Alcohols questions

Assignment: Questions on Topic 10.2 : Functional groups (Alcohols)

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State the equations for the complete combustion of:

i.  ethanol

1 line

ii. propan-2-ol

1 line

 

 

Propan-2-ol and propan-1-ol can both be oxidized by a warm acidified solution of potassium dichromate(VI).

i. Describe what would be observed in both cases.

3 lines

ii. State the IUPAC name of the product from the oxidation of propan-2-ol and state the simplified equation (use [O] to represent the oxygen from the acidified potassium dichromate(VI) solution).

2 lines

iii. The half-equation for the reduction of the acidified dichromate(VI) ion is:
Cr2O72–(aq) + 14H+(aq) + 6e → 2Cr3+(aq) + 7H2O(l)
Deduce the full equation for the oxidation of propan-2-ol using acidified Cr2O72– ions.

5 lines


iv. State the IUPAC name of the two organic products that can be formed when propan-1-ol is oxidized by warm acidified potassium dichromate(VI) solution.

1 line


v. Explain why propan-1-ol can form two different organic products whereas propan-2-ol only forms one organic product when oxidized by acidified potassium dichromate(VI) solution.

5 lines

vi. Describe how you could separate the two organic products formed from the oxidation of propan-1-ol.

3 lines

 

 

The precise use of language is important in chemistry. Many books state that tertiary alcohols, such as 2-methylpropan-2-ol, (CH3)3COH, are not readily oxidized. Evaluate this statement.

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i. State the equation for the formation of methyl salicylate from the reaction between salicylic acid and methanol. (Upload your answer as an image or as a pdf file.)

5 lines


ii. Aspirin is also an ester that can be formed from salicylic acid. Suggest a possible way in which it could be synthesised starting with salicylic acid.

3 lines

iii. State the name of salicylic acid according to the IUPAC naming system.

1 line

 

 


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