DP Chemistry (last assessment 2024)

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Question 22M.2.hl.TZ1.6b(i)

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Date May 2022 Marks available [Maximum mark: 1] Reference code 22M.2.hl.TZ1.6b(i)
Level hl Paper 2 Time zone TZ1
Command term Deduce Question number b(i) Adapted from N/A
b(i).
[Maximum mark: 1]
22M.2.hl.TZ1.6b(i)

Nitric acid is usually produced by the oxidation of ammonia.

A mixture of nitric acid and sulfuric acid can be used to convert benzene to nitrobenzene, C6H5NO2.

(b(i))

Write an equation for the reaction between the acids to produce the electrophile, NO2+.

[1]

Markscheme

HNO3 + 2H2SO4  NO2+ + H3O+ + 2HSO4-

 

Accept “HNO3 + H2SO4  NO2+ + H2O + HSO4-”.

Accept “HNO3 + H2SO4  H2NO3+ + HSO4-AND “H2NO3+  NO2+ + H2O”.

Accept single arrows instead of equilibrium signs.

Examiners report

Many had difficulties writing the balanced equation(s) for the formation of the nitronium ion.