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Question 23M.2.HL.TZ2.a

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Date May 2023 Marks available [Maximum mark: 6] Reference code 23M.2.HL.TZ2.a
Level HL Paper 2 Time zone TZ2
Command term Deduce, Determine, Identify Question number a Adapted from N/A
a.
[Maximum mark: 6]
23M.2.HL.TZ2.a

An unknown organic compound, X, comprising of only carbon, hydrogen and oxygen was found to contain 48.6 % of carbon and 43.2 % of oxygen.

(i)

Determine the empirical formula.

[3]

Markscheme

«n(C) =» 4.05 «mol»
AND
«n(O) =» 2.70 «mol» ✓

«% H =» 8.2 %
OR
«n(H) =» 8.12 «mol» ✓

«empirical formula =» C3H6O2

Award [2] for the simplest ratio ″1.5 C: 3 H: 1 O″.

The infrared spectrum of X is shown.

[Source: SDBS, National Institute of Advanced Industrial Science and Technology.]

(iii)

Identify the bonds making the major contribution to peaks A and B using section 26 of the data booklet.

 

A: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

B: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

[2]

Markscheme

A:
O-H «in carboxylic acids» ✓

B:
C=O ✓

(iv)

Deduce the structural formula of X.

[1]

Markscheme

Do not accept molecular formula/C2H6O2.