DP Chemistry (last assessment 2024)

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Question 19M.3.sl.TZ1.9a

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Date May 2019 Marks available [Maximum mark: 3] Reference code 19M.3.sl.TZ1.9a
Level sl Paper 3 Time zone TZ1
Command term Explain Question number a Adapted from N/A
a.
[Maximum mark: 3]
19M.3.sl.TZ1.9a

The main fatty acid composition of cocoa butter and coconut oil is detailed below.

 

(a)

The melting points of cocoa butter and coconut oil are 34 °C and 25 °C respectively.

Explain this in terms of their saturated fatty acid composition.

[3]

Markscheme

coconut oil has higher content of lauric/short-chain «saturated» fatty acids
OR
cocoa butter has higher content of stearic/palmitic/longer chain «saturated» fatty acids [✔]

longer chain fatty acids have greater surface area/larger electron cloud  [✔]

stronger London/dispersion/instantaneous dipole-induced dipole forces «between triglycerides of longer chain saturated fatty acids»  [✔]

 

Note: Do not accept arguments that relate to the melting points of saturated and unsaturated fats.

Examiners report

A classic instance of candidates answering the question they thought (or hoped?) they had been asked rather than the one that was asked. Almost all answers referred to the differing amounts of saturated and unsaturated fatty acids present, totally ignoring the fact that the question clearly stated “their saturated fatty acid composition”, where the relative lengths of the chains was the key point. Nevertheless some who went on to discuss the nature of the intermolecular forces between the chains gained some credit.