DP Chemistry (last assessment 2024)

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Question 19M.3.hl.TZ1.7

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Date May 2019 Marks available [Maximum mark: 3] Reference code 19M.3.hl.TZ1.7
Level hl Paper 3 Time zone TZ1
Command term Explain, State Question number 7 Adapted from N/A
7.
[Maximum mark: 3]
19M.3.hl.TZ1.7

EDTA chelates with Ni2+ (aq).

[Ni(H2O)6]2+ (aq) + EDTA4− (aq)  [Ni(EDTA)]2− (aq) + 6H2O (l)

(a)

Explain how entropy affects this equilibrium.

[2]

Markscheme

entropy increases «and the reaction proceeds to the right»   [✔]

more species / free molecules are formed
OR
more ways of distributing energy   [✔]

Examiners report

There were several incorrect responses that products were more ordered than the reactants.

(b)

State the number of coordinate covalent bonds EDTA forms with Ni2+.

[1]

Markscheme

six    [✔]

Examiners report

Proved very challenging with very few candidates knowing the number of coordinate covalent bonds EDTA forms with a nickel ion.