DP Chemistry (last assessment 2024)

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Question 22N.2.hl.TZ0.f.v

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Date November 2022 Marks available [Maximum mark: 3] Reference code 22N.2.hl.TZ0.f.v
Level hl Paper 2 Time zone TZ0
Command term Deduce Question number f.v Adapted from N/A
f.v.
[Maximum mark: 3]
22N.2.hl.TZ0.f.v

Ammonium nitrate, NH4NO3, is used as a high nitrogen fertilizer.

Solid ammonium nitrate can decompose to gaseous dinitrogen monoxide and liquid water.

Deduce the Lewis (electron dot) structure, including formal charges, and shape for dinitrogen monoxide showing nitrogen as the central atom.

 

[3]

Markscheme

Alternative 1

Lewis structure:

 

+/1+/+1 on central N atom AND –/1–/–1 on O atom ✔

 

 

Alternative 2

Lewis structure:

 

+/1+/+1 on central N atom AND –/1–/–1 on other N atom 

 

Shape: linear

 

Accept .

Formal charges are not needed for M1.

Allow ECF for both formal charge and shape.

Only award M3 if the shape corresponds to that expected for the Lewis structure given.

Examiners report

Students on average gained about half marks. Many seemed to be in one of two camps; those that knew of the resonance structures of the molecule, and usually scored 3 marks, and those who gained zero because they did not, though occasionally the latter group would score one of the other marks as an ECF.