DP Chemistry (last assessment 2024)

Test builder »

Question 18M.3.hl.TZ1.20

Select a Test
Date May 2018 Marks available [Maximum mark: 4] Reference code 18M.3.hl.TZ1.20
Level hl Paper 3 Time zone TZ1
Command term Calculate, Explain Question number 20 Adapted from N/A
20.
[Maximum mark: 4]
18M.3.hl.TZ1.20

Organic solvents are commonly used in the pharmaceutical industry.

(a)

Hexane and propanone have vapour pressures of 17 kPa and 24 kPa respectively at 20 °C.

Calculate the vapour pressure, in kPa, at 20 °C of a mixture containing 60% hexane and 40% propanone by mole fraction, using Raoult’s law and assuming the mixture is ideal.

[1]

Markscheme

«vapour pressure = 0.6 × 17 + 0.4 × 24 =»

19.8 «kPa»

[1 mark]

(b)

Explain how hexane and propanone may be separated by fractional distillation.

[3]

Markscheme

Any three of:

different molar masses

OR

different strength of intermolecular forces

 

different boiling points

temperature in «fractionating» column decreases upwards

 

«components» condense at different temperatures/heights

OR

«component with» lower boiling point leaves column first

 

[3 marks]