DP Chemistry (last assessment 2024)

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Question 18M.3.sl.TZ1.3

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Date May 2018 Marks available [Maximum mark: 8] Reference code 18M.3.sl.TZ1.3
Level sl Paper 3 Time zone TZ1
Command term Describe, Discuss, State Question number 3 Adapted from N/A
3.
[Maximum mark: 8]
18M.3.sl.TZ1.3

Aluminium and high density polyethene (HDPE) are both materials readily found in the kitchen, for example as saucepans and mixing bowls respectively. In these applications it is important that they are impermeable to water.

(a)

Discuss, in terms of its structure, why an aluminium saucepan is impermeable to water.

[2]

Markscheme

«close packed» lattice of metal atoms/ions

no spaces for water molecules to pass though the structure

[2 marks]

Both materials are also used in other applications that are more demanding of their physical properties. Carbon nanotubes are often incorporated into their structures to improve certain properties.

(b.i)

State the name given to a material composed of two distinct solid phases.

[1]

Markscheme

composite

[1 mark]

(b.ii)

State one physical property of HDPE that will be affected by the incorporation of carbon nanotubes.

[1]

Markscheme

melting point

OR

permeability

OR

density

OR

conductivity

OR

elasticity/stiffness

OR

brittleness/flexibility

OR

«tensile» strength

 

Accept “colour/transparency”.

[1 mark]

(b.iii)

Describe how carbon nanotubes are produced by chemical vapour deposition (CVD).

[3]

Markscheme

Any three of:

hydrocarbon/carbon-containing gas/compound

mixed with inert gas

heat/high temperature

«transition» metal catalyst

hydrocarbon/carbon compound decomposes to form carbon «nanotubes»

nanotubes form on catalyst surface

 

Accept “ethanol” or specific hydrocarbons.

Accept “N2”, “H2”, “NH3” or specific inert gases.

Accept temperature or range within 600–800 °C.

Accept specific metals such as Ni, Co or Fe.

[3 marks]

(b.iv)

State the property of carbon nanotubes that enables them to form a nematic liquid crystal phase.

[1]

Markscheme

rod shaped molecules

[1 mark]