DP Chemistry (last assessment 2024)

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Question 19M.3.sl.TZ1.11d(i)

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Date May 2019 Marks available [Maximum mark: 3] Reference code 19M.3.sl.TZ1.11d(i)
Level sl Paper 3 Time zone TZ1
Command term Explain Question number d(i) Adapted from N/A
d(i).
[Maximum mark: 3]
19M.3.sl.TZ1.11d(i)

Natural gas is an energy source composed mainly of methane.

(d(i))

Explain how methane absorbs infrared (IR) radiation by referring to its molecular geometry and dipole moment.

[3]

Markscheme

methane is tetrahedral
OR
methane has zero dipole moment/is non-polar/bond polarities cancel  [✔]

Any two of:
IR absorption can result in increased vibrations/bending/stretching  [✔]

only modes that cause change in dipole absorb IR [✔]

for methane this is asymmetric bending/stretching [✔]

Examiners report

Comprehensive answers were rare. Many students gained a mark for correct statements about methane’s molecular geometry or polarity, though quite a few totally disregarded the instruction to refer to these. Some seemed aware of the link to vibrational motion and the better ones also identified the need for a change in dipole moment.