DP Chemistry (last assessment 2024)

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Question 18M.3.hl.TZ1.14

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Date May 2018 Marks available [Maximum mark: 8] Reference code 18M.3.hl.TZ1.14
Level hl Paper 3 Time zone TZ1
Command term Apply, Deduce, Explain, Identify, State Question number 14 Adapted from N/A
14.
[Maximum mark: 8]
18M.3.hl.TZ1.14

Modern electric cars store their energy in lithium ion batteries.

The diagram represents a cell in such a battery delivering a current.

(a.i)

Complete the half-equations on the diagram and identify the species moving between the electrodes.

M18/4/CHEMI/HP3/ENG/TZ1/14.a.i

[3]

Markscheme

 

Accept any balanced equation which shows Li oxidized to Li+ for M3, such as

LiC6 → Li+ + C6 + e–     or

LixC6 → xLi+ + 6C + xe

[3 marks]

(a.ii)

State the factor that limits the maximum current that can be drawn from this cell and how electrodes are designed to maximize the current.

[2]

Markscheme

Limiting factor:

internal resistance «of the cell»

Electrodes design:

large surface area

 

Accept “time it takes ions to diffuse between electrodes”.

Accept specific ways of increasing surface area, such as “porous electrodes”.

Accept “close together/small separation”.

[2 marks]

The carbon footprint of electric cars depends on how the electricity is produced. Nuclear fission of 235U is one source of electrical energy that has a minimal carbon footprint.

(b.ii)

Explain how the proportion of 235U in natural uranium is increased.

[3]

Markscheme

uranium converted to uranium hexafluoride/UF6 gas

 

ALTERNATIVE 1:

gas «allowed to» diffuse

lower mass isotope/235U passes through more rapidly

 

ALTERNATIVE 2:

use of centrifuge

 

higher mass isotope/238U moves/closer to outside of centrifuge

OR

lower mass isotope/235U stays in/removed from middle of centrifuge

 

[3 marks]