DP Chemistry (last assessment 2024)

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Question 19M.3.hl.TZ1.b(ii)

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Date May 2019 Marks available [Maximum mark: 1] Reference code 19M.3.hl.TZ1.b(ii)
Level hl Paper 3 Time zone TZ1
Command term Suggest Question number b(ii) Adapted from N/A
b(ii).
[Maximum mark: 1]
19M.3.hl.TZ1.b(ii)

Lithium has many uses.

The emission spectra obtained by ICP-OES for a mixture containing the isotope 6Li (Li-6) and naturally occurring lithium (Li (N)) is shown.

 

Suggest why ICP-OES does not give good quantitative results for distinguishing 6Li from naturally occurring lithium.

[1]

Markscheme

emission spectra of both «6Li and natural Li» give same colour/produce same «range of» wavelengths
OR
they have same electron transitions/same nuclear charge    [✔]

 

Note: Accept “the spectra are almost identical”.

Examiners report

Most candidates correctly identified the type of bonding and the colour of the emission spectrum of lithium, but frequently referred to the ICP-OES spectra of 6Li and naturally occurring lithium as being the same, rather than similar and thus failed to score the mark in (b)(ii).