DP Chemistry (last assessment 2024)

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Question 17N.3.sl.TZ0.4

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Date November 2017 Marks available [Maximum mark: 7] Reference code 17N.3.sl.TZ0.4
Level sl Paper 3 Time zone TZ0
Command term Explain, Outline, Suggest Question number 4 Adapted from N/A
4.
[Maximum mark: 7]
17N.3.sl.TZ0.4

It is wise to fill dental cavities before irreversible tooth decay sets in. An amalgam (alloy of mercury, silver, and other metals) is often used although many prefer a white composite material.

(a)

Outline the composition of an alloy and a composite.

[2]

Markscheme

Alloy:
mixture of metal with other metals/non-metals

OR

mixture of elements that retains the properties of a metal

Composite:
reinforcing phase embedded in matrix phase

Award [1 max] for implying “composites only have heterogeneous/nonhomogeneous compositions”.

[Max 2 Marks]

(b.i)

Outline why an alloy is usually harder than its components by referring to its structure.

[1]

Markscheme

difference in ionic/atomic radius prevents layers sliding over each other

Accept “difference in diameter/packing of cations prevents layers sliding over each other”.

(b.ii)

At present, composite fillings are more expensive than amalgam fillings.

Suggest why a patient might choose a composite filling.

[1]

Markscheme

concern about Hg poisoning
OR
«composite» is white «so looks more like tooth»
OR
galvanic response potential exists
OR
local allergic potential
OR
less damage/destruction of healthy tooth tissue
OR
long term corrosion requires replacement
OR
gradual darkening of tooth

Accept other correct responses.

(c)

Explain how Inductively Coupled Plasma (ICP) Spectroscopy could be used to determine the concentration of mercury in a sample of dental filling.

[3]

Markscheme

Any three of:

sample injected into argon «plasma»

atoms «of sample» are excited/ionised

OR

electrons are promoted

electrons drop back/recombine with ions AND emit photons of characteristic energies/wavelengths/frequencies

total number of photons is proportional to concentration of element

actual concentration found from calibration/standard curve

Accept "graph/plot" for “curve”.

[Max 3 Marks]