DP Chemistry (last assessment 2024)

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Question 20N.3.sl.TZ0.14c(i)

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Date November 2020 Marks available [Maximum mark: 2] Reference code 20N.3.sl.TZ0.14c(i)
Level sl Paper 3 Time zone TZ0
Command term State and explain Question number c(i) Adapted from N/A
c(i).
[Maximum mark: 2]
20N.3.sl.TZ0.14c(i)

Consider the structures of medicinal molecules in section 37 of the data booklet.

(c(i))

State and explain the relative solubility of codeine in water compared to morphine and diamorphine.

[2]

Markscheme

codeine less soluble «in water» than morphine AND more soluble than diamorphine
OR
morphine > codeine > diamorphine «in terms of solubility in water» ✔

more/stronger/greater hydrogen/H bonding «due to more hydroxyl groups leads to greater solubility» ✔

Examiners report

M1 was correctly presented but most students focused on the polarity of the molecules and presented long arguments where intermolecular forces were ignored. The concept of water solubility and hydrogen bonding was largely ignored.