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Question 19M.2.SL.TZ1.4b.ii

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Date May 2019 Marks available [Maximum mark: 4] Reference code 19M.2.SL.TZ1.4b.ii
Level SL Paper 2 Time zone TZ1
Command term Determine Question number b.ii Adapted from N/A
b.ii.
[Maximum mark: 4]
19M.2.SL.TZ1.4b.ii

A tube of constant circular cross-section, sealed at one end, contains an ideal gas trapped by a cylinder of mercury of length 0.035 m. The whole arrangement is in the Earth’s atmosphere. The density of mercury is 1.36 × 104 kg m–3.

When the mercury is above the gas column the length of the gas column is 0.190 m.

The tube is slowly rotated until the gas column is above the mercury.

The length of the gas column is now 0.208 m. The temperature of the trapped gas does not change during the process.

(b.ii)

Determine the atmospheric pressure. Give a suitable unit for your answer.

[4]

Markscheme

recognition that  nRT A is constant OR 190po + 190pm208po − 208pm

OR  po = 398 18 pm

pressure due to mercury pm = 0.035 × 1.36 × 104 × 9.81(= 4.67 × 103 Pa) ✔

1.03 × 105

Pa OR Nm-2 OR kgm-1s-2

Do not award for a bald correct answer. Working must be shown to award MP3.

Award MP4 for any correct unit of pressure (eg “mm of mercury / Hg”).

Examiners report

This question was left blank by many candidates. Of those who attempted a solution, few appreciated the difference made to the derived equation from 4bi when the tube was rotated. It should be noted that this was also the “unit question” on this exam, and a candidate could have been awarded a mark for clearly writing any correct unit of pressure without doing any calculations. Candidates should be reminded to keep an eye out for this opportunity and to at least write a unit even if the question seems unapproachable.