DP Chemistry (last assessment 2024)

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Question 17N.2.hl.TZ0.5b

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Date November 2017 Marks available [Maximum mark: 1] Reference code 17N.2.hl.TZ0.5b
Level hl Paper 2 Time zone TZ0
Command term Calculate Question number b Adapted from N/A
b.
[Maximum mark: 1]
17N.2.hl.TZ0.5b

Ethane-1,2-diol, HOCH2CH2OH, reacts with thionyl chloride, SOCl2, according to the reaction below.

HOCH2CH2OH (l) + 2SOCl2 (l) → ClCH2CH2Cl (l) + 2SO2 (g) + 2HCl (g)

(b)

Calculate the standard entropy change for this reaction using the following data.

[1]

Markscheme

«ΔSθ = [208.5 + 2(248.1) + 2(186.8)] – [166.9 + 2(278.6)]»

«ΔSθ = +» 354.2 «J K–1 mol–1»