• IB
  • IB Docs (2) Team
    Logout
  • Maths
  • Biology
  • Chemistry
  • Physics
  • Combined Science
  • English Language
  • Geography
  • Other Subjects
GCSE Maths
Edexcel Topic QuestionsRevision NotesPast PapersPast Papers Questions
AQA Topic QuestionsRevision NotesPast Papers
OCR Topic QuestionsRevision NotesPast Papers
GCSE Biology
Edexcel Topic QuestionsRevision NotesPast Papers
AQA Topic QuestionsRevision NotesPast Papers
OCR Gateway Topic QuestionsRevision NotesPast Papers
GCSE Chemistry
Edexcel Topic QuestionsRevision NotesPast Papers
AQA Topic QuestionsRevision NotesPast Papers
OCR Gateway Topic QuestionsRevision NotesPast Papers
GCSE Physics
Edexcel Topic QuestionsRevision NotesPast Papers
AQA Topic QuestionsRevision NotesPast Papers
OCR Gateway Topic QuestionsRevision NotesPast Papers
GCSE Combined Science
Edexcel Combined: Biology Topic QuestionsRevision NotesPast Papers
Edexcel Combined: Chemistry Topic QuestionsRevision NotesPast Papers
Edexcel Combined: Physics Revision NotesPast Papers
AQA Combined: Biology Topic QuestionsRevision NotesPast Papers
AQA Combined: Chemistry Topic QuestionsRevision NotesPast Papers
AQA Combined: Physics Topic QuestionsRevision NotesPast Papers
OCR Gateway Combined: Biology Topic QuestionsRevision Notes
OCR Gateway Combined: Chemistry Revision Notes
OCR Gateway Combined: Physics Revision Notes
GCSE English Language
AQA Revision NotesPractice PapersPast Papers
Edexcel Past Papers
OCR Past Papers
GCSE Geography
AQA Topic QuestionsRevision Notes
Edexcel Topic Questions
GCSE Other Subjects
AQA English LiteratureBusinessComputer ScienceEconomicsFurther MathsGeographyHistoryPsychologySociologyStatistics
Edexcel English LiteratureBusinessComputer ScienceGeographyHistoryPsychologyStatistics
OCR English LiteratureBusinessComputer ScienceEconomicsPsychology
OCR Gateway GeographyHistory
  • Maths
  • Biology
  • Chemistry
  • Physics
  • Double Science
  • Economics
  • English Language
  • Geography
  • Other Subjects
IGCSE Maths
Edexcel Topic QuestionsRevision NotesPast PapersBronze-Silver-Gold Questions
CIE (Extended) Topic QuestionsRevision NotesPast Papers
CIE (Core) Topic QuestionsPast Papers
IGCSE Biology
Edexcel Topic QuestionsRevision NotesPast Papers
CIE 2020-2022 Topic QuestionsRevision NotesPast Papers
CIE 2023-2025 Topic QuestionsRevision NotesPast Papers
IGCSE Chemistry
Edexcel Topic QuestionsRevision NotesPast Papers
CIE 2020-2022 Topic QuestionsRevision NotesPast Papers
CIE 2023-2025 Topic QuestionsRevision NotesPast Papers
IGCSE Physics
Edexcel Topic QuestionsRevision NotesPast Papers
CIE 2020-2022 Topic QuestionsRevision NotesPast Papers
CIE 2023-2025 Topic QuestionsRevision NotesPast Papers
IGCSE Double Science
Edexcel Double: Biology Topic QuestionsRevision NotesPast Papers
Edexcel Double: Chemistry Topic QuestionsRevision NotesPast Papers
Edexcel Double: Physics Topic QuestionsRevision NotesPast Papers
IGCSE Economics
CIE Topic QuestionsRevision NotesPast Papers
IGCSE English Language
CIE Revision NotesPractice PapersPast Papers
Edexcel Past Papers
IGCSE Geography
CIE Revision NotesTopic QuestionsPast Papers
Edexcel Topic QuestionsRevision NotesPast Papers
IGCSE Other Subjects
CIE Additional MathsEnglish LiteratureBusinessComputer ScienceHistorySociology
Edexcel English LiteratureBusinessComputer ScienceHistoryFurther Maths
  • Maths
  • Biology
  • Chemistry
  • Physics
  • English Language
  • Other Subjects
AS Maths
Edexcel Pure MathsMechanicsStatistics
AQA Pure MathsMechanicsStatistics
OCR Pure MathsMechanicsStatistics
CIE Pure 1Pure 2MechanicsProbability & Statistics 1
Edexcel IAS Pure 1Pure 2MechanicsStatistics
AS Biology
AQA Topic QuestionsRevision NotesPast Papers
OCR Topic QuestionsRevision NotesPast Papers
CIE 2019-2021 Topic QuestionsRevision NotesPast Papers
CIE 2022-2024 Topic QuestionsRevision NotesPast Papers
Edexcel IAL Revision Notes
AS Chemistry
Edexcel Revision Notes
AQA Topic QuestionsRevision NotesPast Papers
OCR Revision Notes
CIE 2019-2021 Topic QuestionsRevision NotesPast Papers
CIE 2022-2024 Topic QuestionsRevision NotesPast Papers
Edexcel IAL Revision Notes
AS Physics
Edexcel Revision Notes
AQA Topic QuestionsRevision NotesPast Papers
OCR Revision NotesPast Papers
CIE 2019-2021 Topic QuestionsRevision NotesPast Papers
CIE 2022-2024 Topic QuestionsRevision NotesPast Papers
Edexcel IAL Revision Notes
AS English Language
AQA Past Papers
Edexcel Past Papers
OCR Past Papers
AS Other Subjects
AQA BusinessComputer ScienceEconomicsEnglish LiteratureFurther MathsGeographyHistoryPsychologySociology
Edexcel BusinessEconomicsEnglish LiteratureFurther MathsGeographyHistoryPsychology
OCR BusinessComputer ScienceEconomicsEnglish LiteratureFurther Maths AGeographyHistoryPsychologySociology
CIE Further Maths
  • Maths
  • Biology
  • Chemistry
  • Physics
  • English Language
  • Economics
  • Further Maths
  • Psychology
  • Other Subjects
A Level Maths
Edexcel Pure MathsMechanicsStatistics
AQA Pure MathsMechanicsStatistics
OCR Pure MathsMechanicsStatistics
CIE Pure 1Pure 3MechanicsProbability & Statistics 1Probability & Statistics 2
Edexcel IAL Pure 1Pure 2Pure 3Pure 4Mechanics 1Mechanics 2Statistics 1Statistics 2Decision 1
A Level Biology
Edexcel Topic QuestionsPast Papers
Edexcel A (SNAB) Revision Notes
AQA Topic QuestionsRevision NotesPast Papers
OCR Topic QuestionsRevision NotesPast PapersGold Questions
CIE 2019-2021 Topic QuestionsRevision NotesPast Papers
CIE 2022-2024 Topic QuestionsRevision NotesPast Papers
Edexcel IAL Topic QuestionsRevision NotesPast Papers
A Level Chemistry
Edexcel Topic QuestionsRevision NotesPast Papers
AQA Topic QuestionsRevision NotesPast Papers
OCR Topic QuestionsRevision NotesPast PapersGold Questions
CIE 2019-2021 Topic QuestionsRevision NotesPast Papers
CIE 2022-2024 Topic QuestionsRevision NotesPast Papers
Edexcel IAL Topic QuestionsRevision NotesPast Papers
A Level Physics
Edexcel Topic QuestionsRevision NotesPast Papers
AQA Topic QuestionsRevision NotesPast Papers
OCR Topic QuestionsRevision NotesPast Papers
CIE 2019-2021 Topic QuestionsRevision NotesPast Papers
CIE 2022-2024 Topic QuestionsRevision NotesPast Papers
Edexcel IAL Topic QuestionsRevision NotesPast Papers
A Level English Language
AQA Past Papers
CIE Past Papers
Edexcel Past Papers
OCR Past Papers
Edexcel IAL Past Papers
A Level Economics
Edexcel Topic QuestionsRevision NotesPast Papers
AQA Topic QuestionsPast Papers
OCR Past Papers
CIE Past Papers
A Level Further Maths
Edexcel Topic QuestionsRevision NotesPast Papers
AQA Past Papers
OCR Past Papers
CIE Past Papers
Edexcel IAL Past Papers
A Level Psychology
AQA Topic QuestionsRevision NotesPast Papers
CIE Past Papers
Edexcel Past Papers
OCR Past Papers
Edexcel IAL Past Papers
A Level Other Subjects
AQA BusinessComputer ScienceEconomicsEnglish LiteratureGeographyHistorySociology
CIE BusinessComputer ScienceEconomicsEnglish LiteratureGeographySociology
Edexcel BusinessEconomics AEnglish LiteratureGeographyHistory
OCR BusinessComputer ScienceEconomicsEnglish LiteratureGeographyHistorySociology
Edexcel IAL English LiteratureGeography
CIE IAL History
  • Biology
  • Chemistry
  • Physics
  • Other Subjects
O Level Biology
CIE Topic QuestionsPast Papers
O Level Chemistry
CIE Topic QuestionsPast Papers
O Level Physics
CIE Topic QuestionsPast Papers
O Level Other Subjects
CIE Additional MathsMaths D
  • Maths
  • Biology
  • Chemistry
  • Physics
Pre U Maths
CIE Topic QuestionsPast Papers
Pre U Biology
CIE Topic QuestionsPast Papers
Pre U Chemistry
CIE Topic QuestionsPast Papers
Pre U Physics
CIE Topic QuestionsPast Papers
  • Maths
  • Biology
  • Chemistry
  • Physics
  • Economics
IB Maths
Maths: AA HL Topic QuestionsRevision NotesPractice Papers
Maths: AI HL Topic QuestionsRevision NotesPractice Papers
Maths: AA SL Topic QuestionsRevision NotesPractice Papers
Maths: AI SL Topic QuestionsRevision NotesPractice Papers
IB Biology
Biology: SL Topic QuestionsRevision NotesPractice Papers
Biology: HL Topic QuestionsRevision NotesPractice Papers
IB Chemistry
Chemistry: SL Topic QuestionsRevision NotesPractice Papers
Chemistry: HL Topic QuestionsRevision NotesPractice Papers
IB Physics
Physics: SL Topic QuestionsRevision NotesPractice Papers
Physics: HL Topic QuestionsRevision NotesPractice Papers
IB Economics
Economics: SL Revision Notes

DP IB Chemistry: HL

Revision Notes

Home / IB / Chemistry: HL / DP / Revision Notes / 4. Chemical Bonding & Structure / 4.1 Ionic & Covalent Bonding / 4.1.4 Covalent Bonds


4.1.4 Covalent Bonds


Covalent Bonds

  • Covalent bonding occurs between two non-metals
  • A covalent bond involves the electrostatic attraction between nuclei of two atoms and the electrons of their outer shells
  • No electrons are transferred but only shared in this type of bonding
  • When a covalent bond is formed, two atomic orbitals overlap and a molecular orbital is formed
  • Covalent bonding happens because the electrons are more stable when attracted to two nuclei than when attracted to only one

The positive nucleus of each atom has an attraction for the bonding electrons shared in the covalent bond

  • In a normal covalent bond, each atom provide one of the electrons in the bond. A covalent bond is represented by a short straight line between the two atoms, H-H
  • Covalent bonds should not be regarded as shared electron pairs in a fixed position; the electrons are in a state of constant motion and are best regarded as charge clouds

Hydrogen molecular orbital, downloadable IB Chemistry revision notes

A representation of electron charge clouds. The electrons can be found anywhere in the charge clouds

  • Non-metals are able to share pairs of electrons to form different types of covalent bonds
  • Sharing electrons in the covalent bond allows each of the 2 atoms to achieve an electron configuration similar to a noble gas
    • This makes each atom more stable
  • In some instances, the central atom of a covalently bonded molecule can accommodate more or less than 8 electrons in its outer shell
    • Being able to accommodate more than 8 electrons in the outer shell is known as ‘expanding the octet rule’
    • Accommodating less than 8 electrons in the outer shell means than the central atom is ‘electron deficient’
    • Some examples of this can be found in the section on Lewis structures

Exam Tip

Covalent bonding takes place between two nonmetal atoms.Remember to use the periodic table to decide how many electrons are in the outer shell of a nonmetal atom.

Predicting Covalent Bonding

  • The differences in Pauling electronegativity values can be used to predict whether a bond is covalent or ionic in character

Electronegativity & covalent bonds

  • In diatomic molecules the electron density is shared equally between the two atoms
    • Eg. H2, O2 and Cl2

  • Both atoms will have the same electronegativity value and have an equal attraction for the bonding pair of electrons leading to formation of a covalent bond
  • A difference of less than around 1.0 in electronegativity values will be associated with covalent bonds, although between 1.0 and 2.0 can be considered polar covalent:

You can use the Pauling scale to decide whether a bond is polar or nonpolar:Chemical Bonding Table_4, downloadable AS & A Level Chemistry revision notes

Coordinate Bonds

  • In simple covalent bonds the two atoms involved share electrons
  • Some molecules have a lone pair of electrons that can be donated to form a bond with an electron-deficient atom
    • An electron-deficient atom is an atom that has an unfilled outer orbital
  • So both electrons are from the same atom
  • This type of bonding is called dative covalent bonding or coordinate bond
  • An example of a dative bond is in an ammonium ion
    • The hydrogen ion, H+ is electron-deficient and has space for two electrons in its shell
    • The nitrogen atom in ammonia has a lone pair of electrons which it can donate to the hydrogen ion to form a dative covalent bond

Dative Covalent Bonding Ammonium ion, downloadable IB Chemistry revision notes

Ammonia (NH3) can donate a lone pair to an electron-deficient proton (H+) to form a charged ammonium ion (NH4+)

  • More examples of coordinate bonding can be found in the section on Lewis Structures

Multiple Bonds

  • Non-metals are able to share more than one pair of electrons to form different types of covalent bonds
  • Sharing electrons in the covalent bond allows each of the 2 atoms to achieve an electron configuration similar to a noble gas
    • This makes each atom more stable
  • It is not possible to form a quadruple bond as the repulsion from having 8 electrons in the same region between the two nuclei is too great

Covalent Bonds & Shared Electrons Table

Chemical Bonding Table_8, downloadable AS & A Level Chemistry revision notes

Bond Length & Strength

Bond energy

  • The bond energy is the energy required to break one mole of a particular covalent bond in the gaseous states
    • Bond energy has units of kJ mol-1

  • The larger the bond energy, the stronger the covalent bond is

Bond length

  • The bond length is internuclear distance of two covalently bonded atoms
    • It is the distance from the nucleus of one atom to another atom which forms the covalent bond

  • The greater the forces of attraction between electrons and nuclei, the more the atoms are pulled closer to each other
  • This decreases the bond length of a molecule and increases the strength of the covalent bond
  • Triple bonds are the shortest and strongest covalent bonds due to the large electron density between the nuclei of the two atoms
  • This increase the forces of attraction between the electrons and nuclei of the atoms
  • As a result of this, the atoms are pulled closer together causing a shorter bond length
  • The increased forces of attraction also means that the covalent bond is stronger

Chemical Bonding Bond Lengths and Strengths, downloadable AS & A Level Chemistry revision notes

Triple bonds are the shortest covalent bonds and therefore the strongest ones

 
  • Test your knowledge of covalent bonding:

Worked Example

Which molecules react together to form a dative covalent bond?

A. Cl2 and HF

B. C2H2 and Cl2

C. NH3 and HF

D. CH4 and NH3

Answer:

The correct option is C.

    • To form a dative covalent bond one species must have a lone pair of electrons and the other must be electron deficient.
    • NH3 has a lone pair and HF splits into H+ (electron deficient) and F-

 NH3 +  HF → NH4+ F-



  • 1. Stoichiometric Relationships
    • 1.1 Matter, Chemical Change & the Mole Concept
      • 1.1.1 Elements, Compounds & Mixtures
        • 1.1.2 Equations
          • 1.1.3 State Changes
            • 1.1.4 The Mole Concept
              • 1.1.5 Moles-Mass Problems
                • 1.1.6 Empirical Formulae
                • 1.2 Reacting Masses & Volumes
                  • 1.2.1 Reacting Masses
                    • 1.2.2 Reaction Yields
                      • 1.2.3 Avogadro's Law & Molar Gas Volume
                        • 1.2.4 The Ideal Gas Equation
                          • 1.2.5 Gas Law Relationships
                            • 1.2.6 Real Gases
                              • 1.2.7 Standard Solutions
                                • 1.2.8 Concentration Calculations
                                  • 1.2.9 Titrations
                                • 2. Atomic Structure
                                  • 2.1 Atomic & Electronic Structure
                                    • 2.1.1 The Nuclear Atom
                                      • 2.1.2 Deducing Subatomic Particles
                                        • 2.1.3 Relative Atomic Mass Calculations
                                          • 2.1.4 The Electromagnetic Spectrum
                                            • 2.1.5 Emission Spectra
                                              • 2.1.6 Energy Levels & Sublevels
                                                • 2.1.7 Sublevels & Orbitals
                                                  • 2.1.8 Writing Electron Configurations
                                                • 3. Periodicity
                                                  • 3.1 The Periodic Table & Periodic Trends
                                                    • 3.1.1 The Periodic Table
                                                      • 3.1.2 Periodic Trends: Physical - Atomic & Ionic Radius
                                                        • 3.1.3 Periodic Trends: Physical - Ionisation Energy
                                                          • 3.1.4 Periodic Trends: Physical - Electron Affinity
                                                            • 3.1.5 Periodic Trends: Physical - Electronegativity
                                                              • 3.1.6 Periodic Trends: Chemical
                                                              • 3.2 Oxides, Group 1 & Group 17
                                                                • 3.2.1 Periodic Trends: Oxides Across a Period
                                                                  • 3.2.2 Periodic Trends: Group 1 - The Alkali Metals
                                                                    • 3.2.3 Periodic Trends: Group 17 - The Halogens
                                                                  • 4. Chemical Bonding & Structure
                                                                    • 4.1 Ionic & Covalent Bonding
                                                                      • 4.1.1 Forming Ions
                                                                        • 4.1.2 Ionic Compounds
                                                                          • 4.1.3 Formulae & Names of Ionic Compounds
                                                                            • 4.1.4 Covalent Bonds
                                                                              • 4.1.5 Bond Polarity
                                                                                • 4.1.6 Lewis Structures
                                                                                • 4.2 Resonance, Shapes & Giant Structures
                                                                                  • 4.2.1 Resonance Structures
                                                                                    • 4.2.2 Shapes of Molecules
                                                                                      • 4.2.3 Predicting Molecular Shapes
                                                                                        • 4.2.4 Molecular Polarity
                                                                                          • 4.2.5 Giant Covalent Structures
                                                                                          • 4.3 Intermolecular Forces & Metallic Bonding
                                                                                            • 4.3.1 Types of Intermolecular Forces
                                                                                              • 4.3.2 Deducing Intermolecular Forces
                                                                                                • 4.3.3 Properties of Covalent Compounds
                                                                                                  • 4.3.4 Metallic Bonding
                                                                                                    • 4.3.5 Trends in Melting Points of Metals
                                                                                                      • 4.3.6 Alloys & their Properties
                                                                                                    • 5. Energetics/ Thermochemistry
                                                                                                      • 5.1 Energetics
                                                                                                        • 5.1.1 Energy Changes in Reactions
                                                                                                          • 5.1.2 Standard Enthalpy Change
                                                                                                            • 5.1.3 Calorimetry
                                                                                                              • 5.1.4 Calorimetry Experiments
                                                                                                              • 5.2 Hess's Law
                                                                                                                • 5.2.1 Hess's Law
                                                                                                                  • 5.2.2 Using Hess's Law - Cycles
                                                                                                                    • 5.2.3 Using Hess's Law - Equations
                                                                                                                      • 5.2.4 Using ∆Hf° to Find Enthalpy Changes
                                                                                                                      • 5.3 Bond Enthalpy
                                                                                                                        • 5.3.1 Bond Enthalpy
                                                                                                                          • 5.3.2 Bond Enthalpy Calculations
                                                                                                                            • 5.3.3 Energy Profiles
                                                                                                                              • 5.3.4 Case Study: Ozone
                                                                                                                            • 6. Chemical Kinetics
                                                                                                                              • 6.1 Chemical Kinetics
                                                                                                                                • 6.1.1 Collision Theory
                                                                                                                                  • 6.1.2 Rate of Reaction
                                                                                                                                    • 6.1.3 Measuring Rates
                                                                                                                                      • 6.1.4 Activation Energy
                                                                                                                                        • 6.1.5 Rate Experiments
                                                                                                                                          • 6.1.6 Explaining Rates
                                                                                                                                            • 6.1.7 Maxwell-Boltzmann Curves
                                                                                                                                              • 6.1.8 Energy Profiles & Catalysis
                                                                                                                                            • 7. Equilibrium
                                                                                                                                              • 7.1 Equilibrium
                                                                                                                                                • 7.1.1 The State of Equilibrium
                                                                                                                                                  • 7.1.2 The Equilibrium Law
                                                                                                                                                    • 7.1.3 Equilibrium Constant Relationships
                                                                                                                                                      • 7.1.4 The Reaction Quotient
                                                                                                                                                        • 7.1.5 Le Chatelier's Principle
                                                                                                                                                          • 7.1.6 Catalysts & Equilibrium
                                                                                                                                                        • 8. Acids & Bases
                                                                                                                                                          • 8.1 Theories & Reactions of Acids & Bases
                                                                                                                                                            • 8.1.1 Brønsted–Lowry Acids & Bases
                                                                                                                                                              • 8.1.2 Conjugate Acid-Base Pairs
                                                                                                                                                                • 8.1.3 Characteristic Reactions of Acids
                                                                                                                                                                  • 8.1.4 Neutralization
                                                                                                                                                                  • 8.2 More About Acids
                                                                                                                                                                    • 8.2.1 Acid-base Titrations
                                                                                                                                                                      • 8.2.2 pH & [H⁺]
                                                                                                                                                                        • 8.2.3 Interpreting pH
                                                                                                                                                                          • 8.2.4 The Ionic Product of Water
                                                                                                                                                                            • 8.2.5 Acid-Base Calculations
                                                                                                                                                                              • 8.2.6 pH Meters & Universal Indicator
                                                                                                                                                                                • 8.2.7 Strong & Weak Acids & Bases
                                                                                                                                                                                  • 8.2.8 Comparing Strong & Weak Acids
                                                                                                                                                                                  • 8.3 Acid Deposition
                                                                                                                                                                                    • 8.3.1 Acid Deposition
                                                                                                                                                                                      • 8.3.2 Effects of Acid Deposition
                                                                                                                                                                                        • 8.3.3 Reducing Sulfur Oxide Emissions
                                                                                                                                                                                      • 9. Redox Processes
                                                                                                                                                                                        • 9.1 Redox Processes
                                                                                                                                                                                          • 9.1.1 Oxidation & reduction
                                                                                                                                                                                            • 9.1.2 Deducing Oxidation Numbers
                                                                                                                                                                                              • 9.1.3 Oxidizing & Reducing agents
                                                                                                                                                                                                • 9.1.4 Naming Transition Metal Compounds
                                                                                                                                                                                                  • 9.1.5 Half Equations
                                                                                                                                                                                                    • 9.1.6 The Activity Series
                                                                                                                                                                                                      • 9.1.7 Redox Titrations
                                                                                                                                                                                                        • 9.1.8 The Winkler Method
                                                                                                                                                                                                          • 9.1.9 Voltaic Cells
                                                                                                                                                                                                            • 9.1.10 Electrolytic Cells
                                                                                                                                                                                                          • 10. Organic Chemistry
                                                                                                                                                                                                            • 10.1 Fundamentals of Organic Chemistry
                                                                                                                                                                                                              • 10.1.1 Homologous Series
                                                                                                                                                                                                                • 10.1.2 Understanding Organic Molecules
                                                                                                                                                                                                                  • 10.1.3 Nomenclature
                                                                                                                                                                                                                    • 10.1.4 Organic Families - Hydrocarbons
                                                                                                                                                                                                                      • 10.1.5 Organic Families - Halogenoalkanes
                                                                                                                                                                                                                        • 10.1.6 Organic Families - Alcohols & Ethers
                                                                                                                                                                                                                          • 10.1.7 Organic Families - Carbonyls
                                                                                                                                                                                                                            • 10.1.8 Organic Families - Carboxylic Acids & Esters
                                                                                                                                                                                                                              • 10.1.9 Organic Families - Organic Nitrogen Compounds
                                                                                                                                                                                                                                • 10.1.10 3-D modelling
                                                                                                                                                                                                                                  • 10.1.11 Primary, Secondary & Tertiary atoms
                                                                                                                                                                                                                                    • 10.1.12 Benzene
                                                                                                                                                                                                                                    • 10.2 Functional Group Chemistry
                                                                                                                                                                                                                                      • 10.2.1 Alkanes - Combustion
                                                                                                                                                                                                                                        • 10.2.2 Alkanes - Halogenation
                                                                                                                                                                                                                                          • 10.2.3 Alkenes - Reactivity
                                                                                                                                                                                                                                            • 10.2.4 Alkenes - Hydrogenation
                                                                                                                                                                                                                                              • 10.2.5 Alkenes - Halogenation
                                                                                                                                                                                                                                                • 10.2.6 Alkenes - Hydrohalogenation
                                                                                                                                                                                                                                                  • 10.2.7 Alkenes - Hydration
                                                                                                                                                                                                                                                    • 10.2.8 Addition Polymers
                                                                                                                                                                                                                                                      • 10.2.9 Alcohols - Combustion
                                                                                                                                                                                                                                                        • 10.2.10 Alcohols - Oxidation
                                                                                                                                                                                                                                                          • 10.2.11 Alcohols - Esterification
                                                                                                                                                                                                                                                            • 10.2.12 Halogenoalkanes
                                                                                                                                                                                                                                                              • 10.2.13 Reactions of Benzene
                                                                                                                                                                                                                                                            • 11. Measurements & Data Processes
                                                                                                                                                                                                                                                              • 11.1 Spectroscopic Identification
                                                                                                                                                                                                                                                                • 11.1.1 Index of Hydrogen Deficiency
                                                                                                                                                                                                                                                                  • 11.1.2 Mass Spectrometry
                                                                                                                                                                                                                                                                    • 11.1.3 Nuclear Magnetic Resonance Spectroscopy
                                                                                                                                                                                                                                                                      • 11.1.4 Infrared Spectroscopy
                                                                                                                                                                                                                                                                      • 11.2 Synoptic Data Handling & Graphical Skills
                                                                                                                                                                                                                                                                        • 11.2.1 Recording Data
                                                                                                                                                                                                                                                                          • 11.2.2 Processing Errors
                                                                                                                                                                                                                                                                            • 11.2.3 Reducing the Impact of Errors
                                                                                                                                                                                                                                                                              • 11.2.4 Percentage Error
                                                                                                                                                                                                                                                                                • 11.2.5 Drawing Graphs
                                                                                                                                                                                                                                                                                  • 11.2.6 Analysing Graphs
                                                                                                                                                                                                                                                                                • 12. HL Atomic Structure
                                                                                                                                                                                                                                                                                  • 12.1 Electrons in Atoms
                                                                                                                                                                                                                                                                                    • 12.1.1 Emission Spectra & First Ionisation Energy
                                                                                                                                                                                                                                                                                      • 12.1.2 Ionisation Energy Trends
                                                                                                                                                                                                                                                                                    • 13. HL The Periodic Table- Transition Metals
                                                                                                                                                                                                                                                                                      • 13.1 Transition Metals
                                                                                                                                                                                                                                                                                        • 13.1.1 Transition Elements
                                                                                                                                                                                                                                                                                          • 13.1.2 Variable Oxidation States
                                                                                                                                                                                                                                                                                            • 13.1.3 Complex Ions
                                                                                                                                                                                                                                                                                              • 13.1.4 Catalytic & Magnetic Properties
                                                                                                                                                                                                                                                                                                • 13.1.5 Colour in Transition Metals
                                                                                                                                                                                                                                                                                                  • 13.1.6 Factors Affecting Colour
                                                                                                                                                                                                                                                                                                • 14. HL Chemical Bonding & Structure
                                                                                                                                                                                                                                                                                                  • 14.1 More Structures & Shapes
                                                                                                                                                                                                                                                                                                    • 14.1.1 Covalent Bonds
                                                                                                                                                                                                                                                                                                      • 14.1.2 More Lewis Structures
                                                                                                                                                                                                                                                                                                        • 14.1.3 Further VSEPR Theory
                                                                                                                                                                                                                                                                                                          • 14.1.4 Formal Charge
                                                                                                                                                                                                                                                                                                          • 14.2 Further Aspects of Bonding
                                                                                                                                                                                                                                                                                                            • 14.2.1 Delocalisation & Resonance
                                                                                                                                                                                                                                                                                                              • 14.2.2 Ozone Revisited
                                                                                                                                                                                                                                                                                                                • 14.2.3 Hybrid Orbitals
                                                                                                                                                                                                                                                                                                              • 15. HL Energetics / Thermochemistry
                                                                                                                                                                                                                                                                                                                • 15.1 Energy Cycles
                                                                                                                                                                                                                                                                                                                  • 15.1.1 Key Enthalpy Terms
                                                                                                                                                                                                                                                                                                                    • 15.1.2 Born-Haber Cycles
                                                                                                                                                                                                                                                                                                                      • 15.1.3 Born-Haber Cycle Calculations
                                                                                                                                                                                                                                                                                                                        • 15.1.4 Dissolution Energy Cycles
                                                                                                                                                                                                                                                                                                                          • 15.1.5 Energy Changes in Aqueous Solutions
                                                                                                                                                                                                                                                                                                                          • 15.2 Entropy & Spontaneity
                                                                                                                                                                                                                                                                                                                            • 15.2.1 Entropy
                                                                                                                                                                                                                                                                                                                              • 15.2.2 Calculating Entropy Change
                                                                                                                                                                                                                                                                                                                                • 15.2.3 Gibbs Free Energy
                                                                                                                                                                                                                                                                                                                                  • 15.2.4 Spontaneous Reactions
                                                                                                                                                                                                                                                                                                                                    • 15.2.5 Free Energy & Equilibrium
                                                                                                                                                                                                                                                                                                                                  • 16. HL Chemical Kinetics
                                                                                                                                                                                                                                                                                                                                    • 16.1 Rate Expression & Reaction Mechanism
                                                                                                                                                                                                                                                                                                                                      • 16.1.1 Rate Equations
                                                                                                                                                                                                                                                                                                                                        • 16.1.2 Rate Constants
                                                                                                                                                                                                                                                                                                                                          • 16.1.3 Graphical Representations
                                                                                                                                                                                                                                                                                                                                            • 16.1.4 Rate Determining Step
                                                                                                                                                                                                                                                                                                                                              • 16.1.5 Mechanism Problems
                                                                                                                                                                                                                                                                                                                                              • 16.2 Activation Energy
                                                                                                                                                                                                                                                                                                                                                • 16.2.1 The Arrhenius Equation
                                                                                                                                                                                                                                                                                                                                                  • 16.2.2 Graphing the Arrhenius Equation
                                                                                                                                                                                                                                                                                                                                                    • 16.2.3 Activation Energy from Rate Constants
                                                                                                                                                                                                                                                                                                                                                  • 17. HL Equilibrium
                                                                                                                                                                                                                                                                                                                                                    • 17.1 The Equilibrium Law
                                                                                                                                                                                                                                                                                                                                                      • 17.1.1 Applying the Equilibrium Law
                                                                                                                                                                                                                                                                                                                                                        • 17.1.2 Gibbs Free Energy & the Equilibrium Constant
                                                                                                                                                                                                                                                                                                                                                      • 18. HL Acids & Bases
                                                                                                                                                                                                                                                                                                                                                        • 18.1 Further Aspects of Acids & Bases
                                                                                                                                                                                                                                                                                                                                                          • 18.1.1 Lewis Theory
                                                                                                                                                                                                                                                                                                                                                            • 18.1.2 pH Curves
                                                                                                                                                                                                                                                                                                                                                              • 18.1.3 Indicators
                                                                                                                                                                                                                                                                                                                                                                • 18.1.4 Buffers
                                                                                                                                                                                                                                                                                                                                                                  • 18.1.5 Salt Hydrolysis
                                                                                                                                                                                                                                                                                                                                                                  • 18.2 Calculations Involving Acids & Bases
                                                                                                                                                                                                                                                                                                                                                                    • 18.2.1 Acid & Base Dissociation Constants
                                                                                                                                                                                                                                                                                                                                                                      • 18.2.2 Acid & Base Problem Solving
                                                                                                                                                                                                                                                                                                                                                                    • 19. HL Redox Processes
                                                                                                                                                                                                                                                                                                                                                                      • 19.1 Electrochemical Cells
                                                                                                                                                                                                                                                                                                                                                                        • 19.1.1 Electrochemical Cells
                                                                                                                                                                                                                                                                                                                                                                          • 19.1.2 The Standard Hydrogen Electrode
                                                                                                                                                                                                                                                                                                                                                                            • 19.1.3 Electrolysis of Aqueous Solutions
                                                                                                                                                                                                                                                                                                                                                                              • 19.1.4 Quantitative Electrolysis
                                                                                                                                                                                                                                                                                                                                                                                • 19.1.5 Free Energy & Eº
                                                                                                                                                                                                                                                                                                                                                                                  • 19.1.6 Electroplating
                                                                                                                                                                                                                                                                                                                                                                                • 20. HL Organic Chemistry
                                                                                                                                                                                                                                                                                                                                                                                  • 20.1 Types of Organic Reactions
                                                                                                                                                                                                                                                                                                                                                                                    • 20.1.1 Nucleophilic Substitution Reactions
                                                                                                                                                                                                                                                                                                                                                                                      • 20.1.2 Electrophilic Addition Reactions
                                                                                                                                                                                                                                                                                                                                                                                        • 20.1.3 Electrophilic Substitution Reactions
                                                                                                                                                                                                                                                                                                                                                                                          • 20.1.4 Reduction Reactions
                                                                                                                                                                                                                                                                                                                                                                                          • 20.2 Synthetic Routes
                                                                                                                                                                                                                                                                                                                                                                                            • 20.2.1 Synthesis
                                                                                                                                                                                                                                                                                                                                                                                            • 20.3 Stereoisomerism
                                                                                                                                                                                                                                                                                                                                                                                              • 20.3.1 Stereoisomers
                                                                                                                                                                                                                                                                                                                                                                                                • 20.3.2 Cis-Trans & E/Z Isomers
                                                                                                                                                                                                                                                                                                                                                                                                  • 20.3.3 Optical Isomers
                                                                                                                                                                                                                                                                                                                                                                                                • 21. Measurement & Analysis
                                                                                                                                                                                                                                                                                                                                                                                                  • 21.1 Spectroscopic Identification of Organic compounds
                                                                                                                                                                                                                                                                                                                                                                                                    • 21.1.1 High Resolution NMR
                                                                                                                                                                                                                                                                                                                                                                                                      • 21.1.2 X-Ray Crystallography
                                                                                                                                                                                                                                                                                                                                                                                                        • 21.1.3 Structure Identification Problems
                                                                                                                                                                                                                                                                                                                                                                                                      Stewart Hird

                                                                                                                                                                                                                                                                                                                                                                                                      Author: Stewart

                                                                                                                                                                                                                                                                                                                                                                                                      Stewart has been an enthusiastic GCSE, A Level and IB Chemistry teacher for more than 30 years in the UK as well as overseas, and has been an examiner for IB and A Level, also. As a long-standing Head of Department, Stewart brings a wealth of experience to creating Topic Questions and revision materials for Save My Exams.


                                                                                                                                                                                                                                                                                                                                                                                                      Save My Exams Logo
                                                                                                                                                                                                                                                                                                                                                                                                      Resources
                                                                                                                                                                                                                                                                                                                                                                                                      Home Join Support

                                                                                                                                                                                                                                                                                                                                                                                                      Members
                                                                                                                                                                                                                                                                                                                                                                                                      Members Home Account Logout

                                                                                                                                                                                                                                                                                                                                                                                                      Company
                                                                                                                                                                                                                                                                                                                                                                                                      About Us Contact Us Jobs Terms Privacy Facebook Twitter

                                                                                                                                                                                                                                                                                                                                                                                                      Quick Links
                                                                                                                                                                                                                                                                                                                                                                                                      GCSE Revision Notes IGCSE Revision Notes A Level Revision Notes Biology Chemistry Physics Maths 2022 Advance Information

                                                                                                                                                                                                                                                                                                                                                                                                       
                                                                                                                                                                                                                                                                                                                                                                                                      © IB Documents (2) Team & u/aimlesskr
                                                                                                                                                                                                                                                                                                                                                                                                      IBO was not involved in the production of, and does not endorse, the resources created by Save My Exams.