DP Chemistry (first assessment 2025)
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Structure 3.1—The periodic table: Classification of elements

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Structure 3.1.1—The periodic table consists of periods, groups and blocks. Identify the positions of metals, metalloids and non-metals in the periodic table.

Structure 3.1.2—The period number shows the outer energy level that is occupied by electrons. Elements in a group have a common number of valence electrons. Deduce the electron configuration of an atom up to Z = 36 from the element’s position in the periodic table and vice versa.

Structure 3.1.3—Periodicity refers to trends in properties of elements across a period and down a group.

Structure 3.1.4—Trends in properties of elements down a group include the increasing metallic character of group 1 elements and decreasing non-metallic character of group 17 elements. Describe and explain the reactions of group 1 metals with water, and of group 17 elements with halide ions.

Structure 3.1.5—Metallic and non-metallic properties show a continuum. This includes the trend from basic metal oxides through amphoteric to acidic non-metal oxides. Deduce equations for the reactions with water of the oxides of group 1 and group 2 metals, carbon and sulfur.

Structure 3.1.6—The oxidation state is a number assigned to an atom to show the number of electrons transferred in forming a bond. It is the charge that atom would have if the compound were composed of ions. Deduce the oxidation states of an atom in an ion or a compound.

Structure 3.1.7—Discontinuities occur in the trend of increasing first ionization energy across a period. Explain how these discontinuities provide evidence for the existence of energy sublevels.

Structure 3.1.8—Transition elements have incomplete d-sublevels that give them characteristic properties. Recognize properties, including: variable oxidation state, high melting points, magnetic properties, catalytic properties, formation of coloured compounds and formation of complex ions with ligands.

Structure 3.1.9—The formation of variable oxidation states in transition elements can be explained by the fact that their successive ionization energies are close in value. Deduce the electron configurations of ions of the first-row transition elements.

Structure 3.1.10—Transition element complexes are coloured due to the absorption of light when an electron is promoted between the orbitals in the split d-sublevels. The colour absorbed is complementary to the colour observed. Apply the colour wheel to deduce the wavelengths and frequencies of light absorbed and/or observed.