DP Chemistry (last assessment 2024)

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Question 20N.3.hl.TZ0.18b

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Date November 2020 Marks available [Maximum mark: 2] Reference code 20N.3.hl.TZ0.18b
Level hl Paper 3 Time zone TZ0
Command term Describe Question number b Adapted from N/A
b.
[Maximum mark: 2]
20N.3.hl.TZ0.18b

A mixture of 0.100mol ethanal, 0.100mol ethanol and 0.200mol ethanoic acid is fractionally distilled.

(b)

Describe how this mixture is separated by fractional distillation.

[2]

Markscheme

Any two of:
continuous evaporation and condensation
OR
increased surface area in column helps condensation ✔
Accept “glass «beads» aid condensation «in fractionating column»”.

temperature decreases up the fractionating column ✔

liquids condense at different heights
OR
liquid of lowest boiling point collected first
OR
liquid with weakest intermolecular forces collected first
OR
most volatile component collected first
OR
fractions/liquids collected in order of boiling point/volatility ✔
Accept “liquids collected in order of molar mass”.

Examiners report

In this question candidates were required to describe how the mixture can be separated by fractional distillation. Only the better candidates scored both marks, though most gained at least one mark, usually for stating that the most volatile component is collected first. Many did not convey the idea that there is continuous evaporation and condensation in the process or the fact that the temperature decreases up the fractionating column.