DP Chemistry (first assessment 2025)

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Question 21M.2.SL.TZ1.6

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Date May 2021 Marks available [Maximum mark: 5] Reference code 21M.2.SL.TZ1.6
Level SL Paper 2 Time zone TZ1
Command term Deduce, Draw, Outline, Suggest Question number 6 Adapted from N/A
6.
[Maximum mark: 5]
21M.2.SL.TZ1.6

When dinitrogen pentoxide, N2O5, is heated the colourless gas undergoes thermal decomposition to produce brown nitrogen dioxide:

N2O5 (g) → 2NO2 (g) + 12O2 (g)

Data for the decomposition at constant temperature is given.

(a)

Suggest how the extent of decomposition could be measured.

[1]

Markscheme

use colorimeter
OR
change in colour
OR
change in volume
OR
change in pressure ✔

Accept suitable instruments, e.g. pressure probe/oxygen sensor.

(b(i))

Plot the missing point on the graph and draw the best-fit line.

[2]

Markscheme

point correct ✔

straight line passing close to all points AND through origin ✔


Accept free hand drawn line as long as attempt to be linear and meets criteria for M2.

(b(ii))

Deduce the relationship between the concentration of N2O5 and the rate of reaction.

[1]

Markscheme

« rate of reaction is directly» proportional to/∝[N2O5]
OR
doubling concentration doubles rate ✔


Do not accept “rate increases as concentration increases”/ positive correlation

Accept linear

(b(iii))

Outline why increasing the concentration of N2O5 increases the rate of reaction.

[1]

Markscheme

greater frequency of collisions «as concentration increases»
OR
more collisions per unit time «as concentration increases» ✔


Accept “rate/chance/probability/likelihood” instead of “frequency”.

Do not accept just “more collisions”.