MS. Suggest two advantages of using plasma technology rather than regular mass spectrometry.
-
19M.3.hl.TZ2.b:
Once extracted, the purity of the metal can be assessed using ICP-MS. Suggest two advantages of using plasma technology rather than regular mass spectrometry.
-
19M.3.hl.TZ2.4e:
Carbon nanotubes are added to metals to increase tensile strength.
Write an equation for the formation of carbon nanotubes from carbon monoxide.
-
19M.3.hl.TZ2.4e:
Carbon nanotubes are added to metals to increase tensile strength.
Write an equation for the formation of carbon nanotubes from carbon monoxide.
-
19M.3.hl.TZ2.e:
Carbon nanotubes are added to metals to increase tensile strength.
Write an equation for the formation of carbon nanotubes from carbon monoxide.
-
19M.3.hl.TZ2.5a:
Draw a section of isotactic polychloroethene (polyvinylchloride, PVC) showing all the atoms and all the bonds of four monomer units.
-
19M.3.hl.TZ2.5a:
Draw a section of isotactic polychloroethene (polyvinylchloride, PVC) showing all the atoms and all the bonds of four monomer units.
-
19M.3.hl.TZ2.a:
Draw a section of isotactic polychloroethene (polyvinylchloride, PVC) showing all the atoms and all the bonds of four monomer units.
-
19M.3.hl.TZ2.5c:
Explain how plasticizers affect the properties of plastics.
-
19M.3.hl.TZ2.5c:
Explain how plasticizers affect the properties of plastics.
-
19M.3.hl.TZ2.c:
Explain how plasticizers affect the properties of plastics.
-
19M.3.hl.TZ2.5e:
Outline, giving a reason, how addition and condensation polymerization compare with regard to green chemistry.
-
19M.3.hl.TZ2.5e:
Outline, giving a reason, how addition and condensation polymerization compare with regard to green chemistry.
-
19M.3.hl.TZ2.e:
Outline, giving a reason, how addition and condensation polymerization compare with regard to green chemistry.
-
19M.3.hl.TZ2.6a:
State the number of atoms in the unit cell.
-
19M.3.hl.TZ2.6a:
State the number of atoms in the unit cell.
-
19M.3.hl.TZ2.a:
State the number of atoms in the unit cell.
-
19M.3.hl.TZ2.6b:
Determine the density of calcium, in g cm−3, using section 2 of the data booklet.
Ar = 40.08; metallic radius (r) = 1.97 × 10−10 m
-
19M.3.hl.TZ2.6b:
Determine the density of calcium, in g cm−3, using section 2 of the data booklet.
Ar = 40.08; metallic radius (r) = 1.97 × 10−10 m
-
19M.3.hl.TZ2.b:
Determine the density of calcium, in g cm−3, using section 2 of the data booklet.
Ar = 40.08; metallic radius (r) = 1.97 × 10−10 m
-
19M.3.hl.TZ2.7a:
State what is meant by a superconductor.
-
19M.3.hl.TZ2.7a:
State what is meant by a superconductor.
-
19M.3.hl.TZ2.a:
State what is meant by a superconductor.
-
19M.3.hl.TZ2.8c:
State a method, other than precipitation, of removing heavy metal ions from solution.
-
19M.3.hl.TZ2.8c:
State a method, other than precipitation, of removing heavy metal ions from solution.
-
19M.3.hl.TZ2.c:
State a method, other than precipitation, of removing heavy metal ions from solution.
-
19M.3.hl.TZ2.9a(i):
Some proteins form an α-helix. State the name of another secondary protein structure.
-
19M.3.hl.TZ2.9a(i):
Some proteins form an α-helix. State the name of another secondary protein structure.
-
19M.3.hl.TZ2.a(i):
Some proteins form an α-helix. State the name of another secondary protein structure.
-
19M.3.hl.TZ2.9b:
Explain why an increase in temperature reduces the rate of an enzyme-catalyzed reaction.
-
19M.3.hl.TZ2.9b:
Explain why an increase in temperature reduces the rate of an enzyme-catalyzed reaction.
-
19M.3.hl.TZ2.b:
Explain why an increase in temperature reduces the rate of an enzyme-catalyzed reaction.
-
19M.3.hl.TZ2.10a(ii):
Calculate the pH of the glutamine solution using section 1 of the data booklet.
-
19M.3.hl.TZ2.10a(ii):
Calculate the pH of the glutamine solution using section 1 of the data booklet.
-
19M.3.hl.TZ2.a(ii):
Calculate the pH of the glutamine solution using section 1 of the data booklet.
-
19M.3.hl.TZ2.11a(i):
Deduce the structural formula of phosphatidylcholine.
-
19M.3.hl.TZ2.11a(i):
Deduce the structural formula of phosphatidylcholine.
-
19M.3.hl.TZ2.a(i):
Deduce the structural formula of phosphatidylcholine.
-
19M.3.hl.TZ2.11a(ii):
Identify the type of reaction in (a).
-
19M.3.hl.TZ2.11a(ii):
Identify the type of reaction in (a).
-
19M.3.hl.TZ2.a(ii):
Identify the type of reaction in (a).
-
19M.3.hl.TZ2.11b:
Lecithin is a major component of cell membranes. Describe the structure of a cell membrane.
-
19M.3.hl.TZ2.11b:
Lecithin is a major component of cell membranes. Describe the structure of a cell membrane.
-
19M.3.hl.TZ2.b:
Lecithin is a major component of cell membranes. Describe the structure of a cell membrane.
-
19M.3.hl.TZ2.11d:
Phospholipids are also found in lipoprotein structures.
Describe one effect of increased levels of low-density lipoprotein (LDL) on health.
-
19M.3.hl.TZ2.11d:
Phospholipids are also found in lipoprotein structures.
Describe one effect of increased levels of low-density lipoprotein (LDL) on health.
-
19M.3.hl.TZ2.d:
Phospholipids are also found in lipoprotein structures.
Describe one effect of increased levels of low-density lipoprotein (LDL) on health.
-
19M.3.hl.TZ2.12b:
Classify, giving your reason, the hexose (six-membered) ring of sucrose as an α or β isomer.
-
19M.3.hl.TZ2.12b:
Classify, giving your reason, the hexose (six-membered) ring of sucrose as an α or β isomer.
-
19M.3.hl.TZ2.b:
Classify, giving your reason, the hexose (six-membered) ring of sucrose as an α or β isomer.
-
19M.3.hl.TZ2.16d:
Calculate the half-life of an isotope whose mass falls from 5.0 × 10−5 g to 4.0 × 10−5 g in 31.4 s, using section 1 of the data booklet.
-
19M.3.hl.TZ2.22d:
State why aspirin should not be taken with alcohol.
-
19M.3.hl.TZ2.22d:
State why aspirin should not be taken with alcohol.
-
19M.3.hl.TZ2.d:
State why aspirin should not be taken with alcohol.
-
19M.3.hl.TZ2.24a:
Outline one way in which antiviral drugs work.
-
19M.3.hl.TZ2.24a:
Outline one way in which antiviral drugs work.
-
19M.3.hl.TZ2.a:
Outline one way in which antiviral drugs work.
-
19M.3.sl.TZ1.3a(ii):
Explain why lithium is paramagnetic while lithium hydride is diamagnetic by referring to electron configurations.
-
19M.3.sl.TZ1.3a(ii):
Explain why lithium is paramagnetic while lithium hydride is diamagnetic by referring to electron configurations.
-
19M.3.sl.TZ1.a(ii):
Explain why lithium is paramagnetic while lithium hydride is diamagnetic by referring to electron configurations.
-
19M.3.sl.TZ1.3b(ii):
Suggest a better method.
-
19M.3.sl.TZ1.3b(ii):
Suggest a better method.
-
19M.3.sl.TZ1.b(ii):
Suggest a better method.
-
19M.3.sl.TZ1.4a:
Outline two differences between heterogeneous and homogeneous catalysts.
-
19M.3.sl.TZ1.4a:
Outline two differences between heterogeneous and homogeneous catalysts.
-
19M.3.sl.TZ1.a:
Outline two differences between heterogeneous and homogeneous catalysts.
-
19M.3.sl.TZ1.4b:
Suggest, giving a reason, how elastomers used for the tyre tread can increase the traction between the tyre and the road.
-
19M.3.sl.TZ1.4b:
Suggest, giving a reason, how elastomers used for the tyre tread can increase the traction between the tyre and the road.
-
19M.3.sl.TZ1.b:
Suggest, giving a reason, how elastomers used for the tyre tread can increase the traction between the tyre and the road.
-
19M.3.sl.TZ1.4c(ii):
The trace quantities of dioxins from tyre fires are rarely inhaled and instead settle on the ground.
Describe why this is a health concern.
-
19M.3.sl.TZ1.4c(ii):
The trace quantities of dioxins from tyre fires are rarely inhaled and instead settle on the ground.
Describe why this is a health concern.
-
19M.3.sl.TZ1.c(ii):
The trace quantities of dioxins from tyre fires are rarely inhaled and instead settle on the ground.
Describe why this is a health concern.
-
19M.3.sl.TZ1.9a:
The melting points of cocoa butter and coconut oil are 34 °C and 25 °C respectively.
Explain this in terms of their saturated fatty acid composition.
-
19M.3.sl.TZ1.9a:
The melting points of cocoa butter and coconut oil are 34 °C and 25 °C respectively.
Explain this in terms of their saturated fatty acid composition.
-
19M.3.sl.TZ1.a:
The melting points of cocoa butter and coconut oil are 34 °C and 25 °C respectively.
Explain this in terms of their saturated fatty acid composition.
-
19M.3.sl.TZ1.9b:
Fats contain triglycerides that are esters of glycerol and fatty acids. Deduce an equation for the acid hydrolysis of the following triglyceride.
-
19M.3.sl.TZ1.9b:
Fats contain triglycerides that are esters of glycerol and fatty acids. Deduce an equation for the acid hydrolysis of the following triglyceride.
-
19M.3.sl.TZ1.b:
Fats contain triglycerides that are esters of glycerol and fatty acids. Deduce an equation for the acid hydrolysis of the following triglyceride.
-
19M.3.sl.TZ1.11c(ii):
List the following products, which are also obtained by fractional distillation, according to decreasing volatility: asphalt, diesel, gasoline, lubricating motor oil.
-
19M.3.sl.TZ1.11c(ii):
List the following products, which are also obtained by fractional distillation, according to decreasing volatility: asphalt, diesel, gasoline, lubricating motor oil.
-
19M.3.sl.TZ1.c(ii):
List the following products, which are also obtained by fractional distillation, according to decreasing volatility: asphalt, diesel, gasoline, lubricating motor oil.
-
19M.3.sl.TZ1.12b:
The critical mass for weapons-grade uranium can be as small as 15 kg. Outline what is meant by critical mass by referring to the equation in (a)(i).
-
19M.3.sl.TZ1.12b:
The critical mass for weapons-grade uranium can be as small as 15 kg. Outline what is meant by critical mass by referring to the equation in (a)(i).
-
19M.3.sl.TZ1.b:
The critical mass for weapons-grade uranium can be as small as 15 kg. Outline what is meant by critical mass by referring to the equation in (a)(i).
-
19M.3.sl.TZ2.4e:
Carbon nanotubes are added to metals to increase tensile strength.
Write an equation for the formation of carbon nanotubes from carbon monoxide.
-
19M.3.sl.TZ2.4e:
Carbon nanotubes are added to metals to increase tensile strength.
Write an equation for the formation of carbon nanotubes from carbon monoxide.
-
19M.3.sl.TZ2.e:
Carbon nanotubes are added to metals to increase tensile strength.
Write an equation for the formation of carbon nanotubes from carbon monoxide.
-
19M.3.sl.TZ2.8a:
State the name of the functional group forming part of the ring structure of each monosaccharide unit.
-
19M.3.sl.TZ2.8a:
State the name of the functional group forming part of the ring structure of each monosaccharide unit.
-
19M.3.sl.TZ2.a:
State the name of the functional group forming part of the ring structure of each monosaccharide unit.
-
19N.3.sl.TZ0.3a:
Describe how a heterogeneous catalyst provides an alternative pathway for a reaction.
-
19N.3.sl.TZ0.3a:
Describe how a heterogeneous catalyst provides an alternative pathway for a reaction.
-
19N.3.sl.TZ0.a:
Describe how a heterogeneous catalyst provides an alternative pathway for a reaction.
- 19N.3.sl.TZ0.3b: Distinguish between heterogeneous and homogeneous catalysts, giving one difference.
- 19N.3.sl.TZ0.3b: Distinguish between heterogeneous and homogeneous catalysts, giving one difference.
- 19N.3.sl.TZ0.b: Distinguish between heterogeneous and homogeneous catalysts, giving one difference.
-
19N.3.sl.TZ0.3c:
Nanotubes are used to support the active material in nanocatalysts.
Explain why oxygen cannot be used for the chemical vapour deposition (CVD) preparation of carbon nanotubes.
-
19N.3.sl.TZ0.3c:
Nanotubes are used to support the active material in nanocatalysts.
Explain why oxygen cannot be used for the chemical vapour deposition (CVD) preparation of carbon nanotubes.
-
19N.3.sl.TZ0.c:
Nanotubes are used to support the active material in nanocatalysts.
Explain why oxygen cannot be used for the chemical vapour deposition (CVD) preparation of carbon nanotubes.
- 19N.3.hl.TZ0.4a(ii): Suggest why the resistance of metals increases with temperature.
- 19N.3.hl.TZ0.4a(ii): Suggest why the resistance of metals increases with temperature.
- 19N.3.hl.TZ0.a(ii): Suggest why the resistance of metals increases with temperature.
- 19N.3.hl.TZ0.4b: State two differences between Type I and Type II superconductors.
- 19N.3.hl.TZ0.4b: State two differences between Type I and Type II superconductors.
- 19N.3.hl.TZ0.b: State two differences between Type I and Type II superconductors.
-
19N.3.hl.TZ0.5a:
Draw the structure of the monomers of Kevlar® if the by-product of the condensation polymerization is hydrogen chloride.
-
19N.3.hl.TZ0.5a:
Draw the structure of the monomers of Kevlar® if the by-product of the condensation polymerization is hydrogen chloride.
-
19N.3.hl.TZ0.a:
Draw the structure of the monomers of Kevlar® if the by-product of the condensation polymerization is hydrogen chloride.
-
19N.3.sl.TZ0.5b(i):
Determine the percentage of ionic bonding in alumina using sections 8 and 29 of the data booklet.
-
19N.3.sl.TZ0.5b(i):
Determine the percentage of ionic bonding in alumina using sections 8 and 29 of the data booklet.
-
19N.3.sl.TZ0.b(i):
Determine the percentage of ionic bonding in alumina using sections 8 and 29 of the data booklet.
-
19N.3.hl.TZ0.10a:
Draw the structure of the dipeptide Asp–Phe using section 33 of the data booklet.
-
19N.3.hl.TZ0.10a:
Draw the structure of the dipeptide Asp–Phe using section 33 of the data booklet.
-
19N.3.hl.TZ0.a:
Draw the structure of the dipeptide Asp–Phe using section 33 of the data booklet.
- 19N.3.hl.TZ0.10b(i): Describe, using another method, how a mixture of four amino acids, alanine, arginine, glutamic...
- 19N.3.hl.TZ0.10b(i): Describe, using another method, how a mixture of four amino acids, alanine, arginine, glutamic...
- 19N.3.hl.TZ0.b(i): Describe, using another method, how a mixture of four amino acids, alanine, arginine, glutamic...
- 19N.3.hl.TZ0.10b(ii): Suggest why alanine and glycine separate slightly at pH 6.5.
- 19N.3.hl.TZ0.10b(ii): Suggest why alanine and glycine separate slightly at pH 6.5.
- 19N.3.hl.TZ0.b(ii): Suggest why alanine and glycine separate slightly at pH 6.5.
-
19N.3.hl.TZ0.11b:
Compare the effects of competitive and non-competitive inhibitors.
-
19N.3.hl.TZ0.11b:
Compare the effects of competitive and non-competitive inhibitors.
-
19N.3.hl.TZ0.b:
Compare the effects of competitive and non-competitive inhibitors.
- 19N.3.sl.TZ0.9b: State one impact on health of the increase in LDL cholesterol concentration in blood.
- 19N.3.sl.TZ0.9b: State one impact on health of the increase in LDL cholesterol concentration in blood.
- 19N.3.sl.TZ0.b: State one impact on health of the increase in LDL cholesterol concentration in blood.
-
19N.3.hl.TZ0.13a:
List two components of nucleotides.
-
19N.3.hl.TZ0.13a:
List two components of nucleotides.
-
19N.3.hl.TZ0.a:
List two components of nucleotides.
- 19N.3.hl.TZ0.14b: Explain the biomagnification of the pesticide DDT.
- 19N.3.hl.TZ0.14b: Explain the biomagnification of the pesticide DDT.
- 19N.3.hl.TZ0.b: Explain the biomagnification of the pesticide DDT.
- 19N.3.hl.TZ0.14c: Vitamins are organic compounds essential in small amounts. State the name of one functional...
- 19N.3.hl.TZ0.14c: Vitamins are organic compounds essential in small amounts. State the name of one functional...
- 19N.3.hl.TZ0.c: Vitamins are organic compounds essential in small amounts. State the name of one functional...
- 19N.3.sl.TZ0.10b: Explain the biomagnification of the pesticide DDT.
- 19N.3.sl.TZ0.10b: Explain the biomagnification of the pesticide DDT.
- 19N.3.sl.TZ0.b: Explain the biomagnification of the pesticide DDT.
- 19N.3.hl.TZ0.15c: Explain why maltose, C12H22O11, is soluble in water.
- 19N.3.hl.TZ0.15c: Explain why maltose, C12H22O11, is soluble in water.
- 19N.3.hl.TZ0.c: Explain why maltose, C12H22O11, is soluble in water.
-
19N.3.sl.TZ0.11b:
In a natural gas power station, 1.00 tonne of natural gas produces 2.41 × 104 MJ of electricity.
Calculate the percentage efficiency of the power station.
1 tonne = 1000 kg
Specific energy of natural gas used = 55.4 MJ kg−1 -
19N.3.sl.TZ0.11b:
In a natural gas power station, 1.00 tonne of natural gas produces 2.41 × 104 MJ of electricity.
Calculate the percentage efficiency of the power station.
1 tonne = 1000 kg
Specific energy of natural gas used = 55.4 MJ kg−1 -
19N.3.sl.TZ0.b:
In a natural gas power station, 1.00 tonne of natural gas produces 2.41 × 104 MJ of electricity.
Calculate the percentage efficiency of the power station.
1 tonne = 1000 kg
Specific energy of natural gas used = 55.4 MJ kg−1 -
19N.3.hl.TZ0.16a:
Discuss the data.
-
19N.3.hl.TZ0.16a:
Discuss the data.
-
19N.3.hl.TZ0.a:
Discuss the data.
-
19N.3.hl.TZ0.18a(i):
State the nuclear equation for the fusion reaction.
-
19N.3.hl.TZ0.18a(i):
State the nuclear equation for the fusion reaction.
-
19N.3.hl.TZ0.a(i):
State the nuclear equation for the fusion reaction.
- 19N.3.hl.TZ0.18a(ii): Explain why fusion is an exothermic process.
- 19N.3.hl.TZ0.18a(ii): Explain why fusion is an exothermic process.
- 19N.3.hl.TZ0.a(ii): Explain why fusion is an exothermic process.
-
19N.3.sl.TZ0.14c:
Explain, including a suitable equation, why biofuels are considered to be carbon neutral.
-
19N.3.sl.TZ0.14c:
Explain, including a suitable equation, why biofuels are considered to be carbon neutral.
-
19N.3.sl.TZ0.c:
Explain, including a suitable equation, why biofuels are considered to be carbon neutral.
-
19N.3.hl.TZ0.20a:
Deduce the half-equations for the reactions occurring at the electrodes.
Anode (negative electrode):Cathode (positive electrode):
-
19N.3.hl.TZ0.20a:
Deduce the half-equations for the reactions occurring at the electrodes.
Anode (negative electrode):Cathode (positive electrode):
-
19N.3.hl.TZ0.a:
Deduce the half-equations for the reactions occurring at the electrodes.
Anode (negative electrode):Cathode (positive electrode):
- 19N.3.hl.TZ0.21a: Explain why diamorphine has greater potency than morphine.
- 19N.3.hl.TZ0.21a: Explain why diamorphine has greater potency than morphine.
- 19N.3.hl.TZ0.a: Explain why diamorphine has greater potency than morphine.
-
19N.3.sl.TZ0.16a:
Identify the compound responsible for the acidity of gastric juice, and state whether it is a strong or weak acid.
-
19N.3.sl.TZ0.16a:
Identify the compound responsible for the acidity of gastric juice, and state whether it is a strong or weak acid.
-
19N.3.sl.TZ0.a:
Identify the compound responsible for the acidity of gastric juice, and state whether it is a strong or weak acid.
-
19N.3.hl.TZ0.24a:
Infrared (IR) spectroscopy is used to identify functional groups in organic compounds.
Deduce the wavenumber, in cm−1, of an absorption peak found in the IR spectrum of testosterone but not in that of cholesterol.
-
19N.3.hl.TZ0.24a:
Infrared (IR) spectroscopy is used to identify functional groups in organic compounds.
Deduce the wavenumber, in cm−1, of an absorption peak found in the IR spectrum of testosterone but not in that of cholesterol.
-
19N.3.hl.TZ0.a:
Infrared (IR) spectroscopy is used to identify functional groups in organic compounds.
Deduce the wavenumber, in cm−1, of an absorption peak found in the IR spectrum of testosterone but not in that of cholesterol.
- 19N.3.hl.TZ0.27b: Explain why technetium-99m is the most common radioisotope used in nuclear medicine.
- 19N.3.hl.TZ0.27b: Explain why technetium-99m is the most common radioisotope used in nuclear medicine.
- 19N.3.hl.TZ0.b: Explain why technetium-99m is the most common radioisotope used in nuclear medicine.
- 20N.3.sl.TZ0.4a: Explain these properties of carbon nanotubes.
- 20N.3.sl.TZ0.4a: Explain these properties of carbon nanotubes.
- 20N.3.sl.TZ0.a: Explain these properties of carbon nanotubes.
-
20N.3.sl.TZ0.4b(iii):
Calculate the theoretical mass of magnesium obtained if a current of is used for hours. Use charge and section 2 of the data booklet
-
20N.3.sl.TZ0.4b(iii):
Calculate the theoretical mass of magnesium obtained if a current of is used for hours. Use charge and section 2 of the data booklet
-
20N.3.sl.TZ0.b(iii):
Calculate the theoretical mass of magnesium obtained if a current of is used for hours. Use charge and section 2 of the data booklet
- 20N.3.sl.TZ0.4c: Zeolites can be used as catalysts in the manufacture of CNT. Explain, with reference to their...
- 20N.3.sl.TZ0.4c: Zeolites can be used as catalysts in the manufacture of CNT. Explain, with reference to their...
- 20N.3.sl.TZ0.c: Zeolites can be used as catalysts in the manufacture of CNT. Explain, with reference to their...
- 20N.3.sl.TZ0.4e: Experiments have been done to explore the nematic liquid crystal behaviour of CNT. Justify how...
-
20N.3.sl.TZ0.5a(i):
Proteins are polymers of amino acids. A paper chromatogram of two amino acids, A1 and A2, is obtained using a non-polar solvent.
© International Baccalaureate Organization 2020.
Determine the value of A1.
-
20N.3.sl.TZ0.5a(i):
Proteins are polymers of amino acids. A paper chromatogram of two amino acids, A1 and A2, is obtained using a non-polar solvent.
© International Baccalaureate Organization 2020.
Determine the value of A1.
-
20N.3.sl.TZ0.a(i):
Proteins are polymers of amino acids. A paper chromatogram of two amino acids, A1 and A2, is obtained using a non-polar solvent.
© International Baccalaureate Organization 2020.
Determine the value of A1.
-
20N.3.sl.TZ0.5c:
Proteins are polymers of amino acids.
Describe how the tertiary structure differs from the quaternary structure in hemoglobin.
-
20N.3.sl.TZ0.5c:
Proteins are polymers of amino acids.
Describe how the tertiary structure differs from the quaternary structure in hemoglobin.
-
20N.3.sl.TZ0.c:
Proteins are polymers of amino acids.
Describe how the tertiary structure differs from the quaternary structure in hemoglobin.
-
20N.3.sl.TZ0.6c:
Phospholipids help maintain cellular environments while fatty acid lipids have important roles in energy storage and electrical insulation. Discuss the structural properties of saturated fats needed for these roles.
-
20N.3.sl.TZ0.6c:
Phospholipids help maintain cellular environments while fatty acid lipids have important roles in energy storage and electrical insulation. Discuss the structural properties of saturated fats needed for these roles.
-
20N.3.sl.TZ0.c:
Phospholipids help maintain cellular environments while fatty acid lipids have important roles in energy storage and electrical insulation. Discuss the structural properties of saturated fats needed for these roles.
- 20N.3.sl.TZ0.8b: Suggest, with a reason, if fat-soluble or water-soluble xenobiotics would have a larger BMF.
- 20N.3.sl.TZ0.8b: Suggest, with a reason, if fat-soluble or water-soluble xenobiotics would have a larger BMF.
- 20N.3.sl.TZ0.b: Suggest, with a reason, if fat-soluble or water-soluble xenobiotics would have a larger BMF.
-
20N.3.sl.TZ0.9a:
Calculate the energy released, in , from the complete combustion of of ethanol.
-
20N.3.sl.TZ0.9a:
Calculate the energy released, in , from the complete combustion of of ethanol.
-
20N.3.sl.TZ0.a:
Calculate the energy released, in , from the complete combustion of of ethanol.
- 20N.3.sl.TZ0.9b: State a class of organic compounds found in gasoline.
- 20N.3.sl.TZ0.9b: State a class of organic compounds found in gasoline.
- 20N.3.sl.TZ0.b: State a class of organic compounds found in gasoline.
-
20N.3.sl.TZ0.9c:
Outline the advantages and disadvantages of using biodiesel instead of gasoline as fuel for a car. Exclude any discussion of cost.
-
20N.3.sl.TZ0.9c:
Outline the advantages and disadvantages of using biodiesel instead of gasoline as fuel for a car. Exclude any discussion of cost.
-
20N.3.sl.TZ0.c:
Outline the advantages and disadvantages of using biodiesel instead of gasoline as fuel for a car. Exclude any discussion of cost.
-
20N.3.sl.TZ0.9f(i):
When combusted, all three fuels can release carbon dioxide, a greenhouse gas, as well as particulates. Contrast how carbon dioxide and particulates interact with sunlight.
-
20N.3.sl.TZ0.9f(i):
When combusted, all three fuels can release carbon dioxide, a greenhouse gas, as well as particulates. Contrast how carbon dioxide and particulates interact with sunlight.
-
20N.3.sl.TZ0.f(i):
When combusted, all three fuels can release carbon dioxide, a greenhouse gas, as well as particulates. Contrast how carbon dioxide and particulates interact with sunlight.
-
20N.3.sl.TZ0.9f(ii):
Methane is another greenhouse gas. Contrast the reasons why methane and carbon dioxide are considered significant greenhouse gases.
-
20N.3.sl.TZ0.9f(ii):
Methane is another greenhouse gas. Contrast the reasons why methane and carbon dioxide are considered significant greenhouse gases.
-
20N.3.sl.TZ0.f(ii):
Methane is another greenhouse gas. Contrast the reasons why methane and carbon dioxide are considered significant greenhouse gases.
-
20N.3.sl.TZ0.10b:
The half-life of 238U is years. Calculate the mass of 238U that remains after has decayed for years.
-
20N.3.sl.TZ0.10b:
The half-life of 238U is years. Calculate the mass of 238U that remains after has decayed for years.
-
20N.3.sl.TZ0.b:
The half-life of 238U is years. Calculate the mass of 238U that remains after has decayed for years.
- 20N.3.sl.TZ0.10c: Outline a health risk produced by exposure to radioactive decay.
- 20N.3.sl.TZ0.10c: Outline a health risk produced by exposure to radioactive decay.
- 20N.3.sl.TZ0.c: Outline a health risk produced by exposure to radioactive decay.
-
20N.3.sl.TZ0.10d:
Deduce the nuclear equation for the decay of uranium-238 to thorium-234.
-
20N.3.sl.TZ0.10d:
Deduce the nuclear equation for the decay of uranium-238 to thorium-234.
-
20N.3.sl.TZ0.d:
Deduce the nuclear equation for the decay of uranium-238 to thorium-234.
- 20N.3.sl.TZ0.10e: Thorium-234 has a higher binding energy per nucleon than uranium-238. Outline what is meant by...
- 20N.3.sl.TZ0.e: Thorium-234 has a higher binding energy per nucleon than uranium-238. Outline what is meant by...
- 20N.3.sl.TZ0.10e: Thorium-234 has a higher binding energy per nucleon than uranium-238. Outline what is meant by...
- 20N.3.sl.TZ0.11b: Aspirin crystals are rinsed with water after recrystallization to remove impurities.Suggest why...
- 20N.3.sl.TZ0.11b: Aspirin crystals are rinsed with water after recrystallization to remove impurities.Suggest why...
- 20N.3.sl.TZ0.b: Aspirin crystals are rinsed with water after recrystallization to remove impurities.Suggest why...
-
20N.3.sl.TZ0.12:
Consider the following antacids:
Show that antacid X is more effective, per tablet, than antacid Y.
-
20N.3.sl.TZ0.12:
Consider the following antacids:
Show that antacid X is more effective, per tablet, than antacid Y.
- 20N.3.sl.TZ0.14a(i): Name two functional groups that both zanamivir and oseltamivir contain.
- 20N.3.sl.TZ0.14a(i): Name two functional groups that both zanamivir and oseltamivir contain.
- 20N.3.sl.TZ0.a(i): Name two functional groups that both zanamivir and oseltamivir contain.
- 20N.3.sl.TZ0.14b(i): Circle the side-chain in penicillin on the structure below.
- 20N.3.sl.TZ0.14b(i): Circle the side-chain in penicillin on the structure below.
- 20N.3.sl.TZ0.b(i): Circle the side-chain in penicillin on the structure below.
-
20N.3.sl.TZ0.14b(ii):
Explain, with reference to the action of penicillin, why new penicillins with different side-chains need to be produced.
-
20N.3.sl.TZ0.14b(ii):
Explain, with reference to the action of penicillin, why new penicillins with different side-chains need to be produced.
-
20N.3.sl.TZ0.b(ii):
Explain, with reference to the action of penicillin, why new penicillins with different side-chains need to be produced.
-
20N.3.hl.TZ0.3a:
Outline the two distinct phases of this composite.
-
20N.3.hl.TZ0.3a:
Outline the two distinct phases of this composite.
-
20N.3.hl.TZ0.a:
Outline the two distinct phases of this composite.
- 20N.3.hl.TZ0.3b(i): Thermoplastic composites are increasingly replacing thermosets. Suggest one advantage of...
- 20N.3.hl.TZ0.3b(i): Thermoplastic composites are increasingly replacing thermosets. Suggest one advantage of...
- 20N.3.hl.TZ0.b(i): Thermoplastic composites are increasingly replacing thermosets. Suggest one advantage of...
- 20N.3.hl.TZ0.3b(ii): Explain how thermoplastics, such as polyvinylchloride, PVC, can be made more flexible by the...
- 20N.3.hl.TZ0.3b(ii): Explain how thermoplastics, such as polyvinylchloride, PVC, can be made more flexible by the...
- 20N.3.hl.TZ0.b(ii): Explain how thermoplastics, such as polyvinylchloride, PVC, can be made more flexible by the...
- 20N.3.hl.TZ0.3b(iii): Explain why phthalates are replaced by other plasticizers in the production of plastics.
- 20N.3.hl.TZ0.3b(iii): Explain why phthalates are replaced by other plasticizers in the production of plastics.
- 20N.3.hl.TZ0.b(iii): Explain why phthalates are replaced by other plasticizers in the production of plastics.
- 20N.3.hl.TZ0.3c: Classify PVC and polyethene terephthalate, PET, as addition or condensation polymers and deduce...
- 20N.3.hl.TZ0.3c: Classify PVC and polyethene terephthalate, PET, as addition or condensation polymers and deduce...
- 20N.3.hl.TZ0.c: Classify PVC and polyethene terephthalate, PET, as addition or condensation polymers and deduce...
- 20N.3.hl.TZ0.4a: Explain these properties of carbon nanotubes.
- 20N.3.hl.TZ0.4a: Explain these properties of carbon nanotubes.
- 20N.3.hl.TZ0.a: Explain these properties of carbon nanotubes.
-
20N.3.hl.TZ0.4b(ii):
Explain the role of electrons in superconducting materials in terms of the Bardeen–Cooper–Schrieffer (BCS) theory.
-
20N.3.hl.TZ0.4b(ii):
Explain the role of electrons in superconducting materials in terms of the Bardeen–Cooper–Schrieffer (BCS) theory.
-
20N.3.hl.TZ0.b(ii):
Explain the role of electrons in superconducting materials in terms of the Bardeen–Cooper–Schrieffer (BCS) theory.
-
20N.3.hl.TZ0.4c(i):
Alloying metals changes their properties. Suggest one property of magnesium that could be improved by making a magnesium–CNT alloy.
-
20N.3.hl.TZ0.4c(i):
Alloying metals changes their properties. Suggest one property of magnesium that could be improved by making a magnesium–CNT alloy.
-
20N.3.hl.TZ0.c(i):
Alloying metals changes their properties. Suggest one property of magnesium that could be improved by making a magnesium–CNT alloy.
-
20N.3.hl.TZ0.4c(ii):
Pure magnesium needed for making alloys can be obtained by electrolysis of molten magnesium chloride.
© International Baccalaureate Organization 2020
Calculate the theoretical mass of magnesium obtained if a current of 3.00 A is used for hours. Use charge :(Q) = current (I) × time (t) and section 2 of the data booklet.
-
20N.3.hl.TZ0.4c(ii):
Pure magnesium needed for making alloys can be obtained by electrolysis of molten magnesium chloride.
© International Baccalaureate Organization 2020
Calculate the theoretical mass of magnesium obtained if a current of 3.00 A is used for hours. Use charge :(Q) = current (I) × time (t) and section 2 of the data booklet.
-
20N.3.hl.TZ0.c(ii):
Pure magnesium needed for making alloys can be obtained by electrolysis of molten magnesium chloride.
© International Baccalaureate Organization 2020
Calculate the theoretical mass of magnesium obtained if a current of 3.00 A is used for hours. Use charge :(Q) = current (I) × time (t) and section 2 of the data booklet.
- 20N.3.hl.TZ0.4d: Zeolites can be used as catalysts in the manufacture of CNT. Explain, with reference to their...
- 20N.3.hl.TZ0.4d: Zeolites can be used as catalysts in the manufacture of CNT. Explain, with reference to their...
- 20N.3.hl.TZ0.d: Zeolites can be used as catalysts in the manufacture of CNT. Explain, with reference to their...
- 20N.3.hl.TZ0.4e: Experiments have been done to explore the nematic liquid crystal behaviour of CNT. Justify how...
- 20N.3.hl.TZ0.4e: Experiments have been done to explore the nematic liquid crystal behaviour of CNT. Justify how...
- 20N.3.hl.TZ0.e: Experiments have been done to explore the nematic liquid crystal behaviour of CNT. Justify how...
-
20N.3.hl.TZ0.5b:
Precipitation is one method used to treat waste water.
Zinc, cadmium, nickel, and lead are metal ions which can be removed by precipitation. Explain why waste water is adjusted to a pH of 9−10 to remove these ions by referring to section 32 of the data booklet.
-
20N.3.hl.TZ0.5b:
Precipitation is one method used to treat waste water.
Zinc, cadmium, nickel, and lead are metal ions which can be removed by precipitation. Explain why waste water is adjusted to a pH of 9−10 to remove these ions by referring to section 32 of the data booklet.
-
20N.3.hl.TZ0.b:
Precipitation is one method used to treat waste water.
Zinc, cadmium, nickel, and lead are metal ions which can be removed by precipitation. Explain why waste water is adjusted to a pH of 9−10 to remove these ions by referring to section 32 of the data booklet.
- 20N.3.hl.TZ0.8a: The diverse functions of biological molecules depend on their structure and shape. Classify...
- 20N.3.hl.TZ0.8a: The diverse functions of biological molecules depend on their structure and shape. Classify...
- 20N.3.hl.TZ0.a: The diverse functions of biological molecules depend on their structure and shape. Classify...
-
20N.3.hl.TZ0.8b(ii):
The diverse functions of biological molecules depend on their structure and shape.
Draw the nitrogenous base that is paired with guanine in DNA, showing the hydrogen bonds between the bases. Use section 34 of the data booklet.
-
20N.3.hl.TZ0.8b(ii):
The diverse functions of biological molecules depend on their structure and shape.
Draw the nitrogenous base that is paired with guanine in DNA, showing the hydrogen bonds between the bases. Use section 34 of the data booklet.
-
20N.3.hl.TZ0.b(ii):
The diverse functions of biological molecules depend on their structure and shape.
Draw the nitrogenous base that is paired with guanine in DNA, showing the hydrogen bonds between the bases. Use section 34 of the data booklet.
-
20N.3.hl.TZ0.10b(i):
Determine the value of and in the absence and presence of the inhibitor.
-
20N.3.hl.TZ0.10b(i):
Determine the value of and in the absence and presence of the inhibitor.
-
20N.3.hl.TZ0.b(i):
Determine the value of and in the absence and presence of the inhibitor.
-
20N.3.hl.TZ0.11a:
Calculate the energy released, in , from the complete combustion of of ethanol.
-
20N.3.hl.TZ0.11a:
Calculate the energy released, in , from the complete combustion of of ethanol.
-
20N.3.hl.TZ0.a:
Calculate the energy released, in , from the complete combustion of of ethanol.
-
20N.3.hl.TZ0.11c:
Outline the advantages and disadvantages of using biodiesel instead of gasoline as fuel for a car. Exclude any discussion of cost.
-
20N.3.hl.TZ0.11c:
Outline the advantages and disadvantages of using biodiesel instead of gasoline as fuel for a car. Exclude any discussion of cost.
-
20N.3.hl.TZ0.c:
Outline the advantages and disadvantages of using biodiesel instead of gasoline as fuel for a car. Exclude any discussion of cost.
- 20N.3.hl.TZ0.11d: A mixture of gasoline and ethanol is often used as a fuel. Suggest an advantage of such a mixture...
- 20N.3.hl.TZ0.11d: A mixture of gasoline and ethanol is often used as a fuel. Suggest an advantage of such a mixture...
- 20N.3.hl.TZ0.d: A mixture of gasoline and ethanol is often used as a fuel. Suggest an advantage of such a mixture...
-
20N.3.hl.TZ0.11e(ii):
Methane is another greenhouse gas. Contrast the reasons why methane and carbon dioxide are considered significant greenhouse gases.
-
20N.3.hl.TZ0.11e(ii):
Methane is another greenhouse gas. Contrast the reasons why methane and carbon dioxide are considered significant greenhouse gases.
-
20N.3.hl.TZ0.e(ii):
Methane is another greenhouse gas. Contrast the reasons why methane and carbon dioxide are considered significant greenhouse gases.
-
20N.3.hl.TZ0.14a:
Doping of silicon increases the conductivity in semiconductors.
Describe the doping in p-type and n-type semiconductors.
-
20N.3.hl.TZ0.14a:
Doping of silicon increases the conductivity in semiconductors.
Describe the doping in p-type and n-type semiconductors.
-
20N.3.hl.TZ0.a:
Doping of silicon increases the conductivity in semiconductors.
Describe the doping in p-type and n-type semiconductors.
-
20N.3.hl.TZ0.15a:
Deduce the structural formula of the by-product of this reaction.
-
20N.3.hl.TZ0.15a:
Deduce the structural formula of the by-product of this reaction.
-
20N.3.hl.TZ0.a:
Deduce the structural formula of the by-product of this reaction.
- 20N.3.hl.TZ0.15b: Aspirin crystals are rinsed with water after recrystallization to remove impurities.Suggest why...
- 20N.3.hl.TZ0.15b: Aspirin crystals are rinsed with water after recrystallization to remove impurities.Suggest why...
- 20N.3.hl.TZ0.b: Aspirin crystals are rinsed with water after recrystallization to remove impurities.Suggest why...
-
20N.3.hl.TZ0.15d:
Comment on the risk of overdose when taking aspirin as an analgesic, referring to the following values, for a person weighing :
Minimum therapeutic dose
Estimated minimum lethal dose
-
20N.3.hl.TZ0.15d:
Comment on the risk of overdose when taking aspirin as an analgesic, referring to the following values, for a person weighing :
Minimum therapeutic dose
Estimated minimum lethal dose
-
20N.3.hl.TZ0.d:
Comment on the risk of overdose when taking aspirin as an analgesic, referring to the following values, for a person weighing :
Minimum therapeutic dose
Estimated minimum lethal dose
-
20N.3.hl.TZ0.15e:
Explain how IR spectroscopy can be used to distinguish aspirin from salicylic acid.
-
20N.3.hl.TZ0.15e:
Explain how IR spectroscopy can be used to distinguish aspirin from salicylic acid.
-
20N.3.hl.TZ0.e:
Explain how IR spectroscopy can be used to distinguish aspirin from salicylic acid.
- 20N.3.hl.TZ0.17b: Discuss the properties that make a radioisotope suitable for diagnosis.
- 20N.3.hl.TZ0.17b: Discuss the properties that make a radioisotope suitable for diagnosis.
- 20N.3.hl.TZ0.b: Discuss the properties that make a radioisotope suitable for diagnosis.
-
20N.3.hl.TZ0.18a(ii):
The vapour pressure of pure ethanal at is .
Calculate the vapour pressure of ethanal above the liquid mixture at .
-
20N.3.hl.TZ0.18a(ii):
The vapour pressure of pure ethanal at is .
Calculate the vapour pressure of ethanal above the liquid mixture at .
-
20N.3.hl.TZ0.a(ii):
The vapour pressure of pure ethanal at is .
Calculate the vapour pressure of ethanal above the liquid mixture at .
- 20N.3.hl.TZ0.18b: Describe how this mixture is separated by fractional distillation.
- 20N.3.hl.TZ0.18b: Describe how this mixture is separated by fractional distillation.
- 20N.3.hl.TZ0.b: Describe how this mixture is separated by fractional distillation.
- 20N.3.hl.TZ0.19b(i): Circle the side-chain in penicillin on the structure below.
- 20N.3.hl.TZ0.19b(i): Circle the side-chain in penicillin on the structure below.
- 20N.3.hl.TZ0.b(i): Circle the side-chain in penicillin on the structure below.
-
20N.3.hl.TZ0.19b(ii):
Explain, with reference to the action of penicillin, why new penicillins with different side-chains need to be produced.
-
20N.3.hl.TZ0.19b(ii):
Explain, with reference to the action of penicillin, why new penicillins with different side-chains need to be produced.
-
20N.3.hl.TZ0.b(ii):
Explain, with reference to the action of penicillin, why new penicillins with different side-chains need to be produced.
- 20N.3.hl.TZ0.19c(i): State and explain the relative solubility of codeine in water compared to morphine and diamorphine.
- 20N.3.hl.TZ0.19c(i): State and explain the relative solubility of codeine in water compared to morphine and diamorphine.
- 20N.3.hl.TZ0.c(i): State and explain the relative solubility of codeine in water compared to morphine and diamorphine.
- 20N.3.hl.TZ0.19c(ii): State the natural source from which codeine, morphine and diamorphine are obtained.
- 20N.3.hl.TZ0.19c(ii): State the natural source from which codeine, morphine and diamorphine are obtained.
- 20N.3.hl.TZ0.c(ii): State the natural source from which codeine, morphine and diamorphine are obtained.
- 20N.3.hl.TZ0.19d: Circle two chiral carbons in the section of the Taxol structure below.
- 20N.3.hl.TZ0.19d: Circle two chiral carbons in the section of the Taxol structure below.
- 20N.3.hl.TZ0.d: Circle two chiral carbons in the section of the Taxol structure below.
- 23M.1.SL.TZ1.15: Which diagram shows the enthalpy change for dissolving solid, X, in water, if the temperature...
- 23M.1.SL.TZ1.15: Which diagram shows the enthalpy change for dissolving solid, X, in water, if the temperature...
- 23M.1.HL.TZ2.4: What is the correct ground state electron orbital configuration for 2s22p2?
- 23M.1.SL.TZ2.5: What is the correct ground state electron orbital configuration for 2s22p2?
- 23M.1.HL.TZ2.4: What is the correct ground state electron orbital configuration for 2s22p2?
- 23M.1.SL.TZ2.5: What is the correct ground state electron orbital configuration for 2s22p2?
- 23M.2.HL.TZ1.3ai: Outline the meaning of homologous series.
- 23M.2.SL.TZ1.3ai: Outline the meaning of homologous series.
- 23M.2.HL.TZ1.3ai: Outline the meaning of homologous series.
- 23M.2.HL.TZ1.i: Outline the meaning of homologous series.
- 23M.2.SL.TZ1.3ai: Outline the meaning of homologous series.
- 23M.2.SL.TZ1.i: Outline the meaning of homologous series.
- 23M.2.HL.TZ2.7a: Identify the type of reaction.
- 23M.2.HL.TZ2.7a: Identify the type of reaction.
- 23M.2.HL.TZ2.a: Identify the type of reaction.
Sub sections and their related questions
A: Materials
-
17N.3.sl.TZ0.4a:
Outline the composition of an alloy and a composite.
- 17N.3.sl.TZ0.4b.i: Outline why an alloy is usually harder than its components by referring to its structure.
- 17N.3.sl.TZ0.4b.ii: At present, composite fillings are more expensive than amalgam fillings. Suggest why a patient...
-
17N.3.sl.TZ0.4c:
Explain how Inductively Coupled Plasma (ICP) Spectroscopy could be used to determine the concentration of mercury in a sample of dental filling.
-
17N.3.sl.TZ0.5:
Catalysts can take many forms and are used in many industrial processes.
Suggest two reasons why it might be worth using a more expensive catalyst to increase the rate of a reaction.
-
17N.3.sl.TZ0.6a:
State equations for the formation of iron nanoparticles and carbon atoms from Fe(CO)5 in the HIPCO process.
- 17N.3.sl.TZ0.6b: Outline why the iron nanoparticle catalysts produced by the HIPCO process are more efficient than...
- 17N.3.sl.TZ0.6c: Discuss one possible risk associated with the use of nanotechnology.
-
17N.3.sl.TZ0.7a:
Outline two properties a substance should have to be used as liquid-crystal in a liquid-crystal display.
-
17N.3.sl.TZ0.7b.i:
Describe how the structures of LDPE and HDPE affect one mechanical property of the plastics.
-
17N.3.sl.TZ0.7b.ii:
One of the two infrared (IR) spectra is that of polyethene and the other of polytetrafluoroethene (PTFE).
Deduce, with a reason, which spectrum is that of PTFE. Infrared data is given in section 26 of the data booklet.
-
17N.3.sl.TZ0.7c:
Many plastics used to be incinerated. Deduce an equation for the complete combustion of two repeating units of PVC, (–C2H3Cl–)2.
-
17N.3.hl.TZ0.6b:
Explain why Type 2 superconductors are generally more useful than Type 1.
- 17N.3.hl.TZ0.7b: Describe how the monomers of addition polymers and of condensation polymers differ.
-
17N.3.hl.TZ0.7c:
Identify the type of intermolecular bonding that is responsible for Kevlar®’s strength.
-
17N.3.hl.TZ0.8a:
Calculate the total number of cobalt atoms within its unit cell.
-
17N.3.hl.TZ0.8b.i:
The atomic radius, r, of cobalt is 1.18 × 10–8 cm. Determine the edge length, in cm, of the unit cell, a, using the second diagram.
-
17N.3.hl.TZ0.8b.ii:
Determine a value for the density of cobalt, in g cm–3, using data from sections 2 and 6 of the data booklet and your answers from (a) and (b) (i).
If you did not obtain an answer to (b) (i), use 3.00 × 10–8 cm but this is not the correct answer.
- 17N.3.hl.TZ0.9a: State the name of one method, other than precipitation, of removing heavy metal ions from...
-
17N.3.hl.TZ0.9b:
The solubility product, Ksp , of cadmium sulfide, CdS, is 8.0 × 10–27. Determine the concentration of cadmium ions in 1.0 dm3 of a saturated solution of cadmium sulfide to which 0.10 mol of solid sodium sulfide has been added, stating any assumption you make.
-
18M.3.hl.TZ1.4c.i:
Draw the structure of the monomer from which nylon-6 is produced by a condensation reaction.
-
18M.3.hl.TZ1.4c.ii:
Deduce, giving a reason, whether the atom economy of a condensation polymerization, such as this, would be greater or less than an addition polymerization, such as the formation of HDPE.
-
18M.3.hl.TZ1.5b:
The diagram illustrates the crystal structure of aluminium metal with the unit cell indicated. Outline the significance of the unit cell.
-
18M.3.hl.TZ1.5c:
When X-rays of wavelength 0.154 nm are directed at a crystal of aluminium, the first order diffraction pattern is observed at 18°. Determine the separation of layers of aluminium atoms in the crystal, in m, using section 1 of the data booklet.
-
18M.3.hl.TZ1.5d.i:
Deduce what the shape of the graph indicates about aluminium.
-
18M.3.hl.TZ1.5d.ii:
Outline why the resistance of aluminium increases above 1.2 K.
-
18M.3.hl.TZ1.5e:
The concentration of aluminium in drinking water can be reduced by precipitating aluminium hydroxide. Calculate the maximum concentration of aluminium ions in water of pH 7 at 298 K. Solubility product of aluminium hydroxide = 3.3 × 10−34 at 298 K.
-
18M.3.hl.TZ2.4a.i:
Deduce the number of atoms per unit cell in vanadium.
-
18M.3.hl.TZ2.4a.ii:
Calculate the expected first order diffraction pattern angle, in degrees, if x-rays of wavelength 150 pm are directed at a crystal of vanadium. Assume the edge length of the crystal to be the same as separation of layers of vanadium atoms found by x-ray diffraction. Use section 1 of the data booklet.
-
18M.3.hl.TZ2.4a.iii:
Calculate the average mass, in g, of a vanadium atom by using sections 2 and 6 of the data booklet.
-
18M.3.hl.TZ2.4a.iv:
Determine the volume, in cm3, of a vanadium unit cell.
-
18M.3.hl.TZ2.4a.v:
Determine the density, in g cm−3, of vanadium by using your answers to (a)(i), (a)(iii) and (a)(iv).
-
18M.3.hl.TZ2.4b.i:
Vanadium and other transition metals can interfere with cell metabolism.
State and explain one process, other than by creating free radicals, by which transition metals interfere with cell metabolism.
-
18M.3.hl.TZ2.4b.ii:
Vanadium(IV) ions can create free radicals by a Fenton reaction.
Deduce the equation for the reaction of V4+ with hydrogen peroxide.
-
18M.3.hl.TZ2.5c.i:
Distinguish between the manufacture of polyester and polyethene.
-
18M.3.hl.TZ2.6b:
MWCNT are very small in size and can greatly increase switching speeds in a liquid crystal allowing the liquid crystal to change orientation quickly.
Discuss two other properties a substance should have to be suitable for use in liquid crystal displays.
-
18M.3.sl.TZ1.3a:
Discuss, in terms of its structure, why an aluminium saucepan is impermeable to water.
-
18M.3.sl.TZ1.3b.i:
State the name given to a material composed of two distinct solid phases.
-
18M.3.sl.TZ1.3b.ii:
State one physical property of HDPE that will be affected by the incorporation of carbon nanotubes.
-
18M.3.sl.TZ1.3b.iii:
Describe how carbon nanotubes are produced by chemical vapour deposition (CVD).
-
18M.3.sl.TZ1.3b.iv:
State the property of carbon nanotubes that enables them to form a nematic liquid crystal phase.
-
18M.3.sl.TZ1.4a:
Both of these are thermoplastic polymers. Outline what this term means.
-
18M.3.sl.TZ1.4b.i:
Compare and contrast the structures of HDPE and LDPE.
-
18M.3.sl.TZ1.4b.ii:
State one way in which a physical property of HDPE, other than density, differs from that of LDPE as a result of this structural difference.
-
18M.3.sl.TZ1.4c.i:
The production of HDPE involves the use of homogeneous catalysts. Outline how homogeneous catalysts reduce the activation energy of reactions.
-
18M.3.sl.TZ1.4c.ii:
Trace amounts of metal from the catalysts used in the production of HDPE sometimes remain in the product. State a technique that could be used to measure the concentration of the metal.
-
18M.3.sl.TZ1.4d:
Suggest two of the major obstacles, other than collection and economic factors, which have to be overcome in plastic recycling.
-
18M.3.sl.TZ1.4e:
Suggest why there are so many different ways in which plastics can be classified. HDPE can, for example, be categorized thermoplastic, an addition polymer, having Resin Identification Code (RIC) 2, etc.
-
18M.3.sl.TZ1.5:
Aluminium is produced by the electrolysis of a molten electrolyte containing bauxite.
Determine the mass, in g, of aluminium produced by the passage of a charge of 1.296 × 1013 C. Use sections 2 and 6 of the data booklet.
-
18M.3.sl.TZ2.3a:
ICP-OES/MS can be used to analyse alloys and composites. Distinguish between alloys and composites.
-
18M.3.sl.TZ2.3b:
ICP-MS is a reference mode for analysis. The following correlation graphs between ICP-OES and ICP-MS were produced for yttrium and nickel.
Each y-axis shows concentrations calculated by ICP-OES; each x-axis shows concentrations for the same sample as found by ICP-MS.
The line in each graph is y = x.
Discuss the effectiveness of ICP-OES for yttrium and nickel.
-
18M.3.sl.TZ2.3c.i:
Identify the purpose of each graph.
-
18M.3.sl.TZ2.3c.ii:
Calculate, to four significant figures, the concentration, in μg kg−1, of vanadium in oil giving a signal intensity of 14 950.
-
18M.3.sl.TZ2.3c.iii:
Vanadium(V) oxide is used as the catalyst in the conversion of sulfur dioxide to sulfur trioxide.
SO2(g) + V2O5(s) → SO3(g) + 2VO2(s)
O2(g) + 2VO2(s) → V2O5(s)
Outline how vanadium(V) oxide acts as a catalyst.
-
18M.3.sl.TZ2.4a:
Sketch four repeating units of the polymer to show atactic and isotactic polypropene.
-
18M.3.sl.TZ2.4b.i:
State the chemical reason why plastics do not degrade easily.
-
18M.3.sl.TZ2.4b.ii:
Compare two ways in which recycling differs from reusing plastics.
-
18M.3.sl.TZ2.4c:
Civilizations are often characterized by the materials they use.
Suggest an advantage polymers have over materials from the iron age.
-
18M.3.sl.TZ2.5a:
State the source of carbon for MWCNT produced by arc discharge and by CVD.
-
18M.3.sl.TZ2.5b:
Discuss three properties a substance should have to be suitable for use in liquid crystal displays.
-
18N.3.sl.TZ0.2a:
Outline why this type of classification is not entirely satisfactory by using magnesium diboride, MgB2, as an example. Refer to sections 8 and 29 of the data booklet.
-
18N.3.sl.TZ0.2b.i:
Structures of poly(methyl acrylate), PMA, and Bakelite® are shown.
Suggest, giving reasons, which is the thermoplastic polymer and which is the thermosetting polymer.
-
18N.3.sl.TZ0.2b.ii:
In an incomplete combustion of the polyvinyl chloride, PVC, it was found that hydrogen chloride, carbon monoxide, carbon dioxide, and water vapour were released.
Formulate an equation for this reaction using the formula of the PVC repeating unit.
- 18N.3.sl.TZ0.2c.i: A zeolite is an alternative catalyst for this reaction. Explain how zeolites act as selective...
- 18N.3.sl.TZ0.2c.ii: Identify another advantage of using a zeolite instead of concentrated sulfuric acid.
-
18N.3.sl.TZ0.2d:
Repeating units of several polymers are listed.
The infrared (IR) spectrum of one of these polymers is shown.
Deduce, giving a reason, the name of this polymer and its Resin Identification Code (RIC), using sections 26 and 30 in the data booklet.
- 18N.3.sl.TZ0.3a: State the type of particle present in the plasma formed.
-
18N.3.sl.TZ0.3b:
An unknown antacid sample has a lead ion concentration of 0.50 μg dm‒3.
Calculate the concentration of lead ions in the sample in mol dm‒3.
-
18N.3.sl.TZ0.3c:
Electrolysis is used to obtain lead from Pb2+ (aq) solution.
Determine the time, in hours, required to produce 0.0500 mol lead using a current (I) of 1.34 A. Use section 2 of the data booklet and the equation, charge (Q) = current (I) × time (t, in seconds).
- 18N.3.sl.TZ0.4a: Outline two observations that he could have made.
- 18N.3.sl.TZ0.4b: The structure of biphenyl nitrile is shown. Describe, giving a reason, a feature of the...
-
18N.3.sl.TZ0.4c:
Arc discharge, consisting of two inert metal electrodes in a liquid solvent, is one method of producing carbon nanotubes (CNTs).
Predict, giving a reason, the electrode at which the solvent cyclohexane, C6H12, will decompose to form CNTs.
-
18N.3.hl.TZ0.2a:
Outline why this type of classification is not entirely satisfactory by using magnesium diboride, MgB2, as an example. Refer to sections 8 and 29 of the data booklet.
-
18N.3.hl.TZ0.2b:
Structures of poly(methyl acrylate), PMA, and Bakelite® are shown.
Suggest, giving reasons, which is the thermoplastic polymer and which is the thermosetting polymer.
- 18N.3.hl.TZ0.2c: A zeolite is an alternative catalyst for this reaction. Explain how zeolites act as selective...
- 18N.3.hl.TZ0.2d.i: State the names of the two terminal functional groups in X.
- 18N.3.hl.TZ0.2d.ii: Deduce the repeating unit of the polymer of X.
-
18N.3.hl.TZ0.2d.iii:
Repeating units of several polymers are listed.
The infrared (IR) spectrum of one of these polymers is shown.
Deduce, giving a reason, the name of this polymer and its Resin Identification Code (RIC), using sections 26 and 30 in the data booklet.
- 18N.3.hl.TZ0.3a: State the type of particle present in the plasma formed.
-
18N.3.hl.TZ0.3b.i:
Calculate the concentration of lead ions in the sample in mol dm‒3.
-
18N.3.hl.TZ0.3b.ii:
Lead ions are toxic and can be precipitated using hydroxide ions.
Pb2+ (aq) + 2OH‒ (aq) Pb(OH)2 (s)
Sufficient sodium hydroxide solid is added to the antacid sample to produce a 1.0 × 10‒2 mol dm‒3 hydroxide ion solution at 298 K.
Deduce if a precipitate will be formed, using section 32 of the data booklet.
If you did not calculate the concentration of lead ions in (b)(i), use the value of 2.4 × 10−4 mol dm‒3, but this is not the correct value.
-
18N.3.hl.TZ0.3c:
Electrolysis is used to obtain lead from Pb2+ (aq) solution.
Determine the time, in hours, required to produce 0.0500 mol lead using a current (I) of 1.34 A. Use section 2 of the data booklet and the equation, charge (Q) = current (I) × time (t, in seconds).
- 18N.3.hl.TZ0.3d.i: State one feature of a chelating agent.
-
18N.3.hl.TZ0.3d.ii:
An aqueous lead(II) ion reacts with three ethane-1,2-diamine molecules to form an octahedral chelate ion.
Outline why the chelate ion is more stable than the reactants.
- 18N.3.hl.TZ0.5a.i: State the name of the crystal structure of gold.
-
18N.3.hl.TZ0.5a.ii:
Calculate the number of atoms per unit cell of gold, showing your working.
-
18N.3.hl.TZ0.5b:
The edge length of the gold unit cell is 4.08 × 10‒8 cm.
Determine the density of gold in g cm‒3, using sections 2 and 6 of the data booklet.
-
19M.3.hl.TZ1.3a:
Identify the type of bonding in lithium hydride, using sections 8 and 29 of the data booklet.
-
19M.3.hl.TZ1.3b(i):
Identify the colour of the emission spectrum of lithium using section 17 of the data booklet.
-
19M.3.hl.TZ1.3b(ii):
Suggest why ICP-OES does not give good quantitative results for distinguishing 6Li from naturally occurring lithium.
-
19M.3.hl.TZ1.3b(iii):
Suggest a better method.
-
19M.3.hl.TZ1.3c:
Lithium is obtained by electrolysis of molten lithium chloride. Calculate the time, in seconds, taken to deposit 0.694 g Li using a current of 2.00 A.
Q (charge) = I (current) × t (time)
-
19M.3.hl.TZ1.3d(i):
Lithium has shown some superconductive properties when doped into graphene or when under high pressure. Under high pressure, however, the Meissner effect is absent.
Describe the Meissner effect.
-
19M.3.hl.TZ1.3d(ii):
At very low temperatures, lithium atoms enhance the phonon binding of electrons in graphene suggesting the formation of Cooper pairs.
Explain how Cooper pairs are formed.
-
19M.3.hl.TZ1.3e:
Lithium forms a crystalline lattice with the unit cell structure shown below.
X-ray diffraction shows that the length of the edge of the unit cell is 3.51 × 10−8 cm.
Determine the density of lithium, in g cm−3, using sections 2 and 6 of the data booklet.
-
19M.3.hl.TZ1.4a:
Outline two differences between heterogeneous and homogeneous catalysts.
-
19M.3.hl.TZ1.4b:
Suggest, giving a reason, how elastomers used for the tyre tread can increase the traction between the tyre and the road.
-
19M.3.hl.TZ1.4c:
Tyre fires emit trace quantities of polychlorinated dibenzofurans and polychlorinated dibenzo-p-dioxin.
Outline, using section 31 of the data booklet, why polychlorinated dibenzofuran is not classed chemically as a dioxin but considered “dioxin-like”.
-
19M.3.hl.TZ1.4d:
Classify polybutadiene as either an addition or condensation polymer, giving a reason.
-
19M.3.hl.TZ1.4e:
State one factor considered when making green chemistry polymers.
-
19M.3.hl.TZ1.5a:
Label with an asterisk, *, the chiral carbon atom.
-
19M.3.hl.TZ1.5b:
Explain the effects of very low and high temperatures on the liquid-crystal behaviour of this molecule.
Low temperature:
High temperature:
-
19M.3.hl.TZ1.6a:
Describe the structure and bonding of a carbon nanotube.
Structure:
Bonding:
-
19M.3.hl.TZ1.6b:
Suggest one application for carbon nanotubes.
-
19M.3.hl.TZ1.7a:
Explain how entropy affects this equilibrium.
-
19M.3.hl.TZ1.7b:
State the number of coordinate covalent bonds EDTA forms with Ni2+.
-
19M.3.hl.TZ2.3:
Describe the characteristics of the nematic liquid crystal phase.
Shape of molecules:
Distribution:
-
19M.3.hl.TZ2.4a:
Determine the mass of aluminium, in g, that could be extracted from an appropriate solution by a charge of 48 250 C. Use sections 2 and 6 of the data booklet.
-
19M.3.hl.TZ2.4b:
Once extracted, the purity of the metal can be assessed using ICP-MS. Suggest two advantages of using plasma technology rather than regular mass spectrometry.
-
19M.3.hl.TZ2.4c:
Explain the action of metals as heterogeneous catalysts.
-
19M.3.hl.TZ2.4d:
Outline how alloys conduct electricity and why they are often harder than pure metals.
Conduct electricity:
Harder than pure metals:
-
19M.3.hl.TZ2.4e:
Carbon nanotubes are added to metals to increase tensile strength.
Write an equation for the formation of carbon nanotubes from carbon monoxide.
-
19M.3.hl.TZ2.5a:
Draw a section of isotactic polychloroethene (polyvinylchloride, PVC) showing all the atoms and all the bonds of four monomer units.
-
19M.3.hl.TZ2.5c:
Explain how plasticizers affect the properties of plastics.
-
19M.3.hl.TZ2.5d:
Suggest why the addition of plasticizers is controversial.
-
19M.3.hl.TZ2.5e:
Outline, giving a reason, how addition and condensation polymerization compare with regard to green chemistry.
-
19M.3.hl.TZ2.5f:
Draw the full structural formula of the organic functional group formed during the polymerization of the two reactants below.
-
19M.3.hl.TZ2.6a:
State the number of atoms in the unit cell.
-
19M.3.hl.TZ2.6b:
Determine the density of calcium, in g cm−3, using section 2 of the data booklet.
Ar = 40.08; metallic radius (r) = 1.97 × 10−10 m
-
19M.3.hl.TZ2.7a:
State what is meant by a superconductor.
-
19M.3.hl.TZ2.8a:
Outline why heavy metals are toxic.
-
19M.3.hl.TZ2.8b:
Determine the maximum concentration of lead(II) ions at 298 K in a solution in which the concentration of carbonate ions is maintained at 1.10 × 10−4 mol dm−3. Use section 32 of the data booklet.
-
19M.3.hl.TZ2.8c:
State a method, other than precipitation, of removing heavy metal ions from solution.
-
19M.3.hl.TZ2.18b:
Outline one approach to controlling industrial emissions of carbon dioxide.
-
19M.3.sl.TZ1.3a(i):
Identify the type of bonding in lithium hydride, using sections 8 and 29 of the data booklet.
-
19M.3.sl.TZ1.3a(ii):
Explain why lithium is paramagnetic while lithium hydride is diamagnetic by referring to electron configurations.
-
19M.3.sl.TZ1.3b(i):
Suggest why ICP-OES does not give good quantitative results for distinguishing 6Li from naturally occurring lithium.
-
19M.3.sl.TZ1.3b(ii):
Suggest a better method.
-
19M.3.sl.TZ1.3c:
Lithium is obtained by electrolysis of molten lithium chloride. Calculate the time, in seconds, taken to deposit 0.694 g Li using a current of 2.00 A.
Q (charge) = I (current) × t (time)
-
19M.3.sl.TZ1.4a:
Outline two differences between heterogeneous and homogeneous catalysts.
-
19M.3.sl.TZ1.4b:
Suggest, giving a reason, how elastomers used for the tyre tread can increase the traction between the tyre and the road.
-
19M.3.sl.TZ1.4c(i):
Tyre fires emit trace quantities of polychlorinated dibenzofurans and polychlorinated dibenzo-p-dioxin.
Outline, using section 31 of the data booklet, why polychlorinated dibenzofuran is not classed chemically as a dioxin but considered “dioxin-like”.
-
19M.3.sl.TZ1.4c(ii):
The trace quantities of dioxins from tyre fires are rarely inhaled and instead settle on the ground.
Describe why this is a health concern.
-
19M.3.sl.TZ1.5a:
State the name of the functional group which allows the molecule to be responsive to applied electric fields.
-
19M.3.sl.TZ1.5b:
Explain the effects of very low and high temperatures on the liquid-crystal behaviour of this molecule.
Low temperature:
High temperature:
-
19M.3.sl.TZ1.6a:
Describe the structure and bonding of a carbon nanotube.
Structure:
Bonding:
-
19M.3.sl.TZ1.6b:
Suggest one application for carbon nanotubes.
-
19M.3.sl.TZ2.3:
Describe the characteristics of the nematic liquid crystal phase and the effect that an electric field has on it.
Shape of molecules:Distribution:
Effect of electric field:
-
19M.3.sl.TZ2.4a:
Determine the mass of aluminium, in g, that could be extracted from an appropriate solution by a charge of 48250 C. Use sections 2 and 6 of the data booklet.
-
19M.3.sl.TZ2.4b:
Once extracted, the purity of the metal can be assessed using ICP-MS. Suggest two advantages of using plasma technology rather than regular mass spectrometry.
-
19M.3.sl.TZ2.4c:
Explain the action of metals as heterogeneous catalysts.
-
19M.3.sl.TZ2.4d:
Outline how alloys conduct electricity and why they are often harder than pure metals.
Conduct electricity:
Harder than pure metals:
-
19M.3.sl.TZ2.4e:
Carbon nanotubes are added to metals to increase tensile strength.
Write an equation for the formation of carbon nanotubes from carbon monoxide.
-
19M.3.sl.TZ2.5a:
Draw a section of isotactic polychloroethene (polyvinylchloride, PVC) showing all the atoms and all the bonds of four monomer units.
-
19M.3.sl.TZ2.5c:
Identify a hazardous product of the incineration of polychloroethene.
-
19M.3.sl.TZ2.5d:
Explain how plasticizers affect the properties of plastics.
-
19M.3.sl.TZ2.5e:
Suggest why the addition of plasticizers is controversial.
-
19N.3.sl.TZ0.3a:
Describe how a heterogeneous catalyst provides an alternative pathway for a reaction.
- 19N.3.sl.TZ0.3b: Distinguish between heterogeneous and homogeneous catalysts, giving one difference.
-
19N.3.sl.TZ0.3c:
Nanotubes are used to support the active material in nanocatalysts.
Explain why oxygen cannot be used for the chemical vapour deposition (CVD) preparation of carbon nanotubes.
- 19N.3.hl.TZ0.4a(i): Outline how resistance to electric currents occurs in metals.
- 19N.3.hl.TZ0.4a(ii): Suggest why the resistance of metals increases with temperature.
- 19N.3.hl.TZ0.4b: State two differences between Type I and Type II superconductors.
-
19N.3.hl.TZ0.5a:
Draw the structure of the monomers of Kevlar® if the by-product of the condensation polymerization is hydrogen chloride.
- 19N.3.hl.TZ0.5b: State and explain why plasticizers are added to polymers.
- 19N.3.hl.TZ0.5c: Discuss why the recycling of plastics is an energy intensive process.
-
19N.3.sl.TZ0.5a:
Discuss why different methods of reduction are needed to extract metals.
-
19N.3.sl.TZ0.5b(i):
Determine the percentage of ionic bonding in alumina using sections 8 and 29 of the data booklet.
-
19N.3.sl.TZ0.5b(ii):
Write half-equations for the electrolysis of molten alumina using graphite electrodes, deducing the state symbols of the products.
Anode (positive electrode):
Cathode (negative electrode):
-
19N.3.hl.TZ0.7:
X-ray crystallography of a metal crystal produces a diffraction pattern of bright spots.
Using X-rays of wavelength 1.54 × 10−10 m, the first bright spots were produced at an angle θ of 22.3° from the centre.
Calculate the separation between planes of atoms in the lattice, in meters, using section 1 of the data booklet.
-
19N.3.hl.TZ0.8:
1.40 × 10−3 g of NaOH (s) are dissolved in 250.0 cm3 of 1.00 × 10−11 mol dm−3 Pb(OH)2 (aq) solution.
Determine the change in lead ion concentration in the solution, using section 32 of the data booklet.
- 19N.3.sl.TZ0.6a: Describe the arrangement of soap molecules in the nematic liquid crystal phase.
- 19N.3.sl.TZ0.6b: State how liquid crystals are affected by an electric field.
-
19N.3.sl.TZ0.4a:
Draw a section of an isotactic polypropene polymer chain containing four repeating units.
- 19N.3.sl.TZ0.4b: Predict, with a reason, whether isotactic or atactic polypropene has the higher melting point.
- 19N.3.sl.TZ0.4c: Polypropene is a thermoplastic. Outline what is meant by thermoplastic.
- 19N.3.sl.TZ0.4d: Discuss why the recycling of plastics is an energy intensive process.
-
20N.3.sl.TZ0.3a:
Outline the two distinct phases of this composite.
- 20N.3.sl.TZ0.3b(i): Thermoplastic composites are increasingly replacing thermosets. Suggest one advantage of...
- 20N.3.sl.TZ0.3b(ii): Explain how thermoplastics, such as polyvinylchloride, PVC, can be made more flexible by the...
- 20N.3.sl.TZ0.3c: Explain why phthalates are replaced by other plasticizers in the production of plastics.
- 20N.3.sl.TZ0.4a: Explain these properties of carbon nanotubes.
- 20N.3.sl.TZ0.4b(i): Alloying metals changes their properties. Suggest one property of magnesium that could be...
-
20N.3.sl.TZ0.4b(ii):
Pure magnesium needed for making alloys can be obtained by electrolysis of molten magnesium chloride.
© International Baccalaureate Organization 2020.
Write the half-equations for the reactions occurring in this electrolysis.
-
20N.3.sl.TZ0.4b(iii):
Calculate the theoretical mass of magnesium obtained if a current of is used for hours. Use charge and section 2 of the data booklet
-
20N.3.sl.TZ0.4b(iv):
Suggest a gas which should be continuously passed over the molten magnesium in the electrolytic cell.
- 20N.3.sl.TZ0.4c: Zeolites can be used as catalysts in the manufacture of CNT. Explain, with reference to their...
- 20N.3.sl.TZ0.4d: Experiments have been done to explore the nematic liquid crystal behaviour of CNT. Justify how...
-
20N.3.hl.TZ0.3a:
Outline the two distinct phases of this composite.
- 20N.3.hl.TZ0.3b(i): Thermoplastic composites are increasingly replacing thermosets. Suggest one advantage of...
- 20N.3.hl.TZ0.3b(ii): Explain how thermoplastics, such as polyvinylchloride, PVC, can be made more flexible by the...
- 20N.3.hl.TZ0.3b(iii): Explain why phthalates are replaced by other plasticizers in the production of plastics.
- 20N.3.hl.TZ0.3c: Classify PVC and polyethene terephthalate, PET, as addition or condensation polymers and deduce...
- 20N.3.hl.TZ0.4a: Explain these properties of carbon nanotubes.
- 20N.3.hl.TZ0.4b(i): CNT can act as Type 2 superconductors. Outline why Type 2 superconductors are generally more...
-
20N.3.hl.TZ0.4b(ii):
Explain the role of electrons in superconducting materials in terms of the Bardeen–Cooper–Schrieffer (BCS) theory.
-
20N.3.hl.TZ0.4c(i):
Alloying metals changes their properties. Suggest one property of magnesium that could be improved by making a magnesium–CNT alloy.
-
20N.3.hl.TZ0.4c(ii):
Pure magnesium needed for making alloys can be obtained by electrolysis of molten magnesium chloride.
© International Baccalaureate Organization 2020
Calculate the theoretical mass of magnesium obtained if a current of 3.00 A is used for hours. Use charge :(Q) = current (I) × time (t) and section 2 of the data booklet.
-
20N.3.hl.TZ0.4c(iii):
Suggest a gas which should be continuously passed over the molten magnesium in the electrolytic cell.
- 20N.3.hl.TZ0.4d: Zeolites can be used as catalysts in the manufacture of CNT. Explain, with reference to their...
- 20N.3.hl.TZ0.4e: Experiments have been done to explore the nematic liquid crystal behaviour of CNT. Justify how...
-
20N.3.hl.TZ0.5a:
Precipitation is one method used to treat waste water.
Phosphates, , in waste water can be removed by precipitation with magnesium ions. of magnesium phosphate is .
Calculate the maximum solubility of phosphate ions in a solution containing magnesium ions.
-
20N.3.hl.TZ0.5b:
Precipitation is one method used to treat waste water.
Zinc, cadmium, nickel, and lead are metal ions which can be removed by precipitation. Explain why waste water is adjusted to a pH of 9−10 to remove these ions by referring to section 32 of the data booklet.
- 23M.2.HL.TZ1.3ai: Outline the meaning of homologous series.
- 23M.2.HL.TZ2.7a: Identify the type of reaction.
- 23M.2.SL.TZ1.3ai: Outline the meaning of homologous series.
-
19M.3.hl.TZ1.3a:
Identify the type of bonding in lithium hydride, using sections 8 and 29 of the data booklet.
-
19M.3.hl.TZ1.3b(i):
Identify the colour of the emission spectrum of lithium using section 17 of the data booklet.
-
19M.3.hl.TZ1.3b(ii):
Suggest why ICP-OES does not give good quantitative results for distinguishing 6Li from naturally occurring lithium.
-
19M.3.hl.TZ1.3b(iii):
Suggest a better method.
-
19M.3.hl.TZ1.3c:
Lithium is obtained by electrolysis of molten lithium chloride. Calculate the time, in seconds, taken to deposit 0.694 g Li using a current of 2.00 A.
Q (charge) = I (current) × t (time)
-
19M.3.hl.TZ1.3d(i):
Lithium has shown some superconductive properties when doped into graphene or when under high pressure. Under high pressure, however, the Meissner effect is absent.
Describe the Meissner effect.
-
19M.3.hl.TZ1.3d(ii):
At very low temperatures, lithium atoms enhance the phonon binding of electrons in graphene suggesting the formation of Cooper pairs.
Explain how Cooper pairs are formed.
-
19M.3.hl.TZ1.3e:
Lithium forms a crystalline lattice with the unit cell structure shown below.
X-ray diffraction shows that the length of the edge of the unit cell is 3.51 × 10−8 cm.
Determine the density of lithium, in g cm−3, using sections 2 and 6 of the data booklet.
-
19M.3.hl.TZ1.a:
Identify the type of bonding in lithium hydride, using sections 8 and 29 of the data booklet.
-
19M.3.hl.TZ1.b(i):
Identify the colour of the emission spectrum of lithium using section 17 of the data booklet.
-
19M.3.hl.TZ1.b(ii):
Suggest why ICP-OES does not give good quantitative results for distinguishing 6Li from naturally occurring lithium.
-
19M.3.hl.TZ1.b(iii):
Suggest a better method.
-
19M.3.hl.TZ1.c:
Lithium is obtained by electrolysis of molten lithium chloride. Calculate the time, in seconds, taken to deposit 0.694 g Li using a current of 2.00 A.
Q (charge) = I (current) × t (time)
-
19M.3.hl.TZ1.d(i):
Lithium has shown some superconductive properties when doped into graphene or when under high pressure. Under high pressure, however, the Meissner effect is absent.
Describe the Meissner effect.
-
19M.3.hl.TZ1.d(ii):
At very low temperatures, lithium atoms enhance the phonon binding of electrons in graphene suggesting the formation of Cooper pairs.
Explain how Cooper pairs are formed.
-
19M.3.hl.TZ1.e:
Lithium forms a crystalline lattice with the unit cell structure shown below.
X-ray diffraction shows that the length of the edge of the unit cell is 3.51 × 10−8 cm.
Determine the density of lithium, in g cm−3, using sections 2 and 6 of the data booklet.
-
19M.3.hl.TZ1.4a:
Outline two differences between heterogeneous and homogeneous catalysts.
-
19M.3.hl.TZ1.4b:
Suggest, giving a reason, how elastomers used for the tyre tread can increase the traction between the tyre and the road.
-
19M.3.hl.TZ1.4c:
Tyre fires emit trace quantities of polychlorinated dibenzofurans and polychlorinated dibenzo-p-dioxin.
Outline, using section 31 of the data booklet, why polychlorinated dibenzofuran is not classed chemically as a dioxin but considered “dioxin-like”.
-
19M.3.hl.TZ1.4d:
Classify polybutadiene as either an addition or condensation polymer, giving a reason.
-
19M.3.hl.TZ1.4e:
State one factor considered when making green chemistry polymers.
-
19M.3.hl.TZ1.a:
Outline two differences between heterogeneous and homogeneous catalysts.
-
19M.3.hl.TZ1.b:
Suggest, giving a reason, how elastomers used for the tyre tread can increase the traction between the tyre and the road.
-
19M.3.hl.TZ1.c:
Tyre fires emit trace quantities of polychlorinated dibenzofurans and polychlorinated dibenzo-p-dioxin.
Outline, using section 31 of the data booklet, why polychlorinated dibenzofuran is not classed chemically as a dioxin but considered “dioxin-like”.
-
19M.3.hl.TZ1.d:
Classify polybutadiene as either an addition or condensation polymer, giving a reason.
-
19M.3.hl.TZ1.e:
State one factor considered when making green chemistry polymers.
-
19M.3.hl.TZ1.5a:
Label with an asterisk, *, the chiral carbon atom.
-
19M.3.hl.TZ1.5b:
Explain the effects of very low and high temperatures on the liquid-crystal behaviour of this molecule.
Low temperature:
High temperature:
-
19M.3.hl.TZ1.a:
Label with an asterisk, *, the chiral carbon atom.
-
19M.3.hl.TZ1.b:
Explain the effects of very low and high temperatures on the liquid-crystal behaviour of this molecule.
Low temperature:
High temperature:
-
19M.3.hl.TZ1.6a:
Describe the structure and bonding of a carbon nanotube.
Structure:
Bonding:
-
19M.3.hl.TZ1.6b:
Suggest one application for carbon nanotubes.
-
19M.3.hl.TZ1.a:
Describe the structure and bonding of a carbon nanotube.
Structure:
Bonding:
-
19M.3.hl.TZ1.b:
Suggest one application for carbon nanotubes.
-
19M.3.hl.TZ1.7a:
Explain how entropy affects this equilibrium.
-
19M.3.hl.TZ1.7b:
State the number of coordinate covalent bonds EDTA forms with Ni2+.
-
19M.3.hl.TZ1.a:
Explain how entropy affects this equilibrium.
-
19M.3.hl.TZ1.b:
State the number of coordinate covalent bonds EDTA forms with Ni2+.
-
19M.3.hl.TZ2.3:
Describe the characteristics of the nematic liquid crystal phase.
Shape of molecules:
Distribution:
-
19M.3.hl.TZ2.4a:
Determine the mass of aluminium, in g, that could be extracted from an appropriate solution by a charge of 48 250 C. Use sections 2 and 6 of the data booklet.
-
19M.3.hl.TZ2.4b:
Once extracted, the purity of the metal can be assessed using ICP-MS. Suggest two advantages of using plasma technology rather than regular mass spectrometry.
-
19M.3.hl.TZ2.4c:
Explain the action of metals as heterogeneous catalysts.
-
19M.3.hl.TZ2.4d:
Outline how alloys conduct electricity and why they are often harder than pure metals.
Conduct electricity:
Harder than pure metals:
-
19M.3.hl.TZ2.4e:
Carbon nanotubes are added to metals to increase tensile strength.
Write an equation for the formation of carbon nanotubes from carbon monoxide.
-
19M.3.hl.TZ2.a:
Determine the mass of aluminium, in g, that could be extracted from an appropriate solution by a charge of 48 250 C. Use sections 2 and 6 of the data booklet.
-
19M.3.hl.TZ2.b:
Once extracted, the purity of the metal can be assessed using ICP-MS. Suggest two advantages of using plasma technology rather than regular mass spectrometry.
-
19M.3.hl.TZ2.c:
Explain the action of metals as heterogeneous catalysts.
-
19M.3.hl.TZ2.d:
Outline how alloys conduct electricity and why they are often harder than pure metals.
Conduct electricity:
Harder than pure metals:
-
19M.3.hl.TZ2.e:
Carbon nanotubes are added to metals to increase tensile strength.
Write an equation for the formation of carbon nanotubes from carbon monoxide.
-
19M.3.hl.TZ2.5a:
Draw a section of isotactic polychloroethene (polyvinylchloride, PVC) showing all the atoms and all the bonds of four monomer units.
-
19M.3.hl.TZ2.5c:
Explain how plasticizers affect the properties of plastics.
-
19M.3.hl.TZ2.5d:
Suggest why the addition of plasticizers is controversial.
-
19M.3.hl.TZ2.5e:
Outline, giving a reason, how addition and condensation polymerization compare with regard to green chemistry.
-
19M.3.hl.TZ2.5f:
Draw the full structural formula of the organic functional group formed during the polymerization of the two reactants below.
-
19M.3.hl.TZ2.a:
Draw a section of isotactic polychloroethene (polyvinylchloride, PVC) showing all the atoms and all the bonds of four monomer units.
-
19M.3.hl.TZ2.c:
Explain how plasticizers affect the properties of plastics.
-
19M.3.hl.TZ2.d:
Suggest why the addition of plasticizers is controversial.
-
19M.3.hl.TZ2.e:
Outline, giving a reason, how addition and condensation polymerization compare with regard to green chemistry.
-
19M.3.hl.TZ2.f:
Draw the full structural formula of the organic functional group formed during the polymerization of the two reactants below.
-
19M.3.hl.TZ2.6a:
State the number of atoms in the unit cell.
-
19M.3.hl.TZ2.6b:
Determine the density of calcium, in g cm−3, using section 2 of the data booklet.
Ar = 40.08; metallic radius (r) = 1.97 × 10−10 m
-
19M.3.hl.TZ2.a:
State the number of atoms in the unit cell.
-
19M.3.hl.TZ2.b:
Determine the density of calcium, in g cm−3, using section 2 of the data booklet.
Ar = 40.08; metallic radius (r) = 1.97 × 10−10 m
-
19M.3.hl.TZ2.7a:
State what is meant by a superconductor.
-
19M.3.hl.TZ2.a:
State what is meant by a superconductor.
-
19M.3.hl.TZ2.8a:
Outline why heavy metals are toxic.
-
19M.3.hl.TZ2.8b:
Determine the maximum concentration of lead(II) ions at 298 K in a solution in which the concentration of carbonate ions is maintained at 1.10 × 10−4 mol dm−3. Use section 32 of the data booklet.
-
19M.3.hl.TZ2.8c:
State a method, other than precipitation, of removing heavy metal ions from solution.
-
19M.3.hl.TZ2.a:
Outline why heavy metals are toxic.
-
19M.3.hl.TZ2.b:
Determine the maximum concentration of lead(II) ions at 298 K in a solution in which the concentration of carbonate ions is maintained at 1.10 × 10−4 mol dm−3. Use section 32 of the data booklet.
-
19M.3.hl.TZ2.c:
State a method, other than precipitation, of removing heavy metal ions from solution.
-
19M.3.hl.TZ2.18b:
Outline one approach to controlling industrial emissions of carbon dioxide.
-
19M.3.hl.TZ2.b:
Outline one approach to controlling industrial emissions of carbon dioxide.
-
19M.3.sl.TZ1.3a(i):
Identify the type of bonding in lithium hydride, using sections 8 and 29 of the data booklet.
-
19M.3.sl.TZ1.3a(ii):
Explain why lithium is paramagnetic while lithium hydride is diamagnetic by referring to electron configurations.
-
19M.3.sl.TZ1.3b(i):
Suggest why ICP-OES does not give good quantitative results for distinguishing 6Li from naturally occurring lithium.
-
19M.3.sl.TZ1.3b(ii):
Suggest a better method.
-
19M.3.sl.TZ1.3c:
Lithium is obtained by electrolysis of molten lithium chloride. Calculate the time, in seconds, taken to deposit 0.694 g Li using a current of 2.00 A.
Q (charge) = I (current) × t (time)
-
19M.3.sl.TZ1.a(i):
Identify the type of bonding in lithium hydride, using sections 8 and 29 of the data booklet.
-
19M.3.sl.TZ1.a(ii):
Explain why lithium is paramagnetic while lithium hydride is diamagnetic by referring to electron configurations.
-
19M.3.sl.TZ1.b(i):
Suggest why ICP-OES does not give good quantitative results for distinguishing 6Li from naturally occurring lithium.
-
19M.3.sl.TZ1.b(ii):
Suggest a better method.
-
19M.3.sl.TZ1.c:
Lithium is obtained by electrolysis of molten lithium chloride. Calculate the time, in seconds, taken to deposit 0.694 g Li using a current of 2.00 A.
Q (charge) = I (current) × t (time)
-
19M.3.sl.TZ1.4a:
Outline two differences between heterogeneous and homogeneous catalysts.
-
19M.3.sl.TZ1.4b:
Suggest, giving a reason, how elastomers used for the tyre tread can increase the traction between the tyre and the road.
-
19M.3.sl.TZ1.4c(i):
Tyre fires emit trace quantities of polychlorinated dibenzofurans and polychlorinated dibenzo-p-dioxin.
Outline, using section 31 of the data booklet, why polychlorinated dibenzofuran is not classed chemically as a dioxin but considered “dioxin-like”.
-
19M.3.sl.TZ1.4c(ii):
The trace quantities of dioxins from tyre fires are rarely inhaled and instead settle on the ground.
Describe why this is a health concern.
-
19M.3.sl.TZ1.a:
Outline two differences between heterogeneous and homogeneous catalysts.
-
19M.3.sl.TZ1.b:
Suggest, giving a reason, how elastomers used for the tyre tread can increase the traction between the tyre and the road.
-
19M.3.sl.TZ1.c(i):
Tyre fires emit trace quantities of polychlorinated dibenzofurans and polychlorinated dibenzo-p-dioxin.
Outline, using section 31 of the data booklet, why polychlorinated dibenzofuran is not classed chemically as a dioxin but considered “dioxin-like”.
-
19M.3.sl.TZ1.c(ii):
The trace quantities of dioxins from tyre fires are rarely inhaled and instead settle on the ground.
Describe why this is a health concern.
-
19M.3.sl.TZ1.5a:
State the name of the functional group which allows the molecule to be responsive to applied electric fields.
-
19M.3.sl.TZ1.5b:
Explain the effects of very low and high temperatures on the liquid-crystal behaviour of this molecule.
Low temperature:
High temperature:
-
19M.3.sl.TZ1.a:
State the name of the functional group which allows the molecule to be responsive to applied electric fields.
-
19M.3.sl.TZ1.b:
Explain the effects of very low and high temperatures on the liquid-crystal behaviour of this molecule.
Low temperature:
High temperature:
-
19M.3.sl.TZ1.6a:
Describe the structure and bonding of a carbon nanotube.
Structure:
Bonding:
-
19M.3.sl.TZ1.6b:
Suggest one application for carbon nanotubes.
-
19M.3.sl.TZ1.a:
Describe the structure and bonding of a carbon nanotube.
Structure:
Bonding:
-
19M.3.sl.TZ1.b:
Suggest one application for carbon nanotubes.
-
19M.3.sl.TZ2.3:
Describe the characteristics of the nematic liquid crystal phase and the effect that an electric field has on it.
Shape of molecules:Distribution:
Effect of electric field:
-
19M.3.sl.TZ2.4a:
Determine the mass of aluminium, in g, that could be extracted from an appropriate solution by a charge of 48250 C. Use sections 2 and 6 of the data booklet.
-
19M.3.sl.TZ2.4b:
Once extracted, the purity of the metal can be assessed using ICP-MS. Suggest two advantages of using plasma technology rather than regular mass spectrometry.
-
19M.3.sl.TZ2.4c:
Explain the action of metals as heterogeneous catalysts.
-
19M.3.sl.TZ2.4d:
Outline how alloys conduct electricity and why they are often harder than pure metals.
Conduct electricity:
Harder than pure metals:
-
19M.3.sl.TZ2.4e:
Carbon nanotubes are added to metals to increase tensile strength.
Write an equation for the formation of carbon nanotubes from carbon monoxide.
-
19M.3.sl.TZ2.a:
Determine the mass of aluminium, in g, that could be extracted from an appropriate solution by a charge of 48250 C. Use sections 2 and 6 of the data booklet.
-
19M.3.sl.TZ2.b:
Once extracted, the purity of the metal can be assessed using ICP-MS. Suggest two advantages of using plasma technology rather than regular mass spectrometry.
-
19M.3.sl.TZ2.c:
Explain the action of metals as heterogeneous catalysts.
-
19M.3.sl.TZ2.d:
Outline how alloys conduct electricity and why they are often harder than pure metals.
Conduct electricity:
Harder than pure metals:
-
19M.3.sl.TZ2.e:
Carbon nanotubes are added to metals to increase tensile strength.
Write an equation for the formation of carbon nanotubes from carbon monoxide.
-
19M.3.sl.TZ2.5a:
Draw a section of isotactic polychloroethene (polyvinylchloride, PVC) showing all the atoms and all the bonds of four monomer units.
-
19M.3.sl.TZ2.5c:
Identify a hazardous product of the incineration of polychloroethene.
-
19M.3.sl.TZ2.5d:
Explain how plasticizers affect the properties of plastics.
-
19M.3.sl.TZ2.5e:
Suggest why the addition of plasticizers is controversial.
-
19M.3.sl.TZ2.a:
Draw a section of isotactic polychloroethene (polyvinylchloride, PVC) showing all the atoms and all the bonds of four monomer units.
-
19M.3.sl.TZ2.c:
Identify a hazardous product of the incineration of polychloroethene.
-
19M.3.sl.TZ2.d:
Explain how plasticizers affect the properties of plastics.
-
19M.3.sl.TZ2.e:
Suggest why the addition of plasticizers is controversial.
-
19N.3.sl.TZ0.3a:
Describe how a heterogeneous catalyst provides an alternative pathway for a reaction.
- 19N.3.sl.TZ0.3b: Distinguish between heterogeneous and homogeneous catalysts, giving one difference.
-
19N.3.sl.TZ0.3c:
Nanotubes are used to support the active material in nanocatalysts.
Explain why oxygen cannot be used for the chemical vapour deposition (CVD) preparation of carbon nanotubes.
-
19N.3.sl.TZ0.a:
Describe how a heterogeneous catalyst provides an alternative pathway for a reaction.
- 19N.3.sl.TZ0.b: Distinguish between heterogeneous and homogeneous catalysts, giving one difference.
-
19N.3.sl.TZ0.c:
Nanotubes are used to support the active material in nanocatalysts.
Explain why oxygen cannot be used for the chemical vapour deposition (CVD) preparation of carbon nanotubes.
- 19N.3.hl.TZ0.4a(i): Outline how resistance to electric currents occurs in metals.
- 19N.3.hl.TZ0.4a(ii): Suggest why the resistance of metals increases with temperature.
- 19N.3.hl.TZ0.4b: State two differences between Type I and Type II superconductors.
- 19N.3.hl.TZ0.a(i): Outline how resistance to electric currents occurs in metals.
- 19N.3.hl.TZ0.a(ii): Suggest why the resistance of metals increases with temperature.
- 19N.3.hl.TZ0.b: State two differences between Type I and Type II superconductors.
-
19N.3.hl.TZ0.5a:
Draw the structure of the monomers of Kevlar® if the by-product of the condensation polymerization is hydrogen chloride.
- 19N.3.hl.TZ0.5b: State and explain why plasticizers are added to polymers.
- 19N.3.hl.TZ0.5c: Discuss why the recycling of plastics is an energy intensive process.
-
19N.3.hl.TZ0.a:
Draw the structure of the monomers of Kevlar® if the by-product of the condensation polymerization is hydrogen chloride.
- 19N.3.hl.TZ0.b: State and explain why plasticizers are added to polymers.
- 19N.3.hl.TZ0.c: Discuss why the recycling of plastics is an energy intensive process.
-
19N.3.sl.TZ0.5a:
Discuss why different methods of reduction are needed to extract metals.
-
19N.3.sl.TZ0.5b(i):
Determine the percentage of ionic bonding in alumina using sections 8 and 29 of the data booklet.
-
19N.3.sl.TZ0.5b(ii):
Write half-equations for the electrolysis of molten alumina using graphite electrodes, deducing the state symbols of the products.
Anode (positive electrode):
Cathode (negative electrode):
-
19N.3.sl.TZ0.a:
Discuss why different methods of reduction are needed to extract metals.
-
19N.3.sl.TZ0.b(i):
Determine the percentage of ionic bonding in alumina using sections 8 and 29 of the data booklet.
-
19N.3.sl.TZ0.b(ii):
Write half-equations for the electrolysis of molten alumina using graphite electrodes, deducing the state symbols of the products.
Anode (positive electrode):
Cathode (negative electrode):
-
19N.3.hl.TZ0.7:
X-ray crystallography of a metal crystal produces a diffraction pattern of bright spots.
Using X-rays of wavelength 1.54 × 10−10 m, the first bright spots were produced at an angle θ of 22.3° from the centre.
Calculate the separation between planes of atoms in the lattice, in meters, using section 1 of the data booklet.
-
19N.3.hl.TZ0.8:
1.40 × 10−3 g of NaOH (s) are dissolved in 250.0 cm3 of 1.00 × 10−11 mol dm−3 Pb(OH)2 (aq) solution.
Determine the change in lead ion concentration in the solution, using section 32 of the data booklet.
- 19N.3.sl.TZ0.6a: Describe the arrangement of soap molecules in the nematic liquid crystal phase.
- 19N.3.sl.TZ0.6b: State how liquid crystals are affected by an electric field.
- 19N.3.sl.TZ0.a: Describe the arrangement of soap molecules in the nematic liquid crystal phase.
- 19N.3.sl.TZ0.b: State how liquid crystals are affected by an electric field.
-
19N.3.sl.TZ0.4a:
Draw a section of an isotactic polypropene polymer chain containing four repeating units.
- 19N.3.sl.TZ0.4b: Predict, with a reason, whether isotactic or atactic polypropene has the higher melting point.
- 19N.3.sl.TZ0.4c: Polypropene is a thermoplastic. Outline what is meant by thermoplastic.
- 19N.3.sl.TZ0.4d: Discuss why the recycling of plastics is an energy intensive process.
-
19N.3.sl.TZ0.a:
Draw a section of an isotactic polypropene polymer chain containing four repeating units.
- 19N.3.sl.TZ0.b: Predict, with a reason, whether isotactic or atactic polypropene has the higher melting point.
- 19N.3.sl.TZ0.c: Polypropene is a thermoplastic. Outline what is meant by thermoplastic.
- 19N.3.sl.TZ0.d: Discuss why the recycling of plastics is an energy intensive process.
-
20N.3.sl.TZ0.3a:
Outline the two distinct phases of this composite.
- 20N.3.sl.TZ0.3b(i): Thermoplastic composites are increasingly replacing thermosets. Suggest one advantage of...
- 20N.3.sl.TZ0.3b(ii): Explain how thermoplastics, such as polyvinylchloride, PVC, can be made more flexible by the...
- 20N.3.sl.TZ0.3c: Explain why phthalates are replaced by other plasticizers in the production of plastics.
-
20N.3.sl.TZ0.a:
Outline the two distinct phases of this composite.
- 20N.3.sl.TZ0.b(i): Thermoplastic composites are increasingly replacing thermosets. Suggest one advantage of...
- 20N.3.sl.TZ0.b(ii): Explain how thermoplastics, such as polyvinylchloride, PVC, can be made more flexible by the...
- 20N.3.sl.TZ0.c: Explain why phthalates are replaced by other plasticizers in the production of plastics.
- 20N.3.sl.TZ0.4a: Explain these properties of carbon nanotubes.
- 20N.3.sl.TZ0.4b(i): Alloying metals changes their properties. Suggest one property of magnesium that could be...
-
20N.3.sl.TZ0.4b(ii):
Pure magnesium needed for making alloys can be obtained by electrolysis of molten magnesium chloride.
© International Baccalaureate Organization 2020.
Write the half-equations for the reactions occurring in this electrolysis.
-
20N.3.sl.TZ0.4b(iii):
Calculate the theoretical mass of magnesium obtained if a current of is used for hours. Use charge and section 2 of the data booklet
-
20N.3.sl.TZ0.4b(iv):
Suggest a gas which should be continuously passed over the molten magnesium in the electrolytic cell.
- 20N.3.sl.TZ0.4c: Zeolites can be used as catalysts in the manufacture of CNT. Explain, with reference to their...
- 20N.3.sl.TZ0.4d: Experiments have been done to explore the nematic liquid crystal behaviour of CNT. Justify how...
- 20N.3.sl.TZ0.4e: Experiments have been done to explore the nematic liquid crystal behaviour of CNT. Justify how...
- 20N.3.sl.TZ0.a: Explain these properties of carbon nanotubes.
- 20N.3.sl.TZ0.b(i): Alloying metals changes their properties. Suggest one property of magnesium that could be...
-
20N.3.sl.TZ0.b(ii):
Pure magnesium needed for making alloys can be obtained by electrolysis of molten magnesium chloride.
© International Baccalaureate Organization 2020.
Write the half-equations for the reactions occurring in this electrolysis.
-
20N.3.sl.TZ0.b(iii):
Calculate the theoretical mass of magnesium obtained if a current of is used for hours. Use charge and section 2 of the data booklet
-
20N.3.sl.TZ0.b(iv):
Suggest a gas which should be continuously passed over the molten magnesium in the electrolytic cell.
- 20N.3.sl.TZ0.c: Zeolites can be used as catalysts in the manufacture of CNT. Explain, with reference to their...
- 20N.3.sl.TZ0.d: Experiments have been done to explore the nematic liquid crystal behaviour of CNT. Justify how...
-
20N.3.hl.TZ0.3a:
Outline the two distinct phases of this composite.
- 20N.3.hl.TZ0.3b(i): Thermoplastic composites are increasingly replacing thermosets. Suggest one advantage of...
- 20N.3.hl.TZ0.3b(ii): Explain how thermoplastics, such as polyvinylchloride, PVC, can be made more flexible by the...
- 20N.3.hl.TZ0.3b(iii): Explain why phthalates are replaced by other plasticizers in the production of plastics.
- 20N.3.hl.TZ0.3c: Classify PVC and polyethene terephthalate, PET, as addition or condensation polymers and deduce...
-
20N.3.hl.TZ0.a:
Outline the two distinct phases of this composite.
- 20N.3.hl.TZ0.b(i): Thermoplastic composites are increasingly replacing thermosets. Suggest one advantage of...
- 20N.3.hl.TZ0.b(ii): Explain how thermoplastics, such as polyvinylchloride, PVC, can be made more flexible by the...
- 20N.3.hl.TZ0.b(iii): Explain why phthalates are replaced by other plasticizers in the production of plastics.
- 20N.3.hl.TZ0.c: Classify PVC and polyethene terephthalate, PET, as addition or condensation polymers and deduce...
- 20N.3.hl.TZ0.4a: Explain these properties of carbon nanotubes.
- 20N.3.hl.TZ0.4b(i): CNT can act as Type 2 superconductors. Outline why Type 2 superconductors are generally more...
-
20N.3.hl.TZ0.4b(ii):
Explain the role of electrons in superconducting materials in terms of the Bardeen–Cooper–Schrieffer (BCS) theory.
-
20N.3.hl.TZ0.4c(i):
Alloying metals changes their properties. Suggest one property of magnesium that could be improved by making a magnesium–CNT alloy.
-
20N.3.hl.TZ0.4c(ii):
Pure magnesium needed for making alloys can be obtained by electrolysis of molten magnesium chloride.
© International Baccalaureate Organization 2020
Calculate the theoretical mass of magnesium obtained if a current of 3.00 A is used for hours. Use charge :(Q) = current (I) × time (t) and section 2 of the data booklet.
-
20N.3.hl.TZ0.4c(iii):
Suggest a gas which should be continuously passed over the molten magnesium in the electrolytic cell.
- 20N.3.hl.TZ0.4d: Zeolites can be used as catalysts in the manufacture of CNT. Explain, with reference to their...
- 20N.3.hl.TZ0.4e: Experiments have been done to explore the nematic liquid crystal behaviour of CNT. Justify how...
- 20N.3.hl.TZ0.a: Explain these properties of carbon nanotubes.
- 20N.3.hl.TZ0.b(i): CNT can act as Type 2 superconductors. Outline why Type 2 superconductors are generally more...
-
20N.3.hl.TZ0.b(ii):
Explain the role of electrons in superconducting materials in terms of the Bardeen–Cooper–Schrieffer (BCS) theory.
-
20N.3.hl.TZ0.c(i):
Alloying metals changes their properties. Suggest one property of magnesium that could be improved by making a magnesium–CNT alloy.
-
20N.3.hl.TZ0.c(ii):
Pure magnesium needed for making alloys can be obtained by electrolysis of molten magnesium chloride.
© International Baccalaureate Organization 2020
Calculate the theoretical mass of magnesium obtained if a current of 3.00 A is used for hours. Use charge :(Q) = current (I) × time (t) and section 2 of the data booklet.
-
20N.3.hl.TZ0.c(iii):
Suggest a gas which should be continuously passed over the molten magnesium in the electrolytic cell.
- 20N.3.hl.TZ0.d: Zeolites can be used as catalysts in the manufacture of CNT. Explain, with reference to their...
- 20N.3.hl.TZ0.e: Experiments have been done to explore the nematic liquid crystal behaviour of CNT. Justify how...
-
20N.3.hl.TZ0.5a:
Precipitation is one method used to treat waste water.
Phosphates, , in waste water can be removed by precipitation with magnesium ions. of magnesium phosphate is .
Calculate the maximum solubility of phosphate ions in a solution containing magnesium ions.
-
20N.3.hl.TZ0.5b:
Precipitation is one method used to treat waste water.
Zinc, cadmium, nickel, and lead are metal ions which can be removed by precipitation. Explain why waste water is adjusted to a pH of 9−10 to remove these ions by referring to section 32 of the data booklet.
-
20N.3.hl.TZ0.a:
Precipitation is one method used to treat waste water.
Phosphates, , in waste water can be removed by precipitation with magnesium ions. of magnesium phosphate is .
Calculate the maximum solubility of phosphate ions in a solution containing magnesium ions.
-
20N.3.hl.TZ0.b:
Precipitation is one method used to treat waste water.
Zinc, cadmium, nickel, and lead are metal ions which can be removed by precipitation. Explain why waste water is adjusted to a pH of 9−10 to remove these ions by referring to section 32 of the data booklet.
-
17N.3.sl.TZ0.4a:
Outline the composition of an alloy and a composite.
- 17N.3.sl.TZ0.4b.i: Outline why an alloy is usually harder than its components by referring to its structure.
- 17N.3.sl.TZ0.4b.ii: At present, composite fillings are more expensive than amalgam fillings. Suggest why a patient...
-
17N.3.sl.TZ0.4c:
Explain how Inductively Coupled Plasma (ICP) Spectroscopy could be used to determine the concentration of mercury in a sample of dental filling.
-
17N.3.sl.TZ0.a:
Outline the composition of an alloy and a composite.
- 17N.3.sl.TZ0.b.i: Outline why an alloy is usually harder than its components by referring to its structure.
- 17N.3.sl.TZ0.b.ii: At present, composite fillings are more expensive than amalgam fillings. Suggest why a patient...
-
17N.3.sl.TZ0.c:
Explain how Inductively Coupled Plasma (ICP) Spectroscopy could be used to determine the concentration of mercury in a sample of dental filling.
-
17N.3.sl.TZ0.5:
Catalysts can take many forms and are used in many industrial processes.
Suggest two reasons why it might be worth using a more expensive catalyst to increase the rate of a reaction.
-
17N.3.sl.TZ0.6a:
State equations for the formation of iron nanoparticles and carbon atoms from Fe(CO)5 in the HIPCO process.
- 17N.3.sl.TZ0.6b: Outline why the iron nanoparticle catalysts produced by the HIPCO process are more efficient than...
- 17N.3.sl.TZ0.6c: Discuss one possible risk associated with the use of nanotechnology.
-
17N.3.sl.TZ0.a:
State equations for the formation of iron nanoparticles and carbon atoms from Fe(CO)5 in the HIPCO process.
- 17N.3.sl.TZ0.b: Outline why the iron nanoparticle catalysts produced by the HIPCO process are more efficient than...
- 17N.3.sl.TZ0.c: Discuss one possible risk associated with the use of nanotechnology.
-
17N.3.sl.TZ0.7a:
Outline two properties a substance should have to be used as liquid-crystal in a liquid-crystal display.
-
17N.3.sl.TZ0.7b.i:
Describe how the structures of LDPE and HDPE affect one mechanical property of the plastics.
-
17N.3.sl.TZ0.7b.ii:
One of the two infrared (IR) spectra is that of polyethene and the other of polytetrafluoroethene (PTFE).
Deduce, with a reason, which spectrum is that of PTFE. Infrared data is given in section 26 of the data booklet.
-
17N.3.sl.TZ0.7c:
Many plastics used to be incinerated. Deduce an equation for the complete combustion of two repeating units of PVC, (–C2H3Cl–)2.
-
17N.3.sl.TZ0.a:
Outline two properties a substance should have to be used as liquid-crystal in a liquid-crystal display.
-
17N.3.sl.TZ0.b.i:
Describe how the structures of LDPE and HDPE affect one mechanical property of the plastics.
-
17N.3.sl.TZ0.b.ii:
One of the two infrared (IR) spectra is that of polyethene and the other of polytetrafluoroethene (PTFE).
Deduce, with a reason, which spectrum is that of PTFE. Infrared data is given in section 26 of the data booklet.
-
17N.3.sl.TZ0.c:
Many plastics used to be incinerated. Deduce an equation for the complete combustion of two repeating units of PVC, (–C2H3Cl–)2.
-
17N.3.hl.TZ0.6b:
Explain why Type 2 superconductors are generally more useful than Type 1.
-
17N.3.hl.TZ0.b:
Explain why Type 2 superconductors are generally more useful than Type 1.
- 17N.3.hl.TZ0.7b: Describe how the monomers of addition polymers and of condensation polymers differ.
-
17N.3.hl.TZ0.7c:
Identify the type of intermolecular bonding that is responsible for Kevlar®’s strength.
- 17N.3.hl.TZ0.b: Describe how the monomers of addition polymers and of condensation polymers differ.
-
17N.3.hl.TZ0.c:
Identify the type of intermolecular bonding that is responsible for Kevlar®’s strength.
-
17N.3.hl.TZ0.8a:
Calculate the total number of cobalt atoms within its unit cell.
-
17N.3.hl.TZ0.8b.i:
The atomic radius, r, of cobalt is 1.18 × 10–8 cm. Determine the edge length, in cm, of the unit cell, a, using the second diagram.
-
17N.3.hl.TZ0.8b.ii:
Determine a value for the density of cobalt, in g cm–3, using data from sections 2 and 6 of the data booklet and your answers from (a) and (b) (i).
If you did not obtain an answer to (b) (i), use 3.00 × 10–8 cm but this is not the correct answer.
-
17N.3.hl.TZ0.a:
Calculate the total number of cobalt atoms within its unit cell.
-
17N.3.hl.TZ0.b.i:
The atomic radius, r, of cobalt is 1.18 × 10–8 cm. Determine the edge length, in cm, of the unit cell, a, using the second diagram.
-
17N.3.hl.TZ0.b.ii:
Determine a value for the density of cobalt, in g cm–3, using data from sections 2 and 6 of the data booklet and your answers from (a) and (b) (i).
If you did not obtain an answer to (b) (i), use 3.00 × 10–8 cm but this is not the correct answer.
- 17N.3.hl.TZ0.9a: State the name of one method, other than precipitation, of removing heavy metal ions from...
-
17N.3.hl.TZ0.9b:
The solubility product, Ksp , of cadmium sulfide, CdS, is 8.0 × 10–27. Determine the concentration of cadmium ions in 1.0 dm3 of a saturated solution of cadmium sulfide to which 0.10 mol of solid sodium sulfide has been added, stating any assumption you make.
- 17N.3.hl.TZ0.a: State the name of one method, other than precipitation, of removing heavy metal ions from...
-
17N.3.hl.TZ0.b:
The solubility product, Ksp , of cadmium sulfide, CdS, is 8.0 × 10–27. Determine the concentration of cadmium ions in 1.0 dm3 of a saturated solution of cadmium sulfide to which 0.10 mol of solid sodium sulfide has been added, stating any assumption you make.
-
18M.3.hl.TZ1.4c.i:
Draw the structure of the monomer from which nylon-6 is produced by a condensation reaction.
-
18M.3.hl.TZ1.4c.ii:
Deduce, giving a reason, whether the atom economy of a condensation polymerization, such as this, would be greater or less than an addition polymerization, such as the formation of HDPE.
-
18M.3.hl.TZ1.c.i:
Draw the structure of the monomer from which nylon-6 is produced by a condensation reaction.
-
18M.3.hl.TZ1.c.ii:
Deduce, giving a reason, whether the atom economy of a condensation polymerization, such as this, would be greater or less than an addition polymerization, such as the formation of HDPE.
-
18M.3.hl.TZ1.5b:
The diagram illustrates the crystal structure of aluminium metal with the unit cell indicated. Outline the significance of the unit cell.
-
18M.3.hl.TZ1.5c:
When X-rays of wavelength 0.154 nm are directed at a crystal of aluminium, the first order diffraction pattern is observed at 18°. Determine the separation of layers of aluminium atoms in the crystal, in m, using section 1 of the data booklet.
-
18M.3.hl.TZ1.5d.i:
Deduce what the shape of the graph indicates about aluminium.
-
18M.3.hl.TZ1.5d.ii:
Outline why the resistance of aluminium increases above 1.2 K.
-
18M.3.hl.TZ1.5e:
The concentration of aluminium in drinking water can be reduced by precipitating aluminium hydroxide. Calculate the maximum concentration of aluminium ions in water of pH 7 at 298 K. Solubility product of aluminium hydroxide = 3.3 × 10−34 at 298 K.
-
18M.3.hl.TZ1.b:
The diagram illustrates the crystal structure of aluminium metal with the unit cell indicated. Outline the significance of the unit cell.
-
18M.3.hl.TZ1.c:
When X-rays of wavelength 0.154 nm are directed at a crystal of aluminium, the first order diffraction pattern is observed at 18°. Determine the separation of layers of aluminium atoms in the crystal, in m, using section 1 of the data booklet.
-
18M.3.hl.TZ1.d.i:
Deduce what the shape of the graph indicates about aluminium.
-
18M.3.hl.TZ1.d.ii:
Outline why the resistance of aluminium increases above 1.2 K.
-
18M.3.hl.TZ1.e:
The concentration of aluminium in drinking water can be reduced by precipitating aluminium hydroxide. Calculate the maximum concentration of aluminium ions in water of pH 7 at 298 K. Solubility product of aluminium hydroxide = 3.3 × 10−34 at 298 K.
- 23M.2.HL.TZ1.3ai: Outline the meaning of homologous series.
- 23M.2.HL.TZ1.i: Outline the meaning of homologous series.
- 23M.2.HL.TZ2.7a: Identify the type of reaction.
- 23M.2.HL.TZ2.a: Identify the type of reaction.
- 23M.2.SL.TZ1.3ai: Outline the meaning of homologous series.
- 23M.2.SL.TZ1.i: Outline the meaning of homologous series.
-
18M.3.hl.TZ2.4a.i:
Deduce the number of atoms per unit cell in vanadium.
-
18M.3.hl.TZ2.4a.ii:
Calculate the expected first order diffraction pattern angle, in degrees, if x-rays of wavelength 150 pm are directed at a crystal of vanadium. Assume the edge length of the crystal to be the same as separation of layers of vanadium atoms found by x-ray diffraction. Use section 1 of the data booklet.
-
18M.3.hl.TZ2.4a.iii:
Calculate the average mass, in g, of a vanadium atom by using sections 2 and 6 of the data booklet.
-
18M.3.hl.TZ2.4a.iv:
Determine the volume, in cm3, of a vanadium unit cell.
-
18M.3.hl.TZ2.4a.v:
Determine the density, in g cm−3, of vanadium by using your answers to (a)(i), (a)(iii) and (a)(iv).
-
18M.3.hl.TZ2.4b.i:
Vanadium and other transition metals can interfere with cell metabolism.
State and explain one process, other than by creating free radicals, by which transition metals interfere with cell metabolism.
-
18M.3.hl.TZ2.4b.ii:
Vanadium(IV) ions can create free radicals by a Fenton reaction.
Deduce the equation for the reaction of V4+ with hydrogen peroxide.
-
18M.3.hl.TZ2.a.i:
Deduce the number of atoms per unit cell in vanadium.
-
18M.3.hl.TZ2.a.ii:
Calculate the expected first order diffraction pattern angle, in degrees, if x-rays of wavelength 150 pm are directed at a crystal of vanadium. Assume the edge length of the crystal to be the same as separation of layers of vanadium atoms found by x-ray diffraction. Use section 1 of the data booklet.
-
18M.3.hl.TZ2.a.iii:
Calculate the average mass, in g, of a vanadium atom by using sections 2 and 6 of the data booklet.
-
18M.3.hl.TZ2.a.iv:
Determine the volume, in cm3, of a vanadium unit cell.
-
18M.3.hl.TZ2.a.v:
Determine the density, in g cm−3, of vanadium by using your answers to (a)(i), (a)(iii) and (a)(iv).
-
18M.3.hl.TZ2.b.i:
Vanadium and other transition metals can interfere with cell metabolism.
State and explain one process, other than by creating free radicals, by which transition metals interfere with cell metabolism.
-
18M.3.hl.TZ2.b.ii:
Vanadium(IV) ions can create free radicals by a Fenton reaction.
Deduce the equation for the reaction of V4+ with hydrogen peroxide.
-
18M.3.hl.TZ2.5c.i:
Distinguish between the manufacture of polyester and polyethene.
-
18M.3.hl.TZ2.c.i:
Distinguish between the manufacture of polyester and polyethene.
-
18M.3.hl.TZ2.6b:
MWCNT are very small in size and can greatly increase switching speeds in a liquid crystal allowing the liquid crystal to change orientation quickly.
Discuss two other properties a substance should have to be suitable for use in liquid crystal displays.
-
18M.3.hl.TZ2.b:
MWCNT are very small in size and can greatly increase switching speeds in a liquid crystal allowing the liquid crystal to change orientation quickly.
Discuss two other properties a substance should have to be suitable for use in liquid crystal displays.
-
18M.3.sl.TZ1.3a:
Discuss, in terms of its structure, why an aluminium saucepan is impermeable to water.
-
18M.3.sl.TZ1.3b.i:
State the name given to a material composed of two distinct solid phases.
-
18M.3.sl.TZ1.3b.ii:
State one physical property of HDPE that will be affected by the incorporation of carbon nanotubes.
-
18M.3.sl.TZ1.3b.iii:
Describe how carbon nanotubes are produced by chemical vapour deposition (CVD).
-
18M.3.sl.TZ1.3b.iv:
State the property of carbon nanotubes that enables them to form a nematic liquid crystal phase.
-
18M.3.sl.TZ1.a:
Discuss, in terms of its structure, why an aluminium saucepan is impermeable to water.
-
18M.3.sl.TZ1.b.i:
State the name given to a material composed of two distinct solid phases.
-
18M.3.sl.TZ1.b.ii:
State one physical property of HDPE that will be affected by the incorporation of carbon nanotubes.
-
18M.3.sl.TZ1.b.iii:
Describe how carbon nanotubes are produced by chemical vapour deposition (CVD).
-
18M.3.sl.TZ1.b.iv:
State the property of carbon nanotubes that enables them to form a nematic liquid crystal phase.
-
18M.3.sl.TZ1.4a:
Both of these are thermoplastic polymers. Outline what this term means.
-
18M.3.sl.TZ1.4b.i:
Compare and contrast the structures of HDPE and LDPE.
-
18M.3.sl.TZ1.4b.ii:
State one way in which a physical property of HDPE, other than density, differs from that of LDPE as a result of this structural difference.
-
18M.3.sl.TZ1.4c.i:
The production of HDPE involves the use of homogeneous catalysts. Outline how homogeneous catalysts reduce the activation energy of reactions.
-
18M.3.sl.TZ1.4c.ii:
Trace amounts of metal from the catalysts used in the production of HDPE sometimes remain in the product. State a technique that could be used to measure the concentration of the metal.
-
18M.3.sl.TZ1.4d:
Suggest two of the major obstacles, other than collection and economic factors, which have to be overcome in plastic recycling.
-
18M.3.sl.TZ1.4e:
Suggest why there are so many different ways in which plastics can be classified. HDPE can, for example, be categorized thermoplastic, an addition polymer, having Resin Identification Code (RIC) 2, etc.
-
18M.3.sl.TZ1.a:
Both of these are thermoplastic polymers. Outline what this term means.
-
18M.3.sl.TZ1.b.i:
Compare and contrast the structures of HDPE and LDPE.
-
18M.3.sl.TZ1.b.ii:
State one way in which a physical property of HDPE, other than density, differs from that of LDPE as a result of this structural difference.
-
18M.3.sl.TZ1.c.i:
The production of HDPE involves the use of homogeneous catalysts. Outline how homogeneous catalysts reduce the activation energy of reactions.
-
18M.3.sl.TZ1.c.ii:
Trace amounts of metal from the catalysts used in the production of HDPE sometimes remain in the product. State a technique that could be used to measure the concentration of the metal.
-
18M.3.sl.TZ1.d:
Suggest two of the major obstacles, other than collection and economic factors, which have to be overcome in plastic recycling.
-
18M.3.sl.TZ1.e:
Suggest why there are so many different ways in which plastics can be classified. HDPE can, for example, be categorized thermoplastic, an addition polymer, having Resin Identification Code (RIC) 2, etc.
-
18M.3.sl.TZ1.5:
Aluminium is produced by the electrolysis of a molten electrolyte containing bauxite.
Determine the mass, in g, of aluminium produced by the passage of a charge of 1.296 × 1013 C. Use sections 2 and 6 of the data booklet.
-
18M.3.sl.TZ2.3a:
ICP-OES/MS can be used to analyse alloys and composites. Distinguish between alloys and composites.
-
18M.3.sl.TZ2.3b:
ICP-MS is a reference mode for analysis. The following correlation graphs between ICP-OES and ICP-MS were produced for yttrium and nickel.
Each y-axis shows concentrations calculated by ICP-OES; each x-axis shows concentrations for the same sample as found by ICP-MS.
The line in each graph is y = x.
Discuss the effectiveness of ICP-OES for yttrium and nickel.
-
18M.3.sl.TZ2.3c.i:
Identify the purpose of each graph.
-
18M.3.sl.TZ2.3c.ii:
Calculate, to four significant figures, the concentration, in μg kg−1, of vanadium in oil giving a signal intensity of 14 950.
-
18M.3.sl.TZ2.3c.iii:
Vanadium(V) oxide is used as the catalyst in the conversion of sulfur dioxide to sulfur trioxide.
SO2(g) + V2O5(s) → SO3(g) + 2VO2(s)
O2(g) + 2VO2(s) → V2O5(s)
Outline how vanadium(V) oxide acts as a catalyst.
-
18M.3.sl.TZ2.a:
ICP-OES/MS can be used to analyse alloys and composites. Distinguish between alloys and composites.
-
18M.3.sl.TZ2.b:
ICP-MS is a reference mode for analysis. The following correlation graphs between ICP-OES and ICP-MS were produced for yttrium and nickel.
Each y-axis shows concentrations calculated by ICP-OES; each x-axis shows concentrations for the same sample as found by ICP-MS.
The line in each graph is y = x.
Discuss the effectiveness of ICP-OES for yttrium and nickel.
-
18M.3.sl.TZ2.c.i:
Identify the purpose of each graph.
-
18M.3.sl.TZ2.c.ii:
Calculate, to four significant figures, the concentration, in μg kg−1, of vanadium in oil giving a signal intensity of 14 950.
-
18M.3.sl.TZ2.c.iii:
Vanadium(V) oxide is used as the catalyst in the conversion of sulfur dioxide to sulfur trioxide.
SO2(g) + V2O5(s) → SO3(g) + 2VO2(s)
O2(g) + 2VO2(s) → V2O5(s)
Outline how vanadium(V) oxide acts as a catalyst.
-
18M.3.sl.TZ2.4a:
Sketch four repeating units of the polymer to show atactic and isotactic polypropene.
-
18M.3.sl.TZ2.4b.i:
State the chemical reason why plastics do not degrade easily.
-
18M.3.sl.TZ2.4b.ii:
Compare two ways in which recycling differs from reusing plastics.
-
18M.3.sl.TZ2.4c:
Civilizations are often characterized by the materials they use.
Suggest an advantage polymers have over materials from the iron age.
-
18M.3.sl.TZ2.a:
Sketch four repeating units of the polymer to show atactic and isotactic polypropene.
-
18M.3.sl.TZ2.b.i:
State the chemical reason why plastics do not degrade easily.
-
18M.3.sl.TZ2.b.ii:
Compare two ways in which recycling differs from reusing plastics.
-
18M.3.sl.TZ2.c:
Civilizations are often characterized by the materials they use.
Suggest an advantage polymers have over materials from the iron age.
-
18M.3.sl.TZ2.5a:
State the source of carbon for MWCNT produced by arc discharge and by CVD.
-
18M.3.sl.TZ2.5b:
Discuss three properties a substance should have to be suitable for use in liquid crystal displays.
-
18M.3.sl.TZ2.a:
State the source of carbon for MWCNT produced by arc discharge and by CVD.
-
18M.3.sl.TZ2.b:
Discuss three properties a substance should have to be suitable for use in liquid crystal displays.
-
18N.3.sl.TZ0.2a:
Outline why this type of classification is not entirely satisfactory by using magnesium diboride, MgB2, as an example. Refer to sections 8 and 29 of the data booklet.
-
18N.3.sl.TZ0.2b.i:
Structures of poly(methyl acrylate), PMA, and Bakelite® are shown.
Suggest, giving reasons, which is the thermoplastic polymer and which is the thermosetting polymer.
-
18N.3.sl.TZ0.2b.ii:
In an incomplete combustion of the polyvinyl chloride, PVC, it was found that hydrogen chloride, carbon monoxide, carbon dioxide, and water vapour were released.
Formulate an equation for this reaction using the formula of the PVC repeating unit.
- 18N.3.sl.TZ0.2c.i: A zeolite is an alternative catalyst for this reaction. Explain how zeolites act as selective...
- 18N.3.sl.TZ0.2c.ii: Identify another advantage of using a zeolite instead of concentrated sulfuric acid.
-
18N.3.sl.TZ0.2d:
Repeating units of several polymers are listed.
The infrared (IR) spectrum of one of these polymers is shown.
Deduce, giving a reason, the name of this polymer and its Resin Identification Code (RIC), using sections 26 and 30 in the data booklet.
-
18N.3.sl.TZ0.a:
Outline why this type of classification is not entirely satisfactory by using magnesium diboride, MgB2, as an example. Refer to sections 8 and 29 of the data booklet.
-
18N.3.sl.TZ0.b.i:
Structures of poly(methyl acrylate), PMA, and Bakelite® are shown.
Suggest, giving reasons, which is the thermoplastic polymer and which is the thermosetting polymer.
-
18N.3.sl.TZ0.b.ii:
In an incomplete combustion of the polyvinyl chloride, PVC, it was found that hydrogen chloride, carbon monoxide, carbon dioxide, and water vapour were released.
Formulate an equation for this reaction using the formula of the PVC repeating unit.
- 18N.3.sl.TZ0.c.i: A zeolite is an alternative catalyst for this reaction. Explain how zeolites act as selective...
- 18N.3.sl.TZ0.c.ii: Identify another advantage of using a zeolite instead of concentrated sulfuric acid.
-
18N.3.sl.TZ0.d:
Repeating units of several polymers are listed.
The infrared (IR) spectrum of one of these polymers is shown.
Deduce, giving a reason, the name of this polymer and its Resin Identification Code (RIC), using sections 26 and 30 in the data booklet.
- 18N.3.sl.TZ0.3a: State the type of particle present in the plasma formed.
-
18N.3.sl.TZ0.3b:
An unknown antacid sample has a lead ion concentration of 0.50 μg dm‒3.
Calculate the concentration of lead ions in the sample in mol dm‒3.
-
18N.3.sl.TZ0.3c:
Electrolysis is used to obtain lead from Pb2+ (aq) solution.
Determine the time, in hours, required to produce 0.0500 mol lead using a current (I) of 1.34 A. Use section 2 of the data booklet and the equation, charge (Q) = current (I) × time (t, in seconds).
- 18N.3.sl.TZ0.a: State the type of particle present in the plasma formed.
-
18N.3.sl.TZ0.b:
An unknown antacid sample has a lead ion concentration of 0.50 μg dm‒3.
Calculate the concentration of lead ions in the sample in mol dm‒3.
-
18N.3.sl.TZ0.c:
Electrolysis is used to obtain lead from Pb2+ (aq) solution.
Determine the time, in hours, required to produce 0.0500 mol lead using a current (I) of 1.34 A. Use section 2 of the data booklet and the equation, charge (Q) = current (I) × time (t, in seconds).
- 18N.3.sl.TZ0.4a: Outline two observations that he could have made.
- 18N.3.sl.TZ0.4b: The structure of biphenyl nitrile is shown. Describe, giving a reason, a feature of the...
-
18N.3.sl.TZ0.4c:
Arc discharge, consisting of two inert metal electrodes in a liquid solvent, is one method of producing carbon nanotubes (CNTs).
Predict, giving a reason, the electrode at which the solvent cyclohexane, C6H12, will decompose to form CNTs.
- 18N.3.sl.TZ0.a: Outline two observations that he could have made.
- 18N.3.sl.TZ0.b: The structure of biphenyl nitrile is shown. Describe, giving a reason, a feature of the...
-
18N.3.sl.TZ0.c:
Arc discharge, consisting of two inert metal electrodes in a liquid solvent, is one method of producing carbon nanotubes (CNTs).
Predict, giving a reason, the electrode at which the solvent cyclohexane, C6H12, will decompose to form CNTs.
-
18N.3.hl.TZ0.2a:
Outline why this type of classification is not entirely satisfactory by using magnesium diboride, MgB2, as an example. Refer to sections 8 and 29 of the data booklet.
-
18N.3.hl.TZ0.2b:
Structures of poly(methyl acrylate), PMA, and Bakelite® are shown.
Suggest, giving reasons, which is the thermoplastic polymer and which is the thermosetting polymer.
- 18N.3.hl.TZ0.2c: A zeolite is an alternative catalyst for this reaction. Explain how zeolites act as selective...
- 18N.3.hl.TZ0.2d.i: State the names of the two terminal functional groups in X.
- 18N.3.hl.TZ0.2d.ii: Deduce the repeating unit of the polymer of X.
-
18N.3.hl.TZ0.2d.iii:
Repeating units of several polymers are listed.
The infrared (IR) spectrum of one of these polymers is shown.
Deduce, giving a reason, the name of this polymer and its Resin Identification Code (RIC), using sections 26 and 30 in the data booklet.
-
18N.3.hl.TZ0.a:
Outline why this type of classification is not entirely satisfactory by using magnesium diboride, MgB2, as an example. Refer to sections 8 and 29 of the data booklet.
-
18N.3.hl.TZ0.b:
Structures of poly(methyl acrylate), PMA, and Bakelite® are shown.
Suggest, giving reasons, which is the thermoplastic polymer and which is the thermosetting polymer.
- 18N.3.hl.TZ0.c: A zeolite is an alternative catalyst for this reaction. Explain how zeolites act as selective...
- 18N.3.hl.TZ0.d.i: State the names of the two terminal functional groups in X.
- 18N.3.hl.TZ0.d.ii: Deduce the repeating unit of the polymer of X.
-
18N.3.hl.TZ0.d.iii:
Repeating units of several polymers are listed.
The infrared (IR) spectrum of one of these polymers is shown.
Deduce, giving a reason, the name of this polymer and its Resin Identification Code (RIC), using sections 26 and 30 in the data booklet.
- 18N.3.hl.TZ0.3a: State the type of particle present in the plasma formed.
-
18N.3.hl.TZ0.3b.i:
Calculate the concentration of lead ions in the sample in mol dm‒3.
-
18N.3.hl.TZ0.3b.ii:
Lead ions are toxic and can be precipitated using hydroxide ions.
Pb2+ (aq) + 2OH‒ (aq) Pb(OH)2 (s)
Sufficient sodium hydroxide solid is added to the antacid sample to produce a 1.0 × 10‒2 mol dm‒3 hydroxide ion solution at 298 K.
Deduce if a precipitate will be formed, using section 32 of the data booklet.
If you did not calculate the concentration of lead ions in (b)(i), use the value of 2.4 × 10−4 mol dm‒3, but this is not the correct value.
-
18N.3.hl.TZ0.3c:
Electrolysis is used to obtain lead from Pb2+ (aq) solution.
Determine the time, in hours, required to produce 0.0500 mol lead using a current (I) of 1.34 A. Use section 2 of the data booklet and the equation, charge (Q) = current (I) × time (t, in seconds).
- 18N.3.hl.TZ0.3d.i: State one feature of a chelating agent.
-
18N.3.hl.TZ0.3d.ii:
An aqueous lead(II) ion reacts with three ethane-1,2-diamine molecules to form an octahedral chelate ion.
Outline why the chelate ion is more stable than the reactants.
- 18N.3.hl.TZ0.a: State the type of particle present in the plasma formed.
-
18N.3.hl.TZ0.b.i:
Calculate the concentration of lead ions in the sample in mol dm‒3.
-
18N.3.hl.TZ0.b.ii:
Lead ions are toxic and can be precipitated using hydroxide ions.
Pb2+ (aq) + 2OH‒ (aq) Pb(OH)2 (s)
Sufficient sodium hydroxide solid is added to the antacid sample to produce a 1.0 × 10‒2 mol dm‒3 hydroxide ion solution at 298 K.
Deduce if a precipitate will be formed, using section 32 of the data booklet.
If you did not calculate the concentration of lead ions in (b)(i), use the value of 2.4 × 10−4 mol dm‒3, but this is not the correct value.
-
18N.3.hl.TZ0.c:
Electrolysis is used to obtain lead from Pb2+ (aq) solution.
Determine the time, in hours, required to produce 0.0500 mol lead using a current (I) of 1.34 A. Use section 2 of the data booklet and the equation, charge (Q) = current (I) × time (t, in seconds).
- 18N.3.hl.TZ0.d.i: State one feature of a chelating agent.
-
18N.3.hl.TZ0.d.ii:
An aqueous lead(II) ion reacts with three ethane-1,2-diamine molecules to form an octahedral chelate ion.
Outline why the chelate ion is more stable than the reactants.
- 18N.3.hl.TZ0.5a.i: State the name of the crystal structure of gold.
-
18N.3.hl.TZ0.5a.ii:
Calculate the number of atoms per unit cell of gold, showing your working.
-
18N.3.hl.TZ0.5b:
The edge length of the gold unit cell is 4.08 × 10‒8 cm.
Determine the density of gold in g cm‒3, using sections 2 and 6 of the data booklet.
- 18N.3.hl.TZ0.a.i: State the name of the crystal structure of gold.
-
18N.3.hl.TZ0.a.ii:
Calculate the number of atoms per unit cell of gold, showing your working.
-
18N.3.hl.TZ0.b:
The edge length of the gold unit cell is 4.08 × 10‒8 cm.
Determine the density of gold in g cm‒3, using sections 2 and 6 of the data booklet.
B: Biochemistry
- 17N.3.sl.TZ0.8a.ii: The empirical formula of fructose is CH2O. Suggest why linoleic acid releases more energy per...
- 17N.3.sl.TZ0.8b.i: State the type of reaction occurring during the titration.
-
17N.3.sl.TZ0.8b.ii:
Calculate the volume of iodine solution used to reach the end-point.
-
17N.3.sl.TZ0.8c:
Outline the importance of linoleic acid for human health.
-
17N.3.sl.TZ0.9a:
Describe what is meant by a condensation reaction.
- 17N.3.sl.TZ0.9b: Draw the structure of galactose on the skeleton provided.
-
17N.3.sl.TZ0.9c:
Explain how the inclusion of carbohydrates in plastics makes them biodegradable.
-
17N.3.sl.TZ0.10a:
Explain, at the molecular level, why vitamin D is soluble in fats. Use section 35 of the data booklet.
- 17N.3.sl.TZ0.10b: State one function of vitamin D in the body.
- 17N.3.sl.TZ0.11: Enzyme activity depends on many factors. Explain how pH change causes loss of activity of an enzyme.
-
17N.3.hl.TZ0.11a:
Determine the value of the Michaelis constant, Km, by annotating the graph.
-
17N.3.hl.TZ0.11b.i:
The malonate ion acts as an inhibitor for the enzyme.
Suggest, on the molecular level, how the malonate ion is able to inhibit the enzyme.
-
17N.3.hl.TZ0.11b.ii:
Draw a curve on the graph above showing the effect of the presence of the malonate ion inhibitor on the rate of reaction.
-
17N.3.hl.TZ0.13:
The stability of DNA is due to interactions of its hydrophilic and hydrophobic components.
Outline the interactions of the phosphate groups in DNA with water and with surrounding proteins (histones).
-
17N.3.hl.TZ0.14a:
State the half-equation for the reduction of molecular oxygen to water in acidic conditions.
- 17N.3.hl.TZ0.14b: Outline the change in oxidation state of the iron ions in heme groups that occurs when molecular...
-
17N.3.hl.TZ0.15b:
Retinal is the key molecule involved in vision. Explain the roles of cis and trans-retinal in vision and how the isomers are formed in the visual cycle.
-
18M.3.hl.TZ1.6d:
Describe how DNA determines the primary structure of a protein such as insulin.
-
18M.3.hl.TZ1.8b:
Outline why cellulose fibres are strong.
-
18M.3.hl.TZ1.9a:
Explain with reference to the binding site on the enzyme how a non-competitive inhibitor lowers the value of Vmax.
-
18M.3.hl.TZ1.9b:
Outline the significance of the value of the Michaelis constant, Km.
-
18M.3.hl.TZ1.10a:
Outline why anthocyanins are coloured.
-
18M.3.hl.TZ1.10b:
Explain why the blue colour of a quinoidal base changes to the red colour of a flavylium cation as pH decreases.
-
18M.3.hl.TZ2.8c:
Draw the structures of the main form of glycine in buffer solutions of pH 1.0 and 6.0.
The pKa of glycine is 2.34.
-
18M.3.hl.TZ2.8d:
Calculate the pH of a buffer system with a concentration of 1.25 × 10−3 mol dm−3 carbonic acid and 2.50 × 10−2 mol dm−3 sodium hydrogen carbonate. Use section 1 of the data booklet.
pKa (carbonic acid) = 6.36
-
18M.3.hl.TZ2.8e:
Sketch the wedge and dash (3-D) representations of alanine enantiomers.
-
18M.3.hl.TZ2.8f:
UV-Vis spectroscopy can be used to determine the unknown concentration of a substance in a solution.
Calculate the concentration of an unknown sample of pepsin with an absorbance of 0.725 using section 1 of the data booklet.
Cell length = 1.00 cm
Molar absorptivity (extinction coefficient) of the sample = 49650 dm3 cm−1 mol−1
-
18M.3.hl.TZ2.8g:
A different series of pepsin samples is used to develop a calibration curve.
Estimate the concentration of an unknown sample of pepsin with an absorbance of 0.30 from the graph.
-
18M.3.hl.TZ2.10b:
Explain how the structure of vitamin A is important to vision using section 35 of the data booklet.
-
18M.3.hl.TZ2.11a:
Hemoglobin’s oxygen dissociation curve is shown at a given temperature. Sketch the curve on the graph at a higher temperature.
-
18M.3.hl.TZ2.11b:
Outline two differences between normal hemoglobin and foetal hemoglobin.
-
18M.3.hl.TZ2.12:
DNA is a biopolymer made up of nucleotides. List two components of a nucleotide.
-
18M.3.sl.TZ1.6a:
Draw the structural formula of a dipeptide containing the residues of valine, Val, and asparagine, Asn, using section 33 of the data booklet.
-
18M.3.sl.TZ1.6b:
Deduce the strongest intermolecular forces that would occur between the following amino acid residues in a protein chain.
-
18M.3.sl.TZ1.6c.i:
State the name of the process used to break down the insulin protein into its constituent amino acids.
-
18M.3.sl.TZ1.6c.ii:
Outline how the amino acids may be identified from a paper chromatogram.
-
18M.3.sl.TZ1.7a.i:
Identify the type of rancidity occurring in saturated lipids and the structural feature that causes it.
-
18M.3.sl.TZ1.7a.ii:
State one factor that increases the rate at which saturated lipids become rancid.
-
18M.3.sl.TZ1.7b:
Butter contains varying proportions of oleic, myristic, palmitic and stearic acids. Explain in terms of their structures why stearic acid has a higher melting point than oleic acid, using section 34 of the data booklet.
-
18M.3.sl.TZ1.7c.i:
Fish oil is an excellent dietary source of omega-3 fatty acids. Outline one impact on health of consuming omega-3 fatty acids.
-
18M.3.sl.TZ1.7c.ii:
Predict the solubility of retinol (vitamin A) in body fat, giving a reason. Use section 35 of the data booklet.
-
18M.3.sl.TZ1.7c.iii:
Explain why sharks and swordfish sometimes contain high concentrations of mercury and polychlorinated biphenyls (PCBs).
-
18M.3.sl.TZ1.7c.iv:
Plastics are another source of marine pollution. Outline one way in which plastics can be made more biodegradable.
-
18M.3.sl.TZ1.8a:
State the specific type of linkage formed between α-glucose fragments in both maltose and amylose.
-
18M.3.sl.TZ1.8b:
A person with diabetes suffering very low blood sugar (hypoglycaemia) may be advised to consume glucose immediately and then eat a small amount of starchy food such as a sandwich. Explain this advice in terms of the properties of glucose and starch.
-
18M.3.sl.TZ2.6a:
Identify the type of chemical reaction that occurs between fatty acids and glycerol to form lipids and the by-product of the reaction.
-
18M.3.sl.TZ2.6b:
Arachidonic acid is a polyunsaturated omega-6 fatty acid found in peanut oil.
Determine the number of carbon–carbon double bonds present if the iodine number for the compound is 334. (Arachidonic acid Mr = 304.5)
-
18M.3.sl.TZ2.6c:
Deduce the structure of the lipid formed by the reaction between lauric acid and glycerol (propane-1,2,3-triol) using section 34 of the data booklet.
-
18M.3.sl.TZ2.6d:
Outline one impact food labelling has had on the consumption of foods containing different types of lipids.
-
18M.3.sl.TZ2.6e:
Determine, to the correct number of significant figures, the energy produced by the respiration of 29.9 g of C5H10O5.
ΔHc (C5H10O5) = 205.9 kJ mol−1
-
18M.3.sl.TZ2.6f:
Explain why lipids provide more energy than carbohydrates and proteins.
-
18M.3.sl.TZ2.7a:
Draw the dipeptide represented by the formula Ala-Gly using section 33 of the data booklet.
-
18M.3.sl.TZ2.7c:
Outline why amino acids have high melting points.
-
18M.3.sl.TZ2.8:
Green Chemistry reduces the production of hazardous materials and chemical waste.
Outline two specific examples or technological processes of how Green Chemistry has accomplished this environmental impact.
-
18M.3.sl.TZ2.9:
Explain the solubility of vitamins A and C using section 35 of the data booklet.
- 18N.3.sl.TZ0.5a: The formation of proteins from amino acids is an example of an anabolic reaction in the human...
-
18N.3.sl.TZ0.5b:
Suggest why it is advisable for those living in northerly or southerly latitudes (that is away from the equator) to take vitamin D supplements during the winter.
- 18N.3.sl.TZ0.5c: Explain how a xenobiotic is biomagnified.
- 18N.3.sl.TZ0.6a: Describe the interaction responsible for the secondary structure of a protein.
- 18N.3.sl.TZ0.6b.i: Explain the action of an enzyme and state one of its limitations.
- 18N.3.sl.TZ0.6b.ii: Enzymes are widely used in washing detergents. Outline how they improve the efficiency of the...
- 18N.3.sl.TZ0.7a: A phospholipid generally consists of two hydrophobic fatty acids and a hydrophilic...
-
18N.3.sl.TZ0.7b.i:
The iodine number is the maximum mass of iodine that reacts with 100 g of an unsaturated compound.
Determine the iodine number of stearidonic acid, C17H27COOH.
- 18N.3.sl.TZ0.7b.ii: State two functions of lipids in the body.
- 18N.3.sl.TZ0.7c: Outline one effect of increased levels of low-density lipoproteins in the blood.
- 18N.3.sl.TZ0.8a: Name the type of link between the two monosaccharide residues.
- 18N.3.sl.TZ0.8b: Outline how the two monomer structures, galactose and glucose, differ.
- 18N.3.hl.TZ0.7a: State the feature of DNA that determines the primary structure of proteins synthesised by a cell.
- 18N.3.hl.TZ0.7b: Suggest one concern about the use of genetically modified, GM, food.
- 18N.3.hl.TZ0.8a: Describe the interaction responsible for the secondary structure of a protein.
- 18N.3.hl.TZ0.8b: Explain the action of an enzyme and state one of its limitations.
-
18N.3.hl.TZ0.8c:
Contrast the actions of non-competitive and competitive inhibitors of an enzyme and state their effects on the maximum rate of reaction, Vmax, and the Michaelis–Menten constant, Km.
-
18N.3.hl.TZ0.9a:
The iodine number is the maximum mass of iodine that reacts with 100 g of an unsaturated compound.
Determine the iodine number of stearidonic acid, C17H27COOH.
- 18N.3.hl.TZ0.9b: State two functions of lipids in the body.
- 18N.3.hl.TZ0.9c: Outline one effect of increased levels of low-density lipoproteins in the blood.
- 18N.3.hl.TZ0.10a: Name the type of link between the two monosaccharide residues.
- 18N.3.hl.TZ0.10b: Outline how the two monomer structures, galactose and glucose, differ.
- 18N.3.hl.TZ0.10c.i: Outline the difference between their structures.
- 18N.3.hl.TZ0.10c.ii: Outline why cellulose is an essential part of human diet.
- 18N.3.hl.TZ0.11a: A graph showing saturation of oxygen against partial pressure of oxygen is shown. Explain the...
-
18N.3.hl.TZ0.11b:
Explain why carbon monoxide is very toxic and how it may be possible to treat carbon monoxide poisoning.
-
19M.3.hl.TZ1.8a:
Draw the structure of the repeating unit of starch and state the type of linkage formed between these units.
Type of linkage:
-
19M.3.hl.TZ1.8b:
Formulate the equation for the complete hydrolysis of a starch molecule, (C6H10O5)n.
-
19M.3.hl.TZ1.8c:
Calculate the energy released, in kJ g−1, when 3.49 g of starch are completely combusted in a calorimeter, increasing the temperature of 975 g of water from 21.0 °C to 36.0 °C. Use section 1 of the data booklet.
-
19M.3.hl.TZ1.8d:
Explain how the inclusion of starch in plastics makes them biodegradable.
-
19M.3.hl.TZ1.9a:
Draw a circle around the functional group formed between the amino acids and state its name.
Name:
-
19M.3.hl.TZ1.9b:
A mixture of phenylalanine and aspartic acid is separated by gel electrophoresis with a buffer of pH = 5.5.
Deduce their relative positions after electrophoresis, annotating them on the diagram. Use section 33 of the data booklet.
-
19M.3.hl.TZ1.9c:
Aspartic acid is obtained synthetically as a racemic mixture. Draw the three‑dimensional shape of each isomer showing their spatial relationship to each other. Use section 33 of the data booklet.
-
19M.3.hl.TZ1.10a:
The melting points of cocoa butter and coconut oil are 34 °C and 25 °C respectively.
Explain this in terms of their saturated fatty acid composition.
-
19M.3.hl.TZ1.10b:
Fats contain triglycerides that are esters of glycerol and fatty acids. Deduce an equation for the acid hydrolysis of the following triglyceride.
-
19M.3.hl.TZ1.10c:
The addition of partially hydrogenated cocoa butter to chocolate increases its melting point and the content of trans-fatty acids (trans-fats).
Outline one effect of trans-fatty acids on health.
-
19M.3.hl.TZ1.11a:
The absorption spectrum of β-carotene is shown below.
Explain its colour in terms of its absorption bands. Use section 17 of the data booklet.
-
19M.3.hl.TZ1.11b:
The absorption spectrum of chlorophyll a is shown below.
Suggest how the combination of chlorophyll a and carotenoids is beneficial for photosynthesis.
-
19M.3.hl.TZ1.12a(i):
A Michaelis–Menten plot for an enzyme-catalysed reaction is shown.
Sketch a curve to show the effect of a competitive inhibitor.
-
19M.3.hl.TZ1.12a(ii):
Suggest, based on the Michaelis–Menten plot, how a competitive inhibitor such as ethanol reduces the toxicity of methanol.
-
19M.3.hl.TZ1.12b:
Enzymatic activity is studied in buffered aqueous solutions.
Calculate the ratio in which 0.1 mol dm−3 NaH2PO4 (aq) and 0.1 mol dm−3 Na2HPO4 (aq) should be mixed to obtain a buffer with pH = 6.10. Use section 1 of the data booklet.
pKa (NaH2PO4) = 7.20
-
19M.3.hl.TZ1.13:
Ascorbic acid and retinol are two important vitamins.
Explain why ascorbic acid is soluble in water and retinol is not. Use section 35 of the data booklet.
-
19M.3.hl.TZ1.14a:
Outline what is meant by genetically modified organisms.
-
19M.3.hl.TZ1.14b:
Outline one benefit of the use of these products.
-
19M.3.hl.TZ1.19b(i):
Deduce the protons responsible for signals X and Y by marking them on the structure of aspirin in (a). Use section 27 of the data booklet.
-
19M.3.hl.TZ1.19b(ii):
Identify the splitting pattern of signals X and Y.
X:
Y:
-
19M.3.hl.TZ2.9a(i):
Some proteins form an α-helix. State the name of another secondary protein structure.
-
19M.3.hl.TZ2.9a(ii):
Compare and contrast the bonding responsible for the two secondary structures.
One similarity:
One difference:
-
19M.3.hl.TZ2.9b:
Explain why an increase in temperature reduces the rate of an enzyme-catalyzed reaction.
-
19M.3.hl.TZ2.9c:
State and explain how a competitive inhibitor affects the maximum rate, Vmax, of an enzyme-catalyzed reaction.
-
19M.3.hl.TZ2.9d(i):
Suggest two reasons why oil decomposes faster at the surface of the ocean than at greater depth.
-
19M.3.hl.TZ2.9d(ii):
Oil spills can be treated with an enzyme mixture to speed up decomposition.
Outline one factor to be considered when assessing the greenness of an enzyme mixture.
-
19M.3.hl.TZ2.10a(i):
Outline which pKa value should be used when calculating the pH of the solution, giving your reason.
-
19M.3.hl.TZ2.10a(ii):
Calculate the pH of the glutamine solution using section 1 of the data booklet.
-
19M.3.hl.TZ2.10b:
Describe what is meant by the genetic code and how it relates to protein synthesis.
-
19M.3.hl.TZ2.11a(i):
Deduce the structural formula of phosphatidylcholine.
-
19M.3.hl.TZ2.11a(ii):
Identify the type of reaction in (a).
-
19M.3.hl.TZ2.11b:
Lecithin is a major component of cell membranes. Describe the structure of a cell membrane.
-
19M.3.hl.TZ2.11c:
Lecithin aids the body’s absorption of vitamin E.
Suggest why vitamin E is fat-soluble.
-
19M.3.hl.TZ2.11d:
Phospholipids are also found in lipoprotein structures.
Describe one effect of increased levels of low-density lipoprotein (LDL) on health.
-
19M.3.hl.TZ2.12a:
State the name of the functional group forming part of the ring structure of each monosaccharide unit.
-
19M.3.hl.TZ2.12b:
Classify, giving your reason, the hexose (six-membered) ring of sucrose as an α or β isomer.
-
19M.3.hl.TZ2.12c:
Sketch the cyclic structures of the two monosaccharides which combine to form sucrose.
-
19M.3.hl.TZ2.13a:
Outline why the complex formed between Fe2+ and oxygen is red. Refer to the diagram above and section 17 of the data booklet.
-
19M.3.hl.TZ2.13b(i):
Explain the shape of the curve.
- 19M.3.hl.TZ2.13b(ii): Sketch another line to show the effect of an increase in body temperature on the oxygen...
-
19M.3.sl.TZ1.7a:
Draw the structure of the repeating unit of starch and state the type of linkage formed between these units.
Type of linkage:
-
19M.3.sl.TZ1.7b:
Formulate the equation for the complete hydrolysis of a starch molecule, (C6H10O5)n.
-
19M.3.sl.TZ1.7c:
Calculate the energy released, in kJ g−1, when 3.49 g of starch are completely combusted in a calorimeter, increasing the temperature of 975 g of water from 21.0 °C to 36.0 °C. Use section 1 of the data booklet.
-
19M.3.sl.TZ1.7d:
Explain how the inclusion of starch in plastics makes them biodegradable.
-
19M.3.sl.TZ1.8a:
Draw a circle around the functional group formed between the amino acids and state its name.
Name:
-
19M.3.sl.TZ1.8b:
A mixture of phenylalanine and aspartic acid is separated by gel electrophoresis with a buffer of pH = 5.5.
Deduce their relative positions after electrophoresis, annotating them on the diagram. Use section 33 of the data booklet.
-
19M.3.sl.TZ1.9a:
The melting points of cocoa butter and coconut oil are 34 °C and 25 °C respectively.
Explain this in terms of their saturated fatty acid composition.
-
19M.3.sl.TZ1.9b:
Fats contain triglycerides that are esters of glycerol and fatty acids. Deduce an equation for the acid hydrolysis of the following triglyceride.
-
19M.3.sl.TZ1.9c:
The addition of partially hydrogenated cocoa butter to chocolate increases its melting point and the content of trans-fatty acids (trans-fats).
Outline two effects of trans-fatty acids on health.
-
19M.3.sl.TZ1.10:
Ascorbic acid and retinol are two important vitamins.
Explain why ascorbic acid is soluble in water and retinol is not. Use section 35 of the data booklet.
-
19M.3.sl.TZ2.6a(i) :
Some proteins form an α-helix. State the name of another secondary protein structure.
-
19M.3.sl.TZ2.6a(ii):
Compare and contrast the bonding responsible for the two secondary structures.
One similarity:
One difference:
-
19M.3.sl.TZ2.6b:
Explain why an increase in temperature reduces the rate of an enzyme-catalyzed reaction.
-
19M.3.sl.TZ2.6c(i):
Suggest two reasons why oil decomposes faster at the surface of the ocean than at greater depth.
-
19M.3.sl.TZ2.6c(ii):
Oil spills can be treated with an enzyme mixture to speed up decomposition.
Outline one factor to be considered when assessing the greenness of an enzyme mixture.
-
19M.3.sl.TZ2.7a(i):
Deduce the structural formula of phosphatidylcholine.
-
19M.3.sl.TZ2.7a(ii):
Identify the type of reaction in (a).
-
19M.3.sl.TZ2.7b:
Lecithin is a major component of cell membranes. Describe the structure of a cell membrane.
-
19M.3.sl.TZ2.7c:
Predict, giving a reason, the relative energy density of a carbohydrate and a lipid of similar molar mass.
-
19M.3.sl.TZ2.7d:
Lecithin aids the body’s absorption of vitamin E.
Suggest why vitamin E is fat-soluble.
-
19M.3.sl.TZ2.7e:
Phospholipids are also found in lipoprotein structures.
Describe two effects of increased levels of low-density lipoprotein (LDL) on health.
-
19M.3.sl.TZ2.8a:
State the name of the functional group forming part of the ring structure of each monosaccharide unit.
-
19M.3.sl.TZ2.8b:
Sketch the cyclic structures of the two monosaccharides which combine to form sucrose.
-
19N.3.sl.TZ0.7a:
Draw the structure of the dipeptide Asp–Phe using section 33 of the data booklet.
-
19N.3.sl.TZ0.7b:
The isoelectric point of amino acids is the intermediate pH at which an amino acid is electrically neutral.
Suggest why Asp and Phe have different isoelectric points.
-
19N.3.hl.TZ0.10a:
Draw the structure of the dipeptide Asp–Phe using section 33 of the data booklet.
- 19N.3.hl.TZ0.10b(i): Describe, using another method, how a mixture of four amino acids, alanine, arginine, glutamic...
- 19N.3.hl.TZ0.10b(ii): Suggest why alanine and glycine separate slightly at pH 6.5.
-
19N.3.hl.TZ0.10b(iii):
Calculate the ratio of [A−] : [HA] in a buffer of pH 6.0 given that pKa for the acid is 4.83, using section 1 of the data booklet.
- 19N.3.hl.TZ0.11a: Outline the significance of the Michaelis constant Km.
-
19N.3.hl.TZ0.11b:
Compare the effects of competitive and non-competitive inhibitors.
-
19N.3.sl.TZ0.9a:
The iodine number is the number of grams of iodine which reacts with 100 g of fat. Calculate the iodine number of oleic acid.
- 19N.3.sl.TZ0.9b: State one impact on health of the increase in LDL cholesterol concentration in blood.
- 19N.3.sl.TZ0.9c: Explain why stearic acid has a higher melting point than oleic acid.
- 19N.3.sl.TZ0.9d(i): State one similarity and one difference in composition between phospholipids and...
-
19N.3.sl.TZ0.9d(ii):
Identify a reagent that hydrolyses triglycerides.
-
19N.3.hl.TZ0.12a:
The iodine number is the number of grams of iodine which reacts with 100 g of fat. Calculate the iodine number of oleic acid.
-
19N.3.hl.TZ0.12b:
The chemical change in stored fats causes rancidity characterized by an unpleasant smell or taste.
Compare hydrolytic and oxidative rancidity.
- 19N.3.hl.TZ0.12c: State one similarity and one difference in composition between phospholipids and...
-
19N.3.hl.TZ0.13a:
List two components of nucleotides.
- 19N.3.hl.TZ0.13b: Explain how the double-helical structure of DNA is stabilized once formed.
- 19N.3.hl.TZ0.14a: The graph shows the change in oxygen partial pressure in blood, measured at different pH...
- 19N.3.hl.TZ0.14b: Explain the biomagnification of the pesticide DDT.
- 19N.3.hl.TZ0.14c: Vitamins are organic compounds essential in small amounts. State the name of one functional...
- 19N.3.sl.TZ0.10a: State the name of one functional group common to all three vitamins shown in section 35 of the...
- 19N.3.sl.TZ0.10b: Explain the biomagnification of the pesticide DDT.
- 19N.3.sl.TZ0.10c: Explain why maltose, C12H22O11, is soluble in water.
- 19N.3.hl.TZ0.15a: Describe the function of chlorophyll in photosynthesis.
- 19N.3.hl.TZ0.15b: Compare and contrast the structures of starch and cellulose. One similarity: One difference:
- 19N.3.hl.TZ0.15c: Explain why maltose, C12H22O11, is soluble in water.
- 19N.3.sl.TZ0.8a: The graph shows the relationship between the temperature and the rate of an enzyme-catalysed...
-
19N.3.sl.TZ0.8b:
Explain why a change in pH affects the tertiary structure of an enzyme in solution.
- 19N.3.sl.TZ0.8c: State one use of enzymes in reducing environmental problems.
-
20N.3.sl.TZ0.5a(i):
Proteins are polymers of amino acids. A paper chromatogram of two amino acids, A1 and A2, is obtained using a non-polar solvent.
© International Baccalaureate Organization 2020.
Determine the value of A1.
-
20N.3.sl.TZ0.5a(ii):
Proteins are polymers of amino acids.
The mixture is composed of glycine, , and isoleucine, . Their structures can be found in section 33 of the data booklet.
Deduce, referring to relative affinities and , the identity of A1.
-
20N.3.sl.TZ0.5b:
Proteins are polymers of amino acids.
Glycine is one of the amino acids in the primary structure of hemoglobin.
State the type of bonding responsible for the α-helix in the secondary structure.
-
20N.3.sl.TZ0.5c:
Proteins are polymers of amino acids.
Describe how the tertiary structure differs from the quaternary structure in hemoglobin.
-
20N.3.sl.TZ0.6a:
Deduce the products of the hydrolysis of a non-substituted phospholipid, where and represent long alkyl chains.
-
20N.3.sl.TZ0.6b(i):
A representation of a phospholipid bilayer cell membrane is shown:
© International Baccalaureate Organization 2020.
Identify the components of the phospholipid labelled A and B.
-
20N.3.sl.TZ0.6c:
Phospholipids help maintain cellular environments while fatty acid lipids have important roles in energy storage and electrical insulation. Discuss the structural properties of saturated fats needed for these roles.
- 20N.3.sl.TZ0.7a: The diverse functions of biological molecules depend on their structure and shape. Classify...
-
20N.3.sl.TZ0.7b(i):
The diverse functions of biological molecules depend on their structure and shape.
Deduce the straight chain structure of deoxyribose from its ring structure drawn in section 34 of the data booklet.
-
20N.3.sl.TZ0.7b(ii):
The diverse functions of biological molecules depend on their structure and shape.
Sucrose is a disaccharide formed in the reaction of glucose with fructose.
Identify the reaction type and the newly formed functional group that joins the monosaccharide units in the product.
-
20N.3.sl.TZ0.8a:
Calculate the BMF if a shark consumes mackerel in one year. Each mackerel weighs on average. The per body weight. Assume chemical remains in the shark’s body for two years.
- 20N.3.sl.TZ0.8b: Suggest, with a reason, if fat-soluble or water-soluble xenobiotics would have a larger BMF.
-
20N.3.hl.TZ0.6a(i):
Proteins are polymers of amino acids.
A paper chromatogram of two amino acids, A1 and A2, is obtained using a non-polar solvent.
© International Baccalaureate Organization 2020.
Determine the value of A1.
-
20N.3.hl.TZ0.6a(ii):
Proteins are polymers of amino acids.
The mixture is composed of glycine, , and isoleucine, . Their structures can be found in section 33 of the data booklet.
Deduce, referring to relative affinities and , the identity of A1.
-
20N.3.hl.TZ0.6b:
Proteins are polymers of amino acids.
Glycine is one of the amino acids in the primary structure of hemoglobin.
State the type of bonding responsible for the α-helix in the secondary structure.
- 20N.3.hl.TZ0.6c(i): Proteins are polymers of amino acids. Sketch and label two oxygen dissociation curves, one for...
-
20N.3.hl.TZ0.6c(ii):
Proteins are polymers of amino acids.
Explain why the affinity for oxygen of foetal hemoglobin differs from that of adult hemoglobin.
- 20N.3.hl.TZ0.8a: The diverse functions of biological molecules depend on their structure and shape. Classify...
-
20N.3.hl.TZ0.8b(i):
The diverse functions of biological molecules depend on their structure and shape.
Deduce the straight chain structure of deoxyribose from its ring structure drawn in section 34 of the data booklet.
-
20N.3.hl.TZ0.8b(ii):
The diverse functions of biological molecules depend on their structure and shape.
Draw the nitrogenous base that is paired with guanine in DNA, showing the hydrogen bonds between the bases. Use section 34 of the data booklet.
- 20N.3.hl.TZ0.8c: The diverse functions of biological molecules depend on their structure and shape. Retinal is...
- 20N.3.hl.TZ0.10a: Identify the type of inhibition shown in the graph.
-
20N.3.hl.TZ0.10b(i):
Determine the value of and in the absence and presence of the inhibitor.
-
20N.3.hl.TZ0.10b(ii):
Outline the significance of the value of the Michaelis constant, .
-
19M.3.hl.TZ1.8a:
Draw the structure of the repeating unit of starch and state the type of linkage formed between these units.
Type of linkage:
-
19M.3.hl.TZ1.8b:
Formulate the equation for the complete hydrolysis of a starch molecule, (C6H10O5)n.
-
19M.3.hl.TZ1.8c:
Calculate the energy released, in kJ g−1, when 3.49 g of starch are completely combusted in a calorimeter, increasing the temperature of 975 g of water from 21.0 °C to 36.0 °C. Use section 1 of the data booklet.
-
19M.3.hl.TZ1.8d:
Explain how the inclusion of starch in plastics makes them biodegradable.
-
19M.3.hl.TZ1.a:
Draw the structure of the repeating unit of starch and state the type of linkage formed between these units.
Type of linkage:
-
19M.3.hl.TZ1.b:
Formulate the equation for the complete hydrolysis of a starch molecule, (C6H10O5)n.
-
19M.3.hl.TZ1.c:
Calculate the energy released, in kJ g−1, when 3.49 g of starch are completely combusted in a calorimeter, increasing the temperature of 975 g of water from 21.0 °C to 36.0 °C. Use section 1 of the data booklet.
-
19M.3.hl.TZ1.d:
Explain how the inclusion of starch in plastics makes them biodegradable.
-
19M.3.hl.TZ1.9a:
Draw a circle around the functional group formed between the amino acids and state its name.
Name:
-
19M.3.hl.TZ1.9b:
A mixture of phenylalanine and aspartic acid is separated by gel electrophoresis with a buffer of pH = 5.5.
Deduce their relative positions after electrophoresis, annotating them on the diagram. Use section 33 of the data booklet.
-
19M.3.hl.TZ1.9c:
Aspartic acid is obtained synthetically as a racemic mixture. Draw the three‑dimensional shape of each isomer showing their spatial relationship to each other. Use section 33 of the data booklet.
-
19M.3.hl.TZ1.a:
Draw a circle around the functional group formed between the amino acids and state its name.
Name:
-
19M.3.hl.TZ1.b:
A mixture of phenylalanine and aspartic acid is separated by gel electrophoresis with a buffer of pH = 5.5.
Deduce their relative positions after electrophoresis, annotating them on the diagram. Use section 33 of the data booklet.
-
19M.3.hl.TZ1.c:
Aspartic acid is obtained synthetically as a racemic mixture. Draw the three‑dimensional shape of each isomer showing their spatial relationship to each other. Use section 33 of the data booklet.
-
19M.3.hl.TZ1.10a:
The melting points of cocoa butter and coconut oil are 34 °C and 25 °C respectively.
Explain this in terms of their saturated fatty acid composition.
-
19M.3.hl.TZ1.10b:
Fats contain triglycerides that are esters of glycerol and fatty acids. Deduce an equation for the acid hydrolysis of the following triglyceride.
-
19M.3.hl.TZ1.10c:
The addition of partially hydrogenated cocoa butter to chocolate increases its melting point and the content of trans-fatty acids (trans-fats).
Outline one effect of trans-fatty acids on health.
-
19M.3.hl.TZ1.a:
The melting points of cocoa butter and coconut oil are 34 °C and 25 °C respectively.
Explain this in terms of their saturated fatty acid composition.
-
19M.3.hl.TZ1.b:
Fats contain triglycerides that are esters of glycerol and fatty acids. Deduce an equation for the acid hydrolysis of the following triglyceride.
-
19M.3.hl.TZ1.c:
The addition of partially hydrogenated cocoa butter to chocolate increases its melting point and the content of trans-fatty acids (trans-fats).
Outline one effect of trans-fatty acids on health.
-
19M.3.hl.TZ1.11a:
The absorption spectrum of β-carotene is shown below.
Explain its colour in terms of its absorption bands. Use section 17 of the data booklet.
-
19M.3.hl.TZ1.11b:
The absorption spectrum of chlorophyll a is shown below.
Suggest how the combination of chlorophyll a and carotenoids is beneficial for photosynthesis.
-
19M.3.hl.TZ1.a:
The absorption spectrum of β-carotene is shown below.
Explain its colour in terms of its absorption bands. Use section 17 of the data booklet.
-
19M.3.hl.TZ1.b:
The absorption spectrum of chlorophyll a is shown below.
Suggest how the combination of chlorophyll a and carotenoids is beneficial for photosynthesis.
-
19M.3.hl.TZ1.12a(i):
A Michaelis–Menten plot for an enzyme-catalysed reaction is shown.
Sketch a curve to show the effect of a competitive inhibitor.
-
19M.3.hl.TZ1.12a(ii):
Suggest, based on the Michaelis–Menten plot, how a competitive inhibitor such as ethanol reduces the toxicity of methanol.
-
19M.3.hl.TZ1.12b:
Enzymatic activity is studied in buffered aqueous solutions.
Calculate the ratio in which 0.1 mol dm−3 NaH2PO4 (aq) and 0.1 mol dm−3 Na2HPO4 (aq) should be mixed to obtain a buffer with pH = 6.10. Use section 1 of the data booklet.
pKa (NaH2PO4) = 7.20
-
19M.3.hl.TZ1.a(i):
A Michaelis–Menten plot for an enzyme-catalysed reaction is shown.
Sketch a curve to show the effect of a competitive inhibitor.
-
19M.3.hl.TZ1.a(ii):
Suggest, based on the Michaelis–Menten plot, how a competitive inhibitor such as ethanol reduces the toxicity of methanol.
-
19M.3.hl.TZ1.b:
Enzymatic activity is studied in buffered aqueous solutions.
Calculate the ratio in which 0.1 mol dm−3 NaH2PO4 (aq) and 0.1 mol dm−3 Na2HPO4 (aq) should be mixed to obtain a buffer with pH = 6.10. Use section 1 of the data booklet.
pKa (NaH2PO4) = 7.20
-
19M.3.hl.TZ1.13:
Ascorbic acid and retinol are two important vitamins.
Explain why ascorbic acid is soluble in water and retinol is not. Use section 35 of the data booklet.
-
19M.3.hl.TZ1.14a:
Outline what is meant by genetically modified organisms.
-
19M.3.hl.TZ1.14b:
Outline one benefit of the use of these products.
-
19M.3.hl.TZ1.a:
Outline what is meant by genetically modified organisms.
-
19M.3.hl.TZ1.b:
Outline one benefit of the use of these products.
-
19M.3.hl.TZ1.19b(i):
Deduce the protons responsible for signals X and Y by marking them on the structure of aspirin in (a). Use section 27 of the data booklet.
-
19M.3.hl.TZ1.19b(ii):
Identify the splitting pattern of signals X and Y.
X:
Y:
-
19M.3.hl.TZ1.b(i):
Deduce the protons responsible for signals X and Y by marking them on the structure of aspirin in (a). Use section 27 of the data booklet.
-
19M.3.hl.TZ1.b(ii):
Identify the splitting pattern of signals X and Y.
X:
Y:
-
19M.3.hl.TZ2.9a(i):
Some proteins form an α-helix. State the name of another secondary protein structure.
-
19M.3.hl.TZ2.9a(ii):
Compare and contrast the bonding responsible for the two secondary structures.
One similarity:
One difference:
-
19M.3.hl.TZ2.9b:
Explain why an increase in temperature reduces the rate of an enzyme-catalyzed reaction.
-
19M.3.hl.TZ2.9c:
State and explain how a competitive inhibitor affects the maximum rate, Vmax, of an enzyme-catalyzed reaction.
-
19M.3.hl.TZ2.9d(i):
Suggest two reasons why oil decomposes faster at the surface of the ocean than at greater depth.
-
19M.3.hl.TZ2.9d(ii):
Oil spills can be treated with an enzyme mixture to speed up decomposition.
Outline one factor to be considered when assessing the greenness of an enzyme mixture.
-
19M.3.hl.TZ2.a(i):
Some proteins form an α-helix. State the name of another secondary protein structure.
-
19M.3.hl.TZ2.a(ii):
Compare and contrast the bonding responsible for the two secondary structures.
One similarity:
One difference:
-
19M.3.hl.TZ2.b:
Explain why an increase in temperature reduces the rate of an enzyme-catalyzed reaction.
-
19M.3.hl.TZ2.c:
State and explain how a competitive inhibitor affects the maximum rate, Vmax, of an enzyme-catalyzed reaction.
-
19M.3.hl.TZ2.d(i):
Suggest two reasons why oil decomposes faster at the surface of the ocean than at greater depth.
-
19M.3.hl.TZ2.d(ii):
Oil spills can be treated with an enzyme mixture to speed up decomposition.
Outline one factor to be considered when assessing the greenness of an enzyme mixture.
-
19M.3.hl.TZ2.10a(i):
Outline which pKa value should be used when calculating the pH of the solution, giving your reason.
-
19M.3.hl.TZ2.10a(ii):
Calculate the pH of the glutamine solution using section 1 of the data booklet.
-
19M.3.hl.TZ2.10b:
Describe what is meant by the genetic code and how it relates to protein synthesis.
-
19M.3.hl.TZ2.a(i):
Outline which pKa value should be used when calculating the pH of the solution, giving your reason.
-
19M.3.hl.TZ2.a(ii):
Calculate the pH of the glutamine solution using section 1 of the data booklet.
-
19M.3.hl.TZ2.b:
Describe what is meant by the genetic code and how it relates to protein synthesis.
-
19M.3.hl.TZ2.11a(i):
Deduce the structural formula of phosphatidylcholine.
-
19M.3.hl.TZ2.11a(ii):
Identify the type of reaction in (a).
-
19M.3.hl.TZ2.11b:
Lecithin is a major component of cell membranes. Describe the structure of a cell membrane.
-
19M.3.hl.TZ2.11c:
Lecithin aids the body’s absorption of vitamin E.
Suggest why vitamin E is fat-soluble.
-
19M.3.hl.TZ2.11d:
Phospholipids are also found in lipoprotein structures.
Describe one effect of increased levels of low-density lipoprotein (LDL) on health.
-
19M.3.hl.TZ2.a(i):
Deduce the structural formula of phosphatidylcholine.
-
19M.3.hl.TZ2.a(ii):
Identify the type of reaction in (a).
-
19M.3.hl.TZ2.b:
Lecithin is a major component of cell membranes. Describe the structure of a cell membrane.
-
19M.3.hl.TZ2.c:
Lecithin aids the body’s absorption of vitamin E.
Suggest why vitamin E is fat-soluble.
-
19M.3.hl.TZ2.d:
Phospholipids are also found in lipoprotein structures.
Describe one effect of increased levels of low-density lipoprotein (LDL) on health.
-
19M.3.hl.TZ2.12a:
State the name of the functional group forming part of the ring structure of each monosaccharide unit.
-
19M.3.hl.TZ2.12b:
Classify, giving your reason, the hexose (six-membered) ring of sucrose as an α or β isomer.
-
19M.3.hl.TZ2.12c:
Sketch the cyclic structures of the two monosaccharides which combine to form sucrose.
-
19M.3.hl.TZ2.a:
State the name of the functional group forming part of the ring structure of each monosaccharide unit.
-
19M.3.hl.TZ2.b:
Classify, giving your reason, the hexose (six-membered) ring of sucrose as an α or β isomer.
-
19M.3.hl.TZ2.c:
Sketch the cyclic structures of the two monosaccharides which combine to form sucrose.
-
19M.3.hl.TZ2.13a:
Outline why the complex formed between Fe2+ and oxygen is red. Refer to the diagram above and section 17 of the data booklet.
-
19M.3.hl.TZ2.13b(i):
Explain the shape of the curve.
- 19M.3.hl.TZ2.13b(ii): Sketch another line to show the effect of an increase in body temperature on the oxygen...
-
19M.3.hl.TZ2.a:
Outline why the complex formed between Fe2+ and oxygen is red. Refer to the diagram above and section 17 of the data booklet.
-
19M.3.hl.TZ2.b(i):
Explain the shape of the curve.
- 19M.3.hl.TZ2.b(ii): Sketch another line to show the effect of an increase in body temperature on the oxygen...
-
19M.3.sl.TZ1.7a:
Draw the structure of the repeating unit of starch and state the type of linkage formed between these units.
Type of linkage:
-
19M.3.sl.TZ1.7b:
Formulate the equation for the complete hydrolysis of a starch molecule, (C6H10O5)n.
-
19M.3.sl.TZ1.7c:
Calculate the energy released, in kJ g−1, when 3.49 g of starch are completely combusted in a calorimeter, increasing the temperature of 975 g of water from 21.0 °C to 36.0 °C. Use section 1 of the data booklet.
-
19M.3.sl.TZ1.7d:
Explain how the inclusion of starch in plastics makes them biodegradable.
-
19M.3.sl.TZ1.a:
Draw the structure of the repeating unit of starch and state the type of linkage formed between these units.
Type of linkage:
-
19M.3.sl.TZ1.b:
Formulate the equation for the complete hydrolysis of a starch molecule, (C6H10O5)n.
-
19M.3.sl.TZ1.c:
Calculate the energy released, in kJ g−1, when 3.49 g of starch are completely combusted in a calorimeter, increasing the temperature of 975 g of water from 21.0 °C to 36.0 °C. Use section 1 of the data booklet.
-
19M.3.sl.TZ1.d:
Explain how the inclusion of starch in plastics makes them biodegradable.
-
19M.3.sl.TZ1.8a:
Draw a circle around the functional group formed between the amino acids and state its name.
Name:
-
19M.3.sl.TZ1.8b:
A mixture of phenylalanine and aspartic acid is separated by gel electrophoresis with a buffer of pH = 5.5.
Deduce their relative positions after electrophoresis, annotating them on the diagram. Use section 33 of the data booklet.
-
19M.3.sl.TZ1.a:
Draw a circle around the functional group formed between the amino acids and state its name.
Name:
-
19M.3.sl.TZ1.b:
A mixture of phenylalanine and aspartic acid is separated by gel electrophoresis with a buffer of pH = 5.5.
Deduce their relative positions after electrophoresis, annotating them on the diagram. Use section 33 of the data booklet.
-
19M.3.sl.TZ1.9a:
The melting points of cocoa butter and coconut oil are 34 °C and 25 °C respectively.
Explain this in terms of their saturated fatty acid composition.
-
19M.3.sl.TZ1.9b:
Fats contain triglycerides that are esters of glycerol and fatty acids. Deduce an equation for the acid hydrolysis of the following triglyceride.
-
19M.3.sl.TZ1.9c:
The addition of partially hydrogenated cocoa butter to chocolate increases its melting point and the content of trans-fatty acids (trans-fats).
Outline two effects of trans-fatty acids on health.
-
19M.3.sl.TZ1.a:
The melting points of cocoa butter and coconut oil are 34 °C and 25 °C respectively.
Explain this in terms of their saturated fatty acid composition.
-
19M.3.sl.TZ1.b:
Fats contain triglycerides that are esters of glycerol and fatty acids. Deduce an equation for the acid hydrolysis of the following triglyceride.
-
19M.3.sl.TZ1.c:
The addition of partially hydrogenated cocoa butter to chocolate increases its melting point and the content of trans-fatty acids (trans-fats).
Outline two effects of trans-fatty acids on health.
-
19M.3.sl.TZ1.10:
Ascorbic acid and retinol are two important vitamins.
Explain why ascorbic acid is soluble in water and retinol is not. Use section 35 of the data booklet.
-
19M.3.sl.TZ2.6a(i):
Some proteins form an α-helix. State the name of another secondary protein structure.
-
19M.3.sl.TZ2.6a(ii):
Compare and contrast the bonding responsible for the two secondary structures.
One similarity:
One difference:
-
19M.3.sl.TZ2.6b:
Explain why an increase in temperature reduces the rate of an enzyme-catalyzed reaction.
-
19M.3.sl.TZ2.6c(i):
Suggest two reasons why oil decomposes faster at the surface of the ocean than at greater depth.
-
19M.3.sl.TZ2.6c(ii):
Oil spills can be treated with an enzyme mixture to speed up decomposition.
Outline one factor to be considered when assessing the greenness of an enzyme mixture.
-
19M.3.sl.TZ2.a(i):
Some proteins form an α-helix. State the name of another secondary protein structure.
-
19M.3.sl.TZ2.a(ii):
Compare and contrast the bonding responsible for the two secondary structures.
One similarity:
One difference:
-
19M.3.sl.TZ2.b:
Explain why an increase in temperature reduces the rate of an enzyme-catalyzed reaction.
-
19M.3.sl.TZ2.c(i):
Suggest two reasons why oil decomposes faster at the surface of the ocean than at greater depth.
-
19M.3.sl.TZ2.c(ii):
Oil spills can be treated with an enzyme mixture to speed up decomposition.
Outline one factor to be considered when assessing the greenness of an enzyme mixture.
-
19M.3.sl.TZ2.7a(i):
Deduce the structural formula of phosphatidylcholine.
-
19M.3.sl.TZ2.7a(ii):
Identify the type of reaction in (a).
-
19M.3.sl.TZ2.7b:
Lecithin is a major component of cell membranes. Describe the structure of a cell membrane.
-
19M.3.sl.TZ2.7c:
Predict, giving a reason, the relative energy density of a carbohydrate and a lipid of similar molar mass.
-
19M.3.sl.TZ2.7d:
Lecithin aids the body’s absorption of vitamin E.
Suggest why vitamin E is fat-soluble.
-
19M.3.sl.TZ2.7e:
Phospholipids are also found in lipoprotein structures.
Describe two effects of increased levels of low-density lipoprotein (LDL) on health.
-
19M.3.sl.TZ2.a(i):
Deduce the structural formula of phosphatidylcholine.
-
19M.3.sl.TZ2.a(ii):
Identify the type of reaction in (a).
-
19M.3.sl.TZ2.b:
Lecithin is a major component of cell membranes. Describe the structure of a cell membrane.
-
19M.3.sl.TZ2.c:
Predict, giving a reason, the relative energy density of a carbohydrate and a lipid of similar molar mass.
-
19M.3.sl.TZ2.d:
Lecithin aids the body’s absorption of vitamin E.
Suggest why vitamin E is fat-soluble.
-
19M.3.sl.TZ2.e:
Phospholipids are also found in lipoprotein structures.
Describe two effects of increased levels of low-density lipoprotein (LDL) on health.
-
19M.3.sl.TZ2.8a:
State the name of the functional group forming part of the ring structure of each monosaccharide unit.
-
19M.3.sl.TZ2.8b:
Sketch the cyclic structures of the two monosaccharides which combine to form sucrose.
-
19M.3.sl.TZ2.a:
State the name of the functional group forming part of the ring structure of each monosaccharide unit.
-
19M.3.sl.TZ2.b:
Sketch the cyclic structures of the two monosaccharides which combine to form sucrose.
-
19N.3.sl.TZ0.7a:
Draw the structure of the dipeptide Asp–Phe using section 33 of the data booklet.
-
19N.3.sl.TZ0.7b:
The isoelectric point of amino acids is the intermediate pH at which an amino acid is electrically neutral.
Suggest why Asp and Phe have different isoelectric points.
-
19N.3.sl.TZ0.a:
Draw the structure of the dipeptide Asp–Phe using section 33 of the data booklet.
-
19N.3.sl.TZ0.b:
The isoelectric point of amino acids is the intermediate pH at which an amino acid is electrically neutral.
Suggest why Asp and Phe have different isoelectric points.
-
19N.3.hl.TZ0.10a:
Draw the structure of the dipeptide Asp–Phe using section 33 of the data booklet.
- 19N.3.hl.TZ0.10b(i): Describe, using another method, how a mixture of four amino acids, alanine, arginine, glutamic...
- 19N.3.hl.TZ0.10b(ii): Suggest why alanine and glycine separate slightly at pH 6.5.
-
19N.3.hl.TZ0.10b(iii):
Calculate the ratio of [A−] : [HA] in a buffer of pH 6.0 given that pKa for the acid is 4.83, using section 1 of the data booklet.
-
19N.3.hl.TZ0.a:
Draw the structure of the dipeptide Asp–Phe using section 33 of the data booklet.
- 19N.3.hl.TZ0.b(i): Describe, using another method, how a mixture of four amino acids, alanine, arginine, glutamic...
- 19N.3.hl.TZ0.b(ii): Suggest why alanine and glycine separate slightly at pH 6.5.
-
19N.3.hl.TZ0.b(iii):
Calculate the ratio of [A−] : [HA] in a buffer of pH 6.0 given that pKa for the acid is 4.83, using section 1 of the data booklet.
- 19N.3.hl.TZ0.11a: Outline the significance of the Michaelis constant Km.
-
19N.3.hl.TZ0.11b:
Compare the effects of competitive and non-competitive inhibitors.
- 19N.3.hl.TZ0.a: Outline the significance of the Michaelis constant Km.
-
19N.3.hl.TZ0.b:
Compare the effects of competitive and non-competitive inhibitors.
-
19N.3.sl.TZ0.9a:
The iodine number is the number of grams of iodine which reacts with 100 g of fat. Calculate the iodine number of oleic acid.
- 19N.3.sl.TZ0.9b: State one impact on health of the increase in LDL cholesterol concentration in blood.
- 19N.3.sl.TZ0.9c: Explain why stearic acid has a higher melting point than oleic acid.
- 19N.3.sl.TZ0.9d(i): State one similarity and one difference in composition between phospholipids and...
-
19N.3.sl.TZ0.9d(ii):
Identify a reagent that hydrolyses triglycerides.
-
19N.3.sl.TZ0.a:
The iodine number is the number of grams of iodine which reacts with 100 g of fat. Calculate the iodine number of oleic acid.
- 19N.3.sl.TZ0.b: State one impact on health of the increase in LDL cholesterol concentration in blood.
- 19N.3.sl.TZ0.c: Explain why stearic acid has a higher melting point than oleic acid.
- 19N.3.sl.TZ0.d(i): State one similarity and one difference in composition between phospholipids and...
-
19N.3.sl.TZ0.d(ii):
Identify a reagent that hydrolyses triglycerides.
-
19N.3.hl.TZ0.12a:
The iodine number is the number of grams of iodine which reacts with 100 g of fat. Calculate the iodine number of oleic acid.
-
19N.3.hl.TZ0.12b:
The chemical change in stored fats causes rancidity characterized by an unpleasant smell or taste.
Compare hydrolytic and oxidative rancidity.
- 19N.3.hl.TZ0.12c: State one similarity and one difference in composition between phospholipids and...
-
19N.3.hl.TZ0.a:
The iodine number is the number of grams of iodine which reacts with 100 g of fat. Calculate the iodine number of oleic acid.
-
19N.3.hl.TZ0.b:
The chemical change in stored fats causes rancidity characterized by an unpleasant smell or taste.
Compare hydrolytic and oxidative rancidity.
- 19N.3.hl.TZ0.c: State one similarity and one difference in composition between phospholipids and...
-
19N.3.hl.TZ0.13a:
List two components of nucleotides.
- 19N.3.hl.TZ0.13b: Explain how the double-helical structure of DNA is stabilized once formed.
-
19N.3.hl.TZ0.a:
List two components of nucleotides.
- 19N.3.hl.TZ0.b: Explain how the double-helical structure of DNA is stabilized once formed.
- 19N.3.hl.TZ0.14a: The graph shows the change in oxygen partial pressure in blood, measured at different pH...
- 19N.3.hl.TZ0.14b: Explain the biomagnification of the pesticide DDT.
- 19N.3.hl.TZ0.14c: Vitamins are organic compounds essential in small amounts. State the name of one functional...
- 19N.3.hl.TZ0.a: The graph shows the change in oxygen partial pressure in blood, measured at different pH...
- 19N.3.hl.TZ0.b: Explain the biomagnification of the pesticide DDT.
- 19N.3.hl.TZ0.c: Vitamins are organic compounds essential in small amounts. State the name of one functional...
- 19N.3.sl.TZ0.10a: State the name of one functional group common to all three vitamins shown in section 35 of the...
- 19N.3.sl.TZ0.10b: Explain the biomagnification of the pesticide DDT.
- 19N.3.sl.TZ0.10c: Explain why maltose, C12H22O11, is soluble in water.
- 19N.3.sl.TZ0.a: State the name of one functional group common to all three vitamins shown in section 35 of the...
- 19N.3.sl.TZ0.b: Explain the biomagnification of the pesticide DDT.
- 19N.3.sl.TZ0.c: Explain why maltose, C12H22O11, is soluble in water.
- 19N.3.hl.TZ0.15a: Describe the function of chlorophyll in photosynthesis.
- 19N.3.hl.TZ0.15b: Compare and contrast the structures of starch and cellulose. One similarity: One difference:
- 19N.3.hl.TZ0.15c: Explain why maltose, C12H22O11, is soluble in water.
- 19N.3.hl.TZ0.a: Describe the function of chlorophyll in photosynthesis.
- 19N.3.hl.TZ0.b: Compare and contrast the structures of starch and cellulose. One similarity: One difference:
- 19N.3.hl.TZ0.c: Explain why maltose, C12H22O11, is soluble in water.
- 19N.3.sl.TZ0.8a: The graph shows the relationship between the temperature and the rate of an enzyme-catalysed...
-
19N.3.sl.TZ0.8b:
Explain why a change in pH affects the tertiary structure of an enzyme in solution.
- 19N.3.sl.TZ0.8c: State one use of enzymes in reducing environmental problems.
- 19N.3.sl.TZ0.a: The graph shows the relationship between the temperature and the rate of an enzyme-catalysed...
-
19N.3.sl.TZ0.b:
Explain why a change in pH affects the tertiary structure of an enzyme in solution.
- 19N.3.sl.TZ0.c: State one use of enzymes in reducing environmental problems.
-
20N.3.sl.TZ0.5a(i):
Proteins are polymers of amino acids. A paper chromatogram of two amino acids, A1 and A2, is obtained using a non-polar solvent.
© International Baccalaureate Organization 2020.
Determine the value of A1.
-
20N.3.sl.TZ0.5a(ii):
Proteins are polymers of amino acids.
The mixture is composed of glycine, , and isoleucine, . Their structures can be found in section 33 of the data booklet.
Deduce, referring to relative affinities and , the identity of A1.
-
20N.3.sl.TZ0.5b:
Proteins are polymers of amino acids.
Glycine is one of the amino acids in the primary structure of hemoglobin.
State the type of bonding responsible for the α-helix in the secondary structure.
-
20N.3.sl.TZ0.5c:
Proteins are polymers of amino acids.
Describe how the tertiary structure differs from the quaternary structure in hemoglobin.
-
20N.3.sl.TZ0.a(i):
Proteins are polymers of amino acids. A paper chromatogram of two amino acids, A1 and A2, is obtained using a non-polar solvent.
© International Baccalaureate Organization 2020.
Determine the value of A1.
-
20N.3.sl.TZ0.a(ii):
Proteins are polymers of amino acids.
The mixture is composed of glycine, , and isoleucine, . Their structures can be found in section 33 of the data booklet.
Deduce, referring to relative affinities and , the identity of A1.
-
20N.3.sl.TZ0.b:
Proteins are polymers of amino acids.
Glycine is one of the amino acids in the primary structure of hemoglobin.
State the type of bonding responsible for the α-helix in the secondary structure.
-
20N.3.sl.TZ0.c:
Proteins are polymers of amino acids.
Describe how the tertiary structure differs from the quaternary structure in hemoglobin.
-
20N.3.sl.TZ0.6a:
Deduce the products of the hydrolysis of a non-substituted phospholipid, where and represent long alkyl chains.
-
20N.3.sl.TZ0.6b(i):
A representation of a phospholipid bilayer cell membrane is shown:
© International Baccalaureate Organization 2020.
Identify the components of the phospholipid labelled A and B.
-
20N.3.sl.TZ0.6c:
Phospholipids help maintain cellular environments while fatty acid lipids have important roles in energy storage and electrical insulation. Discuss the structural properties of saturated fats needed for these roles.
-
20N.3.sl.TZ0.a:
Deduce the products of the hydrolysis of a non-substituted phospholipid, where and represent long alkyl chains.
-
20N.3.sl.TZ0.b(i):
A representation of a phospholipid bilayer cell membrane is shown:
© International Baccalaureate Organization 2020.
Identify the components of the phospholipid labelled A and B.
-
20N.3.sl.TZ0.c:
Phospholipids help maintain cellular environments while fatty acid lipids have important roles in energy storage and electrical insulation. Discuss the structural properties of saturated fats needed for these roles.
- 20N.3.sl.TZ0.7a: The diverse functions of biological molecules depend on their structure and shape. Classify...
-
20N.3.sl.TZ0.7b(i):
The diverse functions of biological molecules depend on their structure and shape.
Deduce the straight chain structure of deoxyribose from its ring structure drawn in section 34 of the data booklet.
-
20N.3.sl.TZ0.7b(ii):
The diverse functions of biological molecules depend on their structure and shape.
Sucrose is a disaccharide formed in the reaction of glucose with fructose.
Identify the reaction type and the newly formed functional group that joins the monosaccharide units in the product.
- 20N.3.sl.TZ0.a: The diverse functions of biological molecules depend on their structure and shape. Classify...
-
20N.3.sl.TZ0.b(i):
The diverse functions of biological molecules depend on their structure and shape.
Deduce the straight chain structure of deoxyribose from its ring structure drawn in section 34 of the data booklet.
-
20N.3.sl.TZ0.b(ii):
The diverse functions of biological molecules depend on their structure and shape.
Sucrose is a disaccharide formed in the reaction of glucose with fructose.
Identify the reaction type and the newly formed functional group that joins the monosaccharide units in the product.
-
20N.3.sl.TZ0.8a:
Calculate the BMF if a shark consumes mackerel in one year. Each mackerel weighs on average. The per body weight. Assume chemical remains in the shark’s body for two years.
- 20N.3.sl.TZ0.8b: Suggest, with a reason, if fat-soluble or water-soluble xenobiotics would have a larger BMF.
-
20N.3.sl.TZ0.a:
Calculate the BMF if a shark consumes mackerel in one year. Each mackerel weighs on average. The per body weight. Assume chemical remains in the shark’s body for two years.
- 20N.3.sl.TZ0.b: Suggest, with a reason, if fat-soluble or water-soluble xenobiotics would have a larger BMF.
-
20N.3.hl.TZ0.6a(i):
Proteins are polymers of amino acids.
A paper chromatogram of two amino acids, A1 and A2, is obtained using a non-polar solvent.
© International Baccalaureate Organization 2020.
Determine the value of A1.
-
20N.3.hl.TZ0.6a(ii):
Proteins are polymers of amino acids.
The mixture is composed of glycine, , and isoleucine, . Their structures can be found in section 33 of the data booklet.
Deduce, referring to relative affinities and , the identity of A1.
-
20N.3.hl.TZ0.6b:
Proteins are polymers of amino acids.
Glycine is one of the amino acids in the primary structure of hemoglobin.
State the type of bonding responsible for the α-helix in the secondary structure.
- 20N.3.hl.TZ0.6c(i): Proteins are polymers of amino acids. Sketch and label two oxygen dissociation curves, one for...
-
20N.3.hl.TZ0.6c(ii):
Proteins are polymers of amino acids.
Explain why the affinity for oxygen of foetal hemoglobin differs from that of adult hemoglobin.
-
20N.3.hl.TZ0.a(i):
Proteins are polymers of amino acids.
A paper chromatogram of two amino acids, A1 and A2, is obtained using a non-polar solvent.
© International Baccalaureate Organization 2020.
Determine the value of A1.
-
20N.3.hl.TZ0.a(ii):
Proteins are polymers of amino acids.
The mixture is composed of glycine, , and isoleucine, . Their structures can be found in section 33 of the data booklet.
Deduce, referring to relative affinities and , the identity of A1.
-
20N.3.hl.TZ0.b:
Proteins are polymers of amino acids.
Glycine is one of the amino acids in the primary structure of hemoglobin.
State the type of bonding responsible for the α-helix in the secondary structure.
- 20N.3.hl.TZ0.c(i): Proteins are polymers of amino acids. Sketch and label two oxygen dissociation curves, one for...
-
20N.3.hl.TZ0.c(ii):
Proteins are polymers of amino acids.
Explain why the affinity for oxygen of foetal hemoglobin differs from that of adult hemoglobin.
- 20N.3.hl.TZ0.8a: The diverse functions of biological molecules depend on their structure and shape. Classify...
-
20N.3.hl.TZ0.8b(i):
The diverse functions of biological molecules depend on their structure and shape.
Deduce the straight chain structure of deoxyribose from its ring structure drawn in section 34 of the data booklet.
-
20N.3.hl.TZ0.8b(ii):
The diverse functions of biological molecules depend on their structure and shape.
Draw the nitrogenous base that is paired with guanine in DNA, showing the hydrogen bonds between the bases. Use section 34 of the data booklet.
- 20N.3.hl.TZ0.8c: The diverse functions of biological molecules depend on their structure and shape. Retinal is...
- 20N.3.hl.TZ0.a: The diverse functions of biological molecules depend on their structure and shape. Classify...
-
20N.3.hl.TZ0.b(i):
The diverse functions of biological molecules depend on their structure and shape.
Deduce the straight chain structure of deoxyribose from its ring structure drawn in section 34 of the data booklet.
-
20N.3.hl.TZ0.b(ii):
The diverse functions of biological molecules depend on their structure and shape.
Draw the nitrogenous base that is paired with guanine in DNA, showing the hydrogen bonds between the bases. Use section 34 of the data booklet.
- 20N.3.hl.TZ0.c: The diverse functions of biological molecules depend on their structure and shape. Retinal is...
- 20N.3.hl.TZ0.10a: Identify the type of inhibition shown in the graph.
-
20N.3.hl.TZ0.10b(i):
Determine the value of and in the absence and presence of the inhibitor.
-
20N.3.hl.TZ0.10b(ii):
Outline the significance of the value of the Michaelis constant, .
- 20N.3.hl.TZ0.a: Identify the type of inhibition shown in the graph.
-
20N.3.hl.TZ0.b(i):
Determine the value of and in the absence and presence of the inhibitor.
-
20N.3.hl.TZ0.b(ii):
Outline the significance of the value of the Michaelis constant, .
- 17N.3.sl.TZ0.8a.ii: The empirical formula of fructose is CH2O. Suggest why linoleic acid releases more energy per...
- 17N.3.sl.TZ0.8b.i: State the type of reaction occurring during the titration.
-
17N.3.sl.TZ0.8b.ii:
Calculate the volume of iodine solution used to reach the end-point.
-
17N.3.sl.TZ0.8c:
Outline the importance of linoleic acid for human health.
- 17N.3.sl.TZ0.a.ii: The empirical formula of fructose is CH2O. Suggest why linoleic acid releases more energy per...
- 17N.3.sl.TZ0.b.i: State the type of reaction occurring during the titration.
-
17N.3.sl.TZ0.b.ii:
Calculate the volume of iodine solution used to reach the end-point.
-
17N.3.sl.TZ0.c:
Outline the importance of linoleic acid for human health.
-
17N.3.sl.TZ0.9a:
Describe what is meant by a condensation reaction.
- 17N.3.sl.TZ0.9b: Draw the structure of galactose on the skeleton provided.
-
17N.3.sl.TZ0.9c:
Explain how the inclusion of carbohydrates in plastics makes them biodegradable.
-
17N.3.sl.TZ0.a:
Describe what is meant by a condensation reaction.
- 17N.3.sl.TZ0.b: Draw the structure of galactose on the skeleton provided.
-
17N.3.sl.TZ0.c:
Explain how the inclusion of carbohydrates in plastics makes them biodegradable.
-
17N.3.sl.TZ0.10a:
Explain, at the molecular level, why vitamin D is soluble in fats. Use section 35 of the data booklet.
- 17N.3.sl.TZ0.10b: State one function of vitamin D in the body.
-
17N.3.sl.TZ0.a:
Explain, at the molecular level, why vitamin D is soluble in fats. Use section 35 of the data booklet.
- 17N.3.sl.TZ0.b: State one function of vitamin D in the body.
- 17N.3.sl.TZ0.11: Enzyme activity depends on many factors. Explain how pH change causes loss of activity of an enzyme.
-
17N.3.hl.TZ0.11a:
Determine the value of the Michaelis constant, Km, by annotating the graph.
-
17N.3.hl.TZ0.11b.i:
The malonate ion acts as an inhibitor for the enzyme.
Suggest, on the molecular level, how the malonate ion is able to inhibit the enzyme.
-
17N.3.hl.TZ0.11b.ii:
Draw a curve on the graph above showing the effect of the presence of the malonate ion inhibitor on the rate of reaction.
-
17N.3.hl.TZ0.a:
Determine the value of the Michaelis constant, Km, by annotating the graph.
-
17N.3.hl.TZ0.b.i:
The malonate ion acts as an inhibitor for the enzyme.
Suggest, on the molecular level, how the malonate ion is able to inhibit the enzyme.
-
17N.3.hl.TZ0.b.ii:
Draw a curve on the graph above showing the effect of the presence of the malonate ion inhibitor on the rate of reaction.
-
17N.3.hl.TZ0.13:
The stability of DNA is due to interactions of its hydrophilic and hydrophobic components.
Outline the interactions of the phosphate groups in DNA with water and with surrounding proteins (histones).
-
17N.3.hl.TZ0.14a:
State the half-equation for the reduction of molecular oxygen to water in acidic conditions.
- 17N.3.hl.TZ0.14b: Outline the change in oxidation state of the iron ions in heme groups that occurs when molecular...
-
17N.3.hl.TZ0.a:
State the half-equation for the reduction of molecular oxygen to water in acidic conditions.
- 17N.3.hl.TZ0.b: Outline the change in oxidation state of the iron ions in heme groups that occurs when molecular...
-
17N.3.hl.TZ0.15b:
Retinal is the key molecule involved in vision. Explain the roles of cis and trans-retinal in vision and how the isomers are formed in the visual cycle.
-
17N.3.hl.TZ0.b:
Retinal is the key molecule involved in vision. Explain the roles of cis and trans-retinal in vision and how the isomers are formed in the visual cycle.
-
18M.3.hl.TZ1.6d:
Describe how DNA determines the primary structure of a protein such as insulin.
-
18M.3.hl.TZ1.d:
Describe how DNA determines the primary structure of a protein such as insulin.
-
18M.3.hl.TZ1.8b:
Outline why cellulose fibres are strong.
-
18M.3.hl.TZ1.b:
Outline why cellulose fibres are strong.
-
18M.3.hl.TZ1.9a:
Explain with reference to the binding site on the enzyme how a non-competitive inhibitor lowers the value of Vmax.
-
18M.3.hl.TZ1.9b:
Outline the significance of the value of the Michaelis constant, Km.
-
18M.3.hl.TZ1.a:
Explain with reference to the binding site on the enzyme how a non-competitive inhibitor lowers the value of Vmax.
-
18M.3.hl.TZ1.b:
Outline the significance of the value of the Michaelis constant, Km.
-
18M.3.hl.TZ1.10a:
Outline why anthocyanins are coloured.
-
18M.3.hl.TZ1.10b:
Explain why the blue colour of a quinoidal base changes to the red colour of a flavylium cation as pH decreases.
-
18M.3.hl.TZ1.a:
Outline why anthocyanins are coloured.
-
18M.3.hl.TZ1.b:
Explain why the blue colour of a quinoidal base changes to the red colour of a flavylium cation as pH decreases.
-
18M.3.hl.TZ2.8c:
Draw the structures of the main form of glycine in buffer solutions of pH 1.0 and 6.0.
The pKa of glycine is 2.34.
-
18M.3.hl.TZ2.8d:
Calculate the pH of a buffer system with a concentration of 1.25 × 10−3 mol dm−3 carbonic acid and 2.50 × 10−2 mol dm−3 sodium hydrogen carbonate. Use section 1 of the data booklet.
pKa (carbonic acid) = 6.36
-
18M.3.hl.TZ2.8e:
Sketch the wedge and dash (3-D) representations of alanine enantiomers.
-
18M.3.hl.TZ2.8f:
UV-Vis spectroscopy can be used to determine the unknown concentration of a substance in a solution.
Calculate the concentration of an unknown sample of pepsin with an absorbance of 0.725 using section 1 of the data booklet.
Cell length = 1.00 cm
Molar absorptivity (extinction coefficient) of the sample = 49650 dm3 cm−1 mol−1
-
18M.3.hl.TZ2.8g:
A different series of pepsin samples is used to develop a calibration curve.
Estimate the concentration of an unknown sample of pepsin with an absorbance of 0.30 from the graph.
-
18M.3.hl.TZ2.c:
Draw the structures of the main form of glycine in buffer solutions of pH 1.0 and 6.0.
The pKa of glycine is 2.34.
-
18M.3.hl.TZ2.d:
Calculate the pH of a buffer system with a concentration of 1.25 × 10−3 mol dm−3 carbonic acid and 2.50 × 10−2 mol dm−3 sodium hydrogen carbonate. Use section 1 of the data booklet.
pKa (carbonic acid) = 6.36
-
18M.3.hl.TZ2.e:
Sketch the wedge and dash (3-D) representations of alanine enantiomers.
-
18M.3.hl.TZ2.f:
UV-Vis spectroscopy can be used to determine the unknown concentration of a substance in a solution.
Calculate the concentration of an unknown sample of pepsin with an absorbance of 0.725 using section 1 of the data booklet.
Cell length = 1.00 cm
Molar absorptivity (extinction coefficient) of the sample = 49650 dm3 cm−1 mol−1
-
18M.3.hl.TZ2.g:
A different series of pepsin samples is used to develop a calibration curve.
Estimate the concentration of an unknown sample of pepsin with an absorbance of 0.30 from the graph.
-
18M.3.hl.TZ2.10b:
Explain how the structure of vitamin A is important to vision using section 35 of the data booklet.
-
18M.3.hl.TZ2.b:
Explain how the structure of vitamin A is important to vision using section 35 of the data booklet.
-
18M.3.hl.TZ2.11a:
Hemoglobin’s oxygen dissociation curve is shown at a given temperature. Sketch the curve on the graph at a higher temperature.
-
18M.3.hl.TZ2.11b:
Outline two differences between normal hemoglobin and foetal hemoglobin.
-
18M.3.hl.TZ2.a:
Hemoglobin’s oxygen dissociation curve is shown at a given temperature. Sketch the curve on the graph at a higher temperature.
-
18M.3.hl.TZ2.b:
Outline two differences between normal hemoglobin and foetal hemoglobin.
-
18M.3.hl.TZ2.12:
DNA is a biopolymer made up of nucleotides. List two components of a nucleotide.
-
18M.3.sl.TZ1.6a:
Draw the structural formula of a dipeptide containing the residues of valine, Val, and asparagine, Asn, using section 33 of the data booklet.
-
18M.3.sl.TZ1.6b:
Deduce the strongest intermolecular forces that would occur between the following amino acid residues in a protein chain.
-
18M.3.sl.TZ1.6c.i:
State the name of the process used to break down the insulin protein into its constituent amino acids.
-
18M.3.sl.TZ1.6c.ii:
Outline how the amino acids may be identified from a paper chromatogram.
-
18M.3.sl.TZ1.a:
Draw the structural formula of a dipeptide containing the residues of valine, Val, and asparagine, Asn, using section 33 of the data booklet.
-
18M.3.sl.TZ1.b:
Deduce the strongest intermolecular forces that would occur between the following amino acid residues in a protein chain.
-
18M.3.sl.TZ1.c.i:
State the name of the process used to break down the insulin protein into its constituent amino acids.
-
18M.3.sl.TZ1.c.ii:
Outline how the amino acids may be identified from a paper chromatogram.
-
18M.3.sl.TZ1.7a.i:
Identify the type of rancidity occurring in saturated lipids and the structural feature that causes it.
-
18M.3.sl.TZ1.7a.ii:
State one factor that increases the rate at which saturated lipids become rancid.
-
18M.3.sl.TZ1.7b:
Butter contains varying proportions of oleic, myristic, palmitic and stearic acids. Explain in terms of their structures why stearic acid has a higher melting point than oleic acid, using section 34 of the data booklet.
-
18M.3.sl.TZ1.7c.i:
Fish oil is an excellent dietary source of omega-3 fatty acids. Outline one impact on health of consuming omega-3 fatty acids.
-
18M.3.sl.TZ1.7c.ii:
Predict the solubility of retinol (vitamin A) in body fat, giving a reason. Use section 35 of the data booklet.
-
18M.3.sl.TZ1.7c.iii:
Explain why sharks and swordfish sometimes contain high concentrations of mercury and polychlorinated biphenyls (PCBs).
-
18M.3.sl.TZ1.7c.iv:
Plastics are another source of marine pollution. Outline one way in which plastics can be made more biodegradable.
-
18M.3.sl.TZ1.a.i:
Identify the type of rancidity occurring in saturated lipids and the structural feature that causes it.
-
18M.3.sl.TZ1.a.ii:
State one factor that increases the rate at which saturated lipids become rancid.
-
18M.3.sl.TZ1.b:
Butter contains varying proportions of oleic, myristic, palmitic and stearic acids. Explain in terms of their structures why stearic acid has a higher melting point than oleic acid, using section 34 of the data booklet.
-
18M.3.sl.TZ1.c.i:
Fish oil is an excellent dietary source of omega-3 fatty acids. Outline one impact on health of consuming omega-3 fatty acids.
-
18M.3.sl.TZ1.c.ii:
Predict the solubility of retinol (vitamin A) in body fat, giving a reason. Use section 35 of the data booklet.
-
18M.3.sl.TZ1.c.iii:
Explain why sharks and swordfish sometimes contain high concentrations of mercury and polychlorinated biphenyls (PCBs).
-
18M.3.sl.TZ1.c.iv:
Plastics are another source of marine pollution. Outline one way in which plastics can be made more biodegradable.
-
18M.3.sl.TZ1.8a:
State the specific type of linkage formed between α-glucose fragments in both maltose and amylose.
-
18M.3.sl.TZ1.8b:
A person with diabetes suffering very low blood sugar (hypoglycaemia) may be advised to consume glucose immediately and then eat a small amount of starchy food such as a sandwich. Explain this advice in terms of the properties of glucose and starch.
-
18M.3.sl.TZ1.a:
State the specific type of linkage formed between α-glucose fragments in both maltose and amylose.
-
18M.3.sl.TZ1.b:
A person with diabetes suffering very low blood sugar (hypoglycaemia) may be advised to consume glucose immediately and then eat a small amount of starchy food such as a sandwich. Explain this advice in terms of the properties of glucose and starch.
-
18M.3.sl.TZ2.6a:
Identify the type of chemical reaction that occurs between fatty acids and glycerol to form lipids and the by-product of the reaction.
-
18M.3.sl.TZ2.6b:
Arachidonic acid is a polyunsaturated omega-6 fatty acid found in peanut oil.
Determine the number of carbon–carbon double bonds present if the iodine number for the compound is 334. (Arachidonic acid Mr = 304.5)
-
18M.3.sl.TZ2.6c:
Deduce the structure of the lipid formed by the reaction between lauric acid and glycerol (propane-1,2,3-triol) using section 34 of the data booklet.
-
18M.3.sl.TZ2.6d:
Outline one impact food labelling has had on the consumption of foods containing different types of lipids.
-
18M.3.sl.TZ2.6e:
Determine, to the correct number of significant figures, the energy produced by the respiration of 29.9 g of C5H10O5.
ΔHc (C5H10O5) = 205.9 kJ mol−1
-
18M.3.sl.TZ2.6f:
Explain why lipids provide more energy than carbohydrates and proteins.
-
18M.3.sl.TZ2.a:
Identify the type of chemical reaction that occurs between fatty acids and glycerol to form lipids and the by-product of the reaction.
-
18M.3.sl.TZ2.b:
Arachidonic acid is a polyunsaturated omega-6 fatty acid found in peanut oil.
Determine the number of carbon–carbon double bonds present if the iodine number for the compound is 334. (Arachidonic acid Mr = 304.5)
-
18M.3.sl.TZ2.c:
Deduce the structure of the lipid formed by the reaction between lauric acid and glycerol (propane-1,2,3-triol) using section 34 of the data booklet.
-
18M.3.sl.TZ2.d:
Outline one impact food labelling has had on the consumption of foods containing different types of lipids.
-
18M.3.sl.TZ2.e:
Determine, to the correct number of significant figures, the energy produced by the respiration of 29.9 g of C5H10O5.
ΔHc (C5H10O5) = 205.9 kJ mol−1
-
18M.3.sl.TZ2.f:
Explain why lipids provide more energy than carbohydrates and proteins.
-
18M.3.sl.TZ2.7a:
Draw the dipeptide represented by the formula Ala-Gly using section 33 of the data booklet.
-
18M.3.sl.TZ2.7c:
Outline why amino acids have high melting points.
-
18M.3.sl.TZ2.a:
Draw the dipeptide represented by the formula Ala-Gly using section 33 of the data booklet.
-
18M.3.sl.TZ2.c:
Outline why amino acids have high melting points.
-
18M.3.sl.TZ2.8:
Green Chemistry reduces the production of hazardous materials and chemical waste.
Outline two specific examples or technological processes of how Green Chemistry has accomplished this environmental impact.
-
18M.3.sl.TZ2.9:
Explain the solubility of vitamins A and C using section 35 of the data booklet.
- 18N.3.sl.TZ0.5a: The formation of proteins from amino acids is an example of an anabolic reaction in the human...
-
18N.3.sl.TZ0.5b:
Suggest why it is advisable for those living in northerly or southerly latitudes (that is away from the equator) to take vitamin D supplements during the winter.
- 18N.3.sl.TZ0.5c: Explain how a xenobiotic is biomagnified.
- 18N.3.sl.TZ0.a: The formation of proteins from amino acids is an example of an anabolic reaction in the human...
-
18N.3.sl.TZ0.b:
Suggest why it is advisable for those living in northerly or southerly latitudes (that is away from the equator) to take vitamin D supplements during the winter.
- 18N.3.sl.TZ0.c: Explain how a xenobiotic is biomagnified.
- 18N.3.sl.TZ0.6a: Describe the interaction responsible for the secondary structure of a protein.
- 18N.3.sl.TZ0.6b.i: Explain the action of an enzyme and state one of its limitations.
- 18N.3.sl.TZ0.6b.ii: Enzymes are widely used in washing detergents. Outline how they improve the efficiency of the...
- 18N.3.sl.TZ0.a: Describe the interaction responsible for the secondary structure of a protein.
- 18N.3.sl.TZ0.b.i: Explain the action of an enzyme and state one of its limitations.
- 18N.3.sl.TZ0.b.ii: Enzymes are widely used in washing detergents. Outline how they improve the efficiency of the...
- 18N.3.sl.TZ0.7a: A phospholipid generally consists of two hydrophobic fatty acids and a hydrophilic...
-
18N.3.sl.TZ0.7b.i:
The iodine number is the maximum mass of iodine that reacts with 100 g of an unsaturated compound.
Determine the iodine number of stearidonic acid, C17H27COOH.
- 18N.3.sl.TZ0.7b.ii: State two functions of lipids in the body.
- 18N.3.sl.TZ0.7c: Outline one effect of increased levels of low-density lipoproteins in the blood.
- 18N.3.sl.TZ0.a: A phospholipid generally consists of two hydrophobic fatty acids and a hydrophilic...
-
18N.3.sl.TZ0.b.i:
The iodine number is the maximum mass of iodine that reacts with 100 g of an unsaturated compound.
Determine the iodine number of stearidonic acid, C17H27COOH.
- 18N.3.sl.TZ0.b.ii: State two functions of lipids in the body.
- 18N.3.sl.TZ0.c: Outline one effect of increased levels of low-density lipoproteins in the blood.
- 18N.3.sl.TZ0.8a: Name the type of link between the two monosaccharide residues.
- 18N.3.sl.TZ0.8b: Outline how the two monomer structures, galactose and glucose, differ.
- 18N.3.sl.TZ0.a: Name the type of link between the two monosaccharide residues.
- 18N.3.sl.TZ0.b: Outline how the two monomer structures, galactose and glucose, differ.
- 18N.3.hl.TZ0.7a: State the feature of DNA that determines the primary structure of proteins synthesised by a cell.
- 18N.3.hl.TZ0.7b: Suggest one concern about the use of genetically modified, GM, food.
- 18N.3.hl.TZ0.a: State the feature of DNA that determines the primary structure of proteins synthesised by a cell.
- 18N.3.hl.TZ0.b: Suggest one concern about the use of genetically modified, GM, food.
- 18N.3.hl.TZ0.8a: Describe the interaction responsible for the secondary structure of a protein.
- 18N.3.hl.TZ0.8b: Explain the action of an enzyme and state one of its limitations.
-
18N.3.hl.TZ0.8c:
Contrast the actions of non-competitive and competitive inhibitors of an enzyme and state their effects on the maximum rate of reaction, Vmax, and the Michaelis–Menten constant, Km.
- 18N.3.hl.TZ0.a: Describe the interaction responsible for the secondary structure of a protein.
- 18N.3.hl.TZ0.b: Explain the action of an enzyme and state one of its limitations.
-
18N.3.hl.TZ0.c:
Contrast the actions of non-competitive and competitive inhibitors of an enzyme and state their effects on the maximum rate of reaction, Vmax, and the Michaelis–Menten constant, Km.
-
18N.3.hl.TZ0.9a:
The iodine number is the maximum mass of iodine that reacts with 100 g of an unsaturated compound.
Determine the iodine number of stearidonic acid, C17H27COOH.
- 18N.3.hl.TZ0.9b: State two functions of lipids in the body.
- 18N.3.hl.TZ0.9c: Outline one effect of increased levels of low-density lipoproteins in the blood.
-
18N.3.hl.TZ0.a:
The iodine number is the maximum mass of iodine that reacts with 100 g of an unsaturated compound.
Determine the iodine number of stearidonic acid, C17H27COOH.
- 18N.3.hl.TZ0.b: State two functions of lipids in the body.
- 18N.3.hl.TZ0.c: Outline one effect of increased levels of low-density lipoproteins in the blood.
- 18N.3.hl.TZ0.10a: Name the type of link between the two monosaccharide residues.
- 18N.3.hl.TZ0.10b: Outline how the two monomer structures, galactose and glucose, differ.
- 18N.3.hl.TZ0.10c.i: Outline the difference between their structures.
- 18N.3.hl.TZ0.10c.ii: Outline why cellulose is an essential part of human diet.
- 18N.3.hl.TZ0.a: Name the type of link between the two monosaccharide residues.
- 18N.3.hl.TZ0.b: Outline how the two monomer structures, galactose and glucose, differ.
- 18N.3.hl.TZ0.c.i: Outline the difference between their structures.
- 18N.3.hl.TZ0.c.ii: Outline why cellulose is an essential part of human diet.
- 18N.3.hl.TZ0.11a: A graph showing saturation of oxygen against partial pressure of oxygen is shown. Explain the...
-
18N.3.hl.TZ0.11b:
Explain why carbon monoxide is very toxic and how it may be possible to treat carbon monoxide poisoning.
- 18N.3.hl.TZ0.a: A graph showing saturation of oxygen against partial pressure of oxygen is shown. Explain the...
-
18N.3.hl.TZ0.b:
Explain why carbon monoxide is very toxic and how it may be possible to treat carbon monoxide poisoning.
C: Energy
-
17N.3.sl.TZ0.12a:
Calculate the specific energy of octane, C8H18, in kJ kg–1 using sections 1, 6 and 13 of the data booklet.
-
17N.3.sl.TZ0.12b:
A typical wood has a specific energy of 17 × 103 kJ kg–1. Comment on the usefulness of octane and wood for powering a moving vehicle, using your answer to (a).
If you did not work out an answer for (a), use 45 × 103 kJ kg–1 but this is not the correct answer.
-
17N.3.sl.TZ0.12c:
State the name of one renewable source of energy other than wood.
-
17N.3.sl.TZ0.13a:
“Knocking” in an automobile (car) engine can be prevented by increasing the octane number of the fuel. Explain, including an equation with structural formulas, how heptane, C7H16, could be chemically converted to increase its octane number.
-
17N.3.sl.TZ0.13b:
Many like to refer to our “carbon footprint”. Outline one difficulty in quantifying such a concept.
-
17N.3.sl.TZ0.13c:
Climate change or global warming is a consequence of increased levels of carbon dioxide in the atmosphere. Explain how the greenhouse effect warms the surface of the earth.
- 17N.3.sl.TZ0.13d: Outline how water and carbon dioxide absorb infrared radiation.
-
17N.3.sl.TZ0.14a.i:
Compare and contrast fission and fusion in terms of binding energy and the types of nuclei involved.
-
17N.3.sl.TZ0.14a.ii:
Suggest two advantages that fusion has over fission.
-
17N.3.sl.TZ0.14b:
The amount of 228Ac in a sample decreases to one eighth of its original value in about 18 hours due to β-decay. Estimate the half-life of 228Ac.
- 17N.3.sl.TZ0.15a: State the structural feature of chlorophyll that enables it to absorb visible light.
- 17N.3.sl.TZ0.15b: Vegetable oils are too viscous for use as liquid fuels. Describe, using an equation, how a...
-
17N.3.hl.TZ0.18c.i:
Calculate the loss in mass, in kg, and the energy released, in J, when 0.00100 mol of 228Ac decays, each atom losing an electron. Use section 2 of the data booklet and E = mc2.
228Ac → + 228Th
-
17N.3.hl.TZ0.18c.ii:
Determine the energy released, in J, by 0.00100 mol of 228Ac over the course of 18 hours.
- 17N.3.hl.TZ0.18d: Outline how nuclear ionising radiation can damage DNA and enzymes in living cells.
-
17N.3.hl.TZ0.19b:
The natural absorption of light by chlorophyll has been copied by those developing dye-sensitized solar cells (DSSCs). Outline how a DSSC works.
-
17N.3.hl.TZ0.20a:
Deduce the half-equations and the overall equation for the reactions taking place in a direct methanol fuel cell (DMFC) under acidic conditions.
-
17N.3.hl.TZ0.20b:
Outline one advantage and one disadvantage of the methanol cell (DMFC) compared with a hydrogen-oxygen fuel cell.
-
18M.3.hl.TZ1.13a:
Outline the major technical problem affecting the direct use of vegetable oils as fuels in internal combustion engines and the chemical conversion that has overcome this.
-
18M.3.hl.TZ1.13b:
State the formula of a fuel that might be produced from the vegetable oil whose formula is shown.
-
18M.3.hl.TZ1.14a.i:
Complete the half-equations on the diagram and identify the species moving between the electrodes.
-
18M.3.hl.TZ1.14a.ii:
State the factor that limits the maximum current that can be drawn from this cell and how electrodes are designed to maximize the current.
-
18M.3.hl.TZ1.14b.ii:
Explain how the proportion of 235U in natural uranium is increased.
-
18M.3.hl.TZ1.15a:
Early photovoltaic cells were based on silicon containing traces of other elements. State the type of semiconductor produced by doping silicon with indium, In, giving a reason that refers to its electronic structure.
-
18M.3.hl.TZ1.15b:
Dye-sensitized solar cells, DSSCs, use a dye to absorb the sunlight. State two advantages that DSSCs have over traditional silicon based photovoltaic cells.
-
18M.3.hl.TZ1.15c:
The structure of two dyes used in DSSCs are shown.
Predict, giving a reason, which dye will absorb light of longer wavelength.
-
18M.3.hl.TZ2.13c:
Fuel cells have a higher thermodynamic efficiency than octane. The following table gives some information on a direct methanol fuel cell.
Determine the thermodynamic efficiency of a methanol fuel cell operating at 0.576 V.
Use sections 1 and 2 of the data booklet.
-
18M.3.hl.TZ2.16c.i:
Calculate the relative rate of effusion of 235UF6(g) to 238UF6(g) using sections 1 and 6 of the data booklet.
-
18M.3.hl.TZ2.16c.ii:
Explain, based on molecular structure and bonding, why diffusion or centrifuging can be used for enrichment of UF6 but not UO2.
-
18M.3.hl.TZ2.18a:
Draw the Lewis (electron dot) structure for an appropriate doping element in the box in the centre identifying the type of semiconductor formed.
-
18M.3.hl.TZ2.18b.i:
State the feature of the molecules responsible for the absorption of light.
-
18M.3.hl.TZ2.18b.ii:
Outline why complex B absorbs light of longer wavelength than complex A.
-
18M.3.sl.TZ1.9a:
Identify one naturally occurring greenhouse gas, other than carbon dioxide or water vapour, and its natural source.
-
18M.3.sl.TZ1.9b:
Formulate an equation that shows how aqueous carbon dioxide produces hydrogen ions, H+(aq).
-
18M.3.sl.TZ1.9c:
The concentrations of oxygen and nitrogen in the atmosphere are much greater than those of greenhouse gases. Outline why these gases do not absorb infrared radiation.
-
18M.3.sl.TZ1.10a:
Identify an element, other than carbon and hydrogen, found at significant concentrations in fossil fuels.
-
18M.3.sl.TZ1.10b:
Petroleum contains many hydrocarbons. Explain how these are separated by fractional distillation.
-
18M.3.sl.TZ1.10c.i:
Determine the specific energy and energy density of petrol (gasoline), using data from sections 1 and 13 of the data booklet. Assume petrol is pure octane, C8H18. Octane: molar mass = 114.26 g mol−1, density = 0.703 g cm−3.
-
18M.3.sl.TZ1.10c.ii:
Outline why the energy available from an engine will be less than these theoretical values.
-
18M.3.sl.TZ1.11a.i:
Outline the major technical problem affecting the direct use of vegetable oils as fuels in internal combustion engines and the chemical conversion that has overcome this.
-
18M.3.sl.TZ1.11a.ii:
State the formula of a fuel that might be produced from the vegetable oil whose formula is shown.
-
18M.3.sl.TZ1.11b:
Outline why biofuels are considered more environmentally friendly, even though they produce more carbon dioxide per kJ of energy than petroleum based fuels.
-
18M.3.sl.TZ1.12a.ii:
Explain how 235U fission results in a chain reaction, including the concept of critical mass.
-
18M.3.sl.TZ1.12b:
Suggest one reason why there is opposition to the increased use of nuclear fission reactors.
-
18M.3.sl.TZ2.10a:
Outline two reasons why oil is one of the world’s significant energy sources.
-
18M.3.sl.TZ2.10b.i:
Formulate an equation for the cracking of C16H34 into two products with eight carbon atoms each.
-
18M.3.sl.TZ2.10b.ii:
Identify, giving a reason, which product in (b)(i) could be used in petrol (gasoline).
-
18M.3.sl.TZ2.10c.i:
Outline how higher octane fuels help eliminate “knocking” in engines.
-
18M.3.sl.TZ2.10c.ii:
The performance of hydrocarbons as fuels can be improved by catalytic reforming.
Outline how catalytic reforming increases a fuel’s octane rating.
-
18M.3.sl.TZ2.11a:
Explain the molecular mechanism by which carbon dioxide acts as a greenhouse gas.
-
18M.3.sl.TZ2.11b:
Discuss the significance of two greenhouse gases, other than carbon dioxide, in causing global warming or climate change.
-
18M.3.sl.TZ2.12a:
Calculate the thermal efficiency of a steam turbine supplied with steam at 540°C and using a river as the choice of sink at 23 °C.
-
18M.3.sl.TZ2.12b:
Power plants generating electricity by burning coal to boil water operate at approximately 35% efficiency.
State what this means and suggest why it is lower than the thermal efficiency.
-
18M.3.sl.TZ2.13a:
Compare and contrast the process of nuclear fusion with nuclear fission.
-
18M.3.sl.TZ2.13b:
Dubnium-261 has a half-life of 27 seconds and rutherfordium-261 has a half-life of 81 seconds.
Estimate what fraction of the dubnium-261 isotope remains in the same amount of time that of rutherfordium-261 decays.
-
18M.3.sl.TZ2.14a:
Deduce the equation for the transesterification reaction of pentyl octanoate, C7H15COOC5H11, with methanol.
-
18M.3.sl.TZ2.14b:
Outline why the ester product of this reaction is a better diesel fuel than pentyl octanoate.
- 18N.3.sl.TZ0.9a: Explain fusion reactions with reference to binding energy.
- 18N.3.sl.TZ0.9b.i: Outline why the term breeder is used for the reactors.
- 18N.3.sl.TZ0.9b.ii: Deduce the fission reaction when 239Pu is bombarded with a neutron to produce 133Xe and 103Zr.
-
18N.3.sl.TZ0.9c:
Nuclear disasters release radioactive caesium into the atmosphere, which presents serious health risks.
Cs-137 has a half-life of 30 years.
Calculate the percentage of Cs-137 remaining in the atmosphere after 240 years.
-
18N.3.sl.TZ0.10a:
Formulate equation(s) for the conversion of coal and steam to methane.
-
18N.3.sl.TZ0.10b.i:
Calculate the specific energy, in kJ g−1, of methane.
-
18N.3.sl.TZ0.10b.ii:
Comment on the specific energies of hydrogen and methane.
-
18N.3.sl.TZ0.10c:
Calculate the mass, in kg, of carbon dioxide produced by the complete combustion of 72.0 dm3 octane, C8H18.
Density of C8H18 = 703 g dm−3
C8H18 (l) + 12.5O2 (g) → 8CO2 (g) + 9H2O (g)
- 18N.3.sl.TZ0.11a: Suggest another advantage and one disadvantage of solar energy.
- 18N.3.sl.TZ0.11b: Light can be absorbed by chlorophyll and other pigments. Consider molecules A and B represented...
- 18N.3.sl.TZ0.11c.i: State a physical property of vegetable oils that makes them very difficult to use as fuel in...
- 18N.3.sl.TZ0.11c.ii: Describe how vegetable oils can be converted to a more suitable fuel.
- 18N.3.sl.TZ0.11d: Contrast the importance of carbon dioxide and methane as greenhouse gases.
-
18N.3.sl.TZ0.11e:
Explain, using an equation, the effect of increased carbon dioxide in the atmosphere on the pH of lake water.
- 18N.3.hl.TZ0.12a: Explain fusion reactions with reference to binding energy.
- 18N.3.hl.TZ0.12b.i: Outline why the term breeder is used for the reactors.
- 18N.3.hl.TZ0.12b.ii: Deduce the fission reaction when 239Pu is bombarded with a neutron to produce 133Xe and 103Zr.
-
18N.3.hl.TZ0.12c:
Nuclear disasters release radioactive caesium into the atmosphere, which presents serious health risks.
Cs-137 has a half-life of 30 years.
Calculate the percentage of Cs-137 remaining in the atmosphere after 240 years.
-
18N.3.hl.TZ0.12d.i:
Deduce a Lewis (electron dot) structure of the superoxide, O2–, free radical.
- 18N.3.hl.TZ0.12d.ii: Explain why free radicals are harmful to living cells.
-
18N.3.hl.TZ0.13a:
Formulate equation(s) for the conversion of coal and steam to methane.
-
18N.3.hl.TZ0.13b:
Comment on the specific energies of hydrogen and methane.
-
18N.3.hl.TZ0.13c:
Calculate the mass, in kg, of carbon dioxide produced by the complete combustion of 72.0 dm3 octane, C8H18.
Density of C8H18 = 703 g dm−3
C8H18 (l) + 12.5O2 (g) → 8CO2 (g) + 9H2O (g)
- 18N.3.hl.TZ0.14a: Suggest another advantage and one disadvantage of solar energy.
- 18N.3.hl.TZ0.14b.i: State a physical property of vegetable oils that makes them very difficult to use as fuel in...
- 18N.3.hl.TZ0.14b.ii: Describe how vegetable oils can be converted to a more suitable fuel.
- 18N.3.hl.TZ0.14c: Contrast the importance of carbon dioxide and methane as greenhouse gases.
-
18N.3.hl.TZ0.14d:
Explain, using an equation, the effect of increased carbon dioxide in the atmosphere on the pH of lake water.
- 18N.3.hl.TZ0.15a: Outline how a rechargeable battery differs from a primary cell.
-
18N.3.hl.TZ0.15b:
Formulate half-equations for the reactions at the anode (negative electrode) and cathode (positive electrode) during discharge of a lithium-ion battery.
-
18N.3.hl.TZ0.15c:
A voltaic cell consists of a nickel electrode in 1.0 mol dm−3 Ni2+ (aq) solution and a cadmium electrode in a Cd2+ (aq) solution of unknown concentration.
Cd (s) + Ni2+ (aq) → Cd2+ (aq) + Ni (s) EΘcell = 0.14 V
Determine the concentration of the Cd2+ (aq) solution if the cell voltage, E, is 0.19 V at 298 K. Use section 1 of the data booklet.
- 18N.3.hl.TZ0.15d.i: Identify the structural feature of the dye that allows the conversion of solar energy into...
- 18N.3.hl.TZ0.15d.ii: Outline the effect of sunlight on the dye in the solar cell.
- 18N.3.hl.TZ0.15d.iii: State the purpose of TiO2.
-
18N.3.hl.TZ0.15d.iv:
Deduce the reduction half-equation at the cathode.
-
19M.3.hl.TZ1.15a:
Calculate the specific energy of methane, in MJ kg−1, using sections 1, 6 and 13 of the data booklet.
-
19M.3.hl.TZ1.15b(i):
Calculate the maximum electric energy output, in MJ, which can be obtained from burning 1.00 kg of methane by using your answer from (a).
-
19M.3.hl.TZ1.15b(ii):
Hydroelectric power plants produced 16% of the world’s energy in 2015, down from 21% in 1971.
Suggest why hydroelectric power production has a higher efficiency than the other sources given in (b) and why its relative use has decreased despite the high efficiency.
Reason for higher efficiency:
Reason for decreased use:
-
19M.3.hl.TZ1.15c(i):
Methane can also be obtained by fractional distillation of crude oil.
[Source: Image used with kind permission of science-resources.co.uk]
Draw a circle on the diagram to show where the methane fraction is withdrawn.
-
19M.3.hl.TZ1.15c(ii):
List the following products, which are also obtained by fractional distillation, according to decreasing volatility: asphalt, diesel, gasoline, lubricating motor oil.
-
19M.3.hl.TZ1.15d(i):
Explain how methane absorbs infrared (IR) radiation by referring to its molecular geometry and dipole moment.
-
19M.3.hl.TZ1.15d(ii):
Compare methane’s atmospheric abundance and greenhouse effect to that of carbon dioxide.
-
19M.3.hl.TZ1.16a(i):
Write the nuclear equation for this fission reaction.
-
19M.3.hl.TZ1.16a(ii):
Outline why the reaction releases energy.
-
19M.3.hl.TZ1.16a(iii):
The masses of the particles involved in this fission reaction are shown below.
Mass of neutron = 1.00867 amu
Mass of U-235 nucleus = 234.99346 amu
Mass of Ba-144 nucleus = 143.89223 amu
Mass of Kr-89 nucleus = 88.89788 amuDetermine the energy released, in J, when one uranium-235 nucleus undergoes fission. Use this data and information from sections 1 and 2 of the data booklet.
-
19M.3.hl.TZ1.16b:
The critical mass for weapons-grade uranium can be as small as 15 kg. Outline what is meant by critical mass by referring to the equation in (a)(i).
-
19M.3.hl.TZ1.16c:
The daughter product, 89Kr, has a half-life of 3.15 min.
Calculate the time required, in minutes, for its radioactivity to fall to 10% of its initial value, using section 1 of the data booklet.
-
19M.3.hl.TZ1.17a:
Ethanol has a Research Octane Number (RON) of 108.6.
Outline how higher octane fuels affect engine performance.
-
19M.3.hl.TZ1.17b(i):
Ethanol can be used in a direct-ethanol fuel cell (DEFC) as illustrated by the flow chart.
Deduce the half-equations occurring at electrodes A and B.
Electrode A:
Electrode B:
-
19M.3.hl.TZ1.17b(ii):
State the name and function of X in the diagram in (b)(i).
Name:
Function:
-
19M.3.hl.TZ1.17b(iii):
Outline why aqueous ethanol, rather than pure ethanol, is used in a DEFC.
-
19M.3.hl.TZ1.17c:
Biodiesel containing ethanol can be made from renewable resources.
Suggest one environmental disadvantage of producing biodiesel from renewable resources.
-
19M.3.hl.TZ1.18a:
Some solar cells use photovoltaic semi-conductors. Compare, giving reasons, the electrical conductivity of metals and semi-conductors as temperature increases.
-
19M.3.hl.TZ1.18b:
Suggest one advantage of a dye-sensitized solar cell (DSSC) over a silicon based photovoltaic cell.
-
19M.3.hl.TZ2.14:
The regular rise and fall of sea levels, known as tides, can be used to generate energy.
State one advantage, other than limiting greenhouse gas emissions, and one disadvantage of tidal power.
Advantage:
Disadvantage:
-
19M.3.hl.TZ2.15a:
Crude oil can be converted into fuels by fractional distillation and cracking.
Contrast these two processes.
-
19M.3.hl.TZ2.15b:
Determine the specific energy, in kJ g−1, and energy density, in kJ cm−3, of hexane, C6H14. Give both answers to three significant figures.
Hexane: Mr = 86.2; ΔHc = −4163 kJ mol−1; density = 0.660 g cm−3
Specific energy:
Energy density:
-
19M.3.hl.TZ2.15c:
Hydrocarbons need treatment to increase their octane number to prevent pre-ignition (knocking) before they can be used in internal combustion engines.
Describe how this is carried out and the molecular changes that take place.
-
19M.3.hl.TZ2.16a(i):
Determine the other product of the fission reaction of plutonium-239.
-
19M.3.hl.TZ2.16a(ii):
Outline the concept of critical mass with respect to fission reactions.
-
19M.3.hl.TZ2.16a(iii):
Outline one advantage of allowing all countries access to the technology to generate electricity by nuclear fission.
-
19M.3.hl.TZ2.16b:
State one advantage of using fusion reactions rather than fission to generate electrical power.
-
19M.3.hl.TZ2.16c:
Outline how the energy of a fission reaction can be calculated.
-
19M.3.hl.TZ2.16d:
Calculate the half-life of an isotope whose mass falls from 5.0 × 10−5 g to 4.0 × 10−5 g in 31.4 s, using section 1 of the data booklet.
-
19M.3.hl.TZ2.17:
This question is about biofuel.
Evaluate the use of biodiesel in place of diesel from crude oil.
-
19M.3.hl.TZ2.18a:
Describe the effect of infrared (IR) radiation on carbon dioxide molecules.
-
19M.3.hl.TZ2.18b:
Outline one approach to controlling industrial emissions of carbon dioxide.
-
19M.3.hl.TZ2.19a:
Outline how a microbial fuel cell produces an electric current from glucose.
C6H12O6 (aq) + 6O2 (g) → 6CO2 (g) + 6H2O (l)
-
19M.3.hl.TZ2.19b:
The cell potential for the spontaneous reaction when standard magnesium and silver half-cells are connected is +3.17 V.
Determine the cell potential at 298 K when:
[Mg2+] = 0.0500 mol dm−3
[Ag+] = 0.100 mol dm−3Use sections 1 and 2 of the data booklet.
- 19M.3.hl.TZ2.19c: Outline one difference between a primary and a secondary cell.
-
19M.3.hl.TZ2.20a:
Sketch graphs to show the general effect of increasing temperature on the electrical conductivity of semiconductors and metals on the axes below.
-
19M.3.hl.TZ2.20b:
Explain the function of dyes in a dye-sensitized solar cell (DSSC).
-
19M.3.sl.TZ1.11a:
Calculate the specific energy of methane, in MJ kg−1, using sections 1, 6 and 13 of the data booklet.
-
19M.3.sl.TZ1.11b(i):
Calculate the maximum electric energy output, in MJ, which can be obtained from burning 1.00 kg of methane by using your answer from (a).
-
19M.3.sl.TZ1.11b(ii):
Hydroelectric power plants produced 16 % of the world’s energy in 2015, down from 21 % in 1971.
Suggest why hydroelectric power production has a higher efficiency than the other sources given in (b) and why its relative use has decreased despite the high efficiency.
Reason for higher efficiency:
Reason for decreased use:
-
19M.3.sl.TZ1.11c(i):
Methane can also be obtained by fractional distillation of crude oil.
Draw a circle on the diagram to show where the methane fraction is withdrawn.
-
19M.3.sl.TZ1.11c(ii):
List the following products, which are also obtained by fractional distillation, according to decreasing volatility: asphalt, diesel, gasoline, lubricating motor oil.
-
19M.3.sl.TZ1.11d(i):
Explain how methane absorbs infrared (IR) radiation by referring to its molecular geometry and dipole moment.
-
19M.3.sl.TZ1.11d(ii):
Compare methane’s atmospheric abundance and greenhouse effect to that of carbon dioxide.
-
19M.3.sl.TZ1.12a(i):
Write the nuclear equation for this fission reaction.
-
19M.3.sl.TZ1.12a(ii):
Outline why the reaction releases energy.
-
19M.3.sl.TZ1.12b:
The critical mass for weapons-grade uranium can be as small as 15 kg. Outline what is meant by critical mass by referring to the equation in (a)(i).
-
19M.3.sl.TZ1.12c:
The daughter product, 89Kr, has a half-life of 3.15 min.
Calculate the time required, in minutes, for the mass of 89Kr to fall to 6.25 % of its initial value.
-
19M.3.sl.TZ1.13a:
Ethanol has a Research Octane Number (RON) of 108.6.
Outline how higher octane fuels affect engine performance.
-
19M.3.sl.TZ1.13b:
Show that, for combustion of equal masses of fuel, ethanol (Mr = 46 g mol−1) has a lower carbon footprint than octane (Mr = 114 g mol−1).
-
19M.3.sl.TZ1.13c:
Biodiesel containing ethanol can be made from renewable resources.
Suggest one environmental disadvantage of producing biodiesel from renewable resources.
-
19M.3.sl.TZ2.9:
The regular rise and fall of sea levels, known as tides, can be used to generate energy.
State one advantage, other than limiting greenhouse gas emissions, and one disadvantage of tidal power.
Advantage:
Disadvantage:
-
19M.3.sl.TZ2.10a:
Crude oil can be converted into fuels by fractional distillation and cracking.
Contrast these two processes.
-
19M.3.sl.TZ2.10b:
Determine the specific energy, in kJ g−1, and energy density, in kJ cm−3, of hexane, C6H14. Give both answers to three significant figures.
Hexane: Mr = 86.2; ΔHc = −4163 kJ mol−1; density = 0.660 g cm−3
Specific energy:
Energy density:
-
19M.3.sl.TZ2.10c:
Hydrocarbons need treatment to increase their octane number to prevent pre-ignition (knocking) before they can be used in internal combustion engines.
Describe how this is carried out and the molecular changes that take place.
-
19M.3.sl.TZ2.11a(i):
Determine the other product of the fission reaction of plutonium-239.
-
19M.3.sl.TZ2.11a(ii):
Outline the concept of critical mass with respect to fission reactions.
-
19M.3.sl.TZ2.11a(iii):
Outline one advantage of allowing all countries access to the technology to generate electricity by nuclear fission.
-
19M.3.sl.TZ2.11b:
State one advantage of using fusion reactions rather than fission to generate electrical power.
-
19M.3.sl.TZ2.11c:
90Sr, a common product of fission, has a half-life of 28.8 years.
Determine the number of years for the activity of a sample of 90Sr to fall to one eighth () of its initial value.
-
19M.3.sl.TZ2.12a:
The structure of chlorophyll is given in section 35 of the data booklet.
State the feature of the chlorophyll molecule that enables it to absorb light in the visible spectrum.
-
19M.3.sl.TZ2.12b:
Evaluate the use of biodiesel in place of diesel from crude oil.
Strength:
Limitation:
-
19M.3.sl.TZ2.13a:
State one greenhouse gas, other than carbon dioxide.
-
19M.3.sl.TZ2.13b:
Describe the effect of infrared (IR) radiation on carbon dioxide molecules.
-
19M.3.sl.TZ2.13c:
Outline one approach to controlling industrial emissions of carbon dioxide.
-
19N.3.sl.TZ0.11a:
Discuss the data.
-
19N.3.sl.TZ0.11b:
In a natural gas power station, 1.00 tonne of natural gas produces 2.41 × 104 MJ of electricity.
Calculate the percentage efficiency of the power station.
1 tonne = 1000 kg
Specific energy of natural gas used = 55.4 MJ kg−1 -
19N.3.hl.TZ0.16a:
Discuss the data.
- 19N.3.hl.TZ0.16b: Outline what is meant by the degradation of energy.
- 19N.3.sl.TZ0.12a: Suggest why a high-octane number fuel is preferable.
- 19N.3.sl.TZ0.12b(i): Reforming reactions are used to increase the octane number of a hydrocarbon fuel. Suggest the...
- 19N.3.sl.TZ0.12b(ii): The 1H NMR spectrum of one of the products has four signals. The integration trace shows a ratio...
-
19N.3.sl.TZ0.13a(i):
State the nuclear equation for the fusion reaction.
- 19N.3.sl.TZ0.13a(ii): Explain why fusion is an exothermic process.
-
19N.3.sl.TZ0.13b:
Beryllium-8 is a radioactive isotope with a half-life of 6.70 × 10−17 s.
Calculate the mass of beryllium-8 remaining after 2.01 × 10−16 s from a sample initially containing 4.00 g of beryllium-8.
-
19N.3.hl.TZ0.18a(i):
State the nuclear equation for the fusion reaction.
- 19N.3.hl.TZ0.18a(ii): Explain why fusion is an exothermic process.
-
19N.3.hl.TZ0.18a(iii):
Calculate the heat energy released, in J, by the fusion reaction producing one atom of carbon-12. Use section 2 of the data booklet and E = mc2.
-
19N.3.hl.TZ0.18b:
Beryllium-8 is a radioactive isotope with a half-life of 6.70 × 10−17 s.
Calculate the mass of beryllium-8 remaining after 2.01 × 10−16 s from a sample initially containing 4.00 g of beryllium-8.
-
19N.3.sl.TZ0.14a:
Write the equation for the complete combustion of ethanol.
-
19N.3.sl.TZ0.14b:
Outline the evidence that relates global warming to increasing concentrations of greenhouse gases in the atmosphere.
-
19N.3.sl.TZ0.14c:
Explain, including a suitable equation, why biofuels are considered to be carbon neutral.
- 19N.3.sl.TZ0.14d: State the type of reaction that occurs when ethanol reacts with vegetable oil to form biodiesel.
-
19N.3.hl.TZ0.20a:
Deduce the half-equations for the reactions occurring at the electrodes.
Anode (negative electrode):Cathode (positive electrode):
-
19N.3.hl.TZ0.20b(i):
Calculate the cell potential, Eθ, in V, using section 24 of the data booklet.
-
19N.3.hl.TZ0.20b(ii):
Suggest how PEM fuel cells can be used to produce a larger voltage than that calculated in (b)(i).
- 19N.3.hl.TZ0.20c: Suggest an advantage of the PEM fuel cell over the lead-acid battery for use in cars.
- 19N.3.hl.TZ0.20d(i): Outline the functions of the dye, TiO2 and the electrolyte in the operation of the...
- 19N.3.hl.TZ0.20d(ii): Suggest an advantage of the DSSC over silicon-based photovoltaic cells.
-
20N.3.sl.TZ0.9a:
Calculate the energy released, in , from the complete combustion of of ethanol.
- 20N.3.sl.TZ0.9b: State a class of organic compounds found in gasoline.
-
20N.3.sl.TZ0.9c:
Outline the advantages and disadvantages of using biodiesel instead of gasoline as fuel for a car. Exclude any discussion of cost.
-
20N.3.sl.TZ0.9d:
A mixture of gasoline and ethanol is often used as a fuel. Suggest an advantage of such a mixture over the use of pure gasoline. Exclude any discussion of cost.
- 20N.3.sl.TZ0.9e: Contrast the molecular structures of biodiesel and the vegetable oil from which it is formed.
-
20N.3.sl.TZ0.9f(i):
When combusted, all three fuels can release carbon dioxide, a greenhouse gas, as well as particulates. Contrast how carbon dioxide and particulates interact with sunlight.
-
20N.3.sl.TZ0.9f(ii):
Methane is another greenhouse gas. Contrast the reasons why methane and carbon dioxide are considered significant greenhouse gases.
-
20N.3.sl.TZ0.10b:
The half-life of 238U is years. Calculate the mass of 238U that remains after has decayed for years.
- 20N.3.sl.TZ0.10c: Outline a health risk produced by exposure to radioactive decay.
-
20N.3.sl.TZ0.10d:
Deduce the nuclear equation for the decay of uranium-238 to thorium-234.
- 20N.3.sl.TZ0.10e: Thorium-234 has a higher binding energy per nucleon than uranium-238. Outline what is meant by...
-
20N.3.hl.TZ0.11a:
Calculate the energy released, in , from the complete combustion of of ethanol.
- 20N.3.hl.TZ0.11b: State a class of organic compounds found in gasoline.
-
20N.3.hl.TZ0.11c:
Outline the advantages and disadvantages of using biodiesel instead of gasoline as fuel for a car. Exclude any discussion of cost.
- 20N.3.hl.TZ0.11d: A mixture of gasoline and ethanol is often used as a fuel. Suggest an advantage of such a mixture...
-
20N.3.hl.TZ0.11e(i):
When combusted, all three fuels can release carbon dioxide, a greenhouse gas, as well as particulates. Contrast how carbon dioxide and particulates interact with sunlight.
-
20N.3.hl.TZ0.11e(ii):
Methane is another greenhouse gas. Contrast the reasons why methane and carbon dioxide are considered significant greenhouse gases.
-
20N.3.hl.TZ0.11e(iv):
Determine the relative rate of effusion of methane () to carbon dioxide (), under the same conditions of temperature and pressure. Use section 1 of the data booklet.
-
20N.3.hl.TZ0.12b:
The half-life of 238U is years. Calculate the mass of 238U that remains after has decayed for years.
- 20N.3.hl.TZ0.12c: Outline a health risk produced by exposure to radioactive decay.
-
20N.3.hl.TZ0.12d:
Deduce the nuclear equation for the decay of uranium-238 to thorium-234.
- 20N.3.hl.TZ0.12e: Thorium-234 has a higher binding energy per nucleon than uranium-238. Outline what is meant by...
-
20N.3.hl.TZ0.12f:
Determine the nuclear binding energy, in , of using sections 2 and 4 of the data booklet.
The mass of the nucleus is .
-
20N.3.hl.TZ0.14a:
Doping of silicon increases the conductivity in semiconductors.
Describe the doping in p-type and n-type semiconductors.
- 20N.3.hl.TZ0.14b: Doping of silicon increases the conductivity in semiconductors. Explain how doping improves the...
- 23M.1.HL.TZ2.4: What is the correct ground state electron orbital configuration for 2s22p2?
- 23M.1.SL.TZ2.5: What is the correct ground state electron orbital configuration for 2s22p2?
- 23M.1.SL.TZ1.15: Which diagram shows the enthalpy change for dissolving solid, X, in water, if the temperature...
-
19M.3.hl.TZ1.15a:
Calculate the specific energy of methane, in MJ kg−1, using sections 1, 6 and 13 of the data booklet.
-
19M.3.hl.TZ1.15b(i):
Calculate the maximum electric energy output, in MJ, which can be obtained from burning 1.00 kg of methane by using your answer from (a).
-
19M.3.hl.TZ1.15b(ii):
Hydroelectric power plants produced 16% of the world’s energy in 2015, down from 21% in 1971.
Suggest why hydroelectric power production has a higher efficiency than the other sources given in (b) and why its relative use has decreased despite the high efficiency.
Reason for higher efficiency:
Reason for decreased use:
-
19M.3.hl.TZ1.15c(i):
Methane can also be obtained by fractional distillation of crude oil.
[Source: Image used with kind permission of science-resources.co.uk]
Draw a circle on the diagram to show where the methane fraction is withdrawn.
-
19M.3.hl.TZ1.15c(ii):
List the following products, which are also obtained by fractional distillation, according to decreasing volatility: asphalt, diesel, gasoline, lubricating motor oil.
-
19M.3.hl.TZ1.15d(i):
Explain how methane absorbs infrared (IR) radiation by referring to its molecular geometry and dipole moment.
-
19M.3.hl.TZ1.15d(ii):
Compare methane’s atmospheric abundance and greenhouse effect to that of carbon dioxide.
-
19M.3.hl.TZ1.a:
Calculate the specific energy of methane, in MJ kg−1, using sections 1, 6 and 13 of the data booklet.
-
19M.3.hl.TZ1.b(i):
Calculate the maximum electric energy output, in MJ, which can be obtained from burning 1.00 kg of methane by using your answer from (a).
-
19M.3.hl.TZ1.b(ii):
Hydroelectric power plants produced 16% of the world’s energy in 2015, down from 21% in 1971.
Suggest why hydroelectric power production has a higher efficiency than the other sources given in (b) and why its relative use has decreased despite the high efficiency.
Reason for higher efficiency:
Reason for decreased use:
-
19M.3.hl.TZ1.c(i):
Methane can also be obtained by fractional distillation of crude oil.
[Source: Image used with kind permission of science-resources.co.uk]
Draw a circle on the diagram to show where the methane fraction is withdrawn.
-
19M.3.hl.TZ1.c(ii):
List the following products, which are also obtained by fractional distillation, according to decreasing volatility: asphalt, diesel, gasoline, lubricating motor oil.
-
19M.3.hl.TZ1.d(i):
Explain how methane absorbs infrared (IR) radiation by referring to its molecular geometry and dipole moment.
-
19M.3.hl.TZ1.d(ii):
Compare methane’s atmospheric abundance and greenhouse effect to that of carbon dioxide.
-
19M.3.hl.TZ1.16a(i):
Write the nuclear equation for this fission reaction.
-
19M.3.hl.TZ1.16a(ii):
Outline why the reaction releases energy.
-
19M.3.hl.TZ1.16a(iii):
The masses of the particles involved in this fission reaction are shown below.
Mass of neutron = 1.00867 amu
Mass of U-235 nucleus = 234.99346 amu
Mass of Ba-144 nucleus = 143.89223 amu
Mass of Kr-89 nucleus = 88.89788 amuDetermine the energy released, in J, when one uranium-235 nucleus undergoes fission. Use this data and information from sections 1 and 2 of the data booklet.
-
19M.3.hl.TZ1.16b:
The critical mass for weapons-grade uranium can be as small as 15 kg. Outline what is meant by critical mass by referring to the equation in (a)(i).
-
19M.3.hl.TZ1.16c:
The daughter product, 89Kr, has a half-life of 3.15 min.
Calculate the time required, in minutes, for its radioactivity to fall to 10% of its initial value, using section 1 of the data booklet.
-
19M.3.hl.TZ1.a(i):
Write the nuclear equation for this fission reaction.
-
19M.3.hl.TZ1.a(ii):
Outline why the reaction releases energy.
-
19M.3.hl.TZ1.a(iii):
The masses of the particles involved in this fission reaction are shown below.
Mass of neutron = 1.00867 amu
Mass of U-235 nucleus = 234.99346 amu
Mass of Ba-144 nucleus = 143.89223 amu
Mass of Kr-89 nucleus = 88.89788 amuDetermine the energy released, in J, when one uranium-235 nucleus undergoes fission. Use this data and information from sections 1 and 2 of the data booklet.
-
19M.3.hl.TZ1.b:
The critical mass for weapons-grade uranium can be as small as 15 kg. Outline what is meant by critical mass by referring to the equation in (a)(i).
-
19M.3.hl.TZ1.c:
The daughter product, 89Kr, has a half-life of 3.15 min.
Calculate the time required, in minutes, for its radioactivity to fall to 10% of its initial value, using section 1 of the data booklet.
-
19M.3.hl.TZ1.17a:
Ethanol has a Research Octane Number (RON) of 108.6.
Outline how higher octane fuels affect engine performance.
-
19M.3.hl.TZ1.17b(i):
Ethanol can be used in a direct-ethanol fuel cell (DEFC) as illustrated by the flow chart.
Deduce the half-equations occurring at electrodes A and B.
Electrode A:
Electrode B:
-
19M.3.hl.TZ1.17b(ii):
State the name and function of X in the diagram in (b)(i).
Name:
Function:
-
19M.3.hl.TZ1.17b(iii):
Outline why aqueous ethanol, rather than pure ethanol, is used in a DEFC.
-
19M.3.hl.TZ1.17c:
Biodiesel containing ethanol can be made from renewable resources.
Suggest one environmental disadvantage of producing biodiesel from renewable resources.
-
19M.3.hl.TZ1.a:
Ethanol has a Research Octane Number (RON) of 108.6.
Outline how higher octane fuels affect engine performance.
-
19M.3.hl.TZ1.b(i):
Ethanol can be used in a direct-ethanol fuel cell (DEFC) as illustrated by the flow chart.
Deduce the half-equations occurring at electrodes A and B.
Electrode A:
Electrode B:
-
19M.3.hl.TZ1.b(ii):
State the name and function of X in the diagram in (b)(i).
Name:
Function:
-
19M.3.hl.TZ1.b(iii):
Outline why aqueous ethanol, rather than pure ethanol, is used in a DEFC.
-
19M.3.hl.TZ1.c:
Biodiesel containing ethanol can be made from renewable resources.
Suggest one environmental disadvantage of producing biodiesel from renewable resources.
-
19M.3.hl.TZ1.18a:
Some solar cells use photovoltaic semi-conductors. Compare, giving reasons, the electrical conductivity of metals and semi-conductors as temperature increases.
-
19M.3.hl.TZ1.18b:
Suggest one advantage of a dye-sensitized solar cell (DSSC) over a silicon based photovoltaic cell.
-
19M.3.hl.TZ1.a:
Some solar cells use photovoltaic semi-conductors. Compare, giving reasons, the electrical conductivity of metals and semi-conductors as temperature increases.
-
19M.3.hl.TZ1.b:
Suggest one advantage of a dye-sensitized solar cell (DSSC) over a silicon based photovoltaic cell.
-
19M.3.hl.TZ2.14:
The regular rise and fall of sea levels, known as tides, can be used to generate energy.
State one advantage, other than limiting greenhouse gas emissions, and one disadvantage of tidal power.
Advantage:
Disadvantage:
-
19M.3.hl.TZ2.15a:
Crude oil can be converted into fuels by fractional distillation and cracking.
Contrast these two processes.
-
19M.3.hl.TZ2.15b:
Determine the specific energy, in kJ g−1, and energy density, in kJ cm−3, of hexane, C6H14. Give both answers to three significant figures.
Hexane: Mr = 86.2; ΔHc = −4163 kJ mol−1; density = 0.660 g cm−3
Specific energy:
Energy density:
-
19M.3.hl.TZ2.15c:
Hydrocarbons need treatment to increase their octane number to prevent pre-ignition (knocking) before they can be used in internal combustion engines.
Describe how this is carried out and the molecular changes that take place.
-
19M.3.hl.TZ2.a:
Crude oil can be converted into fuels by fractional distillation and cracking.
Contrast these two processes.
-
19M.3.hl.TZ2.b:
Determine the specific energy, in kJ g−1, and energy density, in kJ cm−3, of hexane, C6H14. Give both answers to three significant figures.
Hexane: Mr = 86.2; ΔHc = −4163 kJ mol−1; density = 0.660 g cm−3
Specific energy:
Energy density:
-
19M.3.hl.TZ2.c:
Hydrocarbons need treatment to increase their octane number to prevent pre-ignition (knocking) before they can be used in internal combustion engines.
Describe how this is carried out and the molecular changes that take place.
-
19M.3.hl.TZ2.16a(i):
Determine the other product of the fission reaction of plutonium-239.
-
19M.3.hl.TZ2.16a(ii):
Outline the concept of critical mass with respect to fission reactions.
-
19M.3.hl.TZ2.16a(iii):
Outline one advantage of allowing all countries access to the technology to generate electricity by nuclear fission.
-
19M.3.hl.TZ2.16b:
State one advantage of using fusion reactions rather than fission to generate electrical power.
-
19M.3.hl.TZ2.16c:
Outline how the energy of a fission reaction can be calculated.
-
19M.3.hl.TZ2.16d:
Calculate the half-life of an isotope whose mass falls from 5.0 × 10−5 g to 4.0 × 10−5 g in 31.4 s, using section 1 of the data booklet.
-
19M.3.hl.TZ2.16d:
Calculate the half-life of an isotope whose mass falls from 5.0 × 10−5 g to 4.0 × 10−5 g in 31.4 s, using section 1 of the data booklet.
-
19M.3.hl.TZ2.a(i):
Determine the other product of the fission reaction of plutonium-239.
-
19M.3.hl.TZ2.a(ii):
Outline the concept of critical mass with respect to fission reactions.
-
19M.3.hl.TZ2.a(iii):
Outline one advantage of allowing all countries access to the technology to generate electricity by nuclear fission.
-
19M.3.hl.TZ2.b:
State one advantage of using fusion reactions rather than fission to generate electrical power.
-
19M.3.hl.TZ2.c:
Outline how the energy of a fission reaction can be calculated.
-
19M.3.hl.TZ2.d:
Calculate the half-life of an isotope whose mass falls from 5.0 × 10−5 g to 4.0 × 10−5 g in 31.4 s, using section 1 of the data booklet.
-
19M.3.hl.TZ2.17:
This question is about biofuel.
Evaluate the use of biodiesel in place of diesel from crude oil.
-
19M.3.hl.TZ2.18a:
Describe the effect of infrared (IR) radiation on carbon dioxide molecules.
-
19M.3.hl.TZ2.18b:
Outline one approach to controlling industrial emissions of carbon dioxide.
-
19M.3.hl.TZ2.a:
Describe the effect of infrared (IR) radiation on carbon dioxide molecules.
-
19M.3.hl.TZ2.b:
Outline one approach to controlling industrial emissions of carbon dioxide.
-
19M.3.hl.TZ2.19a:
Outline how a microbial fuel cell produces an electric current from glucose.
C6H12O6 (aq) + 6O2 (g) → 6CO2 (g) + 6H2O (l)
-
19M.3.hl.TZ2.19b:
The cell potential for the spontaneous reaction when standard magnesium and silver half-cells are connected is +3.17 V.
Determine the cell potential at 298 K when:
[Mg2+] = 0.0500 mol dm−3
[Ag+] = 0.100 mol dm−3Use sections 1 and 2 of the data booklet.
- 19M.3.hl.TZ2.19c: Outline one difference between a primary and a secondary cell.
-
19M.3.hl.TZ2.a:
Outline how a microbial fuel cell produces an electric current from glucose.
C6H12O6 (aq) + 6O2 (g) → 6CO2 (g) + 6H2O (l)
-
19M.3.hl.TZ2.b:
The cell potential for the spontaneous reaction when standard magnesium and silver half-cells are connected is +3.17 V.
Determine the cell potential at 298 K when:
[Mg2+] = 0.0500 mol dm−3
[Ag+] = 0.100 mol dm−3Use sections 1 and 2 of the data booklet.
- 19M.3.hl.TZ2.c: Outline one difference between a primary and a secondary cell.
-
19M.3.hl.TZ2.20a:
Sketch graphs to show the general effect of increasing temperature on the electrical conductivity of semiconductors and metals on the axes below.
-
19M.3.hl.TZ2.20b:
Explain the function of dyes in a dye-sensitized solar cell (DSSC).
-
19M.3.hl.TZ2.a:
Sketch graphs to show the general effect of increasing temperature on the electrical conductivity of semiconductors and metals on the axes below.
-
19M.3.hl.TZ2.b:
Explain the function of dyes in a dye-sensitized solar cell (DSSC).
-
19M.3.sl.TZ1.11a:
Calculate the specific energy of methane, in MJ kg−1, using sections 1, 6 and 13 of the data booklet.
-
19M.3.sl.TZ1.11b(i):
Calculate the maximum electric energy output, in MJ, which can be obtained from burning 1.00 kg of methane by using your answer from (a).
-
19M.3.sl.TZ1.11b(ii):
Hydroelectric power plants produced 16 % of the world’s energy in 2015, down from 21 % in 1971.
Suggest why hydroelectric power production has a higher efficiency than the other sources given in (b) and why its relative use has decreased despite the high efficiency.
Reason for higher efficiency:
Reason for decreased use:
-
19M.3.sl.TZ1.11c(i):
Methane can also be obtained by fractional distillation of crude oil.
Draw a circle on the diagram to show where the methane fraction is withdrawn.
-
19M.3.sl.TZ1.11c(ii):
List the following products, which are also obtained by fractional distillation, according to decreasing volatility: asphalt, diesel, gasoline, lubricating motor oil.
-
19M.3.sl.TZ1.11d(i):
Explain how methane absorbs infrared (IR) radiation by referring to its molecular geometry and dipole moment.
-
19M.3.sl.TZ1.11d(ii):
Compare methane’s atmospheric abundance and greenhouse effect to that of carbon dioxide.
-
19M.3.sl.TZ1.a:
Calculate the specific energy of methane, in MJ kg−1, using sections 1, 6 and 13 of the data booklet.
-
19M.3.sl.TZ1.b(i):
Calculate the maximum electric energy output, in MJ, which can be obtained from burning 1.00 kg of methane by using your answer from (a).
-
19M.3.sl.TZ1.b(ii):
Hydroelectric power plants produced 16 % of the world’s energy in 2015, down from 21 % in 1971.
Suggest why hydroelectric power production has a higher efficiency than the other sources given in (b) and why its relative use has decreased despite the high efficiency.
Reason for higher efficiency:
Reason for decreased use:
-
19M.3.sl.TZ1.c(i):
Methane can also be obtained by fractional distillation of crude oil.
Draw a circle on the diagram to show where the methane fraction is withdrawn.
-
19M.3.sl.TZ1.c(ii):
List the following products, which are also obtained by fractional distillation, according to decreasing volatility: asphalt, diesel, gasoline, lubricating motor oil.
-
19M.3.sl.TZ1.d(i):
Explain how methane absorbs infrared (IR) radiation by referring to its molecular geometry and dipole moment.
-
19M.3.sl.TZ1.d(ii):
Compare methane’s atmospheric abundance and greenhouse effect to that of carbon dioxide.
-
19M.3.sl.TZ1.12a(i):
Write the nuclear equation for this fission reaction.
-
19M.3.sl.TZ1.12a(ii):
Outline why the reaction releases energy.
-
19M.3.sl.TZ1.12b:
The critical mass for weapons-grade uranium can be as small as 15 kg. Outline what is meant by critical mass by referring to the equation in (a)(i).
-
19M.3.sl.TZ1.12c:
The daughter product, 89Kr, has a half-life of 3.15 min.
Calculate the time required, in minutes, for the mass of 89Kr to fall to 6.25 % of its initial value.
-
19M.3.sl.TZ1.a(i):
Write the nuclear equation for this fission reaction.
-
19M.3.sl.TZ1.a(ii):
Outline why the reaction releases energy.
-
19M.3.sl.TZ1.b:
The critical mass for weapons-grade uranium can be as small as 15 kg. Outline what is meant by critical mass by referring to the equation in (a)(i).
-
19M.3.sl.TZ1.c:
The daughter product, 89Kr, has a half-life of 3.15 min.
Calculate the time required, in minutes, for the mass of 89Kr to fall to 6.25 % of its initial value.
-
19M.3.sl.TZ1.13a:
Ethanol has a Research Octane Number (RON) of 108.6.
Outline how higher octane fuels affect engine performance.
-
19M.3.sl.TZ1.13b:
Show that, for combustion of equal masses of fuel, ethanol (Mr = 46 g mol−1) has a lower carbon footprint than octane (Mr = 114 g mol−1).
-
19M.3.sl.TZ1.13c:
Biodiesel containing ethanol can be made from renewable resources.
Suggest one environmental disadvantage of producing biodiesel from renewable resources.
-
19M.3.sl.TZ1.a:
Ethanol has a Research Octane Number (RON) of 108.6.
Outline how higher octane fuels affect engine performance.
-
19M.3.sl.TZ1.b:
Show that, for combustion of equal masses of fuel, ethanol (Mr = 46 g mol−1) has a lower carbon footprint than octane (Mr = 114 g mol−1).
-
19M.3.sl.TZ1.c:
Biodiesel containing ethanol can be made from renewable resources.
Suggest one environmental disadvantage of producing biodiesel from renewable resources.
-
19M.3.sl.TZ2.9:
The regular rise and fall of sea levels, known as tides, can be used to generate energy.
State one advantage, other than limiting greenhouse gas emissions, and one disadvantage of tidal power.
Advantage:
Disadvantage:
-
19M.3.sl.TZ2.10a:
Crude oil can be converted into fuels by fractional distillation and cracking.
Contrast these two processes.
-
19M.3.sl.TZ2.10b:
Determine the specific energy, in kJ g−1, and energy density, in kJ cm−3, of hexane, C6H14. Give both answers to three significant figures.
Hexane: Mr = 86.2; ΔHc = −4163 kJ mol−1; density = 0.660 g cm−3
Specific energy:
Energy density:
-
19M.3.sl.TZ2.10c:
Hydrocarbons need treatment to increase their octane number to prevent pre-ignition (knocking) before they can be used in internal combustion engines.
Describe how this is carried out and the molecular changes that take place.
-
19M.3.sl.TZ2.a:
Crude oil can be converted into fuels by fractional distillation and cracking.
Contrast these two processes.
-
19M.3.sl.TZ2.b:
Determine the specific energy, in kJ g−1, and energy density, in kJ cm−3, of hexane, C6H14. Give both answers to three significant figures.
Hexane: Mr = 86.2; ΔHc = −4163 kJ mol−1; density = 0.660 g cm−3
Specific energy:
Energy density:
-
19M.3.sl.TZ2.c:
Hydrocarbons need treatment to increase their octane number to prevent pre-ignition (knocking) before they can be used in internal combustion engines.
Describe how this is carried out and the molecular changes that take place.
-
19M.3.sl.TZ2.11a(i):
Determine the other product of the fission reaction of plutonium-239.
-
19M.3.sl.TZ2.11a(ii):
Outline the concept of critical mass with respect to fission reactions.
-
19M.3.sl.TZ2.11a(iii):
Outline one advantage of allowing all countries access to the technology to generate electricity by nuclear fission.
-
19M.3.sl.TZ2.11b:
State one advantage of using fusion reactions rather than fission to generate electrical power.
-
19M.3.sl.TZ2.11c:
90Sr, a common product of fission, has a half-life of 28.8 years.
Determine the number of years for the activity of a sample of 90Sr to fall to one eighth () of its initial value.
-
19M.3.sl.TZ2.a(i):
Determine the other product of the fission reaction of plutonium-239.
-
19M.3.sl.TZ2.a(ii):
Outline the concept of critical mass with respect to fission reactions.
-
19M.3.sl.TZ2.a(iii):
Outline one advantage of allowing all countries access to the technology to generate electricity by nuclear fission.
-
19M.3.sl.TZ2.b:
State one advantage of using fusion reactions rather than fission to generate electrical power.
-
19M.3.sl.TZ2.c:
90Sr, a common product of fission, has a half-life of 28.8 years.
Determine the number of years for the activity of a sample of 90Sr to fall to one eighth () of its initial value.
-
19M.3.sl.TZ2.12a:
The structure of chlorophyll is given in section 35 of the data booklet.
State the feature of the chlorophyll molecule that enables it to absorb light in the visible spectrum.
-
19M.3.sl.TZ2.12b:
Evaluate the use of biodiesel in place of diesel from crude oil.
Strength:
Limitation:
-
19M.3.sl.TZ2.a:
The structure of chlorophyll is given in section 35 of the data booklet.
State the feature of the chlorophyll molecule that enables it to absorb light in the visible spectrum.
-
19M.3.sl.TZ2.b:
Evaluate the use of biodiesel in place of diesel from crude oil.
Strength:
Limitation:
-
19M.3.sl.TZ2.13a:
State one greenhouse gas, other than carbon dioxide.
-
19M.3.sl.TZ2.13b:
Describe the effect of infrared (IR) radiation on carbon dioxide molecules.
-
19M.3.sl.TZ2.13c:
Outline one approach to controlling industrial emissions of carbon dioxide.
-
19M.3.sl.TZ2.a:
State one greenhouse gas, other than carbon dioxide.
-
19M.3.sl.TZ2.b:
Describe the effect of infrared (IR) radiation on carbon dioxide molecules.
-
19M.3.sl.TZ2.c:
Outline one approach to controlling industrial emissions of carbon dioxide.
-
19N.3.sl.TZ0.11a:
Discuss the data.
-
19N.3.sl.TZ0.11b:
In a natural gas power station, 1.00 tonne of natural gas produces 2.41 × 104 MJ of electricity.
Calculate the percentage efficiency of the power station.
1 tonne = 1000 kg
Specific energy of natural gas used = 55.4 MJ kg−1 -
19N.3.sl.TZ0.a:
Discuss the data.
-
19N.3.sl.TZ0.b:
In a natural gas power station, 1.00 tonne of natural gas produces 2.41 × 104 MJ of electricity.
Calculate the percentage efficiency of the power station.
1 tonne = 1000 kg
Specific energy of natural gas used = 55.4 MJ kg−1 -
19N.3.hl.TZ0.16a:
Discuss the data.
- 19N.3.hl.TZ0.16b: Outline what is meant by the degradation of energy.
-
19N.3.hl.TZ0.a:
Discuss the data.
- 19N.3.hl.TZ0.b: Outline what is meant by the degradation of energy.
- 19N.3.sl.TZ0.12a: Suggest why a high-octane number fuel is preferable.
- 19N.3.sl.TZ0.12b(i): Reforming reactions are used to increase the octane number of a hydrocarbon fuel. Suggest the...
- 19N.3.sl.TZ0.12b(ii): The 1H NMR spectrum of one of the products has four signals. The integration trace shows a ratio...
- 19N.3.sl.TZ0.a: Suggest why a high-octane number fuel is preferable.
- 19N.3.sl.TZ0.b(i): Reforming reactions are used to increase the octane number of a hydrocarbon fuel. Suggest the...
- 19N.3.sl.TZ0.b(ii): The 1H NMR spectrum of one of the products has four signals. The integration trace shows a ratio...
-
19N.3.sl.TZ0.13a(i):
State the nuclear equation for the fusion reaction.
- 19N.3.sl.TZ0.13a(ii): Explain why fusion is an exothermic process.
-
19N.3.sl.TZ0.13b:
Beryllium-8 is a radioactive isotope with a half-life of 6.70 × 10−17 s.
Calculate the mass of beryllium-8 remaining after 2.01 × 10−16 s from a sample initially containing 4.00 g of beryllium-8.
-
19N.3.sl.TZ0.a(i):
State the nuclear equation for the fusion reaction.
- 19N.3.sl.TZ0.a(ii): Explain why fusion is an exothermic process.
-
19N.3.sl.TZ0.b:
Beryllium-8 is a radioactive isotope with a half-life of 6.70 × 10−17 s.
Calculate the mass of beryllium-8 remaining after 2.01 × 10−16 s from a sample initially containing 4.00 g of beryllium-8.
-
19N.3.hl.TZ0.18a(i):
State the nuclear equation for the fusion reaction.
- 19N.3.hl.TZ0.18a(ii): Explain why fusion is an exothermic process.
-
19N.3.hl.TZ0.18a(iii):
Calculate the heat energy released, in J, by the fusion reaction producing one atom of carbon-12. Use section 2 of the data booklet and E = mc2.
-
19N.3.hl.TZ0.18b:
Beryllium-8 is a radioactive isotope with a half-life of 6.70 × 10−17 s.
Calculate the mass of beryllium-8 remaining after 2.01 × 10−16 s from a sample initially containing 4.00 g of beryllium-8.
-
19N.3.hl.TZ0.a(i):
State the nuclear equation for the fusion reaction.
- 19N.3.hl.TZ0.a(ii): Explain why fusion is an exothermic process.
-
19N.3.hl.TZ0.a(iii):
Calculate the heat energy released, in J, by the fusion reaction producing one atom of carbon-12. Use section 2 of the data booklet and E = mc2.
-
19N.3.hl.TZ0.b:
Beryllium-8 is a radioactive isotope with a half-life of 6.70 × 10−17 s.
Calculate the mass of beryllium-8 remaining after 2.01 × 10−16 s from a sample initially containing 4.00 g of beryllium-8.
-
19N.3.sl.TZ0.14a:
Write the equation for the complete combustion of ethanol.
-
19N.3.sl.TZ0.14b:
Outline the evidence that relates global warming to increasing concentrations of greenhouse gases in the atmosphere.
-
19N.3.sl.TZ0.14c:
Explain, including a suitable equation, why biofuels are considered to be carbon neutral.
- 19N.3.sl.TZ0.14d: State the type of reaction that occurs when ethanol reacts with vegetable oil to form biodiesel.
-
19N.3.sl.TZ0.a:
Write the equation for the complete combustion of ethanol.
-
19N.3.sl.TZ0.b:
Outline the evidence that relates global warming to increasing concentrations of greenhouse gases in the atmosphere.
-
19N.3.sl.TZ0.c:
Explain, including a suitable equation, why biofuels are considered to be carbon neutral.
- 19N.3.sl.TZ0.d: State the type of reaction that occurs when ethanol reacts with vegetable oil to form biodiesel.
-
19N.3.hl.TZ0.20a:
Deduce the half-equations for the reactions occurring at the electrodes.
Anode (negative electrode):Cathode (positive electrode):
-
19N.3.hl.TZ0.20b(i):
Calculate the cell potential, Eθ, in V, using section 24 of the data booklet.
-
19N.3.hl.TZ0.20b(ii):
Suggest how PEM fuel cells can be used to produce a larger voltage than that calculated in (b)(i).
- 19N.3.hl.TZ0.20c: Suggest an advantage of the PEM fuel cell over the lead-acid battery for use in cars.
- 19N.3.hl.TZ0.20d(i): Outline the functions of the dye, TiO2 and the electrolyte in the operation of the...
- 19N.3.hl.TZ0.20d(ii): Suggest an advantage of the DSSC over silicon-based photovoltaic cells.
-
19N.3.hl.TZ0.a:
Deduce the half-equations for the reactions occurring at the electrodes.
Anode (negative electrode):Cathode (positive electrode):
-
19N.3.hl.TZ0.b(i):
Calculate the cell potential, Eθ, in V, using section 24 of the data booklet.
-
19N.3.hl.TZ0.b(ii):
Suggest how PEM fuel cells can be used to produce a larger voltage than that calculated in (b)(i).
- 19N.3.hl.TZ0.c: Suggest an advantage of the PEM fuel cell over the lead-acid battery for use in cars.
- 19N.3.hl.TZ0.d(i): Outline the functions of the dye, TiO2 and the electrolyte in the operation of the...
- 19N.3.hl.TZ0.d(ii): Suggest an advantage of the DSSC over silicon-based photovoltaic cells.
-
20N.3.sl.TZ0.9a:
Calculate the energy released, in , from the complete combustion of of ethanol.
- 20N.3.sl.TZ0.9b: State a class of organic compounds found in gasoline.
-
20N.3.sl.TZ0.9c:
Outline the advantages and disadvantages of using biodiesel instead of gasoline as fuel for a car. Exclude any discussion of cost.
-
20N.3.sl.TZ0.9d:
A mixture of gasoline and ethanol is often used as a fuel. Suggest an advantage of such a mixture over the use of pure gasoline. Exclude any discussion of cost.
- 20N.3.sl.TZ0.9e: Contrast the molecular structures of biodiesel and the vegetable oil from which it is formed.
-
20N.3.sl.TZ0.9f(i):
When combusted, all three fuels can release carbon dioxide, a greenhouse gas, as well as particulates. Contrast how carbon dioxide and particulates interact with sunlight.
-
20N.3.sl.TZ0.9f(ii):
Methane is another greenhouse gas. Contrast the reasons why methane and carbon dioxide are considered significant greenhouse gases.
-
20N.3.sl.TZ0.a:
Calculate the energy released, in , from the complete combustion of of ethanol.
- 20N.3.sl.TZ0.b: State a class of organic compounds found in gasoline.
-
20N.3.sl.TZ0.c:
Outline the advantages and disadvantages of using biodiesel instead of gasoline as fuel for a car. Exclude any discussion of cost.
-
20N.3.sl.TZ0.d:
A mixture of gasoline and ethanol is often used as a fuel. Suggest an advantage of such a mixture over the use of pure gasoline. Exclude any discussion of cost.
- 20N.3.sl.TZ0.e: Contrast the molecular structures of biodiesel and the vegetable oil from which it is formed.
-
20N.3.sl.TZ0.f(i):
When combusted, all three fuels can release carbon dioxide, a greenhouse gas, as well as particulates. Contrast how carbon dioxide and particulates interact with sunlight.
-
20N.3.sl.TZ0.f(ii):
Methane is another greenhouse gas. Contrast the reasons why methane and carbon dioxide are considered significant greenhouse gases.
-
20N.3.sl.TZ0.10b:
The half-life of 238U is years. Calculate the mass of 238U that remains after has decayed for years.
- 20N.3.sl.TZ0.10c: Outline a health risk produced by exposure to radioactive decay.
-
20N.3.sl.TZ0.10d:
Deduce the nuclear equation for the decay of uranium-238 to thorium-234.
- 20N.3.sl.TZ0.10e: Thorium-234 has a higher binding energy per nucleon than uranium-238. Outline what is meant by...
-
20N.3.sl.TZ0.b:
The half-life of 238U is years. Calculate the mass of 238U that remains after has decayed for years.
- 20N.3.sl.TZ0.c: Outline a health risk produced by exposure to radioactive decay.
-
20N.3.sl.TZ0.d:
Deduce the nuclear equation for the decay of uranium-238 to thorium-234.
- 20N.3.sl.TZ0.e: Thorium-234 has a higher binding energy per nucleon than uranium-238. Outline what is meant by...
-
20N.3.hl.TZ0.11a:
Calculate the energy released, in , from the complete combustion of of ethanol.
- 20N.3.hl.TZ0.11b: State a class of organic compounds found in gasoline.
-
20N.3.hl.TZ0.11c:
Outline the advantages and disadvantages of using biodiesel instead of gasoline as fuel for a car. Exclude any discussion of cost.
- 20N.3.hl.TZ0.11d: A mixture of gasoline and ethanol is often used as a fuel. Suggest an advantage of such a mixture...
-
20N.3.hl.TZ0.11e(i):
When combusted, all three fuels can release carbon dioxide, a greenhouse gas, as well as particulates. Contrast how carbon dioxide and particulates interact with sunlight.
-
20N.3.hl.TZ0.11e(ii):
Methane is another greenhouse gas. Contrast the reasons why methane and carbon dioxide are considered significant greenhouse gases.
-
20N.3.hl.TZ0.11e(iv):
Determine the relative rate of effusion of methane () to carbon dioxide (), under the same conditions of temperature and pressure. Use section 1 of the data booklet.
-
20N.3.hl.TZ0.a:
Calculate the energy released, in , from the complete combustion of of ethanol.
- 20N.3.hl.TZ0.b: State a class of organic compounds found in gasoline.
-
20N.3.hl.TZ0.c:
Outline the advantages and disadvantages of using biodiesel instead of gasoline as fuel for a car. Exclude any discussion of cost.
- 20N.3.hl.TZ0.d: A mixture of gasoline and ethanol is often used as a fuel. Suggest an advantage of such a mixture...
-
20N.3.hl.TZ0.e(i):
When combusted, all three fuels can release carbon dioxide, a greenhouse gas, as well as particulates. Contrast how carbon dioxide and particulates interact with sunlight.
-
20N.3.hl.TZ0.e(ii):
Methane is another greenhouse gas. Contrast the reasons why methane and carbon dioxide are considered significant greenhouse gases.
-
20N.3.hl.TZ0.e(iv):
Determine the relative rate of effusion of methane () to carbon dioxide (), under the same conditions of temperature and pressure. Use section 1 of the data booklet.
-
20N.3.hl.TZ0.12b:
The half-life of 238U is years. Calculate the mass of 238U that remains after has decayed for years.
- 20N.3.hl.TZ0.12c: Outline a health risk produced by exposure to radioactive decay.
-
20N.3.hl.TZ0.12d:
Deduce the nuclear equation for the decay of uranium-238 to thorium-234.
- 20N.3.hl.TZ0.12e: Thorium-234 has a higher binding energy per nucleon than uranium-238. Outline what is meant by...
-
20N.3.hl.TZ0.12f:
Determine the nuclear binding energy, in , of using sections 2 and 4 of the data booklet.
The mass of the nucleus is .
-
20N.3.hl.TZ0.b:
The half-life of 238U is years. Calculate the mass of 238U that remains after has decayed for years.
- 20N.3.hl.TZ0.c: Outline a health risk produced by exposure to radioactive decay.
-
20N.3.hl.TZ0.d:
Deduce the nuclear equation for the decay of uranium-238 to thorium-234.
- 20N.3.hl.TZ0.e: Thorium-234 has a higher binding energy per nucleon than uranium-238. Outline what is meant by...
-
20N.3.hl.TZ0.f:
Determine the nuclear binding energy, in , of using sections 2 and 4 of the data booklet.
The mass of the nucleus is .
-
20N.3.hl.TZ0.14a:
Doping of silicon increases the conductivity in semiconductors.
Describe the doping in p-type and n-type semiconductors.
- 20N.3.hl.TZ0.14b: Doping of silicon increases the conductivity in semiconductors. Explain how doping improves the...
-
20N.3.hl.TZ0.a:
Doping of silicon increases the conductivity in semiconductors.
Describe the doping in p-type and n-type semiconductors.
- 20N.3.hl.TZ0.b: Doping of silicon increases the conductivity in semiconductors. Explain how doping improves the...
-
17N.3.sl.TZ0.12a:
Calculate the specific energy of octane, C8H18, in kJ kg–1 using sections 1, 6 and 13 of the data booklet.
-
17N.3.sl.TZ0.12b:
A typical wood has a specific energy of 17 × 103 kJ kg–1. Comment on the usefulness of octane and wood for powering a moving vehicle, using your answer to (a).
If you did not work out an answer for (a), use 45 × 103 kJ kg–1 but this is not the correct answer.
-
17N.3.sl.TZ0.12c:
State the name of one renewable source of energy other than wood.
-
17N.3.sl.TZ0.a:
Calculate the specific energy of octane, C8H18, in kJ kg–1 using sections 1, 6 and 13 of the data booklet.
-
17N.3.sl.TZ0.b:
A typical wood has a specific energy of 17 × 103 kJ kg–1. Comment on the usefulness of octane and wood for powering a moving vehicle, using your answer to (a).
If you did not work out an answer for (a), use 45 × 103 kJ kg–1 but this is not the correct answer.
-
17N.3.sl.TZ0.c:
State the name of one renewable source of energy other than wood.
-
17N.3.sl.TZ0.13a:
“Knocking” in an automobile (car) engine can be prevented by increasing the octane number of the fuel. Explain, including an equation with structural formulas, how heptane, C7H16, could be chemically converted to increase its octane number.
-
17N.3.sl.TZ0.13b:
Many like to refer to our “carbon footprint”. Outline one difficulty in quantifying such a concept.
-
17N.3.sl.TZ0.13c:
Climate change or global warming is a consequence of increased levels of carbon dioxide in the atmosphere. Explain how the greenhouse effect warms the surface of the earth.
- 17N.3.sl.TZ0.13d: Outline how water and carbon dioxide absorb infrared radiation.
-
17N.3.sl.TZ0.a:
“Knocking” in an automobile (car) engine can be prevented by increasing the octane number of the fuel. Explain, including an equation with structural formulas, how heptane, C7H16, could be chemically converted to increase its octane number.
-
17N.3.sl.TZ0.b:
Many like to refer to our “carbon footprint”. Outline one difficulty in quantifying such a concept.
-
17N.3.sl.TZ0.c:
Climate change or global warming is a consequence of increased levels of carbon dioxide in the atmosphere. Explain how the greenhouse effect warms the surface of the earth.
- 17N.3.sl.TZ0.d: Outline how water and carbon dioxide absorb infrared radiation.
-
17N.3.sl.TZ0.14a.i:
Compare and contrast fission and fusion in terms of binding energy and the types of nuclei involved.
-
17N.3.sl.TZ0.14a.ii:
Suggest two advantages that fusion has over fission.
-
17N.3.sl.TZ0.14b:
The amount of 228Ac in a sample decreases to one eighth of its original value in about 18 hours due to β-decay. Estimate the half-life of 228Ac.
-
17N.3.sl.TZ0.a.i:
Compare and contrast fission and fusion in terms of binding energy and the types of nuclei involved.
-
17N.3.sl.TZ0.a.ii:
Suggest two advantages that fusion has over fission.
-
17N.3.sl.TZ0.b:
The amount of 228Ac in a sample decreases to one eighth of its original value in about 18 hours due to β-decay. Estimate the half-life of 228Ac.
- 17N.3.sl.TZ0.15a: State the structural feature of chlorophyll that enables it to absorb visible light.
- 17N.3.sl.TZ0.15b: Vegetable oils are too viscous for use as liquid fuels. Describe, using an equation, how a...
- 17N.3.sl.TZ0.a: State the structural feature of chlorophyll that enables it to absorb visible light.
- 17N.3.sl.TZ0.b: Vegetable oils are too viscous for use as liquid fuels. Describe, using an equation, how a...
-
17N.3.hl.TZ0.18c.i:
Calculate the loss in mass, in kg, and the energy released, in J, when 0.00100 mol of 228Ac decays, each atom losing an electron. Use section 2 of the data booklet and E = mc2.
228Ac → + 228Th
-
17N.3.hl.TZ0.18c.ii:
Determine the energy released, in J, by 0.00100 mol of 228Ac over the course of 18 hours.
- 17N.3.hl.TZ0.18d: Outline how nuclear ionising radiation can damage DNA and enzymes in living cells.
-
17N.3.hl.TZ0.c.i:
Calculate the loss in mass, in kg, and the energy released, in J, when 0.00100 mol of 228Ac decays, each atom losing an electron. Use section 2 of the data booklet and E = mc2.
228Ac → + 228Th
-
17N.3.hl.TZ0.c.ii:
Determine the energy released, in J, by 0.00100 mol of 228Ac over the course of 18 hours.
- 17N.3.hl.TZ0.d: Outline how nuclear ionising radiation can damage DNA and enzymes in living cells.
-
17N.3.hl.TZ0.19b:
The natural absorption of light by chlorophyll has been copied by those developing dye-sensitized solar cells (DSSCs). Outline how a DSSC works.
-
17N.3.hl.TZ0.b:
The natural absorption of light by chlorophyll has been copied by those developing dye-sensitized solar cells (DSSCs). Outline how a DSSC works.
-
17N.3.hl.TZ0.20a:
Deduce the half-equations and the overall equation for the reactions taking place in a direct methanol fuel cell (DMFC) under acidic conditions.
-
17N.3.hl.TZ0.20b:
Outline one advantage and one disadvantage of the methanol cell (DMFC) compared with a hydrogen-oxygen fuel cell.
-
17N.3.hl.TZ0.a:
Deduce the half-equations and the overall equation for the reactions taking place in a direct methanol fuel cell (DMFC) under acidic conditions.
-
17N.3.hl.TZ0.b:
Outline one advantage and one disadvantage of the methanol cell (DMFC) compared with a hydrogen-oxygen fuel cell.
-
18M.3.hl.TZ1.13a:
Outline the major technical problem affecting the direct use of vegetable oils as fuels in internal combustion engines and the chemical conversion that has overcome this.
-
18M.3.hl.TZ1.13b:
State the formula of a fuel that might be produced from the vegetable oil whose formula is shown.
-
18M.3.hl.TZ1.a:
Outline the major technical problem affecting the direct use of vegetable oils as fuels in internal combustion engines and the chemical conversion that has overcome this.
-
18M.3.hl.TZ1.b:
State the formula of a fuel that might be produced from the vegetable oil whose formula is shown.
-
18M.3.hl.TZ1.14a.i:
Complete the half-equations on the diagram and identify the species moving between the electrodes.
-
18M.3.hl.TZ1.14a.ii:
State the factor that limits the maximum current that can be drawn from this cell and how electrodes are designed to maximize the current.
-
18M.3.hl.TZ1.14b.ii:
Explain how the proportion of 235U in natural uranium is increased.
-
18M.3.hl.TZ1.a.i:
Complete the half-equations on the diagram and identify the species moving between the electrodes.
-
18M.3.hl.TZ1.a.ii:
State the factor that limits the maximum current that can be drawn from this cell and how electrodes are designed to maximize the current.
-
18M.3.hl.TZ1.b.ii:
Explain how the proportion of 235U in natural uranium is increased.
-
18M.3.hl.TZ1.15a:
Early photovoltaic cells were based on silicon containing traces of other elements. State the type of semiconductor produced by doping silicon with indium, In, giving a reason that refers to its electronic structure.
-
18M.3.hl.TZ1.15b:
Dye-sensitized solar cells, DSSCs, use a dye to absorb the sunlight. State two advantages that DSSCs have over traditional silicon based photovoltaic cells.
-
18M.3.hl.TZ1.15c:
The structure of two dyes used in DSSCs are shown.
Predict, giving a reason, which dye will absorb light of longer wavelength.
-
18M.3.hl.TZ1.a:
Early photovoltaic cells were based on silicon containing traces of other elements. State the type of semiconductor produced by doping silicon with indium, In, giving a reason that refers to its electronic structure.
-
18M.3.hl.TZ1.b:
Dye-sensitized solar cells, DSSCs, use a dye to absorb the sunlight. State two advantages that DSSCs have over traditional silicon based photovoltaic cells.
-
18M.3.hl.TZ1.c:
The structure of two dyes used in DSSCs are shown.
Predict, giving a reason, which dye will absorb light of longer wavelength.
- 23M.1.HL.TZ2.4: What is the correct ground state electron orbital configuration for 2s22p2?
- 23M.1.SL.TZ2.5: What is the correct ground state electron orbital configuration for 2s22p2?
- 23M.1.SL.TZ1.15: Which diagram shows the enthalpy change for dissolving solid, X, in water, if the temperature...
-
18M.3.hl.TZ2.13c:
Fuel cells have a higher thermodynamic efficiency than octane. The following table gives some information on a direct methanol fuel cell.
Determine the thermodynamic efficiency of a methanol fuel cell operating at 0.576 V.
Use sections 1 and 2 of the data booklet.
-
18M.3.hl.TZ2.c:
Fuel cells have a higher thermodynamic efficiency than octane. The following table gives some information on a direct methanol fuel cell.
Determine the thermodynamic efficiency of a methanol fuel cell operating at 0.576 V.
Use sections 1 and 2 of the data booklet.
-
18M.3.hl.TZ2.16c.i:
Calculate the relative rate of effusion of 235UF6(g) to 238UF6(g) using sections 1 and 6 of the data booklet.
-
18M.3.hl.TZ2.16c.ii:
Explain, based on molecular structure and bonding, why diffusion or centrifuging can be used for enrichment of UF6 but not UO2.
-
18M.3.hl.TZ2.c.i:
Calculate the relative rate of effusion of 235UF6(g) to 238UF6(g) using sections 1 and 6 of the data booklet.
-
18M.3.hl.TZ2.c.ii:
Explain, based on molecular structure and bonding, why diffusion or centrifuging can be used for enrichment of UF6 but not UO2.
-
18M.3.hl.TZ2.18a:
Draw the Lewis (electron dot) structure for an appropriate doping element in the box in the centre identifying the type of semiconductor formed.
-
18M.3.hl.TZ2.18b.i:
State the feature of the molecules responsible for the absorption of light.
-
18M.3.hl.TZ2.18b.ii:
Outline why complex B absorbs light of longer wavelength than complex A.
-
18M.3.hl.TZ2.a:
Draw the Lewis (electron dot) structure for an appropriate doping element in the box in the centre identifying the type of semiconductor formed.
-
18M.3.hl.TZ2.b.i:
State the feature of the molecules responsible for the absorption of light.
-
18M.3.hl.TZ2.b.ii:
Outline why complex B absorbs light of longer wavelength than complex A.
-
18M.3.sl.TZ1.9a:
Identify one naturally occurring greenhouse gas, other than carbon dioxide or water vapour, and its natural source.
-
18M.3.sl.TZ1.9b:
Formulate an equation that shows how aqueous carbon dioxide produces hydrogen ions, H+(aq).
-
18M.3.sl.TZ1.9c:
The concentrations of oxygen and nitrogen in the atmosphere are much greater than those of greenhouse gases. Outline why these gases do not absorb infrared radiation.
-
18M.3.sl.TZ1.a:
Identify one naturally occurring greenhouse gas, other than carbon dioxide or water vapour, and its natural source.
-
18M.3.sl.TZ1.b:
Formulate an equation that shows how aqueous carbon dioxide produces hydrogen ions, H+(aq).
-
18M.3.sl.TZ1.c:
The concentrations of oxygen and nitrogen in the atmosphere are much greater than those of greenhouse gases. Outline why these gases do not absorb infrared radiation.
-
18M.3.sl.TZ1.10a:
Identify an element, other than carbon and hydrogen, found at significant concentrations in fossil fuels.
-
18M.3.sl.TZ1.10b:
Petroleum contains many hydrocarbons. Explain how these are separated by fractional distillation.
-
18M.3.sl.TZ1.10c.i:
Determine the specific energy and energy density of petrol (gasoline), using data from sections 1 and 13 of the data booklet. Assume petrol is pure octane, C8H18. Octane: molar mass = 114.26 g mol−1, density = 0.703 g cm−3.
-
18M.3.sl.TZ1.10c.ii:
Outline why the energy available from an engine will be less than these theoretical values.
-
18M.3.sl.TZ1.a:
Identify an element, other than carbon and hydrogen, found at significant concentrations in fossil fuels.
-
18M.3.sl.TZ1.b:
Petroleum contains many hydrocarbons. Explain how these are separated by fractional distillation.
-
18M.3.sl.TZ1.c.i:
Determine the specific energy and energy density of petrol (gasoline), using data from sections 1 and 13 of the data booklet. Assume petrol is pure octane, C8H18. Octane: molar mass = 114.26 g mol−1, density = 0.703 g cm−3.
-
18M.3.sl.TZ1.c.ii:
Outline why the energy available from an engine will be less than these theoretical values.
-
18M.3.sl.TZ1.11a.i:
Outline the major technical problem affecting the direct use of vegetable oils as fuels in internal combustion engines and the chemical conversion that has overcome this.
-
18M.3.sl.TZ1.11a.ii:
State the formula of a fuel that might be produced from the vegetable oil whose formula is shown.
-
18M.3.sl.TZ1.11b:
Outline why biofuels are considered more environmentally friendly, even though they produce more carbon dioxide per kJ of energy than petroleum based fuels.
-
18M.3.sl.TZ1.a.i:
Outline the major technical problem affecting the direct use of vegetable oils as fuels in internal combustion engines and the chemical conversion that has overcome this.
-
18M.3.sl.TZ1.a.ii:
State the formula of a fuel that might be produced from the vegetable oil whose formula is shown.
-
18M.3.sl.TZ1.b:
Outline why biofuels are considered more environmentally friendly, even though they produce more carbon dioxide per kJ of energy than petroleum based fuels.
-
18M.3.sl.TZ1.12a.ii:
Explain how 235U fission results in a chain reaction, including the concept of critical mass.
-
18M.3.sl.TZ1.12b:
Suggest one reason why there is opposition to the increased use of nuclear fission reactors.
-
18M.3.sl.TZ1.a.ii:
Explain how 235U fission results in a chain reaction, including the concept of critical mass.
-
18M.3.sl.TZ1.b:
Suggest one reason why there is opposition to the increased use of nuclear fission reactors.
-
18M.3.sl.TZ2.10a:
Outline two reasons why oil is one of the world’s significant energy sources.
-
18M.3.sl.TZ2.10b.i:
Formulate an equation for the cracking of C16H34 into two products with eight carbon atoms each.
-
18M.3.sl.TZ2.10b.ii:
Identify, giving a reason, which product in (b)(i) could be used in petrol (gasoline).
-
18M.3.sl.TZ2.10c.i:
Outline how higher octane fuels help eliminate “knocking” in engines.
-
18M.3.sl.TZ2.10c.ii:
The performance of hydrocarbons as fuels can be improved by catalytic reforming.
Outline how catalytic reforming increases a fuel’s octane rating.
-
18M.3.sl.TZ2.a:
Outline two reasons why oil is one of the world’s significant energy sources.
-
18M.3.sl.TZ2.b.i:
Formulate an equation for the cracking of C16H34 into two products with eight carbon atoms each.
-
18M.3.sl.TZ2.b.ii:
Identify, giving a reason, which product in (b)(i) could be used in petrol (gasoline).
-
18M.3.sl.TZ2.c.i:
Outline how higher octane fuels help eliminate “knocking” in engines.
-
18M.3.sl.TZ2.c.ii:
The performance of hydrocarbons as fuels can be improved by catalytic reforming.
Outline how catalytic reforming increases a fuel’s octane rating.
-
18M.3.sl.TZ2.11a:
Explain the molecular mechanism by which carbon dioxide acts as a greenhouse gas.
-
18M.3.sl.TZ2.11b:
Discuss the significance of two greenhouse gases, other than carbon dioxide, in causing global warming or climate change.
-
18M.3.sl.TZ2.a:
Explain the molecular mechanism by which carbon dioxide acts as a greenhouse gas.
-
18M.3.sl.TZ2.b:
Discuss the significance of two greenhouse gases, other than carbon dioxide, in causing global warming or climate change.
-
18M.3.sl.TZ2.12a:
Calculate the thermal efficiency of a steam turbine supplied with steam at 540°C and using a river as the choice of sink at 23 °C.
-
18M.3.sl.TZ2.12b:
Power plants generating electricity by burning coal to boil water operate at approximately 35% efficiency.
State what this means and suggest why it is lower than the thermal efficiency.
-
18M.3.sl.TZ2.a:
Calculate the thermal efficiency of a steam turbine supplied with steam at 540°C and using a river as the choice of sink at 23 °C.
-
18M.3.sl.TZ2.b:
Power plants generating electricity by burning coal to boil water operate at approximately 35% efficiency.
State what this means and suggest why it is lower than the thermal efficiency.
-
18M.3.sl.TZ2.13a:
Compare and contrast the process of nuclear fusion with nuclear fission.
-
18M.3.sl.TZ2.13b:
Dubnium-261 has a half-life of 27 seconds and rutherfordium-261 has a half-life of 81 seconds.
Estimate what fraction of the dubnium-261 isotope remains in the same amount of time that of rutherfordium-261 decays.
-
18M.3.sl.TZ2.a:
Compare and contrast the process of nuclear fusion with nuclear fission.
-
18M.3.sl.TZ2.b:
Dubnium-261 has a half-life of 27 seconds and rutherfordium-261 has a half-life of 81 seconds.
Estimate what fraction of the dubnium-261 isotope remains in the same amount of time that of rutherfordium-261 decays.
-
18M.3.sl.TZ2.14a:
Deduce the equation for the transesterification reaction of pentyl octanoate, C7H15COOC5H11, with methanol.
-
18M.3.sl.TZ2.14b:
Outline why the ester product of this reaction is a better diesel fuel than pentyl octanoate.
-
18M.3.sl.TZ2.a:
Deduce the equation for the transesterification reaction of pentyl octanoate, C7H15COOC5H11, with methanol.
-
18M.3.sl.TZ2.b:
Outline why the ester product of this reaction is a better diesel fuel than pentyl octanoate.
- 18N.3.sl.TZ0.9a: Explain fusion reactions with reference to binding energy.
- 18N.3.sl.TZ0.9b.i: Outline why the term breeder is used for the reactors.
- 18N.3.sl.TZ0.9b.ii: Deduce the fission reaction when 239Pu is bombarded with a neutron to produce 133Xe and 103Zr.
-
18N.3.sl.TZ0.9c:
Nuclear disasters release radioactive caesium into the atmosphere, which presents serious health risks.
Cs-137 has a half-life of 30 years.
Calculate the percentage of Cs-137 remaining in the atmosphere after 240 years.
- 18N.3.sl.TZ0.a: Explain fusion reactions with reference to binding energy.
- 18N.3.sl.TZ0.b.i: Outline why the term breeder is used for the reactors.
- 18N.3.sl.TZ0.b.ii: Deduce the fission reaction when 239Pu is bombarded with a neutron to produce 133Xe and 103Zr.
-
18N.3.sl.TZ0.c:
Nuclear disasters release radioactive caesium into the atmosphere, which presents serious health risks.
Cs-137 has a half-life of 30 years.
Calculate the percentage of Cs-137 remaining in the atmosphere after 240 years.
-
18N.3.sl.TZ0.10a:
Formulate equation(s) for the conversion of coal and steam to methane.
-
18N.3.sl.TZ0.10b.i:
Calculate the specific energy, in kJ g−1, of methane.
-
18N.3.sl.TZ0.10b.ii:
Comment on the specific energies of hydrogen and methane.
-
18N.3.sl.TZ0.10c:
Calculate the mass, in kg, of carbon dioxide produced by the complete combustion of 72.0 dm3 octane, C8H18.
Density of C8H18 = 703 g dm−3
C8H18 (l) + 12.5O2 (g) → 8CO2 (g) + 9H2O (g)
-
18N.3.sl.TZ0.a:
Formulate equation(s) for the conversion of coal and steam to methane.
-
18N.3.sl.TZ0.b.i:
Calculate the specific energy, in kJ g−1, of methane.
-
18N.3.sl.TZ0.b.ii:
Comment on the specific energies of hydrogen and methane.
-
18N.3.sl.TZ0.c:
Calculate the mass, in kg, of carbon dioxide produced by the complete combustion of 72.0 dm3 octane, C8H18.
Density of C8H18 = 703 g dm−3
C8H18 (l) + 12.5O2 (g) → 8CO2 (g) + 9H2O (g)
- 18N.3.sl.TZ0.11a: Suggest another advantage and one disadvantage of solar energy.
- 18N.3.sl.TZ0.11b: Light can be absorbed by chlorophyll and other pigments. Consider molecules A and B represented...
- 18N.3.sl.TZ0.11c.i: State a physical property of vegetable oils that makes them very difficult to use as fuel in...
- 18N.3.sl.TZ0.11c.ii: Describe how vegetable oils can be converted to a more suitable fuel.
- 18N.3.sl.TZ0.11d: Contrast the importance of carbon dioxide and methane as greenhouse gases.
-
18N.3.sl.TZ0.11e:
Explain, using an equation, the effect of increased carbon dioxide in the atmosphere on the pH of lake water.
- 18N.3.sl.TZ0.a: Suggest another advantage and one disadvantage of solar energy.
- 18N.3.sl.TZ0.b: Light can be absorbed by chlorophyll and other pigments. Consider molecules A and B represented...
- 18N.3.sl.TZ0.c.i: State a physical property of vegetable oils that makes them very difficult to use as fuel in...
- 18N.3.sl.TZ0.c.ii: Describe how vegetable oils can be converted to a more suitable fuel.
- 18N.3.sl.TZ0.d: Contrast the importance of carbon dioxide and methane as greenhouse gases.
-
18N.3.sl.TZ0.e:
Explain, using an equation, the effect of increased carbon dioxide in the atmosphere on the pH of lake water.
- 18N.3.hl.TZ0.12a: Explain fusion reactions with reference to binding energy.
- 18N.3.hl.TZ0.12b.i: Outline why the term breeder is used for the reactors.
- 18N.3.hl.TZ0.12b.ii: Deduce the fission reaction when 239Pu is bombarded with a neutron to produce 133Xe and 103Zr.
-
18N.3.hl.TZ0.12c:
Nuclear disasters release radioactive caesium into the atmosphere, which presents serious health risks.
Cs-137 has a half-life of 30 years.
Calculate the percentage of Cs-137 remaining in the atmosphere after 240 years.
-
18N.3.hl.TZ0.12d.i:
Deduce a Lewis (electron dot) structure of the superoxide, O2–, free radical.
- 18N.3.hl.TZ0.12d.ii: Explain why free radicals are harmful to living cells.
- 18N.3.hl.TZ0.a: Explain fusion reactions with reference to binding energy.
- 18N.3.hl.TZ0.b.i: Outline why the term breeder is used for the reactors.
- 18N.3.hl.TZ0.b.ii: Deduce the fission reaction when 239Pu is bombarded with a neutron to produce 133Xe and 103Zr.
-
18N.3.hl.TZ0.c:
Nuclear disasters release radioactive caesium into the atmosphere, which presents serious health risks.
Cs-137 has a half-life of 30 years.
Calculate the percentage of Cs-137 remaining in the atmosphere after 240 years.
-
18N.3.hl.TZ0.d.i:
Deduce a Lewis (electron dot) structure of the superoxide, O2–, free radical.
- 18N.3.hl.TZ0.d.ii: Explain why free radicals are harmful to living cells.
-
18N.3.hl.TZ0.13a:
Formulate equation(s) for the conversion of coal and steam to methane.
-
18N.3.hl.TZ0.13b:
Comment on the specific energies of hydrogen and methane.
-
18N.3.hl.TZ0.13c:
Calculate the mass, in kg, of carbon dioxide produced by the complete combustion of 72.0 dm3 octane, C8H18.
Density of C8H18 = 703 g dm−3
C8H18 (l) + 12.5O2 (g) → 8CO2 (g) + 9H2O (g)
-
18N.3.hl.TZ0.a:
Formulate equation(s) for the conversion of coal and steam to methane.
-
18N.3.hl.TZ0.b:
Comment on the specific energies of hydrogen and methane.
-
18N.3.hl.TZ0.c:
Calculate the mass, in kg, of carbon dioxide produced by the complete combustion of 72.0 dm3 octane, C8H18.
Density of C8H18 = 703 g dm−3
C8H18 (l) + 12.5O2 (g) → 8CO2 (g) + 9H2O (g)
- 18N.3.hl.TZ0.14a: Suggest another advantage and one disadvantage of solar energy.
- 18N.3.hl.TZ0.14b.i: State a physical property of vegetable oils that makes them very difficult to use as fuel in...
- 18N.3.hl.TZ0.14b.ii: Describe how vegetable oils can be converted to a more suitable fuel.
- 18N.3.hl.TZ0.14c: Contrast the importance of carbon dioxide and methane as greenhouse gases.
-
18N.3.hl.TZ0.14d:
Explain, using an equation, the effect of increased carbon dioxide in the atmosphere on the pH of lake water.
- 18N.3.hl.TZ0.a: Suggest another advantage and one disadvantage of solar energy.
- 18N.3.hl.TZ0.b.i: State a physical property of vegetable oils that makes them very difficult to use as fuel in...
- 18N.3.hl.TZ0.b.ii: Describe how vegetable oils can be converted to a more suitable fuel.
- 18N.3.hl.TZ0.c: Contrast the importance of carbon dioxide and methane as greenhouse gases.
-
18N.3.hl.TZ0.d:
Explain, using an equation, the effect of increased carbon dioxide in the atmosphere on the pH of lake water.
- 18N.3.hl.TZ0.15a: Outline how a rechargeable battery differs from a primary cell.
-
18N.3.hl.TZ0.15b:
Formulate half-equations for the reactions at the anode (negative electrode) and cathode (positive electrode) during discharge of a lithium-ion battery.
-
18N.3.hl.TZ0.15c:
A voltaic cell consists of a nickel electrode in 1.0 mol dm−3 Ni2+ (aq) solution and a cadmium electrode in a Cd2+ (aq) solution of unknown concentration.
Cd (s) + Ni2+ (aq) → Cd2+ (aq) + Ni (s) EΘcell = 0.14 V
Determine the concentration of the Cd2+ (aq) solution if the cell voltage, E, is 0.19 V at 298 K. Use section 1 of the data booklet.
- 18N.3.hl.TZ0.15d.i: Identify the structural feature of the dye that allows the conversion of solar energy into...
- 18N.3.hl.TZ0.15d.ii: Outline the effect of sunlight on the dye in the solar cell.
- 18N.3.hl.TZ0.15d.iii: State the purpose of TiO2.
-
18N.3.hl.TZ0.15d.iv:
Deduce the reduction half-equation at the cathode.
- 18N.3.hl.TZ0.a: Outline how a rechargeable battery differs from a primary cell.
-
18N.3.hl.TZ0.b:
Formulate half-equations for the reactions at the anode (negative electrode) and cathode (positive electrode) during discharge of a lithium-ion battery.
-
18N.3.hl.TZ0.c:
A voltaic cell consists of a nickel electrode in 1.0 mol dm−3 Ni2+ (aq) solution and a cadmium electrode in a Cd2+ (aq) solution of unknown concentration.
Cd (s) + Ni2+ (aq) → Cd2+ (aq) + Ni (s) EΘcell = 0.14 V
Determine the concentration of the Cd2+ (aq) solution if the cell voltage, E, is 0.19 V at 298 K. Use section 1 of the data booklet.
- 18N.3.hl.TZ0.d.i: Identify the structural feature of the dye that allows the conversion of solar energy into...
- 18N.3.hl.TZ0.d.ii: Outline the effect of sunlight on the dye in the solar cell.
- 18N.3.hl.TZ0.d.iii: State the purpose of TiO2.
-
18N.3.hl.TZ0.d.iv:
Deduce the reduction half-equation at the cathode.
D: Medicinal chemistry
-
17N.3.sl.TZ0.16:
Radioisotopes are used to diagnose and treat various diseases. Explain the low environmental impact of most medical nuclear waste.
- 17N.3.sl.TZ0.17a: Aspirin is a mild analgesic derived from salicylic acid found in willow bark. Describe how mild...
-
17N.3.sl.TZ0.17b.i:
The strong analgesics morphine and codeine are opiates. Outline how codeine can be synthesized from morphine. The structures of morphine and codeine are in section 37 of the data booklet.
-
17N.3.sl.TZ0.17b.ii:
Explain why opiates are addictive.
-
17N.3.sl.TZ0.18a:
Outline the difference between the therapeutic index in animal studies and the therapeutic index in humans.
- 17N.3.sl.TZ0.18b: State the method of drug administration that gives the maximum bioavailability.
-
17N.3.sl.TZ0.19a:
State the names of two functional groups that both compounds contain, using section 37 of the data booklet.
- 17N.3.sl.TZ0.19b: Explain how oseltamivir and zanamivir can stop the spread of the flu virus in the body.
-
17N.3.sl.TZ0.20a:
Explain how ranitidine (Zantac) reduces stomach acid production.
-
17N.3.sl.TZ0.20b:
The pH is maintained in different fluids in the body by the use of buffers.
Calculate the pH of a buffer solution of 0.0200 mol dm–3 carbonic acid, H2CO3, and 0.400 mol dm–3 sodium hydrogen carbonate, NaHCO3. The pKa of carbonic acid is 6.35.
- 17N.3.sl.TZ0.21: Molecules of antibiotics often contain a beta-lactam ring. Explain the importance of the...
-
17N.3.hl.TZ0.21a:
State a nuclear equation to show the decay of lutetium-177.
-
17N.3.hl.TZ0.21b:
The half-life of lutetium-177 is 6.73 days. Determine the percentage of a sample of lutetium-177 remaining after 14.0 days.
-
17N.3.hl.TZ0.21c:
Explain the low environmental impact of most medical nuclear waste.
- 17N.3.hl.TZ0.22a.i: Both spectra show a peak at wavenumber 1700 cm–1. Identify the bond responsible for this peak.
-
17N.3.hl.TZ0.22a.ii:
Deduce which spectrum belongs to paracetamol, giving two reasons for your choice. Use section 26 of the data booklet.
- 17N.3.hl.TZ0.22b: Describe how mild analgesics function.
-
17N.3.hl.TZ0.23b:
Explain the role of the chiral auxiliary in the synthesis of Taxol.
- 17N.3.hl.TZ0.27: Ethanol slows down the reaction time of a driver leading to traffic accidents. Explain how the...
-
18M.3.hl.TZ1.16e:
Many drugs are chiral. Explain how a polarimeter can be used to determine the relative proportion of two enantiomers.
-
18M.3.hl.TZ1.19a:
Describe how ionizing radiation destroys cancer cells.
-
18M.3.hl.TZ1.19b:
Outline how Targeted Alpha Therapy (TAT) is used for treating cancers that have spread throughout the body.
-
18M.3.hl.TZ1.20a:
Hexane and propanone have vapour pressures of 17 kPa and 24 kPa respectively at 20 °C.
Calculate the vapour pressure, in kPa, at 20 °C of a mixture containing 60% hexane and 40% propanone by mole fraction, using Raoult’s law and assuming the mixture is ideal.
-
18M.3.hl.TZ1.20b:
Explain how hexane and propanone may be separated by fractional distillation.
-
18M.3.hl.TZ2.25:
Taxol was originally obtained from the bark of the Pacific yew tree.
Outline how Green Chemistry has improved the process of obtaining Taxol.
-
18M.3.hl.TZ2.26a:
Phosphorous-32 undergoes beta decay. Formulate a balanced nuclear equation for this process.
-
18M.3.hl.TZ2.26b:
The half-life of phosphorus-32 is 14.3 days. Calculate the mass, in g, of 32P remaining after 57.2 days if the initial sample contains 2.63 × 10−8 mol. Use table 1 of the data booklet and Mr = 31.97 g mol−1.
-
18M.3.hl.TZ2.26c:
Explain the targeted alpha therapy (TAT) technique and why it is useful.
-
18M.3.hl.TZ2.27a:
Fuel cells use an electrochemical process to determine the concentration of ethanol.
Formulate the overall equation for this process.
-
18M.3.hl.TZ2.27b:
Predict the chemical shifts and integration for each signal in the 1H NMR spectrum for ethanol using section 27 of the data booklet.
-
18M.3.sl.TZ1.13a:
Aspirin is often taken to reduce pain, swelling or fever. State one other use of aspirin.
-
18M.3.sl.TZ1.13b.i:
State what is meant by the bioavailability of a drug.
-
18M.3.sl.TZ1.13b.ii:
Outline how the bioavailability of aspirin may be increased.
-
18M.3.sl.TZ1.13c.i:
Compare and contrast the IR spectrum of aspirin with that of salicylic acid, using section 26 of the data booklet.
-
18M.3.sl.TZ1.13c.ii:
Describe how penicillin combats bacterial infections.
-
18M.3.sl.TZ1.13c.iii:
Outline two consequences of prescribing antibiotics such as penicillin unnecessarily.
-
18M.3.sl.TZ1.13c.iv:
State how penicillins may be modified to increase their effectiveness.
-
18M.3.sl.TZ1.13d.i:
Morphine and codeine are strong analgesics. Outline how strong analgesics function.
-
18M.3.sl.TZ1.13d.ii:
Suggest one reason why codeine is more widely used than morphine as an analgesic.
-
18M.3.sl.TZ1.14a.i:
An antacid tablet contains 680 mg of calcium carbonate, CaCO3, and 80 mg of magnesium carbonate, MgCO3.
State the equation for the reaction of magnesium carbonate with hydrochloric acid.
-
18M.3.sl.TZ1.14a.ii:
Determine the amount, in mol, of hydrochloric acid neutralized by one antacid tablet.
-
18M.3.sl.TZ1.14b:
Explain how omeprazole (Prilosec) reduces stomach acidity.
-
18M.3.sl.TZ1.15a:
Oseltamivir (Tamiflu) and zanamivir (Relenza) are used against flu viruses. Explain how these drugs function.
-
18M.3.sl.TZ1.15b:
Shikimic acid, the precursor for oseltamivir (Tamiflu), was originally extracted from star anise, and is now produced using genetically modified E. coli bacteria.
Suggest one difficulty associated with synthesizing oseltamivir (Tamiflu) from star anise.
-
18M.3.sl.TZ2.15:
Drug testing is necessary to determine safe and effective doses.
Distinguish between the lethal dose (LD50) and the toxic dose (TD50).
-
18M.3.sl.TZ2.16a.i:
Describe how penicillin combats bacterial infections.
-
18M.3.sl.TZ2.16a.ii:
State how penicillins may be modified to increase their effectiveness.
-
18M.3.sl.TZ2.16b:
State the type of reaction used to synthesize aspirin from salicylic acid.
-
18M.3.sl.TZ2.16c:
Explain why aspirin is not stored in a hot, humid location.
-
18M.3.sl.TZ2.17:
Morphine and diamorphine (heroin) are both opioids.
Explain why diamorphine is more potent than morphine using section 37 of the data booklet.
-
18M.3.sl.TZ2.18a:
Formulate a chemical equation for the neutralization of stomach acid with calcium carbonate.
-
18M.3.sl.TZ2.18b:
Calculate the amount, in mol, of stomach acid neutralized by an antacid tablet containing 0.750 g calcium carbonate.
-
18M.3.sl.TZ2.18c:
Explain how omeprazole (Prilosec) regulates pH in the stomach.
-
18M.3.sl.TZ2.19a:
Identify the names of two functional groups present in zanamivir using section 37 of the data booklet.
-
18M.3.sl.TZ2.19b:
Distinguish between bacteria and viruses.
-
18M.3.sl.TZ2.20:
Drug synthesis often involves solvents.
Identify a common hazardous solvent and a Green solvent that could replace it.
- 18N.3.sl.TZ0.12a: State the internal bond angles in the β-lactam ring and the expected bond angles for the same...
- 18N.3.sl.TZ0.12b: Explain how the open β-lactam ring kills bacteria.
- 18N.3.sl.TZ0.12c: Outline one effect of over-prescription of penicillin.
- 18N.3.sl.TZ0.12d: State how the structure of penicillin can be changed to combat this effect.
- 18N.3.sl.TZ0.12e: Suggest why human cells are not affected by penicillin.
-
18N.3.sl.TZ0.13a:
Explain why diamorphine (heroin) crosses the blood–brain barrier more easily than morphine.
- 18N.3.sl.TZ0.13b: Describe the analgesic action of an opiate.
- 18N.3.sl.TZ0.13c: Outline the meaning of the bioavailability of a drug.
-
18N.3.sl.TZ0.14a:
Determine the pH of a buffer solution that is 0.0100 mol dm−3 sodium hydrogen carbonate and 0.0200 mol dm−3 sodium carbonate, using section 1 of the data booklet.
Ka (hydrogen carbonate ion) = 4.8 × 10−11
-
18N.3.sl.TZ0.14b:
State the equation for the reaction of calcium carbonate, the active ingredient in some antacids, with stomach acid.
- 18N.3.sl.TZ0.14c: Suggest a technique for measuring the percentage mass of calcium carbonate in this type of...
-
18N.3.sl.TZ0.15a:
State one way in which viruses differ from bacteria.
- 18N.3.sl.TZ0.15b: Outline two different ways in which antiviral medications work.
-
18N.3.sl.TZ0.16:
Suggest two reasons why chlorinated solvents should neither be released into the atmosphere nor incinerated (burnt).
- 18N.3.hl.TZ0.16a: State the internal bond angles in the b-lactam ring and the expected bond angles in sp2 and sp3...
- 18N.3.hl.TZ0.16b: Explain how the open β-lactam ring kills bacteria.
- 18N.3.hl.TZ0.16c: State how the structure of penicillin can be modified to combat the effect of resistance caused...
- 18N.3.hl.TZ0.16d: Suggest why human cells are not affected by penicillin.
-
18N.3.hl.TZ0.17a:
Explain why diamorphine (heroin) crosses the blood–brain barrier more easily than morphine.
- 18N.3.hl.TZ0.17b: Outline the meaning of the bioavailability of a drug.
- 18N.3.hl.TZ0.19: Outline two different ways in which antiviral medications work.
-
18N.3.hl.TZ0.21a:
The diagram shows part of a Taxol molecule in skeletal form.
Draw a circle around each chiral carbon.
- 18N.3.hl.TZ0.21b: Outline how chiral auxiliaries are used to synthesize the desired enantiomer.
- 18N.3.hl.TZ0.21c: Explain the process of solvent extraction by which Taxol is isolated.
-
18N.3.hl.TZ0.22a:
Alpha particles are more damaging to human cells than any other nuclear radiation and yet they are used in targeted alpha therapy (TAT).
Explain how TAT is relatively safe to use in the treatment of dispersed cancers.
-
18N.3.hl.TZ0.22b.i:
Technetium-99m () has a half-life of 6.0 hours. Calculate the percentage of remaining in a sample of the radioisotope after two days.
-
18N.3.hl.TZ0.22b.ii:
Suggest why the percentage of technetium-99m remaining in the human body two days after injection will be lower than that calculated in (b)(i).
-
18N.3.hl.TZ0.23a:
State an analytical technique used to separate anabolic steroids from other compounds in an athlete’s urine or blood.
-
18N.3.hl.TZ0.23b:
Ethanol in breath can be detected by a redox reaction. Outline this method of detection. An equation is not required.
-
19M.3.hl.TZ1.19a:
Unreacted salicylic acid may be present as an impurity in aspirin and can be detected in the infrared (IR) spectrum.
Name the functional group and identify the absorption band that diff erentiates salicylic acid from aspirin. Use section 26 of the data booklet.
Name:
Absorption band:
-
19M.3.hl.TZ1.20a:
Identify the feature in penicillin responsible for its antibiotic activity.
-
19M.3.hl.TZ1.20b(i):
The widespread use of penicillin and its derivatives has led to the appearance of resistant S. aureus strains.
Outline how these bacteria inactivate the antibiotics.
-
19M.3.hl.TZ1.20b(ii):
Outline how the structure of penicillin has been modified to overcome this resistance.
-
19M.3.hl.TZ1.21a:
Formulate an equation for the neutralization of stomach acid with calcium carbonate, CaCO3 (s).
-
19M.3.hl.TZ1.21b:
Acid secretion can be regulated by other types of drugs such as omeprazole and ranitidine. Outline how each of these drugs acts to reduce excess stomach acid.
Omeprazole:
Ranitidine:
-
19M.3.hl.TZ1.22a(i):
Draw a circle around the functional group that can be converted to the carboxylate by hydrolysis.
-
19M.3.hl.TZ1.22a(ii):
The resulting active metabolite of oseltamivir can be detected by mass spectrometry (MS) analysis.
Deduce the mass of the expected carboxylate ion.
Mr oseltamivir = 312
-
19M.3.hl.TZ1.22b:
Suggest a reason for using a phosphate salt of oseltamivir in oral tablets.
-
19M.3.hl.TZ1.22c:
Anti-HIV drugs, such as zidovudine, often become less effective over time.
Explain the development of resistant virus strains in the presence of antiviral drugs.
-
19M.3.hl.TZ1.23a:
Explain how opiates act to provide pain relief.
-
19M.3.hl.TZ1.23b:
Discuss how the difference in structure of two opiates, codeine and morphine, affect their ability to cross the blood–brain barrier. Use section 37 of the data booklet.
-
19M.3.hl.TZ1.24a(i):
Determine the percentage of technetium-99m remaining after 24.0 hours.
-
19M.3.hl.TZ1.24a(ii):
Technetium-99 decays further, emitting beta radiation. Formulate the equation for the decay of technetium-99.
-
19M.3.hl.TZ1.24b(i):
Outline what is meant by low-level waste.
-
19M.3.hl.TZ1.24b(ii):
Outline the disposal of LLW.
-
19M.3.hl.TZ1.24c:
Magnetic resonance imaging (MRI) is an application of NMR technology using radiowaves.
Suggest why MRI is much less dangerous than imaging techniques such as X-rays and radiotracers. Use section 3 of the data booklet.
-
19M.3.hl.TZ1.25a:
Identify the chiral carbon atom using an asterisk, *.
-
19M.3.hl.TZ1.25b:
Enantiomers can be identified using a polarimeter. Outline how this instrument differentiates the enantiomers.
-
19M.3.hl.TZ2.21a:
Distinguish between therapeutic window and therapeutic index in humans.
Therapeutic window:
Therapeutic index:
-
19M.3.hl.TZ2.21b:
Explain why diamorphine (heroin) is more potent than morphine using section 37 of the data booklet.
-
19M.3.hl.TZ2.22a:
Predict one absorption band present in an infrared (IR) spectrum of aspirin, using section 26 of the data booklet.
-
19M.3.hl.TZ2.22b(i):
Determine the mass of aspirin which reacted with 16.25 cm3 of 0.100 mol dm−3 NaOH solution.
-
19M.3.hl.TZ2.22b(ii):
Determine the percentage purity of the synthesized aspirin.
-
19M.3.hl.TZ2.22c:
Outline how aspirin can be chemically modified to increase its solubility in water.
-
19M.3.hl.TZ2.22d:
State why aspirin should not be taken with alcohol.
-
19M.3.hl.TZ2.23a(i):
Outline how ranitidine (Zantac) inhibits stomach acid production.
-
19M.3.hl.TZ2.23a(ii):
Outline two advantages of taking ranitidine instead of an antacid which neutralizes excess acid.
-
19M.3.hl.TZ2.23b:
Some antacids contain carbonates.
Determine the pH of a buffer solution which contains 0.160 mol dm−3 CO32− and 0.200 mol dm−3 HCO3−, using section 1 of the data booklet.
pKa (HCO3−) = 10.32
-
19M.3.hl.TZ2.24a:
Outline one way in which antiviral drugs work.
-
19M.3.hl.TZ2.24b:
Discuss two difficulties associated with solving the AIDS problem.
-
19M.3.hl.TZ2.25a:
Examine the synthesis of taxol in terms of green chemistry criteria.
-
19M.3.hl.TZ2.25b:
Outline the operation of a polarimeter used to distinguish between enantiomers.
-
19M.3.hl.TZ2.26a:
Evaluate the suitability of technetium-99m for this use.
-
19M.3.hl.TZ2.26b:
Calculate the percentage of technetium-99m remaining after 10.0 hours. Use section 1 of the data booklet.
-
19M.3.hl.TZ2.27a:
Describe how a fuel cell breathalyser works.
-
19M.3.hl.TZ2.27b:
Alcohol levels in the breath can also be determined using IR spectroscopy.
Suggest, giving a reason, which bond’s absorbance is most useful for detecting ethanol in breath.
Bond:
Reason:
-
19M.3.sl.TZ1.14:
Aspirin can be obtained from salicylic acid.
Unreacted salicylic acid may be present as an impurity in aspirin and can be detected in the infrared (IR) spectrum.
Name the functional group and identify the absorption band that differentiates salicylic acid from aspirin. Use section 26 of the data booklet.
Name:
Absorption band:
-
19M.3.sl.TZ1.15a:
Identify the feature in penicillin responsible for its antibiotic activity.
-
19M.3.sl.TZ1.15b(i):
The widespread use of penicillin and its derivatives has led to the appearance of resistant S. aureus strains.
Outline how these bacteria inactivate the antibiotics.
-
19M.3.sl.TZ1.15b(ii):
Outline how the structure of penicillin has been modified to overcome this resistance.
-
19M.3.sl.TZ1.16a(i):
Formulate an equation for the neutralization of stomach acid with calcium carbonate, CaCO3 (s).
-
19M.3.sl.TZ1.16a(ii):
Determine the volume of CO2 (g), in dm3, produced at STP, when 1.00 g of CaCO3 (s) reacts completely with stomach acid.
Mr CaCO3 = 100.09
-
19M.3.sl.TZ1.16b:
Acid secretion can be regulated by other types of drugs such as omeprazole and ranitidine. Outline how each of these drugs acts to reduce excess stomach acid.
Omeprazole:
Ranitidine:
-
19M.3.sl.TZ1.17a(i):
Draw a circle around the functional group that can be converted to the carboxylate by hydrolysis.
-
19M.3.sl.TZ1.17a(ii):
Suggest a reason for using a phosphate salt of oseltamivir in oral tablets.
-
19M.3.sl.TZ1.17b:
Anti-HIV drugs, such as zidovudine, often become less effective over time.
Explain the development of resistant virus strains in the presence of antiviral drugs.
-
19M.3.sl.TZ1.18a:
Explain how opiates act to provide pain relief.
-
19M.3.sl.TZ1.18b:
Discuss how the difference in structure of two opiates, codeine and morphine, affect their ability to cross the blood–brain barrier. Use section 37 of the data booklet.
-
19M.3.sl.TZ1.19a:
Outline what is meant by low-level waste.
-
19M.3.sl.TZ1.19b:
Outline the disposal of LLW.
-
19M.3.sl.TZ2.14a:
Distinguish between therapeutic window and therapeutic index in humans.
Therapeutic window:
Therapeutic index:
-
19M.3.sl.TZ2.14b(i):
State one advantage of using morphine as an analgesic.
-
19M.3.sl.TZ2.14b(ii):
Explain why diamorphine (heroin) is more potent than morphine using section 37 of the data booklet.
-
19M.3.sl.TZ2.15a:
Predict one absorption band present in an infrared (IR) spectrum of aspirin, using section 26 of the data booklet.
-
19M.3.sl.TZ2.15b(i):
Determine the mass of aspirin which reacted with 16.25 cm3 of 0.100 mol dm−3 NaOH solution.
-
19M.3.sl.TZ2.15b(ii):
Determine the percentage purity of the synthesized aspirin.
-
19M.3.sl.TZ2.15c:
Outline how aspirin can be chemically modified to increase its solubility in water.
-
19M.3.sl.TZ2.15d:
State why aspirin should not be taken with alcohol.
-
19M.3.sl.TZ2.15e:
Outline two factors which must be considered to assess the greenness of any chemical process.
-
19M.3.sl.TZ2.16a(i):
Outline how ranitidine (Zantac) inhibits stomach acid production.
-
19M.3.sl.TZ2.16a(ii):
Outline two advantages of taking ranitidine instead of an antacid which neutralizes excess acid.
-
19M.3.sl.TZ2.16b:
Some antacids contain carbonates.
Determine the pH of a buffer solution which contains 0.160 mol dm−3 CO32− and 0.200 mol dm−3 HCO3−, using section 1 of the data booklet.
pKa (HCO3−) = 10.32
-
19M.3.sl.TZ2.17a:
Outline one way in which antiviral drugs work.
-
19M.3.sl.TZ2.17b:
Discuss two difficulties associated with solving the AIDS problem.
- 19N.3.sl.TZ0.15a: State the names of two functional groups present in all three molecules, using section 37 of the...
- 19N.3.sl.TZ0.15b: Explain why diamorphine has greater potency than morphine.
- 19N.3.hl.TZ0.21a: Explain why diamorphine has greater potency than morphine.
- 19N.3.hl.TZ0.21b: Experimental research on both animals and humans contributes to the development...
-
19N.3.sl.TZ0.16a:
Identify the compound responsible for the acidity of gastric juice, and state whether it is a strong or weak acid.
-
19N.3.sl.TZ0.16b:
An antacid contains calcium carbonate and magnesium carbonate.
Write the equation for the reaction of magnesium carbonate with excess stomach acid.
- 19N.3.sl.TZ0.16c: Outline how ranitidine reduces stomach acidity.
-
19N.3.sl.TZ0.16d:
Calculate the pH of a buffer solution which contains 0.20 mol dm−3 ethanoic acid and 0.50 mol dm−3 sodium ethanoate. Use section 1 of the data booklet.
pKa (ethanoic acid) = 4.76
- 19N.3.sl.TZ0.17a: Suggest one reactant used to prepare aspirin from salicylic acid.
-
19N.3.sl.TZ0.17b:
Aspirin, C6H4(OCOCH3)COOH, is only slightly soluble in water.
Outline, including an equation, how aspirin can be made more water-soluble. Use section 37 in the data booklet.
-
19N.3.hl.TZ0.24a:
Infrared (IR) spectroscopy is used to identify functional groups in organic compounds.
Deduce the wavenumber, in cm−1, of an absorption peak found in the IR spectrum of testosterone but not in that of cholesterol.
-
19N.3.hl.TZ0.24b:
Describe a technique for the detection of steroids in blood and urine.
-
19N.3.hl.TZ0.24c:
Explain how redox chemistry is used to measure the ethanol concentration in a breathalyser.
- 19N.3.hl.TZ0.25a: Explain how the beta-lactam ring is responsible for the antibiotic properties of penicillin....
- 19N.3.hl.TZ0.25b: Outline the impact of antibiotic waste on the environment.
- 19N.3.hl.TZ0.25c: Suggest a concern about the disposal of solvents from drug manufacturing.
- 19N.3.hl.TZ0.25d: Discuss two difficulties, apart from socio-economic factors, associated with finding a cure for...
- 19N.3.hl.TZ0.26a: State the feature of Taxol that is a major challenge in its synthesis. Use section 37 of the data...
-
19N.3.hl.TZ0.26b:
Describe how the challenge in (a) was resolved by pharmaceutical companies.
- 19N.3.hl.TZ0.27a: State two common side effects of radiotherapy.
- 19N.3.hl.TZ0.27b: Explain why technetium-99m is the most common radioisotope used in nuclear medicine.
-
19N.3.hl.TZ0.27c:
25.0 μg of iodine-131, with a half-life of 8.00 days, was left to decay.
Calculate the mass of iodine-131, in μg, remaining after 32.0 days. Use section 1 of the data booklet.
-
19N.3.sl.TZ0.18a:
State one difference between bacteria and viruses.
- 19N.3.sl.TZ0.18b: Discuss two difficulties, apart from socio-economic factors, associated with finding a cure for...
- 19N.3.sl.TZ0.18c: The discovery of penicillins contributed to the development of antibiotics. Explain how the...
- 19N.3.sl.TZ0.19a: Outline the impact of antibiotic waste on the environment.
- 19N.3.sl.TZ0.19b: Suggest a concern about the disposal of solvents from drug manufacturing.
-
20N.3.sl.TZ0.11a:
Deduce the structural formula of the by-product of this reaction.
- 20N.3.sl.TZ0.11b: Aspirin crystals are rinsed with water after recrystallization to remove impurities.Suggest why...
-
20N.3.sl.TZ0.11c:
The solubility of aspirin is increased by converting it to an ionic form. Draw the structure of the ionic form of aspirin.
-
20N.3.sl.TZ0.11d:
Comment on the risk of overdose when taking aspirin as an analgesic, referring to the following values, for a person weighing :
Minimum therapeutic dose
Estimated minimum lethal dose
-
20N.3.sl.TZ0.12:
Consider the following antacids:
Show that antacid X is more effective, per tablet, than antacid Y.
- 20N.3.sl.TZ0.13a: Describe the proper disposal of low-level radioactive waste in hospitals.
-
20N.3.sl.TZ0.13b:
Outline a green chemistry solution for problems generated by the use of organic solvents.
- 20N.3.sl.TZ0.14a(i): Name two functional groups that both zanamivir and oseltamivir contain.
-
20N.3.sl.TZ0.14a(ii):
Explain how zanamivir works as a preventative agent against flu viruses.
- 20N.3.sl.TZ0.14b(i): Circle the side-chain in penicillin on the structure below.
-
20N.3.sl.TZ0.14b(ii):
Explain, with reference to the action of penicillin, why new penicillins with different side-chains need to be produced.
- 20N.3.sl.TZ0.14c(i): State and explain the relative solubility of codeine in water compared to morphine and diamorphine.
- 20N.3.sl.TZ0.14c(ii): State the natural source from which codeine, morphine and diamorphine are obtained.
-
20N.3.hl.TZ0.15a:
Deduce the structural formula of the by-product of this reaction.
- 20N.3.hl.TZ0.15b: Aspirin crystals are rinsed with water after recrystallization to remove impurities.Suggest why...
-
20N.3.hl.TZ0.15c:
The solubility of aspirin is increased by converting it to an ionic form. Draw the structure of the ionic form of aspirin.
-
20N.3.hl.TZ0.15d:
Comment on the risk of overdose when taking aspirin as an analgesic, referring to the following values, for a person weighing :
Minimum therapeutic dose
Estimated minimum lethal dose
-
20N.3.hl.TZ0.15e:
Explain how IR spectroscopy can be used to distinguish aspirin from salicylic acid.
-
20N.3.hl.TZ0.17a:
State the type of radiation technetium-99m emits.
- 20N.3.hl.TZ0.17b: Discuss the properties that make a radioisotope suitable for diagnosis.
-
20N.3.hl.TZ0.17c:
Describe the proper disposal of low-level radioactive waste in hospitals.
-
20N.3.hl.TZ0.17d:
Technetium-99m has a half-life of hours. Calculate the amount of of technetium-99m remaining after hours.
-
20N.3.hl.TZ0.18a(ii):
The vapour pressure of pure ethanal at is .
Calculate the vapour pressure of ethanal above the liquid mixture at .
- 20N.3.hl.TZ0.18b: Describe how this mixture is separated by fractional distillation.
-
20N.3.hl.TZ0.19a:
Explain how zanamivir works as a preventative agent against flu viruses.
- 20N.3.hl.TZ0.19b(i): Circle the side-chain in penicillin on the structure below.
-
20N.3.hl.TZ0.19b(ii):
Explain, with reference to the action of penicillin, why new penicillins with different side-chains need to be produced.
- 20N.3.hl.TZ0.19c(i): State and explain the relative solubility of codeine in water compared to morphine and diamorphine.
- 20N.3.hl.TZ0.19c(ii): State the natural source from which codeine, morphine and diamorphine are obtained.
- 20N.3.hl.TZ0.19d: Circle two chiral carbons in the section of the Taxol structure below.
-
19M.3.hl.TZ1.19a:
Unreacted salicylic acid may be present as an impurity in aspirin and can be detected in the infrared (IR) spectrum.
Name the functional group and identify the absorption band that diff erentiates salicylic acid from aspirin. Use section 26 of the data booklet.
Name:
Absorption band:
-
19M.3.hl.TZ1.a:
Unreacted salicylic acid may be present as an impurity in aspirin and can be detected in the infrared (IR) spectrum.
Name the functional group and identify the absorption band that diff erentiates salicylic acid from aspirin. Use section 26 of the data booklet.
Name:
Absorption band:
-
19M.3.hl.TZ1.20a:
Identify the feature in penicillin responsible for its antibiotic activity.
-
19M.3.hl.TZ1.20b(i):
The widespread use of penicillin and its derivatives has led to the appearance of resistant S. aureus strains.
Outline how these bacteria inactivate the antibiotics.
-
19M.3.hl.TZ1.20b(ii):
Outline how the structure of penicillin has been modified to overcome this resistance.
-
19M.3.hl.TZ1.a:
Identify the feature in penicillin responsible for its antibiotic activity.
-
19M.3.hl.TZ1.b(i):
The widespread use of penicillin and its derivatives has led to the appearance of resistant S. aureus strains.
Outline how these bacteria inactivate the antibiotics.
-
19M.3.hl.TZ1.b(ii):
Outline how the structure of penicillin has been modified to overcome this resistance.
-
19M.3.hl.TZ1.21a:
Formulate an equation for the neutralization of stomach acid with calcium carbonate, CaCO3 (s).
-
19M.3.hl.TZ1.21b:
Acid secretion can be regulated by other types of drugs such as omeprazole and ranitidine. Outline how each of these drugs acts to reduce excess stomach acid.
Omeprazole:
Ranitidine:
-
19M.3.hl.TZ1.a:
Formulate an equation for the neutralization of stomach acid with calcium carbonate, CaCO3 (s).
-
19M.3.hl.TZ1.b:
Acid secretion can be regulated by other types of drugs such as omeprazole and ranitidine. Outline how each of these drugs acts to reduce excess stomach acid.
Omeprazole:
Ranitidine:
-
19M.3.hl.TZ1.22a(i):
Draw a circle around the functional group that can be converted to the carboxylate by hydrolysis.
-
19M.3.hl.TZ1.22a(ii):
The resulting active metabolite of oseltamivir can be detected by mass spectrometry (MS) analysis.
Deduce the mass of the expected carboxylate ion.
Mr oseltamivir = 312
-
19M.3.hl.TZ1.22b:
Suggest a reason for using a phosphate salt of oseltamivir in oral tablets.
-
19M.3.hl.TZ1.22c:
Anti-HIV drugs, such as zidovudine, often become less effective over time.
Explain the development of resistant virus strains in the presence of antiviral drugs.
-
19M.3.hl.TZ1.a(i):
Draw a circle around the functional group that can be converted to the carboxylate by hydrolysis.
-
19M.3.hl.TZ1.a(ii):
The resulting active metabolite of oseltamivir can be detected by mass spectrometry (MS) analysis.
Deduce the mass of the expected carboxylate ion.
Mr oseltamivir = 312
-
19M.3.hl.TZ1.b:
Suggest a reason for using a phosphate salt of oseltamivir in oral tablets.
-
19M.3.hl.TZ1.c:
Anti-HIV drugs, such as zidovudine, often become less effective over time.
Explain the development of resistant virus strains in the presence of antiviral drugs.
-
19M.3.hl.TZ1.23a:
Explain how opiates act to provide pain relief.
-
19M.3.hl.TZ1.23b:
Discuss how the difference in structure of two opiates, codeine and morphine, affect their ability to cross the blood–brain barrier. Use section 37 of the data booklet.
-
19M.3.hl.TZ1.a:
Explain how opiates act to provide pain relief.
-
19M.3.hl.TZ1.b:
Discuss how the difference in structure of two opiates, codeine and morphine, affect their ability to cross the blood–brain barrier. Use section 37 of the data booklet.
-
19M.3.hl.TZ1.24a(i):
Determine the percentage of technetium-99m remaining after 24.0 hours.
-
19M.3.hl.TZ1.24a(ii):
Technetium-99 decays further, emitting beta radiation. Formulate the equation for the decay of technetium-99.
-
19M.3.hl.TZ1.24b(i):
Outline what is meant by low-level waste.
-
19M.3.hl.TZ1.24b(ii):
Outline the disposal of LLW.
-
19M.3.hl.TZ1.24c:
Magnetic resonance imaging (MRI) is an application of NMR technology using radiowaves.
Suggest why MRI is much less dangerous than imaging techniques such as X-rays and radiotracers. Use section 3 of the data booklet.
-
19M.3.hl.TZ1.a(i):
Determine the percentage of technetium-99m remaining after 24.0 hours.
-
19M.3.hl.TZ1.a(ii):
Technetium-99 decays further, emitting beta radiation. Formulate the equation for the decay of technetium-99.
-
19M.3.hl.TZ1.b(i):
Outline what is meant by low-level waste.
-
19M.3.hl.TZ1.b(ii):
Outline the disposal of LLW.
-
19M.3.hl.TZ1.c:
Magnetic resonance imaging (MRI) is an application of NMR technology using radiowaves.
Suggest why MRI is much less dangerous than imaging techniques such as X-rays and radiotracers. Use section 3 of the data booklet.
-
19M.3.hl.TZ1.25a:
Identify the chiral carbon atom using an asterisk, *.
-
19M.3.hl.TZ1.25b:
Enantiomers can be identified using a polarimeter. Outline how this instrument differentiates the enantiomers.
-
19M.3.hl.TZ1.a:
Identify the chiral carbon atom using an asterisk, *.
-
19M.3.hl.TZ1.b:
Enantiomers can be identified using a polarimeter. Outline how this instrument differentiates the enantiomers.
-
19M.3.hl.TZ2.21a:
Distinguish between therapeutic window and therapeutic index in humans.
Therapeutic window:
Therapeutic index:
-
19M.3.hl.TZ2.21b:
Explain why diamorphine (heroin) is more potent than morphine using section 37 of the data booklet.
-
19M.3.hl.TZ2.a:
Distinguish between therapeutic window and therapeutic index in humans.
Therapeutic window:
Therapeutic index:
-
19M.3.hl.TZ2.b:
Explain why diamorphine (heroin) is more potent than morphine using section 37 of the data booklet.
-
19M.3.hl.TZ2.22a:
Predict one absorption band present in an infrared (IR) spectrum of aspirin, using section 26 of the data booklet.
-
19M.3.hl.TZ2.22b(i):
Determine the mass of aspirin which reacted with 16.25 cm3 of 0.100 mol dm−3 NaOH solution.
-
19M.3.hl.TZ2.22b(ii):
Determine the percentage purity of the synthesized aspirin.
-
19M.3.hl.TZ2.22c:
Outline how aspirin can be chemically modified to increase its solubility in water.
-
19M.3.hl.TZ2.22d:
State why aspirin should not be taken with alcohol.
-
19M.3.hl.TZ2.a:
Predict one absorption band present in an infrared (IR) spectrum of aspirin, using section 26 of the data booklet.
-
19M.3.hl.TZ2.b(i):
Determine the mass of aspirin which reacted with 16.25 cm3 of 0.100 mol dm−3 NaOH solution.
-
19M.3.hl.TZ2.b(ii):
Determine the percentage purity of the synthesized aspirin.
-
19M.3.hl.TZ2.c:
Outline how aspirin can be chemically modified to increase its solubility in water.
-
19M.3.hl.TZ2.d:
State why aspirin should not be taken with alcohol.
-
19M.3.hl.TZ2.23a(i):
Outline how ranitidine (Zantac) inhibits stomach acid production.
-
19M.3.hl.TZ2.23a(ii):
Outline two advantages of taking ranitidine instead of an antacid which neutralizes excess acid.
-
19M.3.hl.TZ2.23b:
Some antacids contain carbonates.
Determine the pH of a buffer solution which contains 0.160 mol dm−3 CO32− and 0.200 mol dm−3 HCO3−, using section 1 of the data booklet.
pKa (HCO3−) = 10.32
-
19M.3.hl.TZ2.a(i):
Outline how ranitidine (Zantac) inhibits stomach acid production.
-
19M.3.hl.TZ2.a(ii):
Outline two advantages of taking ranitidine instead of an antacid which neutralizes excess acid.
-
19M.3.hl.TZ2.b:
Some antacids contain carbonates.
Determine the pH of a buffer solution which contains 0.160 mol dm−3 CO32− and 0.200 mol dm−3 HCO3−, using section 1 of the data booklet.
pKa (HCO3−) = 10.32
-
19M.3.hl.TZ2.24a:
Outline one way in which antiviral drugs work.
-
19M.3.hl.TZ2.24b:
Discuss two difficulties associated with solving the AIDS problem.
-
19M.3.hl.TZ2.a:
Outline one way in which antiviral drugs work.
-
19M.3.hl.TZ2.b:
Discuss two difficulties associated with solving the AIDS problem.
-
19M.3.hl.TZ2.25a:
Examine the synthesis of taxol in terms of green chemistry criteria.
-
19M.3.hl.TZ2.25b:
Outline the operation of a polarimeter used to distinguish between enantiomers.
-
19M.3.hl.TZ2.a:
Examine the synthesis of taxol in terms of green chemistry criteria.
-
19M.3.hl.TZ2.b:
Outline the operation of a polarimeter used to distinguish between enantiomers.
-
19M.3.hl.TZ2.26a:
Evaluate the suitability of technetium-99m for this use.
-
19M.3.hl.TZ2.26b:
Calculate the percentage of technetium-99m remaining after 10.0 hours. Use section 1 of the data booklet.
-
19M.3.hl.TZ2.a:
Evaluate the suitability of technetium-99m for this use.
-
19M.3.hl.TZ2.b:
Calculate the percentage of technetium-99m remaining after 10.0 hours. Use section 1 of the data booklet.
-
19M.3.hl.TZ2.27a:
Describe how a fuel cell breathalyser works.
-
19M.3.hl.TZ2.27b:
Alcohol levels in the breath can also be determined using IR spectroscopy.
Suggest, giving a reason, which bond’s absorbance is most useful for detecting ethanol in breath.
Bond:
Reason:
-
19M.3.hl.TZ2.a:
Describe how a fuel cell breathalyser works.
-
19M.3.hl.TZ2.b:
Alcohol levels in the breath can also be determined using IR spectroscopy.
Suggest, giving a reason, which bond’s absorbance is most useful for detecting ethanol in breath.
Bond:
Reason:
-
19M.3.sl.TZ1.14:
Aspirin can be obtained from salicylic acid.
Unreacted salicylic acid may be present as an impurity in aspirin and can be detected in the infrared (IR) spectrum.
Name the functional group and identify the absorption band that differentiates salicylic acid from aspirin. Use section 26 of the data booklet.
Name:
Absorption band:
-
19M.3.sl.TZ1.15a:
Identify the feature in penicillin responsible for its antibiotic activity.
-
19M.3.sl.TZ1.15b(i):
The widespread use of penicillin and its derivatives has led to the appearance of resistant S. aureus strains.
Outline how these bacteria inactivate the antibiotics.
-
19M.3.sl.TZ1.15b(ii):
Outline how the structure of penicillin has been modified to overcome this resistance.
-
19M.3.sl.TZ1.a:
Identify the feature in penicillin responsible for its antibiotic activity.
-
19M.3.sl.TZ1.b(i):
The widespread use of penicillin and its derivatives has led to the appearance of resistant S. aureus strains.
Outline how these bacteria inactivate the antibiotics.
-
19M.3.sl.TZ1.b(ii):
Outline how the structure of penicillin has been modified to overcome this resistance.
-
19M.3.sl.TZ1.16a(i):
Formulate an equation for the neutralization of stomach acid with calcium carbonate, CaCO3 (s).
-
19M.3.sl.TZ1.16a(ii):
Determine the volume of CO2 (g), in dm3, produced at STP, when 1.00 g of CaCO3 (s) reacts completely with stomach acid.
Mr CaCO3 = 100.09
-
19M.3.sl.TZ1.16b:
Acid secretion can be regulated by other types of drugs such as omeprazole and ranitidine. Outline how each of these drugs acts to reduce excess stomach acid.
Omeprazole:
Ranitidine:
-
19M.3.sl.TZ1.a(i):
Formulate an equation for the neutralization of stomach acid with calcium carbonate, CaCO3 (s).
-
19M.3.sl.TZ1.a(ii):
Determine the volume of CO2 (g), in dm3, produced at STP, when 1.00 g of CaCO3 (s) reacts completely with stomach acid.
Mr CaCO3 = 100.09
-
19M.3.sl.TZ1.b:
Acid secretion can be regulated by other types of drugs such as omeprazole and ranitidine. Outline how each of these drugs acts to reduce excess stomach acid.
Omeprazole:
Ranitidine:
-
19M.3.sl.TZ1.17a(i):
Draw a circle around the functional group that can be converted to the carboxylate by hydrolysis.
-
19M.3.sl.TZ1.17a(ii):
Suggest a reason for using a phosphate salt of oseltamivir in oral tablets.
-
19M.3.sl.TZ1.17b:
Anti-HIV drugs, such as zidovudine, often become less effective over time.
Explain the development of resistant virus strains in the presence of antiviral drugs.
-
19M.3.sl.TZ1.a(i):
Draw a circle around the functional group that can be converted to the carboxylate by hydrolysis.
-
19M.3.sl.TZ1.a(ii):
Suggest a reason for using a phosphate salt of oseltamivir in oral tablets.
-
19M.3.sl.TZ1.b:
Anti-HIV drugs, such as zidovudine, often become less effective over time.
Explain the development of resistant virus strains in the presence of antiviral drugs.
-
19M.3.sl.TZ1.18a:
Explain how opiates act to provide pain relief.
-
19M.3.sl.TZ1.18b:
Discuss how the difference in structure of two opiates, codeine and morphine, affect their ability to cross the blood–brain barrier. Use section 37 of the data booklet.
-
19M.3.sl.TZ1.a:
Explain how opiates act to provide pain relief.
-
19M.3.sl.TZ1.b:
Discuss how the difference in structure of two opiates, codeine and morphine, affect their ability to cross the blood–brain barrier. Use section 37 of the data booklet.
-
19M.3.sl.TZ1.19a:
Outline what is meant by low-level waste.
-
19M.3.sl.TZ1.19b:
Outline the disposal of LLW.
-
19M.3.sl.TZ1.a:
Outline what is meant by low-level waste.
-
19M.3.sl.TZ1.b:
Outline the disposal of LLW.
-
19M.3.sl.TZ2.14a:
Distinguish between therapeutic window and therapeutic index in humans.
Therapeutic window:
Therapeutic index:
-
19M.3.sl.TZ2.14b(i):
State one advantage of using morphine as an analgesic.
-
19M.3.sl.TZ2.14b(ii):
Explain why diamorphine (heroin) is more potent than morphine using section 37 of the data booklet.
-
19M.3.sl.TZ2.a:
Distinguish between therapeutic window and therapeutic index in humans.
Therapeutic window:
Therapeutic index:
-
19M.3.sl.TZ2.b(i):
State one advantage of using morphine as an analgesic.
-
19M.3.sl.TZ2.b(ii):
Explain why diamorphine (heroin) is more potent than morphine using section 37 of the data booklet.
-
19M.3.sl.TZ2.15a:
Predict one absorption band present in an infrared (IR) spectrum of aspirin, using section 26 of the data booklet.
-
19M.3.sl.TZ2.15b(i):
Determine the mass of aspirin which reacted with 16.25 cm3 of 0.100 mol dm−3 NaOH solution.
-
19M.3.sl.TZ2.15b(ii):
Determine the percentage purity of the synthesized aspirin.
-
19M.3.sl.TZ2.15c:
Outline how aspirin can be chemically modified to increase its solubility in water.
-
19M.3.sl.TZ2.15d:
State why aspirin should not be taken with alcohol.
-
19M.3.sl.TZ2.15e:
Outline two factors which must be considered to assess the greenness of any chemical process.
-
19M.3.sl.TZ2.a:
Predict one absorption band present in an infrared (IR) spectrum of aspirin, using section 26 of the data booklet.
-
19M.3.sl.TZ2.b(i):
Determine the mass of aspirin which reacted with 16.25 cm3 of 0.100 mol dm−3 NaOH solution.
-
19M.3.sl.TZ2.b(ii):
Determine the percentage purity of the synthesized aspirin.
-
19M.3.sl.TZ2.c:
Outline how aspirin can be chemically modified to increase its solubility in water.
-
19M.3.sl.TZ2.d:
State why aspirin should not be taken with alcohol.
-
19M.3.sl.TZ2.e:
Outline two factors which must be considered to assess the greenness of any chemical process.
-
19M.3.sl.TZ2.16a(i):
Outline how ranitidine (Zantac) inhibits stomach acid production.
-
19M.3.sl.TZ2.16a(ii):
Outline two advantages of taking ranitidine instead of an antacid which neutralizes excess acid.
-
19M.3.sl.TZ2.16b:
Some antacids contain carbonates.
Determine the pH of a buffer solution which contains 0.160 mol dm−3 CO32− and 0.200 mol dm−3 HCO3−, using section 1 of the data booklet.
pKa (HCO3−) = 10.32
-
19M.3.sl.TZ2.a(i):
Outline how ranitidine (Zantac) inhibits stomach acid production.
-
19M.3.sl.TZ2.a(ii):
Outline two advantages of taking ranitidine instead of an antacid which neutralizes excess acid.
-
19M.3.sl.TZ2.b:
Some antacids contain carbonates.
Determine the pH of a buffer solution which contains 0.160 mol dm−3 CO32− and 0.200 mol dm−3 HCO3−, using section 1 of the data booklet.
pKa (HCO3−) = 10.32
-
19M.3.sl.TZ2.17a:
Outline one way in which antiviral drugs work.
-
19M.3.sl.TZ2.17b:
Discuss two difficulties associated with solving the AIDS problem.
-
19M.3.sl.TZ2.a:
Outline one way in which antiviral drugs work.
-
19M.3.sl.TZ2.b:
Discuss two difficulties associated with solving the AIDS problem.
- 19N.3.sl.TZ0.15a: State the names of two functional groups present in all three molecules, using section 37 of the...
- 19N.3.sl.TZ0.15b: Explain why diamorphine has greater potency than morphine.
- 19N.3.sl.TZ0.a: State the names of two functional groups present in all three molecules, using section 37 of the...
- 19N.3.sl.TZ0.b: Explain why diamorphine has greater potency than morphine.
- 19N.3.hl.TZ0.21a: Explain why diamorphine has greater potency than morphine.
- 19N.3.hl.TZ0.21b: Experimental research on both animals and humans contributes to the development...
- 19N.3.hl.TZ0.a: Explain why diamorphine has greater potency than morphine.
- 19N.3.hl.TZ0.b: Experimental research on both animals and humans contributes to the development...
-
19N.3.sl.TZ0.16a:
Identify the compound responsible for the acidity of gastric juice, and state whether it is a strong or weak acid.
-
19N.3.sl.TZ0.16b:
An antacid contains calcium carbonate and magnesium carbonate.
Write the equation for the reaction of magnesium carbonate with excess stomach acid.
- 19N.3.sl.TZ0.16c: Outline how ranitidine reduces stomach acidity.
-
19N.3.sl.TZ0.16d:
Calculate the pH of a buffer solution which contains 0.20 mol dm−3 ethanoic acid and 0.50 mol dm−3 sodium ethanoate. Use section 1 of the data booklet.
pKa (ethanoic acid) = 4.76
-
19N.3.sl.TZ0.a:
Identify the compound responsible for the acidity of gastric juice, and state whether it is a strong or weak acid.
-
19N.3.sl.TZ0.b:
An antacid contains calcium carbonate and magnesium carbonate.
Write the equation for the reaction of magnesium carbonate with excess stomach acid.
- 19N.3.sl.TZ0.c: Outline how ranitidine reduces stomach acidity.
-
19N.3.sl.TZ0.d:
Calculate the pH of a buffer solution which contains 0.20 mol dm−3 ethanoic acid and 0.50 mol dm−3 sodium ethanoate. Use section 1 of the data booklet.
pKa (ethanoic acid) = 4.76
- 19N.3.sl.TZ0.17a: Suggest one reactant used to prepare aspirin from salicylic acid.
-
19N.3.sl.TZ0.17b:
Aspirin, C6H4(OCOCH3)COOH, is only slightly soluble in water.
Outline, including an equation, how aspirin can be made more water-soluble. Use section 37 in the data booklet.
- 19N.3.sl.TZ0.a: Suggest one reactant used to prepare aspirin from salicylic acid.
-
19N.3.sl.TZ0.b:
Aspirin, C6H4(OCOCH3)COOH, is only slightly soluble in water.
Outline, including an equation, how aspirin can be made more water-soluble. Use section 37 in the data booklet.
-
19N.3.hl.TZ0.24a:
Infrared (IR) spectroscopy is used to identify functional groups in organic compounds.
Deduce the wavenumber, in cm−1, of an absorption peak found in the IR spectrum of testosterone but not in that of cholesterol.
-
19N.3.hl.TZ0.24b:
Describe a technique for the detection of steroids in blood and urine.
-
19N.3.hl.TZ0.24c:
Explain how redox chemistry is used to measure the ethanol concentration in a breathalyser.
-
19N.3.hl.TZ0.a:
Infrared (IR) spectroscopy is used to identify functional groups in organic compounds.
Deduce the wavenumber, in cm−1, of an absorption peak found in the IR spectrum of testosterone but not in that of cholesterol.
-
19N.3.hl.TZ0.b:
Describe a technique for the detection of steroids in blood and urine.
-
19N.3.hl.TZ0.c:
Explain how redox chemistry is used to measure the ethanol concentration in a breathalyser.
- 19N.3.hl.TZ0.25a: Explain how the beta-lactam ring is responsible for the antibiotic properties of penicillin....
- 19N.3.hl.TZ0.25b: Outline the impact of antibiotic waste on the environment.
- 19N.3.hl.TZ0.25c: Suggest a concern about the disposal of solvents from drug manufacturing.
- 19N.3.hl.TZ0.25d: Discuss two difficulties, apart from socio-economic factors, associated with finding a cure for...
- 19N.3.hl.TZ0.a: Explain how the beta-lactam ring is responsible for the antibiotic properties of penicillin....
- 19N.3.hl.TZ0.b: Outline the impact of antibiotic waste on the environment.
- 19N.3.hl.TZ0.c: Suggest a concern about the disposal of solvents from drug manufacturing.
- 19N.3.hl.TZ0.d: Discuss two difficulties, apart from socio-economic factors, associated with finding a cure for...
- 19N.3.hl.TZ0.26a: State the feature of Taxol that is a major challenge in its synthesis. Use section 37 of the data...
-
19N.3.hl.TZ0.26b:
Describe how the challenge in (a) was resolved by pharmaceutical companies.
- 19N.3.hl.TZ0.a: State the feature of Taxol that is a major challenge in its synthesis. Use section 37 of the data...
-
19N.3.hl.TZ0.b:
Describe how the challenge in (a) was resolved by pharmaceutical companies.
- 19N.3.hl.TZ0.27a: State two common side effects of radiotherapy.
- 19N.3.hl.TZ0.27b: Explain why technetium-99m is the most common radioisotope used in nuclear medicine.
-
19N.3.hl.TZ0.27c:
25.0 μg of iodine-131, with a half-life of 8.00 days, was left to decay.
Calculate the mass of iodine-131, in μg, remaining after 32.0 days. Use section 1 of the data booklet.
- 19N.3.hl.TZ0.a: State two common side effects of radiotherapy.
- 19N.3.hl.TZ0.b: Explain why technetium-99m is the most common radioisotope used in nuclear medicine.
-
19N.3.hl.TZ0.c:
25.0 μg of iodine-131, with a half-life of 8.00 days, was left to decay.
Calculate the mass of iodine-131, in μg, remaining after 32.0 days. Use section 1 of the data booklet.
-
19N.3.sl.TZ0.18a:
State one difference between bacteria and viruses.
- 19N.3.sl.TZ0.18b: Discuss two difficulties, apart from socio-economic factors, associated with finding a cure for...
- 19N.3.sl.TZ0.18c: The discovery of penicillins contributed to the development of antibiotics. Explain how the...
-
19N.3.sl.TZ0.a:
State one difference between bacteria and viruses.
- 19N.3.sl.TZ0.b: Discuss two difficulties, apart from socio-economic factors, associated with finding a cure for...
- 19N.3.sl.TZ0.c: The discovery of penicillins contributed to the development of antibiotics. Explain how the...
- 19N.3.sl.TZ0.19a: Outline the impact of antibiotic waste on the environment.
- 19N.3.sl.TZ0.19b: Suggest a concern about the disposal of solvents from drug manufacturing.
- 19N.3.sl.TZ0.a: Outline the impact of antibiotic waste on the environment.
- 19N.3.sl.TZ0.b: Suggest a concern about the disposal of solvents from drug manufacturing.
-
20N.3.sl.TZ0.11a:
Deduce the structural formula of the by-product of this reaction.
- 20N.3.sl.TZ0.11b: Aspirin crystals are rinsed with water after recrystallization to remove impurities.Suggest why...
-
20N.3.sl.TZ0.11c:
The solubility of aspirin is increased by converting it to an ionic form. Draw the structure of the ionic form of aspirin.
-
20N.3.sl.TZ0.11d:
Comment on the risk of overdose when taking aspirin as an analgesic, referring to the following values, for a person weighing :
Minimum therapeutic dose
Estimated minimum lethal dose
-
20N.3.sl.TZ0.a:
Deduce the structural formula of the by-product of this reaction.
- 20N.3.sl.TZ0.b: Aspirin crystals are rinsed with water after recrystallization to remove impurities.Suggest why...
-
20N.3.sl.TZ0.c:
The solubility of aspirin is increased by converting it to an ionic form. Draw the structure of the ionic form of aspirin.
-
20N.3.sl.TZ0.d:
Comment on the risk of overdose when taking aspirin as an analgesic, referring to the following values, for a person weighing :
Minimum therapeutic dose
Estimated minimum lethal dose
-
20N.3.sl.TZ0.12:
Consider the following antacids:
Show that antacid X is more effective, per tablet, than antacid Y.
- 20N.3.sl.TZ0.13a: Describe the proper disposal of low-level radioactive waste in hospitals.
-
20N.3.sl.TZ0.13b:
Outline a green chemistry solution for problems generated by the use of organic solvents.
- 20N.3.sl.TZ0.a: Describe the proper disposal of low-level radioactive waste in hospitals.
-
20N.3.sl.TZ0.b:
Outline a green chemistry solution for problems generated by the use of organic solvents.
- 20N.3.sl.TZ0.14a(i): Name two functional groups that both zanamivir and oseltamivir contain.
-
20N.3.sl.TZ0.14a(ii):
Explain how zanamivir works as a preventative agent against flu viruses.
- 20N.3.sl.TZ0.14b(i): Circle the side-chain in penicillin on the structure below.
-
20N.3.sl.TZ0.14b(ii):
Explain, with reference to the action of penicillin, why new penicillins with different side-chains need to be produced.
- 20N.3.sl.TZ0.14c(i): State and explain the relative solubility of codeine in water compared to morphine and diamorphine.
- 20N.3.sl.TZ0.14c(ii): State the natural source from which codeine, morphine and diamorphine are obtained.
- 20N.3.sl.TZ0.a(i): Name two functional groups that both zanamivir and oseltamivir contain.
-
20N.3.sl.TZ0.a(ii):
Explain how zanamivir works as a preventative agent against flu viruses.
- 20N.3.sl.TZ0.b(i): Circle the side-chain in penicillin on the structure below.
-
20N.3.sl.TZ0.b(ii):
Explain, with reference to the action of penicillin, why new penicillins with different side-chains need to be produced.
- 20N.3.sl.TZ0.c(i): State and explain the relative solubility of codeine in water compared to morphine and diamorphine.
- 20N.3.sl.TZ0.c(ii): State the natural source from which codeine, morphine and diamorphine are obtained.
-
20N.3.hl.TZ0.15a:
Deduce the structural formula of the by-product of this reaction.
- 20N.3.hl.TZ0.15b: Aspirin crystals are rinsed with water after recrystallization to remove impurities.Suggest why...
-
20N.3.hl.TZ0.15c:
The solubility of aspirin is increased by converting it to an ionic form. Draw the structure of the ionic form of aspirin.
-
20N.3.hl.TZ0.15d:
Comment on the risk of overdose when taking aspirin as an analgesic, referring to the following values, for a person weighing :
Minimum therapeutic dose
Estimated minimum lethal dose
-
20N.3.hl.TZ0.15e:
Explain how IR spectroscopy can be used to distinguish aspirin from salicylic acid.
-
20N.3.hl.TZ0.a:
Deduce the structural formula of the by-product of this reaction.
- 20N.3.hl.TZ0.b: Aspirin crystals are rinsed with water after recrystallization to remove impurities.Suggest why...
-
20N.3.hl.TZ0.c:
The solubility of aspirin is increased by converting it to an ionic form. Draw the structure of the ionic form of aspirin.
-
20N.3.hl.TZ0.d:
Comment on the risk of overdose when taking aspirin as an analgesic, referring to the following values, for a person weighing :
Minimum therapeutic dose
Estimated minimum lethal dose
-
20N.3.hl.TZ0.e:
Explain how IR spectroscopy can be used to distinguish aspirin from salicylic acid.
-
20N.3.hl.TZ0.17a:
State the type of radiation technetium-99m emits.
- 20N.3.hl.TZ0.17b: Discuss the properties that make a radioisotope suitable for diagnosis.
-
20N.3.hl.TZ0.17c:
Describe the proper disposal of low-level radioactive waste in hospitals.
-
20N.3.hl.TZ0.17d:
Technetium-99m has a half-life of hours. Calculate the amount of of technetium-99m remaining after hours.
-
20N.3.hl.TZ0.a:
State the type of radiation technetium-99m emits.
- 20N.3.hl.TZ0.b: Discuss the properties that make a radioisotope suitable for diagnosis.
-
20N.3.hl.TZ0.c:
Describe the proper disposal of low-level radioactive waste in hospitals.
-
20N.3.hl.TZ0.d:
Technetium-99m has a half-life of hours. Calculate the amount of of technetium-99m remaining after hours.
-
20N.3.hl.TZ0.18a(ii):
The vapour pressure of pure ethanal at is .
Calculate the vapour pressure of ethanal above the liquid mixture at .
- 20N.3.hl.TZ0.18b: Describe how this mixture is separated by fractional distillation.
-
20N.3.hl.TZ0.a(ii):
The vapour pressure of pure ethanal at is .
Calculate the vapour pressure of ethanal above the liquid mixture at .
- 20N.3.hl.TZ0.b: Describe how this mixture is separated by fractional distillation.
-
20N.3.hl.TZ0.19a:
Explain how zanamivir works as a preventative agent against flu viruses.
- 20N.3.hl.TZ0.19b(i): Circle the side-chain in penicillin on the structure below.
-
20N.3.hl.TZ0.19b(ii):
Explain, with reference to the action of penicillin, why new penicillins with different side-chains need to be produced.
- 20N.3.hl.TZ0.19c(i): State and explain the relative solubility of codeine in water compared to morphine and diamorphine.
- 20N.3.hl.TZ0.19c(ii): State the natural source from which codeine, morphine and diamorphine are obtained.
- 20N.3.hl.TZ0.19d: Circle two chiral carbons in the section of the Taxol structure below.
-
20N.3.hl.TZ0.a:
Explain how zanamivir works as a preventative agent against flu viruses.
- 20N.3.hl.TZ0.b(i): Circle the side-chain in penicillin on the structure below.
-
20N.3.hl.TZ0.b(ii):
Explain, with reference to the action of penicillin, why new penicillins with different side-chains need to be produced.
- 20N.3.hl.TZ0.c(i): State and explain the relative solubility of codeine in water compared to morphine and diamorphine.
- 20N.3.hl.TZ0.c(ii): State the natural source from which codeine, morphine and diamorphine are obtained.
- 20N.3.hl.TZ0.d: Circle two chiral carbons in the section of the Taxol structure below.
-
17N.3.sl.TZ0.16:
Radioisotopes are used to diagnose and treat various diseases. Explain the low environmental impact of most medical nuclear waste.
- 17N.3.sl.TZ0.17a: Aspirin is a mild analgesic derived from salicylic acid found in willow bark. Describe how mild...
-
17N.3.sl.TZ0.17b.i:
The strong analgesics morphine and codeine are opiates. Outline how codeine can be synthesized from morphine. The structures of morphine and codeine are in section 37 of the data booklet.
-
17N.3.sl.TZ0.17b.ii:
Explain why opiates are addictive.
- 17N.3.sl.TZ0.a: Aspirin is a mild analgesic derived from salicylic acid found in willow bark. Describe how mild...
-
17N.3.sl.TZ0.b.i:
The strong analgesics morphine and codeine are opiates. Outline how codeine can be synthesized from morphine. The structures of morphine and codeine are in section 37 of the data booklet.
-
17N.3.sl.TZ0.b.ii:
Explain why opiates are addictive.
-
17N.3.sl.TZ0.18a:
Outline the difference between the therapeutic index in animal studies and the therapeutic index in humans.
- 17N.3.sl.TZ0.18b: State the method of drug administration that gives the maximum bioavailability.
-
17N.3.sl.TZ0.a:
Outline the difference between the therapeutic index in animal studies and the therapeutic index in humans.
- 17N.3.sl.TZ0.b: State the method of drug administration that gives the maximum bioavailability.
-
17N.3.sl.TZ0.19a:
State the names of two functional groups that both compounds contain, using section 37 of the data booklet.
- 17N.3.sl.TZ0.19b: Explain how oseltamivir and zanamivir can stop the spread of the flu virus in the body.
-
17N.3.sl.TZ0.a:
State the names of two functional groups that both compounds contain, using section 37 of the data booklet.
- 17N.3.sl.TZ0.b: Explain how oseltamivir and zanamivir can stop the spread of the flu virus in the body.
-
17N.3.sl.TZ0.20a:
Explain how ranitidine (Zantac) reduces stomach acid production.
-
17N.3.sl.TZ0.20b:
The pH is maintained in different fluids in the body by the use of buffers.
Calculate the pH of a buffer solution of 0.0200 mol dm–3 carbonic acid, H2CO3, and 0.400 mol dm–3 sodium hydrogen carbonate, NaHCO3. The pKa of carbonic acid is 6.35.
-
17N.3.sl.TZ0.a:
Explain how ranitidine (Zantac) reduces stomach acid production.
-
17N.3.sl.TZ0.b:
The pH is maintained in different fluids in the body by the use of buffers.
Calculate the pH of a buffer solution of 0.0200 mol dm–3 carbonic acid, H2CO3, and 0.400 mol dm–3 sodium hydrogen carbonate, NaHCO3. The pKa of carbonic acid is 6.35.
- 17N.3.sl.TZ0.21: Molecules of antibiotics often contain a beta-lactam ring. Explain the importance of the...
-
17N.3.hl.TZ0.21a:
State a nuclear equation to show the decay of lutetium-177.
-
17N.3.hl.TZ0.21b:
The half-life of lutetium-177 is 6.73 days. Determine the percentage of a sample of lutetium-177 remaining after 14.0 days.
-
17N.3.hl.TZ0.21c:
Explain the low environmental impact of most medical nuclear waste.
-
17N.3.hl.TZ0.a:
State a nuclear equation to show the decay of lutetium-177.
-
17N.3.hl.TZ0.b:
The half-life of lutetium-177 is 6.73 days. Determine the percentage of a sample of lutetium-177 remaining after 14.0 days.
-
17N.3.hl.TZ0.c:
Explain the low environmental impact of most medical nuclear waste.
- 17N.3.hl.TZ0.22a.i: Both spectra show a peak at wavenumber 1700 cm–1. Identify the bond responsible for this peak.
-
17N.3.hl.TZ0.22a.ii:
Deduce which spectrum belongs to paracetamol, giving two reasons for your choice. Use section 26 of the data booklet.
- 17N.3.hl.TZ0.22b: Describe how mild analgesics function.
- 17N.3.hl.TZ0.a.i: Both spectra show a peak at wavenumber 1700 cm–1. Identify the bond responsible for this peak.
-
17N.3.hl.TZ0.a.ii:
Deduce which spectrum belongs to paracetamol, giving two reasons for your choice. Use section 26 of the data booklet.
- 17N.3.hl.TZ0.b: Describe how mild analgesics function.
-
17N.3.hl.TZ0.23b:
Explain the role of the chiral auxiliary in the synthesis of Taxol.
-
17N.3.hl.TZ0.b:
Explain the role of the chiral auxiliary in the synthesis of Taxol.
- 17N.3.hl.TZ0.27: Ethanol slows down the reaction time of a driver leading to traffic accidents. Explain how the...
-
18M.3.hl.TZ1.16e:
Many drugs are chiral. Explain how a polarimeter can be used to determine the relative proportion of two enantiomers.
-
18M.3.hl.TZ1.e:
Many drugs are chiral. Explain how a polarimeter can be used to determine the relative proportion of two enantiomers.
-
18M.3.hl.TZ1.19a:
Describe how ionizing radiation destroys cancer cells.
-
18M.3.hl.TZ1.19b:
Outline how Targeted Alpha Therapy (TAT) is used for treating cancers that have spread throughout the body.
-
18M.3.hl.TZ1.a:
Describe how ionizing radiation destroys cancer cells.
-
18M.3.hl.TZ1.b:
Outline how Targeted Alpha Therapy (TAT) is used for treating cancers that have spread throughout the body.
-
18M.3.hl.TZ1.20a:
Hexane and propanone have vapour pressures of 17 kPa and 24 kPa respectively at 20 °C.
Calculate the vapour pressure, in kPa, at 20 °C of a mixture containing 60% hexane and 40% propanone by mole fraction, using Raoult’s law and assuming the mixture is ideal.
-
18M.3.hl.TZ1.20b:
Explain how hexane and propanone may be separated by fractional distillation.
-
18M.3.hl.TZ1.a:
Hexane and propanone have vapour pressures of 17 kPa and 24 kPa respectively at 20 °C.
Calculate the vapour pressure, in kPa, at 20 °C of a mixture containing 60% hexane and 40% propanone by mole fraction, using Raoult’s law and assuming the mixture is ideal.
-
18M.3.hl.TZ1.b:
Explain how hexane and propanone may be separated by fractional distillation.
-
18M.3.hl.TZ2.25:
Taxol was originally obtained from the bark of the Pacific yew tree.
Outline how Green Chemistry has improved the process of obtaining Taxol.
-
18M.3.hl.TZ2.26a:
Phosphorous-32 undergoes beta decay. Formulate a balanced nuclear equation for this process.
-
18M.3.hl.TZ2.26b:
The half-life of phosphorus-32 is 14.3 days. Calculate the mass, in g, of 32P remaining after 57.2 days if the initial sample contains 2.63 × 10−8 mol. Use table 1 of the data booklet and Mr = 31.97 g mol−1.
-
18M.3.hl.TZ2.26c:
Explain the targeted alpha therapy (TAT) technique and why it is useful.
-
18M.3.hl.TZ2.a:
Phosphorous-32 undergoes beta decay. Formulate a balanced nuclear equation for this process.
-
18M.3.hl.TZ2.b:
The half-life of phosphorus-32 is 14.3 days. Calculate the mass, in g, of 32P remaining after 57.2 days if the initial sample contains 2.63 × 10−8 mol. Use table 1 of the data booklet and Mr = 31.97 g mol−1.
-
18M.3.hl.TZ2.c:
Explain the targeted alpha therapy (TAT) technique and why it is useful.
-
18M.3.hl.TZ2.27a:
Fuel cells use an electrochemical process to determine the concentration of ethanol.
Formulate the overall equation for this process.
-
18M.3.hl.TZ2.27b:
Predict the chemical shifts and integration for each signal in the 1H NMR spectrum for ethanol using section 27 of the data booklet.
-
18M.3.hl.TZ2.a:
Fuel cells use an electrochemical process to determine the concentration of ethanol.
Formulate the overall equation for this process.
-
18M.3.hl.TZ2.b:
Predict the chemical shifts and integration for each signal in the 1H NMR spectrum for ethanol using section 27 of the data booklet.
-
18M.3.sl.TZ1.13a:
Aspirin is often taken to reduce pain, swelling or fever. State one other use of aspirin.
-
18M.3.sl.TZ1.13b.i:
State what is meant by the bioavailability of a drug.
-
18M.3.sl.TZ1.13b.ii:
Outline how the bioavailability of aspirin may be increased.
-
18M.3.sl.TZ1.13c.i:
Compare and contrast the IR spectrum of aspirin with that of salicylic acid, using section 26 of the data booklet.
-
18M.3.sl.TZ1.13c.ii:
Describe how penicillin combats bacterial infections.
-
18M.3.sl.TZ1.13c.iii:
Outline two consequences of prescribing antibiotics such as penicillin unnecessarily.
-
18M.3.sl.TZ1.13c.iv:
State how penicillins may be modified to increase their effectiveness.
-
18M.3.sl.TZ1.13d.i:
Morphine and codeine are strong analgesics. Outline how strong analgesics function.
-
18M.3.sl.TZ1.13d.ii:
Suggest one reason why codeine is more widely used than morphine as an analgesic.
-
18M.3.sl.TZ1.a:
Aspirin is often taken to reduce pain, swelling or fever. State one other use of aspirin.
-
18M.3.sl.TZ1.b.i:
State what is meant by the bioavailability of a drug.
-
18M.3.sl.TZ1.b.ii:
Outline how the bioavailability of aspirin may be increased.
-
18M.3.sl.TZ1.c.i:
Compare and contrast the IR spectrum of aspirin with that of salicylic acid, using section 26 of the data booklet.
-
18M.3.sl.TZ1.c.ii:
Describe how penicillin combats bacterial infections.
-
18M.3.sl.TZ1.c.iii:
Outline two consequences of prescribing antibiotics such as penicillin unnecessarily.
-
18M.3.sl.TZ1.c.iv:
State how penicillins may be modified to increase their effectiveness.
-
18M.3.sl.TZ1.d.i:
Morphine and codeine are strong analgesics. Outline how strong analgesics function.
-
18M.3.sl.TZ1.d.ii:
Suggest one reason why codeine is more widely used than morphine as an analgesic.
-
18M.3.sl.TZ1.14a.i:
An antacid tablet contains 680 mg of calcium carbonate, CaCO3, and 80 mg of magnesium carbonate, MgCO3.
State the equation for the reaction of magnesium carbonate with hydrochloric acid.
-
18M.3.sl.TZ1.14a.ii:
Determine the amount, in mol, of hydrochloric acid neutralized by one antacid tablet.
-
18M.3.sl.TZ1.14b:
Explain how omeprazole (Prilosec) reduces stomach acidity.
-
18M.3.sl.TZ1.a.i:
An antacid tablet contains 680 mg of calcium carbonate, CaCO3, and 80 mg of magnesium carbonate, MgCO3.
State the equation for the reaction of magnesium carbonate with hydrochloric acid.
-
18M.3.sl.TZ1.a.ii:
Determine the amount, in mol, of hydrochloric acid neutralized by one antacid tablet.
-
18M.3.sl.TZ1.b:
Explain how omeprazole (Prilosec) reduces stomach acidity.
-
18M.3.sl.TZ1.15a:
Oseltamivir (Tamiflu) and zanamivir (Relenza) are used against flu viruses. Explain how these drugs function.
-
18M.3.sl.TZ1.15b:
Shikimic acid, the precursor for oseltamivir (Tamiflu), was originally extracted from star anise, and is now produced using genetically modified E. coli bacteria.
Suggest one difficulty associated with synthesizing oseltamivir (Tamiflu) from star anise.
-
18M.3.sl.TZ1.a:
Oseltamivir (Tamiflu) and zanamivir (Relenza) are used against flu viruses. Explain how these drugs function.
-
18M.3.sl.TZ1.b:
Shikimic acid, the precursor for oseltamivir (Tamiflu), was originally extracted from star anise, and is now produced using genetically modified E. coli bacteria.
Suggest one difficulty associated with synthesizing oseltamivir (Tamiflu) from star anise.
-
18M.3.sl.TZ2.15:
Drug testing is necessary to determine safe and effective doses.
Distinguish between the lethal dose (LD50) and the toxic dose (TD50).
-
18M.3.sl.TZ2.16a.i:
Describe how penicillin combats bacterial infections.
-
18M.3.sl.TZ2.16a.ii:
State how penicillins may be modified to increase their effectiveness.
-
18M.3.sl.TZ2.16b:
State the type of reaction used to synthesize aspirin from salicylic acid.
-
18M.3.sl.TZ2.16c:
Explain why aspirin is not stored in a hot, humid location.
-
18M.3.sl.TZ2.a.i:
Describe how penicillin combats bacterial infections.
-
18M.3.sl.TZ2.a.ii:
State how penicillins may be modified to increase their effectiveness.
-
18M.3.sl.TZ2.b:
State the type of reaction used to synthesize aspirin from salicylic acid.
-
18M.3.sl.TZ2.c:
Explain why aspirin is not stored in a hot, humid location.
-
18M.3.sl.TZ2.17:
Morphine and diamorphine (heroin) are both opioids.
Explain why diamorphine is more potent than morphine using section 37 of the data booklet.
-
18M.3.sl.TZ2.18a:
Formulate a chemical equation for the neutralization of stomach acid with calcium carbonate.
-
18M.3.sl.TZ2.18b:
Calculate the amount, in mol, of stomach acid neutralized by an antacid tablet containing 0.750 g calcium carbonate.
-
18M.3.sl.TZ2.18c:
Explain how omeprazole (Prilosec) regulates pH in the stomach.
-
18M.3.sl.TZ2.a:
Formulate a chemical equation for the neutralization of stomach acid with calcium carbonate.
-
18M.3.sl.TZ2.b:
Calculate the amount, in mol, of stomach acid neutralized by an antacid tablet containing 0.750 g calcium carbonate.
-
18M.3.sl.TZ2.c:
Explain how omeprazole (Prilosec) regulates pH in the stomach.
-
18M.3.sl.TZ2.19a:
Identify the names of two functional groups present in zanamivir using section 37 of the data booklet.
-
18M.3.sl.TZ2.19b:
Distinguish between bacteria and viruses.
-
18M.3.sl.TZ2.a:
Identify the names of two functional groups present in zanamivir using section 37 of the data booklet.
-
18M.3.sl.TZ2.b:
Distinguish between bacteria and viruses.
-
18M.3.sl.TZ2.20:
Drug synthesis often involves solvents.
Identify a common hazardous solvent and a Green solvent that could replace it.
- 18N.3.sl.TZ0.12a: State the internal bond angles in the β-lactam ring and the expected bond angles for the same...
- 18N.3.sl.TZ0.12b: Explain how the open β-lactam ring kills bacteria.
- 18N.3.sl.TZ0.12c: Outline one effect of over-prescription of penicillin.
- 18N.3.sl.TZ0.12d: State how the structure of penicillin can be changed to combat this effect.
- 18N.3.sl.TZ0.12e: Suggest why human cells are not affected by penicillin.
- 18N.3.sl.TZ0.a: State the internal bond angles in the β-lactam ring and the expected bond angles for the same...
- 18N.3.sl.TZ0.b: Explain how the open β-lactam ring kills bacteria.
- 18N.3.sl.TZ0.c: Outline one effect of over-prescription of penicillin.
- 18N.3.sl.TZ0.d: State how the structure of penicillin can be changed to combat this effect.
- 18N.3.sl.TZ0.e: Suggest why human cells are not affected by penicillin.
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18N.3.sl.TZ0.13a:
Explain why diamorphine (heroin) crosses the blood–brain barrier more easily than morphine.
- 18N.3.sl.TZ0.13b: Describe the analgesic action of an opiate.
- 18N.3.sl.TZ0.13c: Outline the meaning of the bioavailability of a drug.
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18N.3.sl.TZ0.a:
Explain why diamorphine (heroin) crosses the blood–brain barrier more easily than morphine.
- 18N.3.sl.TZ0.b: Describe the analgesic action of an opiate.
- 18N.3.sl.TZ0.c: Outline the meaning of the bioavailability of a drug.
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18N.3.sl.TZ0.14a:
Determine the pH of a buffer solution that is 0.0100 mol dm−3 sodium hydrogen carbonate and 0.0200 mol dm−3 sodium carbonate, using section 1 of the data booklet.
Ka (hydrogen carbonate ion) = 4.8 × 10−11
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18N.3.sl.TZ0.14b:
State the equation for the reaction of calcium carbonate, the active ingredient in some antacids, with stomach acid.
- 18N.3.sl.TZ0.14c: Suggest a technique for measuring the percentage mass of calcium carbonate in this type of...
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18N.3.sl.TZ0.a:
Determine the pH of a buffer solution that is 0.0100 mol dm−3 sodium hydrogen carbonate and 0.0200 mol dm−3 sodium carbonate, using section 1 of the data booklet.
Ka (hydrogen carbonate ion) = 4.8 × 10−11
-
18N.3.sl.TZ0.b:
State the equation for the reaction of calcium carbonate, the active ingredient in some antacids, with stomach acid.
- 18N.3.sl.TZ0.c: Suggest a technique for measuring the percentage mass of calcium carbonate in this type of...
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18N.3.sl.TZ0.15a:
State one way in which viruses differ from bacteria.
- 18N.3.sl.TZ0.15b: Outline two different ways in which antiviral medications work.
-
18N.3.sl.TZ0.a:
State one way in which viruses differ from bacteria.
- 18N.3.sl.TZ0.b: Outline two different ways in which antiviral medications work.
-
18N.3.sl.TZ0.16:
Suggest two reasons why chlorinated solvents should neither be released into the atmosphere nor incinerated (burnt).
- 18N.3.hl.TZ0.16a: State the internal bond angles in the b-lactam ring and the expected bond angles in sp2 and sp3...
- 18N.3.hl.TZ0.16b: Explain how the open β-lactam ring kills bacteria.
- 18N.3.hl.TZ0.16c: State how the structure of penicillin can be modified to combat the effect of resistance caused...
- 18N.3.hl.TZ0.16d: Suggest why human cells are not affected by penicillin.
- 18N.3.hl.TZ0.a: State the internal bond angles in the b-lactam ring and the expected bond angles in sp2 and sp3...
- 18N.3.hl.TZ0.b: Explain how the open β-lactam ring kills bacteria.
- 18N.3.hl.TZ0.c: State how the structure of penicillin can be modified to combat the effect of resistance caused...
- 18N.3.hl.TZ0.d: Suggest why human cells are not affected by penicillin.
-
18N.3.hl.TZ0.17a:
Explain why diamorphine (heroin) crosses the blood–brain barrier more easily than morphine.
- 18N.3.hl.TZ0.17b: Outline the meaning of the bioavailability of a drug.
-
18N.3.hl.TZ0.a:
Explain why diamorphine (heroin) crosses the blood–brain barrier more easily than morphine.
- 18N.3.hl.TZ0.b: Outline the meaning of the bioavailability of a drug.
- 18N.3.hl.TZ0.19: Outline two different ways in which antiviral medications work.
-
18N.3.hl.TZ0.21a:
The diagram shows part of a Taxol molecule in skeletal form.
Draw a circle around each chiral carbon.
- 18N.3.hl.TZ0.21b: Outline how chiral auxiliaries are used to synthesize the desired enantiomer.
- 18N.3.hl.TZ0.21c: Explain the process of solvent extraction by which Taxol is isolated.
-
18N.3.hl.TZ0.a:
The diagram shows part of a Taxol molecule in skeletal form.
Draw a circle around each chiral carbon.
- 18N.3.hl.TZ0.b: Outline how chiral auxiliaries are used to synthesize the desired enantiomer.
- 18N.3.hl.TZ0.c: Explain the process of solvent extraction by which Taxol is isolated.
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18N.3.hl.TZ0.22a:
Alpha particles are more damaging to human cells than any other nuclear radiation and yet they are used in targeted alpha therapy (TAT).
Explain how TAT is relatively safe to use in the treatment of dispersed cancers.
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18N.3.hl.TZ0.22b.i:
Technetium-99m () has a half-life of 6.0 hours. Calculate the percentage of remaining in a sample of the radioisotope after two days.
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18N.3.hl.TZ0.22b.ii:
Suggest why the percentage of technetium-99m remaining in the human body two days after injection will be lower than that calculated in (b)(i).
-
18N.3.hl.TZ0.a:
Alpha particles are more damaging to human cells than any other nuclear radiation and yet they are used in targeted alpha therapy (TAT).
Explain how TAT is relatively safe to use in the treatment of dispersed cancers.
-
18N.3.hl.TZ0.b.i:
Technetium-99m () has a half-life of 6.0 hours. Calculate the percentage of remaining in a sample of the radioisotope after two days.
-
18N.3.hl.TZ0.b.ii:
Suggest why the percentage of technetium-99m remaining in the human body two days after injection will be lower than that calculated in (b)(i).
-
18N.3.hl.TZ0.23a:
State an analytical technique used to separate anabolic steroids from other compounds in an athlete’s urine or blood.
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18N.3.hl.TZ0.23b:
Ethanol in breath can be detected by a redox reaction. Outline this method of detection. An equation is not required.
-
18N.3.hl.TZ0.a:
State an analytical technique used to separate anabolic steroids from other compounds in an athlete’s urine or blood.
-
18N.3.hl.TZ0.b:
Ethanol in breath can be detected by a redox reaction. Outline this method of detection. An equation is not required.