DP Chemistry (first assessment 2025)
Question 19M.2.HL.TZ2.g(i)
Date | May 2019 | Marks available | [Maximum mark: 2] | Reference code | 19M.2.HL.TZ2.g(i) |
Level | HL | Paper | 2 | Time zone | TZ2 |
Command term | Determine | Question number | g(i) | Adapted from | N/A |
g(i).
[Maximum mark: 2]
19M.2.HL.TZ2.g(i)
Determine the standard entropy change, in J K−1, for the decomposition of dinitrogen monoxide.
2N2O (g) → 2N2 (g) + O2 (g)
[2]
Markscheme
ΔSθ = 2(Sθ(N2)) + Sθ(O2) – 2(Sθ(N2O))
OR
ΔSθ = 2 × 193 «J mol-1 K-1» + 205 «J mol-1 K-1» – 2 × 220 «J mol-1 K-1» [✔]
«ΔSθ = +»151 «J K-1» [✔]
Note: Award [2] for correct final answer.
Examiners report
Candidates were able to calculate the ΔS of the reaction, though in some cases they failed to multiply by the number of moles.

Syllabus sections
Reactivity 1. What drives chemical reactions? » Reactivity 1.4—Entropy and spontaneity (Additional higher level) » Reactivity 1.4.2—Change in Gibbs energy, ΔG, relates the energy that can be obtained from a chemical reaction to the change in enthalpy, ΔH, change in entropy, ΔS, and absolute temperature, T. Apply the equation ΔG⦵ = ΔH⦵ − TΔS⦵ to calculate unknown values of these terms.